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DOE OSTI2020

Subtask 1.5 – CO2 Injection Monitoring with an Optimized Scalable, Automated, Semipermanent Seismic Array

The scalable, automated, semipermanent seismic array (SASSA) method is a flexible and relatively cost-effective surface geophysical method for regular time-lapse monitoring of the movement of injected carbon dioxide (CO2) in a reservoir for CO2 enhanced oil recovery (EOR) or geologic CO2 storage operations. It has the advantages of a low-environmental-footprint while monitoring regions of a reservoir from the surface without the need for a regular grid distribution of receivers. Automated data collection is possible. As only time-lapse amplitude changes at the reservoir level due to CO2 movement within the reservoir are monitored, the turnaround time to deliver results from the SASSA method can be short, without the need for long, time-consuming data-processing workflows. As data is collected and processed, incremental information can be provided to the field operator. The Energy & Environmental Research Center (EERC) conducted a SASSA field test from September 2018 to November 2020 in a portion of the Bell Creek Field in Montana, which implemented new CO2 EOR field activities during the study period. Lessons learned from a proof-of-concept study were incorporated to improve the data quality of the SASSA method and demonstrate the viability of the technology. The EERC implemented several enhancements to improve data quality, including 1) an iterative survey design, which allowed placing the receivers in strategic locations where the movement of the CO2 in the reservoir could be tracked with minimum interference by the cultural noise in the study area; 2) the use of powerful seismic sources in the form of surface orbital vibrators, and 3) data acquisition during optimal periods. History-matched reservoir simulation was performed to predict gas saturation and pressure response induced by CO2 injection in the study area. The results were compared with the SASSA-measured responses to CO2 injection as a partial validation technique. A match between the two methods was observed for most of the SASSA points predicted to have intersected a CO2 saturation change. The validated results provide confidence that the SASSA method can be used independently as a CO2 saturation monitoring technique. As data are collected and processed, incremental information can be provided to the field operator. The critical components of the SASSA workflow for a successful application of the method are the following: Iterative survey design with information about CO2 injection activities from the oilfield operator. A detailed CO2 injection plan is the key driver to select the strategic monitoring location of the SASSA sensors. After this information is incorporated in the initial distribution of sources and receivers in the study area, high-resolution satellite images are used to identify ground locations not affected by cultural noise sources, such as power lines, pipelines/flow lines, or roadways. In the next iteration of the survey design, a scouting trip to the study area is needed to understand more details of the noise sources identified in the previous step and the intensity of the field activities that can also generate noise during the monitoring. Integrating the information from the scouting trip into the survey design to select the optimum source and receiver locations is the final step. Noise attenuation. The variety of noise types during seismic monitoring of an oil field is enormous. Tailored noise characterization and processing at a node-by-node level can enhance the performance and sensitivity of the SASSA technique. Future advancements that could improve the efficiency and application of the SASSA technology include: Gaining a better understanding of the noise field produced by the seismic source to aid the choice of receiver location. Surface noise from the source can overwhelm the small signal changes due to CO2 that the SASSA method measures. Improved data-processing workflow to automatically analyze and adapt to dynamic noise conditions associated with industrial settings. This subtask was funded through the EERC–DOE Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE- FE0024233.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2013

DarkLight radiation backgrounds

We report measurements of photon and neutron radiation levels observed while transmitting a 0.43 MW electron beam through millimeter-sized apertures and during beam-on, but accelerating gradient RF-on, operation. These measurements were conducted at the Free-Electron Laser (FEL) facility of the Jefferson National Accelerator Laboratory (JLab) using a 100 MeV electron beam from an energy-recovery linear accelerator. The beam was directed successively through 6 mm, 4 mm, and 2 mm diameter apertures of length 127 mm in aluminum at a maximum current of 4.3 mA (430 kW beam power). This study was conducted to characterize radiation levels for experiments that need to operate in this environment, such as the proposed DarkLight Experiment. We find that sustained transmission of a 430 kW CW beam through a 2 mm aperture is feasible with manageable beam-related backgrounds. We also find that during beam-off, RF-on operation, field emission inside the niobium cavities of the accelerator cryomodules is the primary source of ambient radiation.

43 PARTICLE ACCELERATORS↗

DOE OSTI2021

Impact of Rheology Models on Horizontal Well Polymer Flooding in a Heavy Oil Reservoir on Alaska North Slope: A Simulation Study

Polymer rheology can have either a positive or a negative effect on polymer flooding performance under varied circumstances. Many researchers have studied the effect of polymer rheology in a vertical well, but no field scale studies have been conducted to investigate whether polymer rheology is beneficial to polymer flooding in heavy oil reservoirs developed by horizontal wells. In this paper, we conducted a numerical simulation study to examine the effect of HPAM polymer rheology on a polymer flooding pilot, which is the first-ever project conducted on a heavy oil reservoir from Alaska North Slope (ANS) developed by horizontal wells. Three rheology types were considered in the study including the apparent viscosity measured during coreflooding of using a HPAM polymer, the bulk viscosity measured with a viscometer, and a Newtonian flow model. The results suggest that using the bulk viscosity in simulation underestimates the conformance control and the water-oil-ratio reduction capability of the HPAM polymer solution. When the apparent viscosity is used, the incremental oil and sweep were largely increased, and the optimal recovery period of polymer flooding was extended greatly, especially for the heterogeneous formations. Therefore, the rheology type of polymer plays a significant role in the incremental oil recovery and injection profile of the horizontal well system given the pilot test conditions. This study has provided practical guidance to field operators for the ongoing polymer flooding pilot on ANS and will also provide valuable information for other polymer projects conducted in similar conditions.

Leng, Jianqiao↗

DOE OSTI2018

Membrane Accelerated Stress Test Development for Polymer Electrolyte Fuel Cell Durability Validated Using Field and Drive Cycle Testing

A combined chemical/mechanical accelerated stress test (AST) was developed for proton exchange membrane (PEM) fuel cells based on relative humidity cycling (RHC) between dry and saturated gases at open circuit voltage (OCV). Membrane degradation and failure were investigated using scanning electron microscopy and small- and wide-angle X-ray scattering. Changes to membrane thickness, hydrophilic domain spacing, and crystallinity were observed to be most similar between field-operated cells and OCV RHC ASTs, where local thinning and divot-type defects are the primary failure modes. While RHC in air also reproduces these failure modes, it is not aggressive enough to differentiate between different membrane types in >1,333 hours (55 days) of testing. Conversely, steady-state OCV tests result in significant ionomer morphology changes and global thinning, which do not replicate field degradation and failure modes. It is inferred that during the OCV RHC AST, the decay of the membrane's mechanical properties is accelerated such that materials can be evaluated in hundreds, instead of thousands, of hours, while replicating the degradation and failure modes of field operation; associated AST protocols are recommended as OCV RHC at 90°C for 500 hours with wet/dry cycle durations of 30s/45s and 2m/2m for automotive and bus operation, respectively.

25 ENERGY STORAGE↗

DOE OSTI2012

Trip Report-Produced-Water Field Testing

Los Alamos National Laboratory (LANL) conducted field testing of a produced-water pretreatment apparatus with assistance from faculty at the Texas A&M University (TAMU) protein separation sciences laboratory located on the TAMU main campus. The following report details all of the logistics surrounding the testing. The purpose of the test was to use a new, commercially-available filter media housing containing modified zeolite (surfactant-modified zeolite or SMZ) porous medium for use in pretreatment of oil and gas produced water (PW) and frac-flowback waters. The SMZ was tested previously in October, 2010 in a lab-constructed configuration ('old multicolumn system'), and performed well for removal of benzene, toluene, ethylbenzene, and xylenes (BTEX) from PW. However, a less-expensive, modular configuration is needed for field use. A modular system will allow the field operator to add or subtract SMZ filters as needed to accommodate site specific conditions, and to swap out used filters easily in a multi-unit system. This test demonstrated the use of a commercial filter housing with a simple flow modification and packed with SMZ for removing BTEX from a PW source in College Station, Texas. The system will be tested in June 2012 at a field site in Pennsylvania for treating frac-flowback waters. The goals of this test are: (1) to determine sorption efficiency of BTEX in the new configuration; and (2) to observe the range of flow rates, backpressures, and total volume treated at a given flow rate.

42 ENGINEERING↗

DOE OSTI2016

Diffeomorphism-invariant observables and their nonlocal algebra

Gauge-invariant observables for quantum gravity are described, with explicit constructions given primarily to leading order in Newton’s constant, analogous to and extending constructions first given by Dirac in quantum electrodynamics. These can be thought of as operators that create a particle, together with its inseparable gravitational field, and reduce to usual field operators of quantum field theory in the weak-gravity limit; they include both Wilson-line operators and those creating a Coulombic field configuration. We also describe operators creating the field of a particle in motion; as in the electromagnetic case, these are expected to help address infrared problems. An important characteristic of the quantum theory of gravity is the algebra of its observables. Finally, we show that the commutators of the simple observables of this paper are nonlocal, with nonlocality becoming significant in strong field regions, as predicted previously on general grounds.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2018

Residential Advanced Photovoltaic Inverter Pilot Study Results for Select Distribution Secondaries in Hawai'i

Penetration levels of residential rooftop solar photovoltaic (PV) generation on the Hawaiian island of O'ahu have increased significantly in recent years, with many circuits now at the limits of their PV hosting capacity. NREL and Hawaiian Electric have used this opportunity to deploy advanced inverters at new customer installations that would not otherwise have been approved, as a pilot study to gain first-hand operational field data and experience on the impact of inverter-based grid support functions. At each customer location, the deployed advanced inverters were remotely controlled and monitored. Additionally, customer AMI (smart meter) and secondary distribution transformer data was also available for the analysis. The analysis focused on quantifying the customer behind-the-meter voltage rise due to PV production, determining the customer voltage rise with advanced inverters in unity power factor as well as advanced grid support function modes, and estimating the curtailment when inverters have Volt-VAR and Volt-Watt enabled. The results show that: 1) Behind-the-meter voltage rise is often not negligible. 2) An inverter's operating point on a Volt-VAR/Volt-Watt curve depends strongly on the design of the secondary system on which it is installed. 3) The mitigation of voltage rise on the secondary system using Volt-VAR may not be effective if only a small proportion of inverters have grid support enabled, or if the reactance/resistance (X/R) ratio of the grid is low. 4) Volt-Watt curtailment can be estimated using co-located irradiance sensors but there may be opportunities to estimate it using inverter internal electrical measurements. 5) Estimated curtailment is very low for the locations analyzed to date.

14 SOLAR ENERGY↗

DOE OSTI2015

Handbook: Collecting Groundwater Samples from Monitoring Wells in Frenchman Flat, CAU 98

Frenchman Flat basin on the Nevada National Security Site (NNSS) contains Corrective Action Unit (CAU) 98, which is comprised of ten underground nuclear test locations. Environmental management of these test locations is part of the Underground Test Area (UGTA) Activity conducted by the U.S. Department of Energy (DOE) under the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended) with the U.S. Department of Defense (DOD) and the State of Nevada. A Corrective Action Decision Document (CADD)/Corrective Action Plan (CAP) has been approved for CAU 98 (DOE, 2011). The CADD/CAP reports on the Corrective Action Investigation that was conducted for the CAU, which included characterization and modeling. It also presents the recommended corrective actions to address the objective of protecting human health and the environment. The recommended corrective action alternative is “Closure in Place with Modeling, Monitoring, and Institutional Controls.” The role of monitoring is to verify that Contaminants of Concern (COCs) have not exceeded the Safe Drinking Water Act (SDWA) limits (Code of Federal Regulations, 2014) at the regulatory boundary, to ensure that institutional controls are adequate, and to monitor for changed conditions that could affect the closure conditions. The long-term closure monitoring program will be planned and implemented as part of the Closure Report stage after activities specified in the CADD/CAP are complete. Groundwater at the NNSS has been monitored for decades through a variety of programs. Current activities were recently consolidated in an NNSS Integrated Sampling Plan (DOE, 2014). Although monitoring directed by the plan is not intended to meet the FFACO long-term monitoring requirements for a CAU (which will be defined in the Closure Report), the objective to ensure public health protection is similar. It is expected that data collected in accordance with the plan will support the transition to long-term monitoring at each CAU. The sampling plan is designed to ensure that monitoring activities occur in compliance with the UGTA Quality Assurance Plan (DOE, 2012). The sampling plan should be referenced for Quality Assurance (QA) elements and procedures governing sampling activities. The NNSS Integrated Sampling Plan specifies the groundwater monitoring that will occur in CAU 98 until the long-term monitoring program is approved in the Closure Report. The plan specifies the wells that must be monitored and categorizes them by their sampling objective with the associated analytical requirements and frequency. Possible sample collection methods and required standard operating procedures are also presented. The intent of this handbook is to augment the NNSS Integrated Sampling Plan by providing well-specific details for the sampling professional implementing the Sampling Plan in CAU 98, Frenchman Flat. This handbook includes each CAU 98 well designated for sampling in the NNSS Integrated Sampling Plan. The following information is provided in the individual well sections: 1. The purpose of sampling. 2. A physical description of the well. 3. The chemical characteristics of the formation water. 4. Recommended protocols for purging and sampling. The well-specific information has been gathered from numerous historical and current sources cited in each section, but two particularly valuable resources merit special mention. These are the USGS NNSS website (http://nevada.usgs.gov/doe_nv/ntsarea5.cfm) and the UGTA Field Operations website (https://ugta.nv.doe.gov/sites/Field%20Operations/default.aspx). 2 Land surface elevation and measuring point for water level measurements in Frenchman Flat were a focus during CAU investigations (see Appendix B, Attachment 1 in Navarro-Intera, 2014). Both websites listed above provide information on the accepted datum for each well. A summary is found on the home page for the well on the USGS website. Additional information is available through a link in the “Available Data” section to an “MP diagram” with a photo annotated with the datum information. On the UGTA Field Operations well page, the same information is in the “Wellhead Diagram” link. Well RNM-2s does not have an annotated photo at this time. All of the CAU 98 monitoring wells are located within Area 5 of Frenchman Flat, with the exception of ER-11-2 in Area 11 (Figure 1). The wells are clustered in two areas: the northern area (Figure 2) and the central area (Figure 3). Each well is discussed below in geographic order from north to south as follows: ER-11-2, ER-5-3 shallow piezometer, ER-5-3-2, ER-5-5, RNM-1, RNM-2s, and UE-5n.

(1996↗

DOE OSTI2014

Design Study of the High Luminosity LHC Recombination Dipole (D2)

The interaction region design of the high-luminosity LHC requires replacing the recombination dipole magnets (D2) with new ones. The preliminary specifications include an aperture of 105 mm, with 186 mm separation between the twin-aperture axes, and an operating field in the range of 3.5 to 4.5 T. The main design challenge is to decouple the magnetic field in the two apertures and ensure good field quality. The approach adopted for the present D2 magnets, using the iron yoke as a shield between the two apertures, leads to large saturation effects. In this study, we propose an alternative approach where the iron yoke is designed primarily for low saturation, and the resulting large but current-independent cross-talk between the apertures is corrected with an asymmetric arrangement of the conductor blocks. A preliminary solution based on the LHC dipole cable is presented, and the expected harmonics for geometric, saturation and persistent current effects are provided. Finally, the feasibility of an operating field at the high end of the range considered is discussed, to minimize the D2 magnet length and facilitate the space allocation for other components.

43 PARTICLE ACCELERATORS↗

DOE OSTI2017

A Numerical Study of Factors Affecting Fracture-Fluid Cleanup and Produced Gas/Water in Marcellus Shale: Part II

Horizontal wells combined with successful multi-stage hydraulic fracture treatments are currently the most established method for effectively stimulating and enabling economic development of gas bearing organic-rich shale formations. Fracture cleanup in the Stimulated Reservoir Volume (SRV) is critical to stimulation effectiveness and long-term well performance. However, fluid cleanup is often hampered by formation damage, and post-fracture well performance frequently falls below expectations. A systematic study of the factors that hinder fracture fluid cleanup in shale formations can help optimize fracture treatments and better quantify long term volumes of produced water and gas. Fracture fluid cleanup is a complex process influenced by multi-phase flow through porous media (relative permeability hysteresis, capillary pressure etc.), reservoir rock and fluid properties, fracture fluid properties, proppant placement, fracture treatment parameters, and subsequent flowback and field operations. Changing SRV and fracture conductivity as production progresses further adds to the complexity of this problem. Numerical simulation is the best, and most practical approach to investigate such a complicated blend of mechanisms, parameters, their interactions, and subsequent impact on fracture fluid cleanup and well deliverability. In this paper, a 3-dimensional, 2-phase, dual-porosity model was used to investigate the impact of multiphase flow, proppant crushing, proppant diagenesis, shut-in time, reservoir rock compaction, gas slippage, and gas desorption on fracture fluid cleanup, and well performance in Marcellus shale. The research findings have shed light on the factors that substantially constrains efficient fracture fluid cleanup in gas shales, and provided guidelines for improved fracture treatment designs and water management.

58 GEOSCIENCES↗

DOE OSTI2026

Tethered Balloon System Ozone Profiles during CoURAGE Summer Intensive Operational Period Field Campaign Report

During the summer IOP, the small ARM field campaign CRGTBSO3 collected measurements to gain an improved understanding of differences between the atmospheric composition in and just above the marine layer at the CoURAGE TBS site near the eastern shore of Chesapeake Bay. CRGTBSO3 included guest instrumentation with ozone (O 3 ) profile measurements on the TBS and surface O3 and meteorological measurements at the TBS site. An En-Sci 2Z electrochemical cell (ECC) ozonesonde (Komhyr 1969, 1986, Witte et al. 2018) was included on the TBS. The ozonesonde was connected to an InterMet iMet-4RSB radiosonde, and the overall data collected included vertical profiles of ozone, relative humidity, temperature, pressure, and altitude. The CRGTBSO3 iMet-4 radiosonde data is identical to that of the iMet in the Tethered Balloon System Merged Data Product (TBSMERGED; Gaustad and Dexheimer 2025). The TBSMERGED data product also includes meteorological data from a different sensor, the iMet XQ2. In some cases, the iMet XQ2 relative humidity (RH) data may be more accurate than the iMet-4, such as for some instances when the iMet-4 RH data stays at 100% for an extended period throughout a profile.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2017

North Slope of Alaska Snow Intensive Operational Period Field Campaign Report

The campaign was motivated by the need to improve the quantification of measurements of ice-phase precipitation in the Arctic and was by the acquisition and deployment of the new X- and Ka/W-band radars. These radars opened up an opportunity for the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility to obtain spatial estimates of snowfall rates using the polarimetric X-band measurements and dual-frequency measurements (using different combinations of the three wavelengths). However, calculations of X- and Ka-band radar back-scattering of ice crystal aggregates with their complex structure suggest that the commonly used T-matrix approach (Matrosov et al. 2007) for modeling the radar back-scattering underestimates the reflectivity by several decibels, with errors increasing with increasing radar frequency (Botta et al. 2010, 2011). Moreover, the X-band polarimetric measurements and the Ka/W-band measurements are sensitive to the assumed shape of the snow (Botta et al. 2011). One of the five ARM two-dimensional video disdrometers (manufactured by Joanneum Research) were deployed in Barrow at the ARM North Slope of Alaska (NSA) site from 1 October, 2011 to 31 May, 2012 in an attempt to use the instrument in a novel way. The instrument was originally designed to measure the drop size distribution of rain but it seemed worthwhile to explore its capability to quantify ice precipitation particle size and shape distributions in the cold north for scattering calculations and precipitation estimations. Furthermore, this deployment gave us an opportunity to see how reliable it could be in arctic conditions.

Ka-band radar↗

DOE OSTI2018

Unitary Quantization and Para-Fermi Statistics of Order 2

We consider the relationship between the unitary quantization scheme and the para-Fermi statistics of order 2. We propose an appropriate generalization of Green’s ansatz, which has made it possible to transform bilinear and trilinear commutation relations for the creation and annihilation operators for two different para-Fermi fields φ{sub a} and φ{sub b} into identities. We also propose a method for incorporating para-Grassmann numbers ξ{sub k} into the general unitary quantization scheme. For the parastatistics of order 2, a new fact has been revealed: the trilinear relations containing both para-Grassmann variables ξ{sub k} and field operators ak and bm are transformed under a certain reversible mapping into unitary equivalent relations in which commutators are replaced by anticommutators, and vice versa. It is shown that this leads to the existence of two alternative definitions of the coherent state for para-Fermi oscillators. The Klein transformation for Green’s components of operators a{sub k} and b{sub m} is constructed in explicit form, which enabled us to reduce the initial commutation rules for the components to the normal commutation relations for ordinary Fermi fields. We have analyzed a nontrivial relationship between the trilinear commutation relations of the unitary quantization scheme and the so-called Lie supertriple system. The possibility of incorporating the Duffin–Kemmer–Petiau theory into the unitary quantization scheme is discussed briefly.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2012

PILOT TESTING: PRETREATMENT OPTIONS TO ALLOW RE-USE OF FRAC FLOWBACK AND PRODUCED BRINE FOR GAS SHALE RESOURCE DEVELOPMENT

The goal of the A&M DOE NETL Project No. DE-FE0000847 was to develop a mobile, multifunctional water treatment capability designed specifically for “pre-treatment” of field waste brine. The project consisted of constructing s mobile “field laboratory” incorporating new technology for treating high salinity produced water and using the lab to conduct a side-by-side comparison between this new technology and that already existing in field operations. A series of four field trials were performed utilizing the mobile unit to demonstrate the effectiveness of different technology suitable for use with high salinity flow back brines and produced water. The design of the mobile unit was based on previous and current work at the Texas A&M Separation Sciences Pilot Plant. The several treatment techniques which have been found to be successful in both pilot plant and field tests had been tested to incorporate into a single multifunctional process train. Eight different components were evaluated during the trials, two types of oil and grease removal, one BTEX removal step, three micro-filters, and two different nanofilters. The performance of each technique was measured by its separation efficiency, power consumption, and ability to withstand fouling. The field trials were a success. Four different field brines were evaluated in the first trial in New York. Over 16,000 gallons of brine were processed. Using a power cost of $.10 per kWh, media pretreatment power use averaged $0.004 per barrel, solids removal $.04 per barrel and brine “softening” $.84 per barrel. Total power cost was approximately $1.00 per barrel of fluid treated. In Pennsylvania, brines collected from frac ponds were tested in two additional trials. Each of the brines was converted to an oil-free, solids-free brine with no biological activity. Brines were stable over time and would be good candidates for use as a make-up fluid in a subsequent fracturing fluid design. Reports on all of the field trials and subcontractor research have been summarized in this Final Report. Individual field trial reports and research reports are contained in the companion volume titled “Appendices”

Burnett, David↗

DOE OSTI2012

AVESTAR Center for clean energy plant operators of the future

Clean energy plants in the modern grid era will increasingly exploit carbon capture, utilization, and storage (CCUS), fuel/product flexibility, and load following. Integrated power/process plants will require next generation of well-trained engineering and operations professionals. High-fidelity dynamic simulators are well suited for training, education, and R&D on clean energy plant operations. Combining Operator Training System (OTS) with 3D virtual Immersive Training System (ITS) enables simultaneous training of control room and plant field operators of the future. Strong collaboration between industry, academia, and government is required to address advanced R&D challenges. AVESTAR Center brings together simulation technology and world-class expertise focused on accelerating development of clean energy plants and operators of the future.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2016

A temporally and spatially resolved electron density diagnostic method for the edge plasma based on Stark broadening

An electron density diagnostic (≥10{sup 10} cm{sup −3}) capable of high temporal (ms) and spatial (mm) resolution is currently under development at Oak Ridge National Laboratory. The diagnostic is based on measuring the Stark broadened, Doppler-free spectral line profile of the n = 6–2 hydrogen Balmer series transition. The profile is then fit to a fully quantum mechanical model including the appropriate electric and magnetic field operators. The quasi-static approach used to calculate the Doppler-free spectral line profile is outlined here and the results from the model are presented for H-δ spectra for electron densities of 10{sup 10}–10{sup 13} cm{sup −3}. The profile shows complex behavior due to the interaction between the magnetic substates of the atom.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2023

In-Situ Applied Coatings for Mitigating Gas Hydrate Deposition in Deepwater Operations (Final Scientific/Technical Report)

The Project objectives of this work were focused on the need to develop, investigate, and validate for field and commercial deployment robust pipeline surface treatments to prevent / minimize hydrate and other flow assurance solids deposition in subsea oil flowlines. A robust pipeline treatment that can prevent hydrate and wax/asphaltene adhesion/deposition will be a major fundamental breakthrough in hydrate and flow assurance science and engineering, and to critical Deepwater field operations. The project addressed the current major outstanding issue of mitigating gas hydrate and other solids deposition in different pipeline conditions, a major outstanding issue that has not been solved to-date, despite previous attempts/studies. The major goal of this project was to develop and investigate for deployment robust pipeline coatings to mitigate gas hydrate deposition in Deepwater oil flowlines, which will be critical in offshore leak and spill prevention. As oil and gas production wells mature, the water content and oil composition can change and increase the risk of gas hydrate, wax, and asphaltene deposition and blockages in flowlines, with the cost of complete inhibition becoming prohibitive. The ability to mitigate flow assurance risks in maturing flowlines can extend the life of the field, significantly reduce operational costs from inhibitor injection and prevent potential safety hazards to personnel and equipment and can prevent potential environmental hazards leading to catastrophic hydrocarbon emissions. This research allows for a novel, cost-effective method of mitigating gas hydrate and other pipeline solids deposition/blockages in flowlines, extending the life of the field while being minimally disruptive to normal flowline operation. The omniphobic surface treatment developed in this work can significantly improve the economics of energy transport by providing flow assurance and limiting catastrophic blowouts.

02 PETROLEUM↗

DOE OSTI2012

Assessing Natural Isothiocyanate Air Emissions after Field Incorporation of Mustard Cover Crop

A regional air assessment was performed to characterize volatile natural isothiocyanate (NITC) compounds in air during soil incorporation of mustard cover crops in Washington State. Field air sampling and analytical methods were developed specific to three NITCs known to be present in air at appreciable concentrations during/after field incorporation. The maximum observed concentrations in air for the allyl, benzyl, and phenethyl isothiocyanates were respectively 188, 6.1, and 0.7 lg m-3 during mustard incorporation. Based on limited inhalation toxicity information, airborne NITC concentrations did not appear to pose an acute human inhalation exposure concern to field operators and bystanders.

54 ENVIRONMENTAL SCIENCES↗