Qualitative Analysis of Gas Mixtures by Microwave Spectroscopy
Qualitative analysis of gas mixtures by microwave spectroscopy
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Qualitative analysis of gas mixtures by microwave spectroscopy
In considering transfer phenomena in reacting gas mixtures, the following topics are discussed: (1) dynamics of paired collisions; (2) Enskog method for solving the Boltzmann equation, taking into account inelastic collisions; (3) use of the variation principle for approximate solutions; (4) computations of inelastic bracketed expressions; (5) calculation of collision integrals; and (6) formulas for transfer coefficients.
Magnetohydrodynamic (MHD) centrifuge utilizing electric currents and magnetic fields produces a magnetic force which develops supersonic rotational velocities in gas mixtures. Device is superior to ordinary centrifuges because rotation of gas mixture is produced by MHD force rather than mechanical means.
A method is proposed for predicting the translational component of the thermal conductivity of partially ionized gas mixtures. It is approximate but simple in form and offers a significant improvement over commonly utilized approximations. It does not require large computer run times nor storage, thus it is suitable for use with complex flow fields and heat transfer calculations. Results for gas mixtures which are representative of the atmosphere of Jupiter, Earth, and Venus are presented and they compare favorably with results from detailed kinetic theory analyses.
A method for calculating viscosity and thermal conductivity of a helium-xenon (He-Xe) gas mixture was employed, and results were compared to AiResearch (part of Honeywell) analytical data. The method of choice was that presented by Hirschfelder with Singh's third-order correction factor applied to thermal conductivity. Values for viscosity and thermal conductivity were calculated over a temperature range of 400 to 1200 K for He-Xe gas mixture molecular weights of 20.183, 39.94, and 83.8 kg/kmol. First-order values for both transport properties were in good agreement with AiResearch analytical data. Third-order-corrected thermal conductivity values were all greater than AiResearch data, but were considered to be a better approximation of thermal conductivity because higher-order effects of mass and temperature were taken into consideration. Viscosity, conductivity, and Prandtl number were then compared to experimental data presented by Taylor.
Theory for calculating heat conductivity of polyatomic and polar gases and gas mixtures
A review of the convolution theorem for obtaining the cumulative k-distribution of a gas mixture proven in Goody et al. (1989) and a discussion of its application to natural spectra are presented. Computational optimizations for use in analyzing high-altitude gas mixtures are introduced. Comparisons of the results of the optimizations, and criteria for deciding what altitudes are 'high' in this context are given. A few relevant features of the testing support software are examined. Some spectrally integrated results, and the circumstances the might permit substituting the method of principal absorbers are examined.
A procedure has been developed whereby nitrogen can be incorporated into an organic film from an ethylene-nitrogen gas mixture using an internal electrode capacitively coupled radio frequency reactor. The presence of nitrogen has been shown directly by infrared transmittance spectra and electron spectroscopic chemical analysis data, and further indirect evidence was provided by dielectric measurements and by the reverse osmosis properties of the film. Preparation of a nitrogen containing film did not require vapor from an organic nitrogen containing liquid monomer. Some control over the bonding and stoichiometry of the polymer film was provided by the added degree of freedom of the nitrogen partial pressure in the gas mixture. This new parameter strongly affected the dielectric properties of the plasma polymerized film and could affect the reverse osmosis behavior.
Approximate formula for viscosity of binary polar gas mixtures confirmed for unlike cross sections
Centered one-dimensional unsteady expansion calculated for reacting gas mixture subject to vibrational and chemical nonequilibrium
Program computes solutions for flow parameters in arbitrary gas mixtures behind a normal and a reflected normal shock, for in-flight and shock-tube stagnation conditions. Equilibrium flow calculations are made by a free-energy minimization technique coupled with the steady-flow conservation equations and a modified Newton-Raphson iterative scheme.
Fluidic oscillator use as molecular weight sensor for gas mixtures
Properties of nonequilibrium radiation emitted by Mars atmosphere gas mixtures
Spacecraft attitude control microthrustors utilizing catalytically reactive gas mixtures during pulse mode and steady state operation
Computer program in Fortran IV language for equilibrium normal shock and stagnation point solutions for arbitrary gas mixtures
Direct calculation and tables of specific heats and related thermodynamic properties of arbitrary gas mixtures - Mars atmosphere model
The radiolytic breakdown of residual free, physisorbed, and chemisorbed waters is anticipated in the sealed dry storage of spent nuclear fuel (SNF), releasing H 2 gas into the initial cover gas of helium. For aluminum-clad SNF (ASNF) in particular, the expected total hydrogen in the canister is enough to dominate the cover gas mixture if fully released, and based on experimental rates of H 2 generation, H 2 percentages exceeding the lower flammability limit appear likely. However, no evidence of radiolytic generation of O 2 has been observed to date, so the potential for flammability is averted due to the lack O 2 . Lack of oxygen has been credited for avoiding flammability in some existing storage and transportation approaches for SNF and other waste. This report reviews literature on flammability limits with a focus on the limiting oxygen concentration to provide technical underpinnings to refine a flammability criterion for gas mixtures of helium, hydrogen, and oxygen where the oxygen is expected to be the limiting species. While there is general consensus on H 2 flammability limits at standard temperature and pressure, the decay heat and gas generation within ASNF sealed dry storage canisters could push them to elevated temperatures and pressures, so the goal is to identify an oxygen threshold that will bound the behavior over the temperature and pressure range of the U.S. Department of Energy (DOE) Standard Canister. The information reviewed in this document supports the criterion that the oxygen concentration in a He-H 2 -O 2 mixture should be less than 1.5% to avoid flammability at temperatures and pressures relevant to sealed dry storage of ASNF in the DOE Standard Canister, i.e., up to 343°C (650°F) and 500 psig, respectively. Note that while data covering the full range of temperature at atmospheric pressure and nearly the full range of pressure at room temperature were available, data for the combined effects was available only at moderate temperatures and pressures; the recommended 1.5% O 2 threshold is based on the breadth of available data reported here and apparent trends therein.
Inviscid hydrodynamical model for determining density profile of binary single phase gas mixture in swirl and duct flows