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Integrated Pulse Detonation Propulsion and Magnetohydrodynamic Power

The prospects for realizing an integrated pulse detonation propulsion and magnetohydrodynamic (MHD) power system are examined. First, energy requirements for direct detonation initiation of various fuel-oxygen and fuel-air mixtures are deduced from available experimental data and theoretical models. Second, the pumping power requirements for effective chamber scavenging are examined through the introduction of a scavenging ratio parameter and a scavenging efficiency parameter. A series of laboratory experiments were carried out to investigate the basic engineering performance characteristics of a pulse detonation-driven MHD electric power generator. In these experiments, stoichiometric oxy-acetylene mixtures seeded with a cesium hydroxide/methanol spray were detonated at atmospheric pressure in a 1-m-long tube having an i.d. of 2.54 cm. Experiments with a plasma diagnostic channel attached to the end of the tube confirmed the attainment of detonation conditions (p(sub 2)/p(sub 1) approx. 34 and D approx. 2,400 m/sec) and enabled the direct measurement of current density and electrical conductivity (=6 S/m) behind the detonation wave front. In a second set of experiments, a 30-cm-long continuous electrode Faraday channel, having a height of 2.54 cm and a width of 2 cm, was attached to the end of the tube using an area transition duct. The Faraday channel was inserted in applied magnetic fields of 0.6 and 0.95 T. and the electrodes were connected to an active loading circuit to characterize power extraction dependence on load impedance while also simulating higher effective magnetic induction. The experiments indicated peak power extraction at a load impedance between 5 and 10 Ohm. The measured power density was in reasonable agreement with a simple electrodynamic model incorporating a correction for near-electrode potential losses. The time-resolved thrust characteristics of the system were also measured, and it was found that the MHD interaction exerted a negligible influence on system thrust and that the measured I(sub sp) of the system (200 sec) exceeded that computed for an equivalent nozzleless rocket (120 sec).

Litchford, R. J.

Development of a Gas-Fed Pulse Detonation Research Engine

In response to the growing need for empirical data on pulse detonation engine performance and operation, NASA Marshall Space Flight Center has developed and placed into operation a low-cost gas-fed pulse detonation research engine. The guiding design strategy was to achieve a simple and flexible research apparatus, which was inexpensive to build and operate. As such, the engine was designed to operate as a heat sink device, and testing was limited to burst-mode operation with run durations of a few seconds. Wherever possible, maximum use was made of standard off-the-shelf industrial or automotive components. The 5-cm diameter primary tube is about 90-cm long and has been outfitted with a multitude of sensor and optical ports. The primary tube is fed by a coaxial injector through an initiator tube, which is inserted directly into the injector head face. Four auxiliary coaxial injectors are also integrated into the injector head assembly. All propellant flow is controlled with industrial solenoid valves. An automotive electronic ignition system was adapted for use, and spark plugs are mounted in both tubes so that a variety of ignition schemes can be examined. A microprocessor-based fiber-optic engine control system was developed to provide precise control over valve and ignition timing. Initial shakedown testing with hydrogen/oxygen mixtures verified the need for Schelkin spirals in both the initiator and primary tubes to ensure rapid development of the detonation wave. Measured pressure wave time-of-flight indicated detonation velocities of 2.4 km/sec and 2.2 km/sec in the initiator and primary tubes, respectively. These values implied a fuel-lean mixture corresponding to an H2 volume fraction near 0.5. The axial distribution for the detonation velocity was found to be essentially constant along the primary tube. Time-resolved thrust profiles were also acquired for both underfilled and overfilled tube conditions. These profiles are consistent with previous time-resolved measurements on single-cycle tubes where the thrust is found to peak as the detonation wave exits the tube, and decay as the tube blows down.

Litchford, Ron J.

The Use of Steady and Unsteady Detonation Waves for Propulsion Systems

Detonation wave enhanced supersonic combustors such as the Oblique Detonation Wave Engine (ODWE) are attractive propulsion concepts for hypersonic flight. These engines utilize detonation waves to enhance fuel-air mixing and combustion. The benefits of wave combustion systems include shorter and lighter engines which require less cooling and generate lower internal drag. These features allow air-breathing operation at higher Mach numbers than the diffusive burning scramjet delaying the need for rocket engine augmentation. A comprehensive vehicle synthesis code has predicted the aerodynamic characteristics and structural size and weight of a typical single-stage-to-orbit vehicle using an ODWE. Other studies have focused on the use of unsteady or pulsed detonation waves. For low speed applications, pulsed detonation engines (PDE) have advantages in low weight and higher efficiency than turbojets. At hypersonic speeds, the pulsed detonations can be used in conjunction with a scramjet type engine to enhance mixing and provide thrust augmentation.

Adelman, Henry G.

Laser High-Cycle Thermal Fatigue of Pulse Detonation Engine Combustor Materials Tested

Pulse detonation engines (PDE's) have received increasing attention for future aerospace propulsion applications. Because the PDE is designed for a high-frequency, intermittent detonation combustion process, extremely high gas temperatures and pressures can be realized under the nearly constant-volume combustion environment. The PDE's can potentially achieve higher thermodynamic cycle efficiency and thrust density in comparison to traditional constant-pressure combustion gas turbine engines (ref. 1). However, the development of these engines requires robust design of the engine components that must endure harsh detonation environments. In particular, the detonation combustor chamber, which is designed to sustain and confine the detonation combustion process, will experience high pressure and temperature pulses with very short durations (refs. 2 and 3). Therefore, it is of great importance to evaluate PDE combustor materials and components under simulated engine temperatures and stress conditions in the laboratory. In this study, a high-cycle thermal fatigue test rig was established at the NASA Glenn Research Center using a 1.5-kW CO2 laser. The high-power laser, operating in the pulsed mode, can be controlled at various pulse energy levels and waveform distributions. The enhanced laser pulses can be used to mimic the time-dependent temperature and pressure waves encountered in a pulsed detonation engine. Under the enhanced laser pulse condition, a maximum 7.5-kW peak power with a duration of approximately 0.1 to 0.2 msec (a spike) can be achieved, followed by a plateau region that has about one-fifth of the maximum power level with several milliseconds duration. The laser thermal fatigue rig has also been developed to adopt flat and rotating tubular specimen configurations for the simulated engine tests. More sophisticated laser optic systems can be used to simulate the spatial distributions of the temperature and shock waves in the engine. Pulse laser high-cycle thermal fatigue behavior has been investigated on a flat Haynes 188 alloy specimen, under the test condition of 30-Hz cycle frequency (33-msec pulse period and 10-msec pulse width including a 0.2-msec pulse spike; ref. 4). Temperature distributions were calculated with one-dimensional finite difference models. The calculations show that that the 0.2-msec pulse spike can cause an additional 40 C temperature fluctuation with an interaction depth of 0.08 mm near the specimen surface region. This temperature swing will be superimposed onto the temperature swing of 80 C that is induced by the 10-msec laser pulse near the 0.53-mm-deep surface interaction region.

Zhu, Dong-Ming

Pulse Detonation Engine Test Bed Developed

A detonation is a supersonic combustion wave. A Pulse Detonation Engine (PDE) repetitively creates a series of detonation waves to take advantage of rapid burning and high peak pressures to efficiently produce thrust. NASA Glenn Research Center's Combustion Branch has developed a PDE test bed that can reproduce the operating conditions that might be encountered in an actual engine. It allows the rapid and cost-efficient evaluation of the technical issues and technologies associated with these engines. The test bed is modular in design. It consists of various length sections of both 2- and 2.6- in. internal-diameter combustor tubes. These tubes can be bolted together to create a variety of combustor configurations. A series of bosses allow instrumentation to be inserted on the tubes. Dynamic pressure sensors and heat flux gauges have been used to characterize the performance of the test bed. The PDE test bed is designed to utilize an existing calorimeter (for heat load measurement) and windowed (for optical access) combustor sections. It uses hydrogen as the fuel, and oxygen and nitrogen are mixed to simulate air. An electronic controller is used to open the hydrogen and air valves (or a continuous flow of air is used) and to fire the spark at the appropriate times. Scheduled tests on the test bed include an evaluation of the pumping ability of the train of detonation waves for use in an ejector and an evaluation of the pollutants formed in a PDE combustor. Glenn's Combustion Branch uses the National Combustor Code (NCC) to perform numerical analyses of PDE's as well as to evaluate alternative detonative combustion devices. Pulse Detonation Engine testbed.

Breisacher, Kevin J.

Simplified Analysis of Pulse Detonation Rocket Engine B1owdown Gasdynamics and Performance

Pulsed detonation rocket engines (PDREs) have generated considerable research interest in recent years as a chemical propulsion system potentially offering improved performance and reduced complexity compared to conventional rocket engines. The detonative mode of combustion employed by these devices offers a thermodynamic advantage over the constant-pressure deflagrative combustion mode used in conventional rocket engines and gas turbines. However, while this theoretical advantage has spurred a great deal of interest in building PDRE devices, the unsteady blowdown process intrinsic to the PDRE has made realistic estimates of the actual propulsive performance problematic. The recent review article by Kailasanath highlights some of the difficulties in comparing the available experimental measurements with numerical models. The goal of this paper is to improve understanding of PDRE blowdown gasdynamics and performance issues through use of a simplified model that captures the essential features of the unsteady blowdown process, and yet remains computationally inexpensive. The PDRE system studied here is highly idealized, consisting of a constant-area detonation tube with one end closed and the other end open to the environment. The tube is prefilled with a gaseous propellant mixture with no initial velocity or outflow to the environment. The detonation is initiated instantaneously at the closed end of the device. Chapman-Jouguet (C-J) post-detonation gas conditions are calculated using the CET89 version of the NASA thermochemical code. The I-D, unsteady method of characteristics is used to calculate the flowfield following the detonation front. See the compressible flow texts by Thompson and Zucrow and Hoffman for details of this method. Parametric studies of the effect of mixture stoichiometry, fill temperature, and blowdown pressure ratio on performance are reported. A comparison of the performance of an idealized straight-tube PDRE with a conventional steady-state rocket engine is provided. The effect of constant-gamma and equilibrium chemistry assumptions is also examined. Additionally, in order to form an assessment of the accuracy of the model, the flowfield time history is compared to experimental data from Stanford University.

Morris, Christopher I.

NASAs Succeeds in Testing of Advanced Rotating Detonation Rocket Engine for New US Space Flight Capability

June-August 2022, NASA engineers at Marshall Space Flight Center in Huntsville Alabama have successfully fired two regeneratively cooled advanced rotating detonation rocket engines (RDRE’s). The engines have accumulated 17 starts at over 600 seconds of total duration. Multiple firings were achieved of greater than 110 seconds each with detonation modes. A single full throttle test produced over 4000 lbf for 15 seconds with detonation modes. The mean pressure at a single point on the injector face was 620 psia. These tests completed the project’s main objective: demonstrating that additive GRCop-alloy hardware could survive long durations while subjected to the detonative events. 4-5 co-rotating detonations were observed during most tests with a single test showing 2-3 waves. Several other milestones were also achieved including successful demonstration of active throttling with detonation modes, successful ignition without a predetonator, and the use of novel additive manufacturing techniques. The primary collaborator was IN Space, LLC (West Lafayette, IN) through an STMD announcement for collaborative opportunity (ACO). Hot fire testing was conducted at Marshall Space Flight Centers heritage east test area at Test Stand 115 in collaboration with Marshall ET10.

Thomas Teasley

Average Heat Flux Measurements in a Gaseous Detonation-Based Rocket Engine

Rotating detonation rocket engines (RDREs) offer benefits over traditional deflagrative engines, including increased engine performance, compact combustion and negligible detrimental thermoacoustic instabilities due to mode-locking. Realizing the benefits of a detonation-based propulsion system will be accompanied by increased thermal loads due to a combination of heat release at elevated pressure and temperature, as well as compact heat release due to detonation. Managing these heat loads necessitates the development of thermal management strategies. As a first step towards establishing the requirements for detonation-based engine thermal management strategies, this work develops an additively manufactured (AM) water-based, axially resolved calorimeter for integration in an existing 76.8 mm outer diameter (OD) RDRE to measure average chamber heat flux. In particular, the calorimetry outer body provides average heat flux data via circumferential channels at nine axial stations to axially resolve the heat flux distribution on the chamber outer wall. The average heat flux is found to be 5 − 12 MW/m 2 for a straight annulus and 6 − 18 MW/m 2 for a constricted annular configuration which exhibited maximum heat flux at the throat. A difference in heat flux scaling is observed near the detonation region compared to the downstream flow expansion section in the constricted geometry. By quantifying the axial distribution of heat flux, this work seeks to support the development of thermal management systems for long duration firing of detonation-based devices.

Matthew A Maybee

Average Heat Flux Measurements in a Gaseous Detonation-Based Rocket Engine

Rotating detonation rocket engines (RDREs) offer benefits over traditional deflagrative engines, including increased engine performance, compact combustion and negligible detrimental thermoacoustic instabilities due to mode-locking. Realizing the benefits of a detonation-based propulsion system will be accompanied by increased thermal loads due to a combination of heat release at elevated pressure and temperature, as well as compact heat release due to detonation. Managing these heat loads necessitates the development of thermal management strategies. As a first step towards establishing the requirements for detonation-based engine thermal management strategies, this work develops an additively manufactured (AM) water-based, axially resolved calorimeter for integration in an existing 76.8 mm outer diameter (OD) RDRE to measure average chamber heat flux. In particular, the calorimetry outer body provides average heat flux data via circumferential channels at nine axial stations to axially resolve the heat flux distribution on the chamber outer wall. The average heat flux is found to be 5 − 12 MW/m 2 for a straight annulus and 6 − 18 MW/m 2 for a constricted annular configuration which exhibited maximum heat flux at the throat. A difference in heat flux scaling is observed near the detonation region compared to the downstream flow expansion section in the constricted geometry. By quantifying the axial distribution of heat flux, this work seeks to support the development of thermal management systems for long duration firing of detonation-based devices.

Matthew A Maybee

Hypersonic Jets of Detonation Products in the Hydrodynamic Collapse of Macroscopic Voids

Localizing the energetic output from detonation waves has been a long-standing challenge in applied detonation physics. Here, energy localization is achieved via machined millimeter scale voids in pressed samples of PBX 9501, an HMX (1,3,5,7-Tetranitro-1,3,5,7-tetrazocane)-based plastic bonded explosive. A main mechanism of energy localization in these systems, the formation of hydrodynamic jets of dense product gases, is characterized experimentally using a semicylindrical geometry in witness plate impact experiments and streak imaging of the jet propagating into the air. The distance at which the jet is optimally developed is identified and the supersonic flow structure in the vicinity of this feature is explored using hydrocode simulations. This analysis found that most of the kinetic energy of the hydrodynamic jet arises from pressure gradients induced by geometrically mediated squeeze flow lateral to the direction of detonation propagation. This work presents a new development in the control of energetic output from detonation waves and applications to detonation wave shaping are discussed.

42 ENGINEERING

Detonation Waves in High Explosives

A material at high temperature can react or decompose. For an energetic material, the reaction is exothermic and releases chemical energy that would further increase the temperature. Under some circumstances, when a reaction is triggered, such a reaction can propagate and the material rapidly releases a large amount of energy giving rise to an explosion. Examples of such materials are aerosols, suspensions of solid particles or liquid droplets in a gas; such as coal dust, grain dust and fuel-air explosions. Frequently, explosions are due to accidents. A spectacularly destructive example is the recent explosion of a large quantity of ammonium nitrate (thousands of tons) in Beirut, Lebanon (August 2020); see for example Beirut explosion. Ammonium nitrate is used as a fertilizer. It and the aerosols are not considered to be explosives due to the limited conditions for which an explosion can occur. An aerosol gets the oxidizer from the surrounding air. Burning requires diffusion of the oxidizer to the particle surface where the reaction occurs. A large density of small particles is required for a fast enough reaction to support an explosion. In contrast, an explosive is an energetic material with both fuel and oxidizer mixed on a molecular scale (either premixed gases or within molecules of a solid). This allows fast enough reactions over a wide range of conditions to support a self-propagating reactive wave known as a detonation wave. A detonation wave can be controlled and an explosive used for useful purposes such as in mining, construction, demolition, explosive welding, argon flash lamp, pulsed power using a magnetic flux generator [see also Goforth et al., 2015], jet cutter with shaped charge, explosive art, and generating conditions to study the response of materials at high strain rates and high pressures [see for example, Marsh, 1980]. Explosives are also used in conventional munitions and nuclear weapons. The focus of this book is on the theory and phenomenology of solid high explosives (HEs); in particular, plastic-bonded explosives (PBXs). Some aspects of detonation wave theory are needed to interpret explosive data. Hence, the theory is presented before the detonation wave phenomenology. A familiarity with fluid flow, specifically the notion of shock waves and the shock loci are assumed. In the remainder of this chapter we give a brief overview on the basic properties of detonation waves and PBXs.

36 MATERIALS SCIENCE

On the theory of the propagation of detonation in gaseous systems

The existing theory of detonation is critically examined. It is shown that the considerations with which the steady value of the velocity of detonation is chosen are not convincing. In connection with the problem of the process of the chemical reaction in a detonation wave, the objections raised against the conceptions of Le Chatelier and Vieille of the 19th century with regard to the ignition of the gas by the shock wave are refuted. On the basis of this concept, it is possible to give a rigorous foundation for the existing method of computing the detonation velocity. The distributions of the temperature, the pressure, and the velocity in the detonation wave front as the chemical reaction proceeds, are considered. On the assumption of the absence of losses, the pure compression of the gas in the shock wave at the start of the chemical reaction develops a temperature that is near the temperature of combustion of the given mixture at constant pressure.

THEORIES - DETONATION WAVES

Design and Operability of a Variably Premixed Rotating Detonation Engine for the Evaluation of Mixing Effects

The design of a variably premixed rotating detonation engine (RDE) is presented with preliminary experimental results. Premixed operation decouples the mixing process from the detonation cycle, enabling direct comparison with premixed simulations. A porous medium, formed into a ring of 6.45 mm radial thickness, serves as the premixture injector, arresting potential flash-back events. Two chamber geometries are tested, the first aimed at eliminating recirculation zones and comprised of a 7.62 mm wide channel, the width of which the porous injector occupies 85%. The second chamber geometry features a 10.7 mm channel width and a 3.08 mm wide backward-facing step on the internal diameter of the premixture injector. Transverse optical access is incorporated into the design using a transparent outer body. Tests were conducted at mixing conditions ranging from non-premixed to fully premixed with gaseous hydrogen and air reactants in the narrow-channel configuration. Engine operating modes and detonation wave speeds were characterized using aft-end high-speed chemiluminescence imaging, while detonation wave topology and heat release in the refill zone are captured by transverse imaging. A two-wave counterpropagating mode was most commonly observed in the narrow-channel configuration with wave speeds ranging from 49-67% of the theoretical Chapman-Jouguet (CJ) velocity. Fully premixed operation in the backward-facing step configuration rendered wave speeds up to 86% of CJ velocity, consistent with previous non-premixed results using the same channel width and a backward-facing step. These results demonstrate successful premixed RDE operation with high wave speeds and highlight the role of product recirculation zones in stabilizing the detonation cycle.

detonation

Computational Assessment of Inlet Backflow Effects on Rotating Detonation Engine Performance and Operability

The performance impact of flow reversal at the inlet of an airbreathing rotating detonation engine (RDE) is investigated using 2 and 3-dimensional computational fluid dynamic (CFD) simulations. Flow reversal, or backflow, occurs in RDE inlets in the high-pressure region directly behind the rotating detonation front. This is also where most of the engine thrust or pressure gain is produced. The amount of backflow relative to throughflow depends on the inlet design. For the present work, a simple annular ‘slit’ design is used. The simulations are idealized in several ways, including that fuel and air are premixed, but prevented from reacting when within the inlet region. The results indicate that even with idealizations, the impact of inlet backflow on pressure gain can be substantial. The simulations also reveal an intriguing instability that develops in certain configurations. The mass flow rate into the RDE begins to oscillate at a regular frequency that is substantially less than the detonation rotational frequency. This is accompanied by oscillations in the detonation height. The oscillation amplitude grows over time until the detonation ultimately fails. Both the performance and instability results emphasize the need for carefully designed RDE inlets that provide low loss when flow is in the forward direction, but high resistance when the flow is reversed. Development of such high-diodicity inlets is critical to achieving pressure gain in airbreathing RDE’s.

Detonation

Computational Assessment of Inlet Backflow Effects on Rotating Detonation Engine Performance and Operability

The performance impact of flow reversal at the inlet of an airbreathing rotating detonation engine (RDE) is investigated using 2 and 3-dimensional computational fluid dynamic (CFD) simulations. Flow reversal, or backflow, occurs in RDE inlets in the high-pressure region directly behind the rotating detonation front. This is also where most of the engine thrust or pressure gain is produced. The amount of backflow relative to throughflow depends on the inlet design. For the present work, a simple annular ‘slit’ design is used. The simulations are idealized in several ways, including that fuel and air are premixed, but prevented from reacting when within the inlet region. The results indicate that even with idealizations, the impact of inlet backflow on pressure gain can be substantial. The simulations also reveal an intriguing instability that develops in certain configurations. The mass flow rate into the RDE begins to oscillate at a regular frequency that is substantially less than the detonation rotational frequency. This is accompanied by oscillations in the detonation height. The oscillation amplitude grows over time until the detonation ultimately fails. Both the performance and instability results emphasize the need for carefully designed RDE inlets that provide low loss when flow is in the forward direction, but high resistance when the flow is reversed. Development of such high-diodicity inlets is critical to achieving pressure gain in airbreathing RDE’s.

detonation

Effect of Injection Dynamics on Wave Propagation in a Linear Detonation Combustor

Injector response to self-excited and sustained detonation wave propagation in an optically-accessible nonpremixed natural gas-oxygen linear detonation combustor is investigated. 100 kHz measurements of planar laser induced fluorescence (PLIF) of trace quantities of acetone injected into the fuel supply and simultaneous OH∗ chemiluminescence measurements were used to correlate the effect on injection dynamics on detonation wave structure and propagation. Measurements over a range of equivalence ratios (0.61-1.48) revealed wave propagation through regions of high fuel stratification in the axial and transverse direction of reactant injection. Consequently, the propagation of the detonation wave along the channel is through a flow-field with significant variation in fuel mass fraction, reactivity, and sound speeds. At lean conditions, wave propagation frequency is generally lower (∼6 kHz) resulting in longer time between wave passages for mixing and pre-heat resulting in steeper detonation wave-fronts anchored near the injector exit plane. Conversely, at rich equivalence ratios the wave frequency is higher (∼10 kHz) resulting in shorter intra-cycle period for reactant fill and mixing resulting waves lifted from the injection plane that are more compact. Higher chemiluminescence intensity in the post-wave region with deflagrative combustion is observed in these cases. Phase averaged representation of the acetone-PLIF measurements indicate that the fraction of time between wave passages available for reactant fill, mixing and pre-heat is consistent across all equivalence ratios.

Propulsion

Characterization of Reactant Refill and Detonation Wave Dynamics in a GOx/Natural-gas RDRE Using Simultaneous High Repetition-Rate OH-PLIF and Chemiluminescence

The potential application of rotating detonation engines (RDEs) in rocket combustors hinges on a fundamental understanding of detonation wave structure and injector characteristics with fuel and oxidizer compositions relevant in rocket systems. Simultaneous 300 kHz-rate broadband OH* chemiluminescence and OH-PLIF imaging is employed in a fully optically accessible Natural Gas-GOx rotating detonation rocket engine (RDRE) to visualize reactant refill dynamics and detonation wave structure. A custom-built KTP-type optical parametric oscillator (OPO) is coupled with a nanosecond high-repetition-rate burst-mode laser to output284 nm light and target excitation of the Q1(9) transition in the OH radical. Significant deflagrative burning is observed throughout the chamber as a consequence of the oxygen-rich environment. Trailing Azimuthal Reflected Shock Combustion (ARSC) system, similar to those in a H2-air RDE are observed, burning unburned reactants in the region immediately following the primary detonation wave. Contact burning, as indicated in this study, does not seem to be a primary loss mechanism. The simultaneous measurement of OH and OH* show that axial locations exist in the refill process where OH radicals are present, and produced due to shear layer induced deflagration, however, these zones do not produce excited state OH*. While a deeper understanding of the underlying physics in RDRE systems requires further investigation, this work highlights a first-of-its-kind visualization of the turbulent combustion product field and reactant refill characteristics in this highly unsteady environment.

Propulsion

Effect of a collapsing gas bubble on the shock-to-detonation transition in liquid nitromethane

We studied the shock-induced collapse of butane gas bubbles in the homogeneous explosive nitromethane (NM) to investigate the effects of hot spot formation on the detonation process. A butane bubble was injected into a sample of NM, and a shock wave from a flat plate impactor compressed the bubble, creating a localized hot spot. We measured shock and detonation wave speeds with optical velocimetry, and we used a high-speed camera to image the shock propagation and bubble collapse processes. A multiband optical fiber pyrometer measured the time-resolved thermal radiance, and we used the results and emissivity values extracted from spectral fits to estimate temperatures. We measured the characteristics of the shock-to-detonation transition in NM with and without a bubble. All experiments were performed at shock pressures near 8 GPa, where neat NM can detonate. A single bubble in this system was shown to sensitize NM, leading to a reduced run-to-detonation time. We used hydrodynamic modeling to predict shock wave propagation, the extent of chemical reaction, and subsequent temperature rise from the collapsing bubble. We used a temperature-dependent Arrhenius burn model for simulations, and it yielded much better results than reactive burn models that depend only on pressure and density.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND