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At least 55 records · Page 3

Tilted magnetic field study of ZrTe 5

ZrTe 5 , a topological semimetal, has recently attracted great attention due to its extraordinary electronic properties. Extensive studies have been carried out in ZrTe 5 on their charge transport properties. However, there are few studies on their spin properties. One well-developed technique to study spin degeneracy of a Landau level (LL) in a two-dimensional system is by tilting magnetic field. It is known that the Landau level energy is proportional to the magnetic field normal component while the Zeeman energy scales with the total magnetic field. Therefore, these two energy scales can be tuned relatively to each other in a tilted magnetic field.

36 MATERIALS SCIENCE↗

Energy Considerations of Hypothetical Space Drives

The energy requirements of hypothetical, propellant-less space drives are compared to rockets. This serves to provide introductory estimates for potential benefits and to suggest analytical approaches for further study. A "space drive" is defined as an idealized form of propulsion that converts stored potential energy directly into kinetic energy using only the interactions between the spacecraft and its surrounding space. For Earth-to-orbit, the space drive uses 3.7 times less energy. For deep space travel, energy is proportional to the square of delta-v, whereas rocket energy scales exponentially. This has the effect of rendering a space drive 150-orders-of-magnitude better than a 17,000-s Specific Impulse rocket for sending a modest 5000 kg probe to traverse 5 ly in 50 years. Indefinite levitation, which is impossible for a rocket, could conceivably require 62 MJ/kg for a space drive. Assumption sensitivities and further analysis options are offered to guide further inquires.

Millis, Marc G.↗

Gas Scintillation Proportional Counters for High-Energy X-ray Astronomy

A focal plane array of high-pressure gas scintillation proportional counters (GSPC) for a balloon-borne hard-x-ray telescope is under development at the Marshall Space Flight Center. These detectors have an active area of approx. 20 sq cm, and are filled with a high pressure (10(exp 6) Pa) xenon-helium mixture. Imaging is via crossed-grid position-sensitive phototubes sensitive in the UV region. The performance of the GSPC is well matched to that of the telescopes x-ray optics which have response to 75 keV and a focal spot size of approx. 500 microns. The detector s energy resolution, 4% FWHM at 60 keV, is adequate for resolving the broad spectral lines of astrophysical importance and for accurate continuum measurements. Full details of the instrument and its performance will be provided.

Gubarev, Mikhail↗

Deducing Phonon Scattering from Normal Mode Excitations

While the quantum scattering theory has provided the theoretical underpinning for phonon interactions, the correspondence between the phonon modes and normal modes of vibrations has never been fully established; for example, the nature of energy exchange during elementary normal mode interactions remains largely unknown. In this work, by adopting a set of real asymmetric normal mode amplitudes, we first discriminate the normal and Umklapp processes directly from atomistic dynamics. We then demonstrate that the undulating harmonic and anharmonic potentials, which allow a number of interaction pathways, generate several total-energy-conserving forward and backward scattering events including those which are traditionally considered as quantum-forbidden. Although the normal mode energy is proportional to the square of the eigen-frequency, we deduce that the energy exchanged from one mode to another in each elementary interaction is proportional to the frequency – a quantum-like restriction. We anticipate that the current approach can be utilized profitably to discover unbiased scattering channels, many traditionally quantum forbidden, with complex anharmonicities. Our discovery will aid in the development of next-generation Peierls-Boltzmann transport simulations that access normal mode scattering pathways from finite temperature ab initio simulations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Analytic study of the effect of dark energy-dark matter interaction on the growth of structures

Large-scale structure has been shown as a promising cosmic probe for distinguishing and constraining dark energy models. Using the growth index parametrization, we obtain an analytic formula for the growth rate of structures in a coupled dark energy model in which the exchange of energy-momentum is proportional to the dark energy density. We find that the evolution of f σ{sub 8} can be determined analytically once we know the coupling, the dark energy equation of state, the present value of the dark energy density parameter and the current mean amplitude of dark matter fluctuations. After correcting the growth function for the correspondence with the velocity field through the continuity equation in the interacting model, we use our analytic result to compare the model's predictions with large-scale structure observations.

79 ASTRONOMY AND ASTROPHYSICS↗

A high resolution gas scintillation proportional counter for studying low energy cosmic X-ray sources

In recent years much effort has been devoted to the development of large area gas scintillation proportional counters (GSPCs) suitable for use in X-ray astronomy. The paper deals with a low-energy GSPC for use in detecting sub-keV X-rays from cosmic sources. This instrument has a measured energy resolution of 85 eV (FWHM) at 149 eV over a sensitive area of 5 sq cm. The development of imaging capability for this instrument is discussed. Tests are performed on the feasibility of using an arrangement of several phototubes placed adjacent to one another to determine event locations in a large flat counter. A simple prototype has been constructed and successfully operated.

Hamilton, T. T.↗

Lumley's energy cascade dissipation rate model for boundary-free turbulent shear flows

True dissipation occurs mainly at the highest wavenumbers where the eddy sizes are comparatively small. These high wavenumbers receive their energy through the spectral cascade of energy starting with the largest eddies spilling energy into the smaller eddies, passing through each wavenumber until it is dissipated at the microscopic scale. However, a small percentage of the energy does not spill continuously through the cascade but is instantly passed to the higher wavenumbers. Consequently, the smallest eddies receive a certain amount of energy almost immediately. As the spectral energy cascade continues, the highest wavenumber needs a certain time to receive all the energy which has been transferred from the largest eddies. As such, there is a time delay, of the order of tau, between the generation of energy by the largest eddies and the eventual dissipation of this energy. For equilibrium turbulence at high Reynolds numbers, there is a wide range where energy is neither produced by the large eddies nor dissipated by viscosity, but is conserved and passed from wavenumber to higher wavenumbers. The rate at which energy cascades from one wavenumber to another is proportional to the energy contained within that wavenumber. This rate is constant and has been used in the past as a dissipation rate of turbulent kinetic energy. However, this is true only in steady, equilibrium turbulence. Most dissipation models contend that the production of dissipation is proportional to the production of energy and that the destruction of dissipation is proportional to the destruction of energy. In essence, these models state that the change in the dissipation rate is proportional to the change in the kinetic energy. This assumption is obviously incorrect for the case where there is no production of turbulent energy, yet energy continues to cascade from large to small eddies. If the time lag between the onset on the energy cascade to the destruction of energy at the microscale can be modeled, then there will be a better representation of the dissipation process. Development of an energy cascade time scale equation is discussed.

Duncan, B. S.↗

Proton-impact ionization cross sections of adenine measured at 0.5 and 2.0 MeV by electron spectroscopy

Double-differential ionization cross sections (DDCSs) of vapor-phase adenine molecules (C{sub 5}H{sub 5}N{sub 5}) by 0.5- and 2.0-MeV proton impact have been measured by the electron spectroscopy method. Electrons ejected from adenine were analyzed by a 45 Degree-Sign parallel-plate electrostatic spectrometer over an energy range of 1.0-1000 eV at emission angles from 15 Degree-Sign to 165 Degree-Sign . Single-differential cross sections (SDCSs) and total ionization cross sections (TICSs) were also deduced. It was found from the Platzman plot, defined as SDCSs divided by the classical Rutherford knock-on cross sections per target electron, that the SDCSs at higher electron energies are proportional to the total number of valence electrons (50) of adenine, while those at low-energy electrons are highly enhanced due to dipole and higher-order interactions. The present results of TICS are in fairly good agreement with recent classical trajectory Monte Carlo calculations, and moreover, a simple analytical formula gives nearly equivalent cross sections in magnitude at the incident proton energies investigated.

74 ATOMIC AND MOLECULAR PHYSICS↗

The behaviour of minor species in the solar wind

The flow of minor species in the solar wind is considered on the basis of a model in which all species are heated in an arbitrary manner as they leave the sun and the minor species interact with the background proton-electron plasma through the radial electric field associated with the latter and by means of Coulomb collisions. In order to produce satisfactory results in which the ions all move at more or less the same speed at the orbit of the earth, it is necessary to introduce heating functions such that each species is given energy in proportion to its mass. Coulomb collisions are found to be important as a means of removing energy from the heavier species close to the sun and bringing all species closer to thermal equilibrium at great distances from the sun. Substantial velocity differences can occur between species, especially close to the sun. Furthermore it is not difficult to construct solutions in which the bulk velocity of the helium ions exceeds that of the solar wind, as is often observed.

Ryan, J. M.↗

The contribution of bioenergy to the decarbonization of transport: a multi-model assessment

The expected growth in the demand for passenger and freight services exacerbates the challenges of reducing transport GHG emissions, especially as commercial low-carbon alternatives to petroleum fuels are limited for shipping, air and long-distance road travel. Biofuels can offer a pathway to significantly reduce emissions from these sectors, as they can easily substitute for conventional liquid fuels in internal combustion engines. In this paper, we assess the potential of bioenergy to reduce transport GHG emissions through an analysis leveraging various integrated assessment models and scenarios, as part of the 33rd Energy Modeling Forum study (EMF-33). Furthermore, we find that bioenergy can contribute a significant, albeit not dominant, proportion of energy supply to the future transport sector: in scenarios aiming to keep the temperature increase below 2 °C by the end of the twenty-first century, models project that in 2100 bioenergy can provide on average 42 EJ/yr (ranging from 5 to 85 EJ/yr) for transport (compared to 3.7 EJ in 2018), mainly through lignocellulosic fuels. This makes up 9–62% of final transport energy use. Only a small amount of bioenergy is projected to be used in transport through electricity and hydrogen pathways, with a larger role for biofuels in road passenger transport than in freight. The association of carbon capture and storage (CCS) with bioenergy technologies (BECCS) is a key determinant in the role of biofuels in transport, because of the competition for biomass feedstock to provide other final energy carriers along with carbon removal. Among models that consider CCS in the biofuel conversion process the average market share of biofuels is 21% in 2100 (ranging from 2 to 44%), compared to 10% (0–30%) for models that do not. Cumulative direct emissions from the transport sector account for half of the emission budget (from 306 to 776 out of 1,000 GtCO 2 ). However, the carbon intensity of transport decreases as much as other energy sectors in 2100 when accounting for process emissions, including carbon removal from BECCS. Lignocellulosic fuels become more attractive for transport decarbonization if BECCS is not feasible for any energy sectors. Since global transport service demand increases and biomass supply is limited, its allocation to and within the transport sector is uncertain and sensitive to assumptions about political as well as technological and socioeconomic factors.

54 ENVIRONMENTAL SCIENCES↗

Isotopic Enrichment of Boron in the Sputtering of Boron Nitride with Xenon Ions

An experimental study is described to measure the isotopic enrichment of boron. Xenon ions from 100 eV to 1.5 keV were used to sputter a boron nitride target. An ion gun was used to generate the ion beam. The ion current density at the target surface was approximately 30 microA/sq cm. Xenon ions impinged on the target surface at 50 deg angle to the surface normal. Since boron nitride is an insulator, a flood electron gun was used in our experiments to neutralize the positive charge buildup on the target surface. The sputtered secondary ions of boron were detected by a quadrupole mass spectrometer. The spectrometer entrance aperture was located perpendicular to the ion beam direction and 10 mm away from the target surface. The secondary ion flux was observed to be enriched in the heavy isotopes at lower ion energies. The proportion of heavy isotopes in the sputtered secondary ion flux was found to decrease with increasing primary ion energy from 100 to 350 eV. Beyond 350 eV, light isotopes were sputtered preferentially. The light isotope enrichment factor was observed to reach an asymptotic value of 1.27 at 1.5 keV. This trend is similar to that of the isotopic enrichment observed earlier when copper was sputtered with xenon ions in the same energy range.

Ray, P. K.↗

Performance of Gas Scintillation Proportional Counter Array for High-Energy X-Ray Observatory

A focal plane array of high-pressure gas scintillation proportional counters (GSPC) for a High Energy X-Ray Observatory (HERO) is developed at the Marshall Space Flight Center. The array is consisted from eight GSPCs and is a part of balloon born payload scheduled to flight in May 2004. These detectors have an active area of approximately 20 square centimeters, and are filled with a high pressure (10(exp 6) Pa) xenon-helium mixture. Imaging is via crossed-grid position-sensitive phototubes sensitive in the UV region. The performance of the GSPC is well matched to that of the telescopes x-ray optics which have response to 75 keV and a focal spot size of approximately 500 microns. The detector's energy resolution, 4% FWHM at 60 keV, is adequate for resolving the broad spectral lines of astrophysical importance and for accurate continuum measurements. Results of the on-earth detector calibration will be presented and in-flight detector performance will be provided, as available.

Gubarev, Mikhail↗

Nanoscale mapping of the electron density at Al grain boundaries and correlation with grain-boundary energy

Grain-boundary (GB) structures and energies are often calculated and have revealed correlations between the GB energy and change in electron density at the GB. In this work, the plasmon peak in valence electron energy-loss spectroscopy (VEELS) was used to determine the variation in electron density across four well-characterized GBs in Al, spanning a range of known GB energies. The results show that the plasmon energy is lower at the GB than in the adjacent grains due to a decrease in electron density, and the GB energy increases proportional to the density decrease. The decrease in electron density also extends further into adjacent grains with increasing GB energy, extending beyond the geometric changes, or physical width, revealed by electron microscopy. Plasmon damping also increases with increasing GB energy, indicative of increasing disruption of the electron density with increasing GB energy. These results demonstrate that VEELS can be a valuable tool for detecting small electron density changes at GBs, and this change clearly influences, and is correlated to, the GB energy.

36 MATERIALS SCIENCE↗

Improved kinetic neoclassical transport calculation for a low-collisionality QH-mode pedestal

The role of neoclassical, anomalous and neutral transport to the overall H-mode pedestal and scrape-off layer (SOL) structure in an ELM-free QH-mode discharge on DIII-D is explored using XGC0, a 5D full-f multi-species particle-in-cell drift-kinetic solver with self-consistent neutral recycling and sheath potentials. The work in this paper builds on previous work aimed at achieving quantitative agreement between the flux-driven simulation and the experimental electron density, impurity density and orthogonal measurements of impurity temperature and flow profiles. Improved quantitative agreement is achieved by performing the calculations with a more realistic electron mass, larger neutral density and including finite-Larmor-radius corrections self-consistently in the drift-kinetic motion of the particles. Consequently, the simulations provide stronger evidence that the radial electric field (E r ) in the pedestal is primarily established by the required balance between the loss of high-energy tail main ions against a pinch of colder main ions and impurities. The kinetic loss of a small population of ions carrying a large proportion of energy and momentum leads to a separation of the particle and energy transport rates and introduces a source of intrinsic edge torque. Ion orbit loss and finite orbit width effects drive the energy distributions away from Maxwellian, and describe the anisotropy, poloidal asymmetry and local minimum near the separatrix observed in the T i profile.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Neutron Capture Energies for Flux Normalization and Approximate Model for Gamma-Smeared Power

The Consortium for Advanced Simulation of Light Water Reactors (CASL) Virtual Environment for Reactor Applications (VERA) neutronics simulator MPACT has used a single recoverable fission energy for each fissionable nuclide assuming that all recoverable energies come only from fission reaction, for which capture energy is merged with fission energy. This approach includes approximations and requires improvement by separating capture energy from the merged effective recoverable energy. This report documents the procedure to generate recoverable neutron capture energies and the development of a program called CapKappa to generate capture energies. Recoverable neutron capture energies have been generated by using CapKappa with the evaluated nuclear data file (ENDF)/B-7.0 and 7.1 cross section and decay libraries. The new capture kappas were compared to the current SCALE-6.2 and the CASMO-5 capture kappas. These new capture kappas have been incorporated into the Simplified AMPX 51- and 252-group libraries, and they can be used for the AMPX multigroup (MG) libraries and the SCALE code package. The CASL VERA neutronics simulator MPACT does not include a gamma transport capability, which limits it to explicitly estimating local energy deposition from fission, neutron, and gamma slowing down and capture. Since the mean free path of gamma rays is typically much longer than that for the neutron, and the total gamma energy is about 10% to the total energy, the gamma-smeared power distribution is different from the fission power distribution. Explicit local energy deposition through neutron and gamma transport calculation is significantly important in multi-physics whole core simulation with thermal-hydraulic feedback. Therefore, the gamma transport capability should be incorporated into the CASL neutronics simulator MPACT. However, this task will be timeconsuming in developing the neutron induced gamma production and gamma cross section libraries. This study is to investigate an approximate model to estimate gammasmeared power distribution without performing any gamma transport calculation. A simple approximate gamma smearing model has been investigated based on the facts that pinwise gamma energy depositions are almost flat over a fuel assembly, and assembly-wise gamma energy deposition is proportional to kappa-fission energy deposition. The approximate gamma smearing model works well for single assembly cases, and can partly improve the gamma smeared power distribution for the whole core model. Although the power distributions can be improved by the approximate gamma smearing model, still there is an issue to explicitly obtain local energy deposition. A new simple approach or gamma transport/diffusion capability may need to be incorporated into MPACT to estimate local energy deposition for more robust multi-physics simulation.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Energy from Redox Disproportionation of Sugar Carbon Drives Biotic and Abiotic Synthesis

To identify the energy source that drives the biosynthesis of amino acids, lipids, and nucleotides from glucose, we calculated the free energy change due to redox disproportionation of the substrate carbon of: (1) 26-carbon fermentation reactions and (2) the biosynthesis of amino acids and lipids of E. coli from glucose. The free energy (cal/mmol of carbon) of these reactions was plotted as a function of the degree of redox disproportionation of carbon (disproportionative electron transfers (mmol)/mmol of carbon). The zero intercept and proportionality between energy yield and degree of redox disproportionation exhibited by this plot demonstrate that redox disproportionation is the principal energy source of these redox reactions (slope of linear fit = -10.4 cal/mmol of disproportionative electron transfers). The energy and disproportionation values of E. coli amino acid and lipid biosynthesis from glucose lie near this linear curve fit with redox disproportionation accounting for 84% and 96% (and ATP only 6% and 1 %) of the total energy of amino acid and lipid biosynthesis, respectively. These observations establish that redox disproportionation of carbon, and not ATP, is the primary energy source driving amino acid and lipid biosynthesis from glucose. In contrast, we found that nucteotide biosynthesis involves very little redox disproportionation, and consequently depends almost entirely on ATP for energy. The function of sugar redox disproportionation as the major source of free energy for the biosynthesis of amino acids and lipids suggests that sugar disproportionation played a central role in the origin of metabolism, and probably the origin of life.

Weber, Arthur L.↗

Energy from Redox Disproportionation of Sugar Carbon Drives Biotic and Abiotic Synthesis

To identify the energy source that drives the biosynthesis of amino acids, lipids, and nucleotides from glucose, we calculated the free energy change due to redox disproportionation of the substrate carbon of: (1) 26-carbon fermentation reactions and (2) the biosynthesis of amino acids and lipids of E. coli from glucose. The free energy (cal/mmol of carbon) of these reactions was plotted as a function of the degree of redox disproportionation of carbon (disproportionative electron transfers (mmol)/mmol of carbon). The zero intercept and proportionality between energy yield and degree of redox disproportionation exhibited by this plot demonstrate that redox disproportionation is the principal energy source of these redox reactions (slope of linear fit = -10.4 cal/mmol of disproportionative electron transfers). The energy and disproportionation values of E. coli amino acid and lipid biosynthesis from glucose lie near this linear curve fit with redox disproportionation accounting for 84% and 96% (and ATP only 6% and 1%) of the total energy of amino acid and lipid biosynthesis, respectively. These observations establish that redox disproportionation of carbon, and not ATP, is the primary energy source driving amino acid and lipid biosynthesis from glucose. In contrast, we found that nucleotide biosynthesis involves very little redox disproportionation, and consequently depends almost entirely on ATP for energy. The function of sugar redox disproportionation as the major source of free energy for the biosynthesis of amino acids and lipids suggests that sugar disproportionation played a central role in the origin of metabolism, and probably the origin of life.

Weber, Arthur L.↗

Ensemble Kalman filters for dynamical systems with unresolved turbulence

Ensemble Kalman filters are developed for turbulent dynamical systems where the forecast model does not resolve all the active scales of motion. Coarse-resolution models are intended to predict the large-scale part of the true dynamics, but observations invariably include contributions from both the resolved large scales and the unresolved small scales. The error due to the contribution of unresolved scales to the observations, called ‘representation’ or ‘representativeness’ error, is often included as part of the observation error, in addition to the raw measurement error, when estimating the large-scale part of the system. It is here shown how stochastic superparameterization (a multiscale method for subgridscale parameterization) can be used to provide estimates of the statistics of the unresolved scales. In addition, a new framework is developed wherein small-scale statistics can be used to estimate both the resolved and unresolved components of the solution. The one-dimensional test problem from dispersive wave turbulence used here is computationally tractable yet is particularly difficult for filtering because of the non-Gaussian extreme event statistics and substantial small scale turbulence: a shallow energy spectrum proportional to k{sup −5/6} (where k is the wavenumber) results in two-thirds of the climatological variance being carried by the unresolved small scales. Because the unresolved scales contain so much energy, filters that ignore the representation error fail utterly to provide meaningful estimates of the system state. Inclusion of a time-independent climatological estimate of the representation error in a standard framework leads to inaccurate estimates of the large-scale part of the signal; accurate estimates of the large scales are only achieved by using stochastic superparameterization to provide evolving, large-scale dependent predictions of the small-scale statistics. Again, because the unresolved scales contain so much energy, even an accurate estimate of the large-scale part of the system does not provide an accurate estimate of the true state. By providing simultaneous estimates of both the large- and small-scale parts of the solution, the new framework is able to provide accurate estimates of the true system state.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗