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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Isothermal Equation Of State For Compressed Solids

Same equation with three adjustable parameters applies to different materials. Improved equation of state describes pressure on solid as function of relative volume at constant temperature. Even though types of interatomic interactions differ from one substance to another, form of equation determined primarily by overlap of electron wave functions during compression. Consequently, equation universal in sense it applies to variety of substances, including ionic, metallic, covalent, and rare-gas solids. Only three parameters needed to describe equation for given material.

Vinet, Pascal↗
NASA NTRS1985

Finite element analysis of notch behavior using a state variable constitutive equation

The state variable constitutive equation of Bodner and Partom was used to calculate the load-strain response of Inconel 718 at 649 C in the root of a notch. The constitutive equation was used with the Bodner-Partom evolution equation and with a second evolution equation that was derived from a potential function of the stress and state variable. Data used in determining constants for the constitutive models was from one-dimensional smooth bar tests. The response was calculated for a plane stress condition at the root of the notch with a finite element code using constant strain triangular elements. Results from both evolution equations compared favorably with the observed experimental response. The accuracy and efficiency of the finite element calculations also compared favorably to existing methods.

Dame, L. T.↗
NASA NTRS1996

Efficient High Pressure MixtureState Equations

A method is presented for an accurate noniterative, computationally efficient calculation of high pressure fluid mixture equations of state, especially targeted to gas turbines and rocket engines. Pressures above 1 bar and temperatures above 100 K are addressed. The method is based on curve fitting an effective reference state relative to departure funcitons formed using the Peng-Robinson cubic state equation. Fit parameters for H(sub 2), O(sub 2), N(sub 2), propane, n-heptane and methanol are given.

thermodynamics state equations noniterative mixtur↗
NASA NTRS2003

Progress in Developing a New Field-theoretical Crossover Equation-of-State

A new field-theoretical crossover equation-of-state model is being developed. This model of a liquid-gas critical point provides a bridge between the asymptotic equation-of-state behavior close to the transition, obtained by the Guida and Zinn-Justin parametric model [J. Phys. A: Math. Gen. 31, 8103 (1998)], and the expected mean field behavior farther away. The crossover is based on the beta function for the renormalized fourth-order coupling constant and incorporates the correct crossover exponents and critical amplitude ratios in both regimes. A crossover model is now being developed that is consistent with predictions along the critical isochore and along the coexistence curve of the minimal subtraction renormalization approach developed by Dohm and co-workers and recently applied to the O(1) universality class [Phys. Rev. E, 67, 021106 (2003)]. Experimental measurements of the heat capacity at constant volume, isothermal susceptibility, and coexistence curve near the He-3 critical point are being compared to the predictions of this model. The results of these comparisons will be presented.

Rudnick, Joseph↗
NASA NTRS1971

Equation of state for porous metals under strong shock compression.

An equation of state is developed for metals in the high-pressure high-temperature region that can be extended in a thermodynamically consistent manner to the vapor phase. The constants are obtained from observed thermodynamic properties and are specified for Al, Fe, Cu, Ni, Pb, and W. This equation of state was checked against experimental data by computing the Hugoniot curves for normal and porous samples for cases where experimental data are available. Also, the velocity of sound and release isentropes were computed for various shock conditions.

Naumann, R. J.↗
NASA NTRS1989

Equation Of State With Temperature Effects For Solids

Behavior at high temperature predicted from only four parameters. Equations derived to express thermodynamical properties of compressed solids at high temperatures. New equations based on fundamental considerations of thermodynamics, isothermal equation of state, and assumption thermal pressure independent of volume and varies linearly with temperature near and about Debye temperature. Using only four parameters (three are those of isothermal equation of state), new equations describe thermodynamic behavior of material over range of temperatures from approximately Debye temperature to melting point.

Vinet, Pascal↗
NASA NTRS2002

Test of a new field-theoretical crossover equation-of-state

A new field-theoretical crossover equation-of-state model provides a bridge between the asymptotic behavior close to a liquid-gas critical point and the expected mean field behavior farther away.

equation-of-state critical phenomena liquid-gas cr↗
NASA NTRS1994

Astrophysical Applications of Quantum Corrections to the Equation of State of a Plasma

The quantum electrodynamic correction to the equation of state of a plasma at finite temperature is applied to the areas of solar physics and cosmology. A previously neglected, purely quantum term in the correction is found to change the equation of state in the solar core by -0.37%, which is roughly estimated to decrease the calculated high energy neutrino flux by about 2.2%. We also show that a previous calculation of the effect of this correction on big bang nucleosynthesis is incomplete, and we estimate the correction to the primordial helium abundance Y to be Delta A= 1.4 x 10(exp -4). A physical explanation for the correction is found in terms of corrections to the dispersion relation of the electron, positron, and photon.

Heckler, Andrew F.↗
NASA NTRS1976

Scaled equation of state parameters for gases in the critical region

In the light of recent theoretical developments, the paper presents an accurate characterization of anomalous thermodynamic behavior of xenon, helium 4, helium 3, carbon dioxide, steam and oxygen in the critical region. This behavior is associated with long range fluctuations in the system and the physical properties depend primarily on a single variable, namely, the correlation length. A description of the thermodynamic behavior of fluids in terms of scaling laws is formulated, and the two successfully used scaled equations of state (NBS equation and Linear Model parametric equation) are compared. Methods for fitting both equations to experimental equation of state data are developed and formulated, and the optimum fit for each of the two scaled equations of the above gases are presented and the results are compared. By extending the experimental data for the above one-component fluids to partially miscible binary liquids, superfluid liquid helium, ferromagnets and solids exhibiting order-disorder transitions, the principle of universality is concluded. Finally by using this principle, the critical regions for nine additional fluids are described.

Sengers, J. M. H. L.↗
NASA NTRS1987

Effects from equation of state and rheology in dissipative heating in compressible mantle convection

The effects of compressibility on mantle convection are considered, incorporating the effects of equations of state and rheology in the dissipative heating term of the energy equation. The ways in which compression may raise the interior mantle temperature are explicitly demonstrated, and it is shown how this effect can be used to constrain some of the intrinsic parameters associated with the equation of state in the mantle. It is concluded that the coupling between variable viscosity and equation of state in dissipative heating is potentially an important mechanism in mantle convection. These findings emphasize that rheology, equation of state, and radiogenic heating are all linked to each other by nonlinear thermomechanical couplings.

Yuen, David A.↗
NASA NTRS1988

Ion equation of state in quasi-parallel shocks - A simulation result

Ion equation of state in the quasi-parallel collisionless shock is deduced from simulation results. The simulations were performed for theta(bn) = 10 deg, beta = 0.5 and M sub A in the range from 1.2 to 8, where M sub A is the Alfven Mach number, beta is the upstream ratio of plasma pressure to magnetic pressure, and theta(bn) is the angle between the shock normal and the upstream magnetic field. The equation of state can be approximated by a power law with different exponents in the upstream and downstream sides of the shock transition region. The exponent in the upstream side of the transition region is much greater than the adiabatic value of 5/3 and increases with M sub A. The exponent in the downstream side of the transition region is slightly less than 5/3. The results show that ion heating in the quasi-parallel shock is highly nonadiabatic with a large increase in entropy and in temperature ratio in the upstream side of the transition region, while the heating is highly isentropic with a large increase in temperature difference across the principal density jump in the downstream side of the transition region.

Mandt, M. E.↗
NASA NTRS1973

Equation of state of matter at supernuclear densities.

The qualitative features of the equation of state of matter at supernuclear densities are deduced through a careful examination of the nature of particle interactions at short distances and by the introduction of an 'effective baryon mass spectrum.' It is found that the equation of state begins to take on a particularly simple form (the 'asymptotic form') at a relatively low matter density of 100,000 teragrams per cu cm.

Leung, Y. C.↗
NASA NTRS1991

The shock wave equation of state of brucite Mg(OH)2

New shock equation of state (EOS) data on magnesium hydroxide between 12 and 60 GPa is presented. It is found that the brucite EOS data between 12 and 97 GPa can be fit with a single linear U(s) - u(p) relationship: U(s) = 4.76(0.11) + 1.35(0.05)u(p). The third order Birch-Murnaghan equation parameters are K(os) = 51 + or - 4 GPa and K(os)prime = 5.0 + or - 0.4. The first partial release states measured for brucite Mg(OH)2 are reported. Calculated phase boundaries using the EOS data are found to be consistent with the experimental data and indicate that brucite is unlikely to be stable under lower mantle conditions. At high pressure, bulk sound velocities calculated for MgO and Mg(OH)2 are very similar, indicating that the presence of hydrous assemblages in the lower mantle may not produce anomalous bulk seismic velocities. A comparison of densities in brucite and other high-pressure phases under mantle conditions shows that the water content of the lower mantle is between 0 and 3 wt pct.

Duffy, Thomas S.↗