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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Implementation of a Thick-Film Composite Li-Ion Microcathode Using Carbon Nanotubes as the Conductive Filler

This paper describes the development of a thick-film microcathode for use in Li-ion microbatteries in order to provide increased power and energy per area. These cathodes take advantage of a composite porous electrode structure, utilizing carbon nanotubes (CNT) as the conductive filler. The use of carbon nanotubes was found to significantly reduce the measured resistance of the electrodes, increase active material accessibility, and improve electrode performance. In particular, the cycling and power performance of the thick-film cathodes was significantly improved, and the need for compression was eliminated. Cathode thickness and CNT content were optimized to maximize capacity and power performance. Power capability of >50 mW/sq cm (17 mA/sq cm) with discharge capacity of >0.17 mAh/sq cm was demonstrated. The feasibility of fabricating thick-film microcathodes capable of providing the power and capacity needed for use in autonomous microsensor systems was also demonstrated.

Lin, Qian↗
NASA NTRS1983

Elastomeric binders for electrodes

The poor mechanical integrity of the cathode represents an important problem which affects the performance of ambient temperature secondary lithium cells. Repeated charge of a TiS2 cathode may give rise to stresses which disturb the electrode structure and can contribute to capacity loss. An investigation indicates that the use of an inelastic binder material, such as Teflon, aggravates the problem, and can lead to electrode disruption and poor TiS2 particle-particle contact. The feasibility of a use of elastomers as TiS2 binder materials has, therefore, been explored. It was found that elastomeric binders provide an effective approach for simplifying rechargeable cathode fabrication. A pronounced improvement in the mechanical integrity of the cathode structure contributes to a prolonged cycle life.

Yen, S. P. S.↗
NASA NTRS1984

Power Sources Symposium, 31st, Atlantic City, NJ, June 11-14, 1984, Proceedings

The present conference on electrochemical power sources encompasses systems of such types as the thermoelectric, advanced rechargeable, lithium reserve, rechargeable, and nonrechargeable, nickel-cadmium and nickel-hydrogen rechargeable, lead-acid, nickel-zinc and nickel-iron rechargeable, nickel-cadmium and nickel-hydrogen rechargeable, and fuel cells. Attention is given to Si-Ge alloy multicouple technology, sodium-sulfur battery development status, the safety aspects of a rechargeable lithium C cell, fiber-structure electrodes for nickel-cadmium batteries, energy density improvements in Li/carbon monofluoride cells, zinc-air button cell technology, catalyzed cathodes for Li/SOCl2 cells, the effect of polymer structure on the rate capability of the lithium-iodine cell, and a methanol fuel cell powerplant.

Source record↗
NASA NTRS1989

Advances in lightweight nickel electrode technology

Studies are currently underway to further the development of lightweight nickel electrode technology. Work is focused primarily on the space nickel-hydrogen system and nickel-iron system but is also applicable to the nickel-cadmium and nickel-zinc systems. The goal is to reduce electrode weight while maintaining or improving performance, thereby increasing electrode energy density. Two basic electrode structures are being investigated. The first is the traditional nickel sponge produced from sintered nickel-carbonyl powder. The second is a new material for this application which consists of a non-woven mat of nickel fiber. Electrodes are being manufactured, tested, and evaluated at the electrode and cell level.

Coates, Dwaine↗
NASA NTRS1989

Advances in lightweight nickel electrode technology

Studies are currently underway to further the development of lightweight nickel electrode technology. Work is focused primarily on the space nickel-hydrogen system and nickel-iron system but is also applicable to the nickel-cadmium and nickel-zinc systems. The goal is to reduce electrode weight while maintaining or improving performance thereby increasing electrode energy density. Two basic electrode structures are being investigated. The first is the traditional nickel sponge produced from sintered nickel-carbonyl powder and the second is a new material for this application which consists of a non-woven mat of nickel fiber. Electrodes are being manufactured, tested and evaluated at the electrode and cell level.

Coates, Dwaine↗
NASA NTRS1990

Frequency response of electrochemical cells

The main objective was to examine the feasibility of using frequency response techniques (1) as a tool in destructive physical analysis of batteries, particularly for estimating electrode structural parameters such as specific area, porosity, and tortuosity and (2) as a non-destructive testing technique for obtaining information such as state of charge and acceptability for space flight. The phenomena that contribute to the frequency response of an electrode include: (1) double layer capacitance; (2) Faradaic reaction resistance; (3) mass transfer of Warburg impedance; and (4) ohmic solution resistance. Nickel cadmium cells were investigated in solutions of KOH. A significant amount of data was acquired. Quantitative data analysis, using the developed software, is planned for the future.

Thomas, Daniel L.↗
NASA NTRS2007

Metal/Metal Oxide Differential Electrode pH Sensors

Solid-state electrochemical sensors for measuring the degrees of acidity or alkalinity (in terms of pH values) of liquid solutions are being developed. These sensors are intended to supplant older electrochemical pH sensors that include glass electrode structures and reference solutions. The older sensors are fragile and subject to drift. The present developmental solid-state sensors are more rugged and are expected to be usable in harsh environments. The present sensors are based on a differential-electrode measurement principle. Each sensor includes two electrodes, made of different materials, in equilibrium with the solution of interest.

West, William↗
NASA NTRS1977

Optically activated switch/modulator using a photoconductor and two channel waveguides

An optically activated switch was fabricated on LiNbO3 substrate by deposition of photoconductor-metal electrode structure on two channel waveguides obtained by the outdiffusion process. One waveguide was overcoated with a CdS film, and served as a light detector which converted the optical signal in that waveguide into an electric signal. Utilizing the electrooptic effect, this electric signal modulated the light propagating in the second waveguide by changing the refractive index, and the cutoff condition, of the waveguiding channel between two metal electrodes. The waveguides in the optically controlled switch can be either single or multimode. The length of the device can be short in comparison with other switching schemes. When binary optical signals are applied to the two waveguides, the switch can perform logic AND, NEGATION, OR and pseudo-amplification operations.

Goldberg, L.↗
NASA NTRS1996

A Novel Unitized Regenerative Proton Exchange Membrane Fuel Cell

A difficulty encountered in designing a unitized regenerative proton exchange membrane (PEM) fuel cell lies in the incompatibility of electrode structures and electrocatalyst materials optimized for either of the two functions (fuel cell or electrolyzer) with the needs of the other function. This difficulty is compounded in previous regenerative fuel cell designs by the fact that water, which is needed for proton conduction in the PEM during both modes of operation, is the reactant supplied to the anode in the electrolyzer mode of operation and the product formed at the cathode in the fuel cell mode. Drawbacks associated with existing regenerative fuel cells have been addressed. In a first innovation, electrodes function either as oxidation electrodes (hydrogen ionization or oxygen evolution) or as reduction electrodes (oxygen reduction or hydrogen evolution) in the fuel cell and electrolyzer modes, respectively. Control of liquid water within the regenerative fuel cell has been brought about by a second innovation. A novel PEM has been developed with internal channels that permit the direct access of water along the length of the membrane. Lateral diffusion of water along the polymer chains of the PEM provides the water needed at electrode/PEM interfaces. Fabrication of the novel single cell unitized regenerative fuel cell and results obtained on testing it are presented.

Murphy, O. J.↗
NASA NTRS1995

A novel unitized regenerative proton exchange membrane fuel cell

A difficulty encountered in designing a unitized regenerative proton exchange membrane (PEM) fuel cell lies in the incompatibility of electrode structures and electrocatalyst materials optimized for either of the two functions (fuel cell or electrolyzer) with the needs of the other function. This difficulty is compounded in previous regenerative fuel cell designs by the fact that water, which is needed for proton conduction in the PEM during both modes of operation, is the reactant supplied to the anode in the electrolyzer mode of operation and the product formed at the cathode in the fuel cell mode. Drawbacks associated with existing regenerative fuel cells have been addressed in work performed at Lynntech. In a first innovation, electrodes function either as oxidation electrodes (hydrogen ionization or oxygen evolution) or as reduction electrodes (oxygen reduction or hydrogen evolution) in the fuel cell and electrolyzer modes, respectively. Control of liquid water within the regenerative fuel cell has been brought about by a second innovation. A novel PEM has been developed with internal channels that permit the direct access of water along the length of the membrane. Lateral diffusion of water along the polymer chains of the PEM provides the water needed at electrode/PEM interfaces. Fabrication of the novel unitized regenerative fuel cell and results obtained on testing it will be presented.

Murphy, O. J.↗
NASA NTRS1972

Three dimensional potential and current distributions in a Hall generator with assumed velocity profiles

Three-dimensional potential and current distributions in a Faraday segmented MHD generator operating in the Hall mode are computed. Constant conductivity and a Hall parameter of 1.0 is assumed. The electric fields and currents are assumed to be coperiodic with the electrode structure. The flow is assumed to be fully developed and a family of power-law velocity profiles, ranging from parabolic to turbulent, is used to show the effect of the fullness of the velocity profile. Calculation of the square of the current density shows that nonequilibrium heating is not likely to occur along the boundaries. This seems to discount the idea that the generator insulating walls are regions of high conductivity and are therefore responsible for boundary-layer shorting, unless the shorting is a surface phenomenon on the insulating material.

Stankiewicz, N.↗
NASA NTRS1972

An electrohydrodynamic heat pipe.

A heat pipe of new design, using an electrode structure to orient and guide the dielectric liquid phase flow, is proposed. Analysis indicates that the operation of the electrohydrodynamic heat pipe is in direct analogy to capillary devices, with the polarization force acting in place of capillarity. Advantages of these new heat pipes include greatly reduced liquid friction, electrohydrodynamically enhanced evaporation and condensation heat transfer, and a possible voltage-controlled on/off feature. Preliminary calculations indicate that relatively high performance devices are possible.

Jones, T. B.↗
NASA NTRS1973

Charge-coupled device image sensor study

The design specifications and predicted performance characteristics of a Charge-Coupled Device Area Imager and a Charge-Coupled Device Linear Imager are presented. The Imagers recommended are intended for use in space-borne imaging systems and therefore would meet the requirements for the intended application. A unique overlapping metal electrode structure and a buried channel structure are described. Reasons for the particular imager designs are discussed.

Source record↗
NASA NTRS1975

Development of gold alloy catalyst cathode for alkaline electrolyte fuel cells

A program for the development of improved catalyst and Teflon-bonded electrode structures using this improved catalyst is described, for use in fuel cell cathodes. It was found that Au-Pt was superior to the traditional platinum black as a catalyst. The impetus to the program was provided by the discovery that a life-limiting mechanism on the old catalyst was the gradual dissolution of platinum from the cathode and subsequent redeposition in the electrolyte-containing matrix.

Freed, M. S.↗
NASA NTRS1976

Advanced thermionic energy conversion: Joint highlights

A theoretical model was used to study the effects of structured electrodes on converter I-V characteristics and results are given. An auxiliary-ion-source triode operated as a plasmatron was used for studying the enhancement distribution and magnetic effects, and results are reported. Design features of the high current-zero power (ZEPO) converter tests are given.

Source record↗