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At least 55 records · Page 3

Synthesis and investigation into explosive sensitivity for a series of new picramide explosives

Tailoring the molecular properties that govern energetic material sensitivity is essential to improve safety and help develop new energetic materials. Despite this need, understanding the complex chemistry and physics of explosive initiation and propagation is still a challenge. Recent work by our group has reinforced the view that explosive sensitivity under sub-shock conditions is connected to the strength of the weakest covalent bond in the molecule, that is, its “trigger linkage.” These correlations have been observed with different classes of energetic molecules and indicate that “trigger linkage” bond breaking, and heat of explosion are good indicators for the sensitivity trends. Herein we report the synthesis of aliphatic energetic materials with ethane, propane and neopentane backbones. Experimental and computational studies show that the trigger linkage model, based on results from quantum molecular dynamics simulations, correctly predicts trends observed in the impact sensitivity of the molecules. However, while the model predicts the impact sensitivities of the ethane series, the neopentane series has higher impact sensitivities than predicted, which is presumably influenced by crystal packing effects.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The force explosion condition is consistent with spherically symmetric CCSN explosions

ABSTRACT One of the major challenges in core-collapse supernova (CCSN) theory is to predict which stars explode and which collapse to black holes. The analytic force explosion condition (FEC) shows promise in predicting which stars explode in that the FEC is consistent with CCSN simulations that use the light-bulb approximation for neutrino heating and cooling. In this follow-up manuscript, we take the next step and show that the FEC is consistent with the explosion condition when using actual neutrino transport in gr1d simulations. Since most 1D simulations do not explode, to facilitate this test, we enhance the heating efficiency within the gain region. To compare the analytic FEC and radiation-hydrodynamic simulations, this manuscript also presents a practical translation of the physical parameters. For example: we replace the neutrino power deposited in the gain region, Lντg, with the net neutrino heating in the gain region; rather than assuming that $\dot{M}$ is the same everywhere, we calculate $\dot{M}$ within the gain region; and we use the neutrino opacity at the gain radius. With small, yet practical modifications, we show that the FEC predicts the explosion conditions in spherically symmetric CCSN simulations that use neutrino transport.

79 ASTRONOMY AND ASTROPHYSICS↗

The Physics of Core-Collapse Supernovae: Explosion Mechanism and Explosive Nucleosynthesis

Recent developments in multi-dimensional simulations of core-collapse supernovae have considerably improved our understanding of this complex phenomenon. In addition to that, one-dimensional (1D) studies have been employed to study the explosion mechanism and its causal connection to the pre-collapse structure of the star, as well as to explore the vast parameter space of supernovae. Nonetheless, many uncertainties still affect the late stages of the evolution of massive stars, their collapse, and the subsequent shock propagation. In this review, we will briefly summarize the state-of-the-art of both 1D and 3D simulations and how they can be employed to study the evolution of massive stars, supernova explosions, and shock propagation, focusing on the uncertainties that affect each of these phases. Finally, we will illustrate the typical nucleosynthesis products that emerge from the explosion.

Boccioli, Luca (ORCID:000000024819310X)↗

Light curves and spectra from a thermonuclear explosion of a white dwarf merger

Double-degenerate (DD) mergers of carbon–oxygen white dwarfs have recently emerged as a leading candidate for normal Type Ia supernovae (SNe Ia). However, many outstanding questions surround DD mergers, including the characteristics of their light curves and spectra. We have recently identified a spiral instability in the post-merger phase of DD mergers and demonstrated that this instability self-consistently leads to detonation in some cases. We call this the spiral merger SN Ia model. Here, we utilize the SuperNu radiative transfer software to calculate three-dimensional synthetic light curves and spectra of the spiral merger simulation with a system mass of 2.1 M{sub ⊙} from Kashyap et al. Because of their large system masses, both violent and spiral merger light curves are slowly declining. The spiral merger resembles very slowly declining SNe Ia, including SN 2001ay, and provides a more natural explanation for its observed properties than other SN Ia explosion models. Previous synthetic light curves and spectra of violent DD mergers demonstrate a strong dependence on viewing angle, which is in conflict with observations. Here, we demonstrate that the light curves and spectra of the spiral merger are less sensitive to the viewing angle than violent mergers, in closer agreement with observation. We find that the spatial distribution of {sup 56}Ni and IMEs follows a characteristic hourglass shape. We discuss the implications of the asymmetric distribution of {sup 56}Ni for the early-time gamma-ray observations of {sup 56}Ni from SN 2014J. We suggest that DD mergers that agree with the light curves and spectra of normal SNe Ia will likely require a lower system mass.

79 ASTRONOMY AND ASTROPHYSICS↗

“Explosively growing” vortices of unstably stratified atmosphere: “EXPLOSIVELY GROWING” VORTICES

A new type of “explosively growing” vortex structure is investigated theoretically in the framework of ideal fluid hydrodynamics. It is shown that vortex structures may arise in convectively unstable atmospheric layers containing background vorticity. From an exact analytical vortex solution the vertical vorticity structure and toroidal speed are derived and analyzed. The assumption that vorticity is constant with height leads to a solution that grows explosively when the flow is inviscid. The results shown are in agreement with observations and laboratory experiments

54 ENVIRONMENTAL SCIENCES↗

Spectroscopic measurement of high-frequency electric fields in the interaction of explosive debris plasma with magnetized background plasma

The collision-less transfer of momentum and energy from explosive debris plasma to magnetized background plasma is a salient feature of various astrophysical and space environments. While much theoretical and computational work has investigated collision-less coupling mechanisms and relevant parameters, an experimental validation of the results demands the measurement of the complex, collective electric fields associated with debris-background plasma interaction. Emission spectroscopy offers a non-interfering diagnostic of electric fields via the Stark effect. A unique experiment at the University of California, Los Angeles, that combines the Large Plasma Device (LAPD) and the Phoenix laser facility has investigated the marginally super-Alfvénic, quasi-perpendicular expansion of a laser-produced carbon (C) debris plasma through a preformed, magnetized helium (He) background plasma via emission spectroscopy. Spectral profiles of the He II 468.6 nm line measured at the maximum extent of the diamagnetic cavity are observed to intensify, broaden, and develop equally spaced modulations in response to the explosive C debris, indicative of an energetic electron population and strong oscillatory electric fields. The profiles are analyzed via time-dependent Stark effect models corresponding to single-mode and multi-mode monochromatic (single frequency) electric fields, yielding temporally resolved magnitudes and frequencies. The proximity of the measured frequencies to the expected electron plasma frequency suggests the development of the electron beam-plasma instability, and a simple saturation model demonstrates that the measured magnitudes are feasible provided that a sufficiently fast electron population is generated during C debris–He background interaction. Potential sources of the fast electrons, which likely correspond to collision-less coupling mechanisms, are briefly considered.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Mesoscale evolution of voids and microstructural changes in HMX-based explosives during heating through the β-δ phase transition

HMX-based explosives LX-10 and PBX-9501 were heated through the β-δ phase transition. Ultra-small angle x-ray scattering (USAXS) and molecular diffraction were simultaneously recorded as the HMX was heated. Mesoscale voids and structure dramatically change promptly with the β-δ phase transition, rather than with other thermal effects. Also, x-ray induced damage, observed in the USAXS, occurs more readily at elevated temperatures; as such, the dose was reduced to mitigate this effect. Optical microscopy performed during a similar heating cycle gives an indication of changes on longer length scales, while x-ray microtomography, performed before and after heating, shows the character of extensive microstructural damage resulting from the temperature cycle and solid-state phase transition.

36 MATERIALS SCIENCE↗

High-speed imaging of transition from fluid breakup to phase explosion in electric explosion of tungsten wires in air

High-speed visible imaging of sub-microsecond electric explosion of wires at the low specific energy deposition threshold reveals three distinct modes of wire failure as capacitor charge voltage and energy deposition are increased. For 100 micron diameter gold-plated tungsten wires of 2 cm length, deposited energies of 1.9 eV/atom produces a liquid column that undergoes hydrodynamic breakup into droplets with radii of order of wire diameter on timescales of 200 μs. Instability growth, column breakup, and droplet coalescence follow classic Rayleigh-Plateau predictions for instability of viscous fluid column. Above 3.2 eV/atom of deposited energy, wires are seen to abruptly transition to an expanding mixture of micron scale liquid-droplets and vapor within one frame (less than 3.33 μs), which has been termed ‘phase explosion’ in literature. Between these two limits, at 2.5 eV/atom of deposited energy, wire radius is unchanged for the first 10 μs before the onset of a rapid expansion and disintegration that resembles homogenous nucleation of mechanically unstable bubbles. Here, thermodynamic calculations are presented that separate cases by temperature obtained during heating: below boiling point, near boiling point, and exceeding boiling point.

42 ENGINEERING↗

Early Stage of the Explosion of Thin Flat Foils in a High-Current Diode at a Current of 40–80 kA

The initial stage of the nanosecond explosion of 1–15 μm-thick flat foils in a diode with a current of 40–80 kA is studied. Projection radiography is used to take images of exploded foils at a spatial resolution of 3–4 μm using the soft X-ray radiation (E = 2.5–5 keV) of a hybrid X-pinch and at a time resolution of 0.1 ns. Foil strips 0.3–2 mm wide and 0.5–7 mm long were introduced in the return circuit of the diode in a high-current BIN generator with a current amplitude of 270 kA and a current rise time of 100 ns; the main load of the generator is an X-pinch. The experiments demonstrate that small-scale structures, the shape and the size of which depend on the foil material and the current density and distribution in a foil, are formed in a foil. Possible scenarios of the structure formation are discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Passive high explosive neutron inspection (PHENIX): a new method to confirm the presence or absence of high explosives for nuclear treaty verification

Advanced instruments and methods need to be developed now to create a technical basis to support the negotiation of future nuclear arms control treaties. One new capability that is anticipated is the ability to confirm either the declared presence or declared absence of high explosive (HE) material in the presence of special nuclear material (SNM). Towards this goal, Passive HE Neutron Inspection (PHENIX) has been developed and demonstrated as a method for confirming the presence or absence of HE in the presence of plutonium. The method exploits the inherent presence of neutrons associated with the decay of plutonium as an internal probe source for performing prompt gamma-ray neutron activation analysis (PGNAA), searching for the presence of HE as revealed by the emission of characteristic gamma rays following neutron absorption in hydrogen and nitrogen which are building blocks of present-day, military-grade HE. Tests using stoichiometrically-correct hemishells of mock HE with plutonium show that a system can be expected to positively confirm the presence or absence of these signatures, supporting determination of HE presence or absence with Pu, in a few hours. To protect other potentially sensitive gamma-ray signatures from a treaty accountable item, an analog information barrier has been conceptualized and tested which physically prevents the collection of gamma-ray spectral data outside of user selected energy windows strategically chosen to view only narrow spectral regions corresponding to the hydrogen (2223.2 keV) and nitrogen (9807.2 keV, 10,318.2 keV, and 10,829.2 keV) PGNAA signatures.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Using steam explosion or AFEX™ to produce animal feeds and biofuel feedstocks in a biorefinery based on sugarcane residues: Using Steam Explosion or AFEX™ to Produce Animal Feeds and Biofuel Feedstocks in a Biorefinery Based on Sugarcane Residues

Sustainable integration of biofuel (primarily bioethanol) and highly digestible livestock feed in production systems is a potential way to increase the economic returns to agriculture and simultaneously promote energy security, particularly in developing countries. In this work we evaluated the efficacy of steam explosion (StEx) and ammonia fiber expansion (AFEX™) as potential processes for improving the in vitro rumen digestibility, metabolizable energy, and ethanol yields from sugarcane crop residues (bagasse and cane leaf matter, CLM). Ammonia fiber expansion pretreatment enhanced the in vitro true digestibility and metabolizable energy content of sugarcane crop residues by 69% and 26%, respectively compared to untreated controls. On the other hand, StEx increased the true digestibility and metabolizable energy content of the sugarcane residues by 54% and 7%, respectively. Ammonia fiber expansion also increased the total nitrogen content of both sugarcane bagasse and CLM to more than 20.2 g kg -1 dry forage, a more than 230% improvement relative to untreated controls. High solid-loading enzymatic hydrolysis and fermentation of StEx- and AFEX™-pretreated sugarcane crop residues generated yields of up to 3368 and 4360 L of ethanol per hectare of sugarcane cultivated, respectively, at a biomass-degrading enzyme dosage of 20 mg protein per gram glucan. This research strongly suggests that the use of suitably pretreated sugarcane crop residues in integrated sugarcane biofuel-livestock production systems can increase the total per hectare agricultural output without increasing the area of sugarcane cultivated. In effect, this integrated approach promotes more sustainable biofuel production and increased food production while avoiding the potential for indirect land use change.

09 BIOMASS FUELS↗