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At least 55 records · Page 3

FY22 Progress Report on BISON Metallic Fuel Model Development and V&V Using EBR-II Legacy Data

In this report, the activities and achievements made by Argonne National Laboratory for the Nuclear Energy Advanced Modeling and Simulation (NEAMS) BISON code metallic fuel validation and verification project in FY2022 are summarized. The FIPD-BISON integration powered metallic fuel low-burnup swelling framework has been enhanced to cover both radial and axial swelling analyses. Axial-dependent as-fabricated fuel radius profiles have been used to improve the accuracy in evaluating radial swelling strain. The simulations of the IFR experiment X447, which was focused on FCCI/CCCI induced cladding degradation and failure, have been converted into a BISON metallic fuel assessment case with detailed documentation, which is also the first FIPD-BISON integration powered assessment case in BISON. A FIPD-BISON integration repository has been established to be an optional submodule of BISON to support FIPD-BISON integration powered assessment cases. Preliminary trials to simulate the in-cell out-of-pile transient experiment have been made after implementing some essential models such as cladding plasticity models and liquid phase penetration models. The initial results are promising and help identify gaps that need to be filled in FY2023 and beyond, to eventually achieve OPTD-BISON integration powered assessment cases.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Specification of EBR-II Gamma Scan Data from the Precision Gamma Scanner

The gamma scan data stored in the FIPD was originally measured using the Precision Gamma Scanner (PGS) at the Hot Fuel Examination Facility (HFEF) at Idaho National Laboratory (INL). This system was originally manufactured in 1971 (when the facilities, now at INL, were operated by Argonne National Laboratory) and was upgraded on several occasions. It consists of a germanium gamma ray detector (the exact nature of which changed over time as technology improved), a variable-slit collimator that blocks the view of gamma emissions from all but the selected area of the target, and a computer-controlled system for translating a sample past the slit and logging the data.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Specification of EBR-II Contact Profilometry Data

All contact profilometry data stored in FIPD was originally measured using the HFEF vertical contact profilometer, which was an electronic gauge to measure the diameter profile of an element or capsule continuously over the region of interest. The element could be rotated as it passed through the probes if the wire wrap was not to be removed and the element could be returned to reactor for further irradiation. If the wire wrap was removed, the element could be drawn vertically through the probes, rotated, and the process repeated. In this way any cladding ovality could be observed. Figure 1 shows the setup used to measure the fuel pin diameter profile. The ambient temperature during the measurement was ~21-23 ºC. The cladding temperature during the measurement is considered to be similar to the ambient temperature by assuming the fuel decay heat did not impact the cladding temperature. Two documents contain most of the important details about contact profilometry measurements. The first one is the operational manual of the contact profilometer (title: Element contact profilometer operation and maintenance, HFEF/N OMM 4326, DOC. NO. W0202-0007-SA-01). This manual provides: (1) description of the contact profilometer including the functions of each component (support stage, sensing head, control system, and calibration standards, etc.); (2) step-by-step guidance on calibrations, operations, and measurements; and (3) maintenance procedures and other details of the contact profilometer. The second document is a publicly accessible report entitled “A Fuel-element Profilometer for the HFEF.” This report describes the development of the contact profilometer, including the design requirements, features, and details of each component, as well as the acceptance tests for the built system. This document is important because it reports the uncertainties of the measurements with detailed deduction procedures. The reported uncertainties should apply to all hard-copy contact profilometry data in FIPD. Some key information about contact profilometry measurements was extracted from these two documents. Combining the information with other sources, a specification for interpretating the contact profilometry data in FIPD was established.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Specification of EBR-II Laser Profilometry Data

All laser profilometry data stored in FIPD were originally measured using the element laser profilometer system in HFEF/N. The irradiated fuel elements or pins were scanned by a laser beam to measure the outer diameter with position mapping of the spacer wire. The normal operation and data collection were performed automatically with HFEF/N Data Acquisition and Process Control System (DAPCS). With the digital control system, measured laser profilometry data were recorded in digital form on magnetic tapes, different from the analog contact profilometry data recorded by strip-chart record sheets. Two documents contained most of the important details about laser profilometry measurements. The first one is the operational manual of the laser profilometer (title: Element laser profilometer (ELP) operation and maintenance manual, HFEF/N OMM 4329, DOC. NO. W0171-0149-ES-01). This manual provides: (1) description of laser profilometer including the functions of each component (transceiver, retroreflector, clamping guide, shielding enclosure, electronic controller, etc.); (2) step-by-step guidance for calibrations, operations and measurements; and (3) maintenance procedures and other details of the element laser profilometer. Since first issued on 12/1/1986, several revisions/changes of the manual were developed to update the measurement accuracies and other factors for the laser profilometer system. The second document is a publicly accessible conference article titled “the element laser profilometer system in HFEF/N.” This article summarizes important functions and parameters of the laser profilometer. The range of measurements and the uncertainties reported in the article were consistent with the values reported in the operational manual.

42 ENGINEERING↗

Comparison of zirconium redistribution in BISON EBR-II models using FIPD and IMIS databases with experimental Post Irradiation Examination

The BISON code framework is utilized to model and analyze zirconium redistribution within UPuZr metallic fuels. The simulation results are compared against past experimental metallography data to validate the BISON code models. Various BISON models are implemented and compared to properly reflect the Zr present in past data.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NRIC DOME Crane Trade Study and Recommendation

The National Reactor Innovation Center (NRIC) is a national program that was established as part of the Nuclear Energy Innovation Capabilities Act (NEICA). NRIC’s mission is to accelerate the demonstration and deployment of advanced nuclear energy through its mission to inspire stakeholders and the public, empower innovators, and deliver successful outcomes through efficient coordination of partners and resources. NRIC is designed to bridge the gap between research, development, and the marketplace to help convert some of the nation’s most promising advanced nuclear reactors into commercial applications. The NRIC Demonstration of Microreactor Experiments (DOME) facility, formerly known as Experimental Breeder Reactor II (EBR II), located at the Materials and Fuels Complex (MFC) at the Idaho National Laboratory (INL) is intended to allow industrial and other partners the opportunity to test Advanced Microreactors up to 20MW thermal power. The 75-ton capacity polar crane located in the EBR II facility was rendered inoperable to support planned facility demolition in 2015; small holes were flame cut in the girders; hoists and cables were removed; oil was drained from gear boxes; trolley drive, and then filled with absorbent; and the electrical and control umbilical’s were disconnected, removed and disposed. Subsequently, the decision was made to convert the EBR II facility into the DOME test bed.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗

The effect of temperature and burnup on U-10Zr metallic fuel chemical interaction with HT-9: A SEM-EDS study

The fuel cladding chemical interaction (FCCI) between Uranium-Zirconium-based metallic fuel and cladding materials during in-pile service is one of the most constraining phenomena affecting the performance of this fuel system. In this study, we investigated the effect of temperature and burnup on the FCCI development in two U-10 wt.% Zr (U-10Zr) fuel samples with HT-9 cladding irradiated as part of the MFF-3 irradiation test in the Fast Flux Test Facility (FFTF). One sample achieved a burnup of 13.1 at.% and operated with an average inner cladding temperature of 530°C, while the other achieved a burnup of 8.5 at.% and was subjected to an average inner cladding temperature of 615°C. Automated scanning electron microscopy (SEM) back-scattered electron (BSE) imaging of entire fuel cross-sections and SEM energy dispersive x-ray spectroscopy (EDS) analysis on specific fuel-cladding interface regions successfully provided a comprehensive characterization of the depth and type of interaction happening under different irradiation conditions. Further, our analysis shows that FCCI development on both fuel and cladding side is strongly influenced by the inner cladding temperature and, to some extent, the formation and integrity of Zr-rich layers between the fuel and cladding, while the impact of burnup and power is negligible. Measured FCCI thicknesses were compared to BISON simulations using both an empirical model based upon legacy data from the Experimental Breeder Reactor II (EBR II) irradiations and a mechanistic model currently under development for the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program, showing satisfactory agreement. Nonetheless, this comparison supports the need for additional microstructural characterization in intermediate ranges of temperature, power, and burnups in prototypic-length pins.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

History and status of spent fuel treatment at the INL Fuel Conditioning Facility

Experimental Breeder Reactor II (EBR-II) had an illustrious operational history from 1964 to 1994 as one of the first sodium-cooled fast reactors to use sodium-bonded metallic driver fuels and blankets. EBR-II was a testbed for fuel development and reactor design principles. Following shutdown, it was decided to use electrometallurgical methods to treat the spent fuel and blanket materials for final disposition. Here, this paper provides a brief history of U.S. liquid metal cooled reactor development with emphasis on EBR-II, and a technical description of the electrometallurgical methods.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Evaluation of BISON metallic fuel performance modeling against experimental measurements within FIPD and IMIS databases

Simulations were conducted using the BISON fuel performance code on an automated process to read initial and operating conditions from two databases—the Fuels Irradiation and Physics Database (FIPD) and Integral Fast Reactor Materials Information System (IMIS) database. These databases contain metallic fuel data from the Experimental Breeder Reactor-II (EBR-II) and the Fast Flux Test Facility (FFTF). The work demonstrates use of an integrated framework to access EBR-II fuel pin data for evaluating fuel performance models contained within BISON to predict fuel performance of next-generation metallic fuel systems. Between IMIS and FIPD, there is enough information to conduct 1,977 unique EBR-II metallic fuel pin histories from 29 different experiments, and 338 pins from FFTF MFF-3 and MFF-5 with varying levels of details between the two databases. Each of these fuel performance histories includes a high-resolution power history, flux history, coolant channel flow rates, and coolant channel temperatures, and new model developments in BISON since the initial demonstration of this integrated framework. Fission gas release (FGR), cumulative damage fraction, fuel axial swelling, FCCI wastage thickness, cladding profilometry, and burnup were all simulated in BISON and compared to post-irradiation examination (PIE) results to evaluate BISON fuel performance modeling. Implementation of new fuel performance models into a generic BISON input file coupled with IMIS and FIPD yielded results with a better representation of physics than the initial evaluation of the integrated framework. Cladding profilometry, FGR, and fuel axial swelling were found to be in good agreement with PIE measurements for most of the pins simulated. The chosen mechanical contact solver was found to significantly impact the axial fuel swelling and cladding strain predictions when used in conjunction with the U-Pu-Zr hot-pressing model since it bound the fuel to prevent further swelling and increased hydrostatic stresses. This work suggests that fuel performance modeling in BISON under steady-state conditions represents the PIE data well and should be reassessed when new PIE data become available in IMIS and FIPD databases and when improved physical models to better capture fuel performance are added to BISON.

Paaren, Kyle M.↗

The Use of Long-wave Infrared Cameras for Hazardous Waste Remediation - 20457

For over fifty years, infrared cameras have been used in military applications, nondestructive testing, condition monitoring, and predictive maintenance. As infrared cameras continue to become more sophisticated and less expensive, they are providing value in an ever-increasing variety of unique applications, including hazardous waste remediation. This paper describes several instances of how infrared cameras have been used within the US Department of Defense and the US Department of Energy in support of waste remediation projects, including the author's recent use of an infrared camera in support of the Calcine Retrieval Project at the Idaho National Laboratory. Infrared cameras provide images of infrared radiation, or heat energy, which is otherwise invisible to the unaided eye. Infrared radiation is part of the electromagnetic spectrum, which includes visible light. But unlike visible light, infrared has wavelengths longer than the human eye can detect. Infrared is emitted by everything with a temperature above absolute zero (-273 deg. C, or -459 deg. F); the higher the temperature, the greater the infrared thermal radiation, or heat, that is emitted. Even objects that feel cold to us, like ice, emit thermal radiation and can be imaged by infrared cameras. These cameras are typically used to look for abnormally hot or cold spots on a component or target area under normal operating conditions. The method provides a rapid, wide-area, noncontact technique for identifying problems associated with a temperature differential. All infrared cameras can provide qualitative thermal information by displaying relative differences in temperatures within a two-dimensional image. More expensive infrared cameras can also provide quantitative information where an absolute temperature value is assigned to each pixel associated with the displayed two-dimensional image. Proper camera calibration and a solid understanding of heat transfer and thermography techniques are required when using an infrared camera to obtain quantitative information. Case studies outlined in this paper include the rapid, non-intrusive detection of hazardous decontamination solution within one-ton shipping containers at Pine Bluff Arsenal, the non-intrusive identification of residual elemental sodium within the cooling loops of the Experimental Breeder Reactor II (EBR-II) reactor at the Idaho National Laboratory, process monitoring of heat exchanger melt-and-drain efforts during EBR-II decommissioning, and the remote detection of internal steel supports within calcine storage bins prior to bin penetration. For each use of thermography, the author describes a summary of the waste remediation effort, the infrared camera used, the thermal imaging technique employed, and the results obtained. The paper concludes with a discussion on common mistakes to avoid for similar applications of thermography. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Data Mining – Image Analysis of Radiography for Zr Redistribution

The research effort described in this report represents a first attempt to investigate the radial redistribution of Zr in ternary fuel alloys U-xPu-10Zr (x = 0, 8, 19) irradiated in the in-reactor fuel experiments during the operation of the U.S. Department of Energy’s (DOE’s) Experimental Breeder Reactor II (EBR-II) at Idaho National Laboratory (INL) using methods of image processing on post-irradiation neutron radiographs. Approximately 130,000 metal fuel pins were irradiated in EBR-II during its 30 years of operation to develop and characterize existing and prospective fuels. For many of the metal fuel irradiation experiments, neutron radiography imaging was performed historically now allowing application of modern image analysis techniques to characterize fuel behavior, such as fuel swelling, fluff formation, and now, fuel alloy constituent redistribution. The redistribution of fuel components depends on the temperature field, radially, within the fuel. Specifically, Zr is expected to redistribute radially towards the center of the pin, as well as towards the outer zones. Currently, direct imaging of a pin cross-section through optical methods or scanning electron microscopy (SEM) is used to study the constituents’ redistribution, which is very time-consuming and can only be applied to a limited number of pins. An automated image processing technique allowing for the investigation of fuel radial redistribution zones would significantly accelerate data analysis. In general, if the fuel temperature is hot enough, three redistribution zones are expected, corresponding to the main fuel components (e.g., U, Pu, Zr). While more assessment will be performed in fiscal year (FY)-2023, it seems possible to differentiate the pins according to their fuel composition using image analysis techniques on neutron radiographs of metallic fuel pins based on the analysis to date.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Specifications of Legacy U(Pu)Zr Metallography Data

The DOE Nuclear Energy Advanced Reactor Technologies (ART) Program has supported the creation of several databases with information describing the safety performance of fast reactors, components, and fuels. This growing collection of legacy experimental data, operating data, and analysis is available online to registered users. Metallography data is one of the most important types of PIE data being collected, organized and stored in several ART Fast Reactor Databases (https://frdb.ne.anl.gov), including the Fuels Irradiation & Physics Database (FIPD), Out-of-Pile Transient Database (OPTD), and TREAT (the Transient Reactor Test Facility) Experimental Relational Database (TREXR). These databases contain three main sets of metallography data. The first set is the metallography data from Experimental Breeder Reactor-II (EBR-II) and Fast Flux Test Facility (FFTF) irradiated fuel pins measured in the Hot Fuel Examination Facility (HFEF); the second set is the metallography data from EBR-II irradiated fuel pins measured in the Alpha-Gamma Hot Cell Facility (AGHCF); the third set is the metallography data from transient tested fuel pins (the transients tests include the out-of-pile tests and TREAT tests) measured in AGHCF. Since both the second and third sets of data were measured in AGHCF, they are governed by the same specification. The metallography data in the databases are digital images scanned from either positive or negative photos. The quality of the images, including their resolution and contrast, relies on the preserved quality of the pictures and the scanning conditions. To analyze the microstructure of a fuel pin, a series of preparatory steps must be undertaken. These include sectioning, epoxy mounting, mechanical grinding and polishing, and often etching. The resulting samples were then transferred to a secondary hot cell, or glovebox (depending the strength of radiation field) for microscopy examination. The specifications provided herein focus on the metallography examinations. The sample grinding, polishing and etching processes are also discussed. The procedures involving sectioning and epoxy mounting are out of the scope of the current specification; details can be found in the corresponding operation manuals. If more data are collected and added to the ART Fast Reactor Databases, this specification will be updated to accommodate the additional data.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Determination of Scale Bar for AGHCF Metallography Data

The DOE Nuclear Energy Advanced Reactor Technologies (ART) Fast Reactor Program (FRP) has supported the development of several databases containing information on the safety performance of fast reactors, components, and fuels. This growing collection of legacy experimental data, operating data, and analysis is available online to registered users. Metallography data represents one of the most critical types of post-irradiation examination (PIE) data being collected, organized, and archived in several ART Fast Reactor Databases (https://frdb.ne.anl.gov), including the Metallic Fuels Irradiation & Physics Database (FIPD), Out-of-Pile Transient Database (OPTD), and TREAT (the Transient Reactor Test Facility) Experimental Relational Database (TREXR). These databases contain three principal sets of metallography data. The first set comprises metallography data from Experimental Breeder Reactor-II (EBR-II) and Fast Flux Test Facility (FFTF) irradiated fuel pins examined in the Hot Fuel Examination Facility (HFEF). The second set consists of metallography data from EBR-II irradiated fuel pins examined in the Alpha-Gamma Hot Cell Facility (AGHCF). The third set includes metallography data from transient-tested fuel pins (including both out-of-pile furnace tests and TREAT tests) examined in AGHCF. Since both the second and third sets were generated in AGHCF, they are governed by identical specifications. The metallography data in the databases consist of digital images scanned from either positive or negative photographic films. To analyze the microstructure of a fuel pin, a series of preparatory steps are required, including sectioning, epoxy mounting, mechanical grinding and polishing, and etching. Following sample preparation, specimens are transferred for metallographic examination. The AGHCF and HFEF metallography data were generated using optical microscopes manufactured by Leitz and Bausch and Lomb (B&L). Images were recorded on Polaroid film at preset magnifications. Magnification verification for the Leitz and B&L metallographs was conducted every two months prior to 1989 and at least every six months from 1989 through the conclusion of the IFR program. Magnifications determined from imaging of microslide standards were compared to the instrument settings for magnifications ranging from 50× to 500×. If the magnifications determined from standards deviated from the instrument settings, adjustments were made to the bellows extension until agreement was achieved. The specifications for AGHCF and HFEF legacy metallography data have been established based on available hard-copy and digital records, most of which have been incorporated into the data repositories associated with FIPD, OPTD, and TREXR. Detailed specifications including hard-copy records, digitized records, cutting diagrams and sectioning schemes, high-magnification photographs, photomosaics (composites), information tags, scale bars, and magnification verification procedures can be found in a separate report.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Shielding an Infrasound Sensor for INL’s Fuel Conditioning Facility

Idaho National Laboratory (INL) has been pyroprocessing spent fuel from the Experimental Breeder Reactor II (EBR-II). This process occurs in the Fuel Conditioning Facility (FCF) which houses the treatment of DOE-owned sodium-bonded metal fuel. The electrometallurgical methods used in FCF treat the spent fuel from EBR-II for recycling of the uranium. The radiation field present inside FCF throughout the pyroprocessing stages affects any electronic sensors and devices that may be used for research. An example of such device is a seismoacoustic sensor which detects sound and vibration waves from the equipment in the facility. Seismoacoustic sensors are of interest to research nonproliferation techniques.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

The application of synchrotron micro-computed tomography to characterize the three-dimensional microstructure in irradiated nuclear fuel

This research demonstrated the first time that synchrotron X-ray micro-computed tomography (μ-CT) was utilized to analyze the three-dimensional (3-D) morphology of the microstructure of irradiated nuclear fuel. Both absorption contrast and propagation-based phase contrast enhanced μ-CT techniques were evaluated. Porosity and phase region volumes were determined in neutron irradiated uranium 10 wt.% zirconium (U-10Zr) using propagation-based phase contrast enhanced μ-CT. Volumes were determined by image processing software and algorithms, with the porosity volume subsequently compared to the ASTM E562 method. The 3-D porosity of a small region (~ 8 x 10 5 µm 3 ) located in the intermediate fuel redistribution zone that was removed via a focused ion beam was determined to be 7.2% via image processing. A detailed 3-D analysis of the porosity with respect to volume and morphology was provided. Five growth stages of pore evolution were observed including: nucleation, growth, coalescence, interconnected porosity, and extended/interconnected porosity. Four distinct phase regions were identified, including the pores, via both absorption contrast and propagation-based phase contrast enhanced μ-CT. A quantitative comparison of fuel swelling between this localized microscopic U-10Zr fuel region, previously irradiated in the Fast Flux Test Facility, and historic U-10Zr fuels irradiated in the Experimental Breeder Reactor-II (EBR-II) was conducted. It was determined that for similar burnups, the localized swelling in this microscopic fuel region was 7.7%, which was approximately one-half of the value of the macroscopic swelling reported in EBR-II irradiated fuel. With the advent of new specimen preparation tools for irradiated materials, as well as advances in characterization techniques, researchers can now obtain previously inaccessible microstructural insight into irradiated fuels. This possibility naturally lends itself to improved fuel performance models for the nuclear community.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Phosphate-Based Approaches for Dechlorination and Treatment of Salt Waste from Electrochemical Processing of Used Nuclear Fuel: A Perspective on Recent Work

Phosphate-based reagents are being considered by the U.S. Department of Energy (DOE) Office of Nuclear Energy to process halide salt-based nuclear wastes for stabilization prior to disposal. As evidenced by the Experimental Breeder Reactor-II (EBR-II) project, electrochemical processing (pyroprocessing) can be employed to recover uranium and other actinides for reintegration into the nuclear fuel cycle from metallic fuels. The resultant salt-based wastes generated from electrochemical processing of EBR-II fuel contains fission products within a LiCl–KCl eutectic salt that necessitate appropriate disposal. This paper provides an overview of recent efforts to support halide-based salt waste treatment for disposition, as well as a basis for comparison with other related efforts in salt waste treatment through salt partitioning initiatives. The U.S. DOE has selected a phosphate waste form reference material for further investigation and longer-term studies.

electrorefiner↗