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NASA NTRS2007

Clay Bearing Units in the Region around Mawrth Vallis: Stratigraphy, Extent, and Possible Alteration Fronts

The largest exposure of phyllosilicates on Mars occurs on the highland plains around Mawrth Vallis. This exposure extends for about 300 km southward from the edge of the dichotomy boundary, covering an area greater than 200 x 300 kilometers over an elevation range of approximately 2000 meters. At least two different types of hydrated phyllosilicates (Fe/Mg-rich and Al-rich phyllosilicates) have been identified in OMEGA data based on absorption bands near 2.3 and 2.2 micrometers, respectively. These clay-bearing units are associated with layered, indurated light-toned units with complex spatial and stratigraphic relationships, and are unconfomably overlain by a darker, indurated, more heavily cratered unit. Ongoing analysis of OMEGA (approximately 1 kilometer/pixel) and CRISM multi-spectral (MSP, 200 meters/pixel) data reveal hydrated minerals with absorptions at approximately 2.2 or 2.3 micrometers in locations up to 300 kilometers away from the borders of the previously identified extent of clay-bearing units. We seek to: 1) further constrain the mineralogy of the hydrated species identified in [5], and 2) understand spatial and stratigraphic relationships between the different hydrated minerals and the cratered plains units in which they are found. In this work we perform mineralogical and stratigraphic comparisons between units to test whether these extended units may be related, in order to establish a broad zone of alteration.

Dobrea, E. Z. Noe↗

NASA NTRS1981

Methodology of the interpretation of remote sensing data and applications in geology

Methods used for interpreting orbital (LANDSAT) data for regional geological mapping in Brazil are examined. Particular attention is given to the levels of analysis used for studying geomorphology, structural geology, lithology, stratigraphy, surface geology, and dynamic processes. Examples of regional mapping described include: (1) rock intrusions in SE Sao Paulo, the southern parts of Minas Gerais, and the states of Rio de Janeiro, and Espiritu Santo; (2) a preliminary survey of Pre-Cambrian geology in the State of Piaui; and (3) the Gondwana Project - surveying Jaguaribe plants. Mineral exploration in Rio Grande do Sul, and the geology of the Alcalino complex of Itatiaia are discussed as well as the use of automatic classifications of rock intrusions and of ilmenite deposits in the Floresta Region. Aerial photography, side looking radar, and thermal infrared scanning are other types of remote sensors also used in prospecting for geothermal anomalies in the city of Caldas Novas-Goias.

Dejesusparada, N.↗

NASA NTRS2016

Mineralogical and Geochemical Trends in a Fluviolacustrine Sequence in Gale Crater, Mars

The Mars Science Laboratory rover, Curiosity, landed at Gale crater in August 2012 and has been investigating a sequence of dominantly fluviolacustrine sediments deposited 3.6-3.2 billion years ago. Curiosity collects quantitative mineralogical data with the CheMin XRD/XRF instrument and quantitative chemical data with the APXS and ChemCam instruments. These datasets show stratigraphic mineralogical and geochemical variability that suggest a complex aqueous history. The Murray Formation, primarily composed of fine-laminated mudstone, has been studied in detail since the arrival at the Pahrump Hills in September 2014. CheMin data from four samples show variable amounts of iron oxides, phyllosilicates, sulfates, amorphous and crystalline silica, and mafic silicate minerals. Geochemical data throughout the section show that there is significant variability in Zn, Ni, and Mn concentrations. Mineralogical and geochemical trends with stratigraphy suggest one of possibly several aqueous episodes involved alteration in an open system under acidic pH, though other working hypotheses may explain these and other trends. Data from the Murray Formation contrast with those collected from the Sheepbed mudstone located approximately 60 meters below the base of the Murray Formation, which showed evidence for diagenesis in a closed system at circumneutral pH. Ca-sulfates filled late-stage veins in both mudstones.

Rampe, E.↗

NASA NTRS1997

Visual-Stratigraphic Dating of the GISP2 Ice Core: Basis, Reproducibility, and Application

Annual layers are visible in the Greenland Ice Sheet Project 2 ice core from central Greenland, allowing rapid dating of the core. Changes in bubble and grain structure caused by near-surface, primarily summertime formation of hoar complexes provide the main visible annual marker in the Holocene, and changes in "cloudiness" of the ice correlated with dustiness mark Wisconsinan annual cycles; both markers are evident and have been intercalibrated in early Holocene ice. Layer counts are reproducible between different workers and for one worker at different times, with 1% error over century-length times in the Holocene. Reproducibility is typically 5% in Wisconsinan ice-age ice and decreases with increasing age and depth. Cumulative ages from visible stratigraphy are not significantly different from independent ages of prominent events for ice older than the historical record and younger than approximately 50,000 years. Visible observations are not greatly degraded by "brittle ice" or many other core-quality problems, allowing construction of long, consistently sampled time series. High accuracy requires careful study of the core by dedicated observers.

Alley, R. B.↗

NASA NTRSDate not supplied

Experimental Impacts into Strength-Layered Targets: Ejecta Kinematics and Crater Morphometry

Impact craters can serve as probes of the subsurface structure of a planetary body and provide hints about a target's properties. Crater morphology, for example, can be used to estimate the thickness of a regolith layer above a more competent unit. Small lunar craters in the maria show a morphological progression from a simple bowl shape to flat-floored and concentric as crater diameter increases for a given regolith thickness. The final shape is a result of the subsurface flow-field initiated as the projectile transfers its energy and momentum to the target surface. In strength-layered targets, such as the lunar maria, the substrate modifies the flow field and thereby the excavation of the crater. Here we report on a series of experimental impacts into targets composed of a layer of loose sand above a stronger substrate. As we varied the sand's thickness, we imaged individual ejecta trajectories as the craters grew, from which we derived ejection-speed scaling relationships. In addition, we used a 3D scanner to construct topographic maps of the substrate, pre-impact target, and post-impact surface. This permitted us to examine the final craters' morphologies and morphometries with respect to the original stratigraphy of the target. As expected, craters became shallower and smaller as the sand's thickness decreased, transitioning from bowl-shaped to concentric as observed on the Moon. Subtle and important details show that the stronger substrate affected the subsurface flow-field by redirecting material upward and outward even when the interface was still well below the final crater's floor. Compared to the control target (loose sand only), the stronger substrate below the sand layer resulted in a much more complex pattern of ejecta. While most of the ejected material was still contained within a typical outward-moving curtain, a number of ejected particles moved along low-speed, high-angle (near 90°) trajectories. The number of these high-angle trajectories increased as the sand layer thinned, perhaps implying that self-secondary cratering would require the presence of a strong subsurface layer below the impact site. Such results refine our understanding of crater excavation in layered targets with implications for ejecta deposits and final crater shapes observed on the Moon.

Jennifer L B Anderson↗

NASA NTRS2004

Ancient Giant Basin/Aquifer System in the Arabia Region, Mars

Ancient geologic/hydrologic phenomena on Mars observed through the magnetic data [1,2] provide windows to the ancient past through the younger Argyre and Hellas impacts [e.g., 3,4], the northern plains basement [5], and the Tharsis and Elysium magmatic complexes (recently referred to as superplumes [6,7]). These signatures, coupled with highly degraded macrostructures (tectonic features that are tens to thousands of km-long [8]), reflect an energetic planet during its embryonic development (.5 Ga or so of activity) with an active dynamo and magnetosphere [1,2,6]. One such window into the ancient past occurs northwest of the Hellas impact basin in Arabia Terra. Arabia Terra is one of the few water-rich equatorial regions of Mars, as indicated through impact crater [9] and elemental [10,11] information. This region records many unique traits, including stratigraphy, topography, cratering record, structural character, geomorphology, and geophysical, elemental, albedo, and thermal inertia signatures. We interpret these to collectively indicate a possible ancient giant impact basin that later became an important aquifer, as it provided yet another source of water for the formation of putative water bodies that occupied the northern plains [12,13] and addresses possible water-related characteristics that may be observed at the Opportunity landing site. This basin is antipodal to Tharsis and estimated to be at least 3,000 km in diameter.

Dohm, James M.↗

NASA NTRS2007

Space Plasma Ion Processing of the Lunar Soil: Modeling of Radiation-Damaged Rim Widths on Lunar Grains

Chemically and microstructurally complex altered rims around grains in the finest size fraction (<20 micron) of the lunar regolith are the result of multi-stage processes involving both solar ion radiation damage and nanoscale deposition of impact or sputter-derived vapors. The formation of the rims is an important part of the space weathering process, and is closely linked to key changes in optical reflectance and other bulk properties of the lunar surface. Recent application of field-emission scanning transmission electron microscope techniques, including energy dispersive X-ray spectral imaging, is making it easier to unravel the "nano-stratigraphy" of grain rims, and to delineate the portions of rims that represent Radiation-Amorphized (RA) host grain from overlying amorphous material that represents vapor/sputter deposits. For the portion of rims formed by host grain amorphization (henceforth called RA rims), we have been investigating the feasibility of using Monte Carlo-type ion-atom collision models, combined with experimental ion irradiation data, to derive predictive numerical models linking the width of RA rims to the grain s integrated solar ion radiation exposure time.

Chamberlin, S.↗

NASA NTRS1995

Integrated approaches to terminal Proterozoic stratigraphy: an example from the Olenek Uplift, northeastern Siberia

In the Olenek Uplift of northeastern Siberia, the Khorbusuonka Group and overlying Kessyusa and Erkeket formations preserve a significant record of terminal Proterozoic and basal Cambrian Earth history. A composite section more than 350 m thick is reconstructed from numerous exposures along the Khorbusuonka River. The Khorbusuonka Group comprises three principal sedimentary sequences: peritidal dolomites of the Mastakh Formation, which are bounded above and below by red beds; the Khatyspyt and most of the overlying Turkut formations, which shallow upward from relatively deep-water carbonaceous micrites to cross-bedded dolomitic grainstones and stromatolites; and a thin upper Turkut sequence bounded by karst surfaces. The overlying Kessyusa Formation is bounded above and below by erosional surfaces and contains additional parasequence boundaries internally. Ediacaran metazoans, simple trace fossils, and vendotaenids occur in the Khatyspyt Formation; small shelly fossils, more complex trace fossils, and acritarchs all appear near the base of the Kessyusa Formation and diversify upward. The carbon-isotopic composition of carbonates varies stratigraphically in a pattern comparable to that determined for other terminal Proterozoic and basal Cambrian successions. In concert, litho-, bio-, and chemostratigraphic data indicate the importance of the Khorbusuonka Group in the global correlation of terminal Proterozoic sedimentary rocks. Stratigraphic data and a recently determined radiometric date on basal Kessyusa volcanic breccias further underscore the significance of the Olenek region in investigations of the Proterozoic-cambrian boundary.

Non-NASA Center↗

NASA NTRS1991

Interactions of tectonic, igneous, and hydraulic processes in the North Tharsis Region of Mars

Recent work on the north Tharsis of Mars has revealed a complex geologic history involving volcanism, tectonism, flooding, and mass wasting. Our detailed photogeologic analysis of this region found many previously unreported volcanic vents, volcaniclastic flows, irregular cracks, and minor pit chains; additional evidence that volcanic tectonic processes dominated this region throughout Martian geologic time; and the local involvement of these processes with surface and near surface water. Also, photoclinometric profiles were obtained within the region of troughs, simple grabens, and pit chains, as well as average spacings of pits along pit chains. These data were used together with techniques to estimate depths of crustal mechanical discontinuities that may have controlled the development of these features. In turn, such discontinuities may be controlled by stratigraphy, presence of water or ice, or chemical cementation.

Davis, P. A.↗

NASA NTRS1992

Sudbury project (University of Muenster-Ontario Geological Survey): Summary of results - an updated impact model

In 1984 the Ontario Geological Survey initiated a research project on the Sudbury structure (SS) in cooperation with the University of Muenster. The project included field mapping (1984-1989) and petrographic, chemical, and isotope analyses of the major stratigraphic units of the SS. Four diploma theses and four doctoral theses were performed during the project (1984-1992). Specific results of the various investigations are reported. Selected areas of the SS were mapped and sampled: Footwall rocks; Footwall breccia and parts of the sublayer and lower section of the Sudbury Igneous Complex (SIC); Onaping Formation and the upper section of the SIC; and Sudbury breccia and adjacent Footwall rocks along extended profiles up to 55 km from the SIC. All these stratigraphic units of the SS were studied in substantial detail by previous workers. The most important characteristic of the previous research is that it was based either on a volcanic model or on a mixed volcanic-impact model for the origin of the SS. The present project was clearly directed toward a test of the impact origin of the SS without invoking an endogenic component. In general, our results confirm the most widely accepted stratigraphic division of the SS. However, our interpretation of some of the major stratigraphic units is different from most views expressed. The stratigraphy of the SS and its new interpretation is given as a basis for discussion.

Avermann, M.↗

NASA NTRS1999

Martian Polar Impact Craters: A Preliminary Assessment Using Mars Orbiter Laser Altimeter (MOLA)

Our knowledge of the age of the layered polar deposits and their activity in the volatile cycling and climate history of Mars is based to a large extent on their apparent ages as determined from crater counts. Interpretation of the polar stratigraphy (in terms of climate change) is complicated by reported differences in the ages of the northern and southern layered deposits. The north polar residual ice deposits are thought to be relatively young, based on the reported lack of any fresh impact craters in Viking Orbiter Images. Herkenhoff et al., report no craters at all on the North polar layered deposits or ice cap, and placed an upper bound on the surface age (or, alternatively, the vertical resurfacing rate) of 100 thousand years to 10 million years, suggesting that the north polar region is an active resurfacing site. In contrast, the southern polar region was found to have at least 15 impact craters in the layered deposits and cap. Plaut et al, concluded that the surface was less than or = 120 million years old. This reported age difference factor of 100 to 1000 increases complexity in climate and volatile modeling. Recent MOLA results for the topography of the northern polar cap document a handful or more of possible craters, which could result in revised age or resurfacing estimates for the northern cap. This study is a preliminary look at putative craters in both polar caps. Additional information is contained in the original extended abstract.

Sakimoto, S. E. H.↗

NASA NTRS1987

The composition and history of breccia 67015 from North Ray Crater

Feldspathic fragmental breccia (FFB) 67015 from the rim of North Ray Crater was examined and was found to be the most diverse and complex of the Apollo 16 FFBs. It contains a wider range of clast types than any of the others and is not dominated by any single lithology. Several crystalline lithologies, occurring in minor amounts, were identified that represent highland plutonic rocks. Plagioclase fragments are the most abundant breccia constituent, followed by clasts of impact melt rocks and granulites. The impact melts are of two main types: feldspathic fragment-laden melts and mafic, KREEPy melt rocks of VHA basalt composition. Textural evidence indicates that some of the VHA melts were hot and plastic when they accumulated into the breccia. Ar-40 - Ar-39 dates show that both types of melts solidified about 3.9 x 10 to the 9th years ago. Magnetic measurements on clasts show a scatter of NMR directions, making it impossible to read a consistent imprint of an ancient dipolar magnetic field. Previous studies of Apollo 16 stratigraphy suggested that KREEPy melt rocks were introduced to the site as Imbrium impact ejecta, about 3.8 million years ago. Present results indicate that the highlands crust contained KREEP components as early as 3.9 x 10 to the 9th years ago.

Marvin, Ursula B.↗

NASA NTRS2014

Development of a Linear Ion Trap Mass Spectrometer (LITMS) Investigation for Future Planetary Surface Missions

Future surface missions to Mars and other planetary bodies will benefit from continued advances in miniature sensor and sample handling technologies that enable high-performance chemical analyses of natural samples. Fine-scale (approx.1 mm and below) analyses of rock surfaces and interiors, such as exposed on a drill core, will permit (1) the detection of habitability markers including complex organics in association with their original depositional environment, and (2) the characterization of successive layers and gradients that can reveal the time-evolution of those environments. In particular, if broad-based and highly-sensitive mass spectrometry techniques could be brought to such scales, the resulting planetary science capability would be truly powerful. The Linear Ion Trap Mass Spectrometer (LITMS) investigation is designed to conduct fine-scale organic and inorganic analyses of short (approx.5-10 cm) rock cores such as could be acquired by a planetary lander or rover arm-based drill. LITMS combines both pyrolysis/gas chromatograph mass spectrometry (GCMS) of sub-sampled core fines, and laser desorption mass spectrometry (LDMS) of the intact core surface, using a common mass analyzer, enhanced from the design used in the Mars Organic Molecule Analyzer (MOMA) instrument on the 2018 ExoMars rover. LITMS additionally features developments based on the Sample Analysis at Mars (SAM) investigation on MSL and recent NASA-funded prototype efforts in laser mass spectrometry, pyrolysis, and precision subsampling. LITMS brings these combined capabilities to achieve its four measurement objectives: (1) Organics: Broad Survey Detect organic molecules over a wide range of molecular weight, volatility, electronegativity, concentration, and host mineralogy. (2) Organic: Molecular Structure Characterize internal molecular structure to identify individual compounds, and reveal functionalization and processing. (3) Inorganic Host Environment Assess the local chemical/mineralogical makeup of organic host phases to help determine deposition and preservation factors. (4) Chemical Stratigraphy Analyze the fine spatial distribution and variation of key species with depth.

Mars↗

NASA NTRSDate not supplied

Acid Alteration of Clay Minerals With Implication for Mars’ Surface Processes

The co-occurrence of phyllosilicates (clays) and sulfate stratigraphies at many locations on Mars are associated with a sharp change in surface conditions from neutral/alkaline pH during the Noachian (4.1-3.7 Ga) which favored the formation of clays to acidic conditions during the Hesperian (3.7-2.9 Ga) which favored the formation of sulfates. Yet, if these two contrasting geosystems were temporarily sequential, it is unknown how the Hesperian acidic conditions altered the previously formed clay units. We performed laboratory batch experiments to fingerprint the diagnostic features produced during interactions of Mars-analog clays and acidic solutions. Two clays, and silicon (IV) oxide, were reacted with solution of either sulfuric acid or filtered natural acid rock drainage (ARD) in plastic bottles. The solutions were adjusted at four pH values (1, 3, 5, and 7) and reacted at 4, 30, and 80°C for 3, 7, and 14 days. At the end of the experiments, the filtered supernatants were analyzed by ICP-MS while the solids were characterized by X-Ray Diffraction; Energy-Dispersive X-Ray Fluorescence analyses; Raman and Short-Wave Infrared spectroscopies and Scanning Electron Microscopy. Results show that the solution chemistry played a key role in the evolution of the clay-solution systems. In H2SO4 systems, the solution pH steadily increased due to partial clay dissolution with no secondary phase formation detected. Contrary, in the ARD systems, the pH decreased due to the ample presence of Fe which controlled both the reactivity of clays by the growth of protecting surface coatings and the solution pH by the precipitation of Fe nanophases; secondary phase detected included goethite, jarosite, gypsum, and siderite. These results indicate that, on Mars, the chemical interaction between clays and acidic solutions was complex and dependent on the solution chemistry. Acidic, sulfate-rich solutions have a high dissolution capacity and could have induced widespread clay disintegration. Notably, if Fe-rich ARD was involved, the clays on Mars could have remained stable during acidic Hesperian period due to formation of protective coatings. Comparison of our results with martian observations will be performed to determine how acidic conditions could potentially affect clays in sedimentary settings, including the Gale crater.

L. Lefticariu↗

NASA NTRS2018

Sample Return Systems for Extreme Environments (SaRSEE)

Sample return missions offer a greater science yield when compared to missions that only employ in situ experiments or remote sensing observations, since they allow the application of more complex technological and analytical methodologies in controlled terrestrial laboratories,that are both repeatable and can be independently verified. The successful return of extraterrestrial materials over the last four decades has contributed to our understanding of the solar system, but retrieval techniques have largely depended on the use of either soft-landing, or touch-and-go procedures that result in high V requirements, larger spacecraft mass ratios, and return yields typically limited to a few grams of surface materials that have experienced varying degrees of alteration from space weathering. Hard-landing methods using planetary penetrators offer an alternative for sample return that significantly reduce a mission's V and mass ratios,increase sample yields, and allow for the collection of subsurface materials, and lessons can be drawn from previous sample return missions. The following details progress in the design,development, and testing of penetrator/sampler technology capable of surviving subsonic and low, supersonic impact velocities (<700 m/s) that would enable the collection of geologic materials using tether technology to return the sample to a passing spacecraft. The testing of energy absorbing material for protecting the sample, design evolution and field testing of the penetrator, and dynamic modeling of tether behavior during sampling are discussed. It is shown through both modeling and field testing that penetrators at speeds between 300-600 m/s (~Mach 1-2) can penetrator into the ground to depths of 1-2 m with overall structural integrity attained.The first flight tests demonstrated the potential for survivability at these speeds. The second flight series demonstrated core sample collection with partial ejection of the sample return canister. The 3rd flight series demonstrated self-ejection of the sample return system fully intact and with the core retaining the full stratigraphy of the rock bed. The tether analysis shows that the forces on the tether during release and return of the sample to the main spacecraft are all at levels that can easily be handled by existing tether materials. The mass analysis of the requirements indicates that sample return form the asteroids could be handled with Discovery or New Frontier range of missions dependent on the number of samples to be returned to the Earth.

Winglee, R. M.↗

NASA NTRS2020

Mineralogy and Geochemistry of Sedimentary Rocks and Eolian Sediments in Gale Crater, Mars: A Review After Six Earth Years of Exploration with Curiosity

The Mars Science Laboratory Curiosity rover arrived at Mars in August 2012 with a primary goal of characterizing the habitability of ancient and modern environments. Curiosity was sent to Gale crater to study a sequence of ∼3.5 Ga old sedimentary rocks that, based on orbital visible and near- to short-wave infrared reflectance spectra, contain secondary minerals that suggest deposition and/or alteration in liquid water. The sedimentary sequence in the lower slopes of Mount Sharp in Gale crater preserves a dramatic shift on early Mars from a relatively warm and wet climate to a cold and dry climate, based on a transition from smectite-bearing strata to sulfate-bearing strata. The rover is equipped with instruments to examine the sedimentology and identify compositional changes in the stratigraphy. The Chemistry and Mineralogy (CheMin) instrument is one of two internal laboratories on Curiosity and includes a transmission X-ray diffractometer (XRD) and X-ray fluorescence (XRF) spectrometer. CheMin measures loose sediment samples scooped from the surface and drilled rock powders, and the XRD provides quantitative mineralogy to a detection limit of ∼1 wt.% for crystalline phases. Curiosity has traversed>20 km since landing and has primarily been exploring an ancient lake environment fed by streams and groundwater. Of the 19 drilled rock samples analyzed by CheMin as of sol 2300 (January 2019), 15 are from fluvio-lacustrine deposits that comprise the Bradbury and Murray formations. Most of these samples were drilled from units that did not have a clear mineralogical signature from orbit. Results from CheMin demonstrate an astounding diversity in the mineralogy of these rocks that signifies geochemical variations in source rocks, transportation mechanisms, and depositional and diagenetic fluids. Most detrital igneous minerals are basaltic, but the discovery in a few samples of abundant silicate minerals that usually crystallize from evolved magmas on Earth remains enigmatic. Trioctahedral smectite and magnetite at the base of the section may have formed from low-salinity pore waters with a circumneutral pH in lake sediments. A transition to dioctahedral smectite, hematite, and Ca-sulfate going up section suggests a change to more saline and oxidative aqueous conditions in the lake waters themselves and/or in diagenetic fluids. Perhaps one of the biggest mysteries revealed by CheMin is the high abundance of X-ray amorphous materials (15–73 wt.%) in all samples drilled or scooped to date. CheMin has analyzed three modern eolian sands, which have helped constrain sediment transport and mineral segregation across the active Bagnold Dune Field. Ancient eolian sandstones drilled from the Stimson formation differ from modern eolian sands in that they contain abundant magnetite but no olivine, suggesting that diagenetic processes led to the alteration of olivine to release Fe(II) and precipitate magnetite. Fracture-associated halos in the Stimson and the Murray formations are evidence for complex aqueous processes long after the streams and lakes vanished from Gale crater. The sedimentology and composition of the rocks analyzed by Curiosity demonstrate that habitable environments persisted intermittently on the surface or in the subsurface of Gale crater for perhaps more than a billion years.

E.B. Rampe↗