Impact of Conformality and Crystallinity for Ultrathin 4 nm Compact TiO 2 Layers in Perovskite Solar Cells
The rapid rise in power conversion efficiencies of lead-based perovskite solar cells (PSCs) has established their promise, motivating scale-up and commercialization. As a thin film solar cell, interfacial properties are key to the performance of PSCs; there is a need to further understand which properties are important to control. Here, the impact of the compact TiO 2 (com-TiO 2 ) film properties on the performance of mesoporous PSCs is studied. Com-TiO 2 layers are fabricated by spray pyrolysis as well as by atomic layer deposition (ALD), using ALD as a proof-of-concept method to achieve highly conformal films of precisely controlled thickness. The com-TiO 2 layers’ conformality and surface roughness are examined by microscopy techniques; their relative crystallinity is studied by grazing-incidence X-ray diffraction with a synchrotron source and an in situ annealing chamber; and completed devices are analyzed by J–V and impedance spectroscopy techniques. The results show that an ultraconformal comTiO 2 layer can be thinned to 4 nm and match the performance of a ≈50 nm spray-pyrolysis TiO 2 layer. This work concludes that film conformality is the primary consideration for creating a high-performing com-TiO 2 layer, overriding any effects of flm crystallinity—a fnding that can guide fabrication choices for the scale-up of PSCs.