Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Co-I”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3

Monolithic Integrated Radiation Sensor Using Stimulated Luminescence From Alumina

The project goal was to design and test a monolithic integrated device for radiation sensing, using optically stimulated luminescence (OSL) from Al2O3:C. The device would consist of GaN/InGaN-based components epitaxially grown on each side of a A12O3:C substrate. Radiation energy stored in the substrate would be stimulated by visible emission from a GaN light-emitting diode (LED) grown on one side of the device, and the OSL emission from the substrate (in the blue region of the spectrum) would be detected by the InGaN pi-n diode grown on the other side of the substrate. The primary application of the device would be in space radiation environments. Thus, two major research thrusts were launched during this project. Firstly, research at Oklahoma State University (Dr. Stephen W.S. McKeever and Dr. E.G. Yukihara) concentrated on characterization of the OSL properties of Al2O3:C in radiation fields typical of those experienced in low-Earth orbit. Secondly, research at the University of Washington (Co-Is, Dr. T.G. Stoebe and Dr. T. Chen) focused of device development and GaN/InGaN epitaxial growth. While progress in each line of research has been substantial, the ultimate goal (that of producing a working prototype device) has not yet been reached. We detail the research progress and identify outstanding issues in this paper.

McKeever, S. W. S.↗

Monitoring the Hazards of Silicic Volcanoes with Remote Sensing

This report details the final progress on the Solid Earth and Natural Hazards project: Monitoring of Hazards of Silicic Volcanoes with Remote Sensing (SENH99-0000-0159). The original award went to Arizona State University (ASU) with Dr. Jonathan Fink as the P.I. and Dr. Michael Ramsey as the Co-I. In May 2000, Dr. Ramsey left ASU to take a tenure-track faculty position at the University of Pittsburgh. The principle investigators and NASA Headquarters agreed to split the grant award at the HQ level and therefore avoid the double overhead charges that would arise from a university subcontract. The objectives of the science were divided, and coordinated yearly progress reports have been submitted from each University. This report details the final progress on work carried out at Arizona State. A report by Dr. Ramsey at the University of Pittsburgh has already been submitted. The work from both institutions is closely related and this report will reflect that connection.

Fink, Jonathan↗

Astrobiology at Arizona State University: An Overview of Accomplishments

During our five years as an NAI charter member, Arizona State University sponsored a broadly-based program of research and training in Astrobiology to address the origin, evolution and distribution of life in the Solar System. With such a large, diverse and active team, it is not possible in a reasonable space, to cover all details of progress made over the entire five years. The following paragraphs provide an overview update of the specific research areas pursued by the Arizona State University (ASU) Astrobiology team at the end of Year 5 and at the end of the 4 month and subsequent no cost month extensions. for a more detailed review, the reader is referred to the individual annual reports (and Executive Summaries) submitted to the NAI at the end of each of our five years of membership. Appended in electronic form is our complete publication record for all five years, plus a tabulation of undergraduates, graduate students and post-docs supported by our program during this time. The overarching theme of ASU s Astrobiology program was "Exploring the Living Universe: Studies of the Origin, Evolution and Distribution of Life in the Solar System". The NAi-funded research effort was organized under three basic sub- themes: 1. Origins of the Basic Building Blocks of Life. 2. Early Biosphere Evolution. and 3. Exploring for Life in the Solar System. These sub-theme areas were in turn, subdivided into Co-lead research modules. In the paragraphs that follow, accomplishments for individual research modules are briefly outlined, and the key participants presented in tabular form. As noted, publications for each module are appended in hard copy and digital formats, under the name(s) of lead co-Is.

Farmer, Jack↗

Retrieval and Validation of Cirrus Cloud Properties with the Far-Infrared Sensor for Cirrus (FIRSC) During CRYSTAL-FACE

This grant supported the principal investigator's analysis of data obtained during CRYSTAL-FACE by two submillimeter-wave radiometers: the Far-Infrared Sensor for Cirrus (FIRSC) and the Conical Scanning Submillimeter-wave Imaging Radiometer (CoSSIR). The PI led the overall FIRSC investigation, though Co-I Michael Vanek led the instrument component at NASA Langley. The overall CoSSIR investigation was led by James Wang at NASA Goddard, but the cirrus retrieval and validation was performed at the University of Colorado. The goal of this research was to demonstrate the submillimeter-wave cirrus cloud remote sensing technique, provide retrievals of ice water path (IWP) and median mass particle diameter (D(sub me)), and perform validation of the cirrus retrievals using other CRYSTAL-FACE datasets.

Evans, K. Franklin↗

Influence of Coronal Abundance Variations

The PI of this project was Jeff Scargle of NASA/Ames. Co-I's were Alma Connors of Eureka Scientific/Wellesley, and myself. Part of the work was subcontracted to Eureka Scientific via SAO, with Vinay Kashyap as PI. This project was originally assigned grant number NCC2-1206, and was later changed to NCC2-1350 for administrative reasons. The goal of the project was to obtain, derive, and develop statistical and data analysis tools that would be of use in the analyses of high-resolution, high-sensitivity data that are becoming available with new instruments. This is envisioned as a cross-disciplinary effort with a number of "collaborators" including some at SA0 (Aneta Siemiginowska, Peter Freeman) and at the Harvard Statistics department (David van Dyk, Rostislav Protassov, Xiao-li Meng, Epaminondas Sourlas, et al). We have developed a new tool to reliably measure the metallicities of thermal plasma. It is unfeasible to obtain high-resolution grating spectra for most stars, and one must make the best possible determination based on lower-resolution, CCD-type spectra. It has been noticed that most analyses of such spectra have resulted in measured metallicities that were significantly lower than when compared with analyses of high- resolution grating data where available (see, e.g., Brickhouse et al., 2000, ApJ 530,387). Such results have led to the proposal of the existence of so-called Metal Abundance Deficient, or "MAD" stars (e.g., Drake, J.J., 1996, Cool Stars 9, ASP Conf.Ser. 109, 203). We however find that much of these analyses may be systematically underestimating the metallicities, and using a newly developed method to correctly treat the low-counts regime at the high-energy tail of the stellar spectra (van Dyk et al. 2001, ApJ 548,224), have found that the metallicities of these stars are generally comparable to their photospheric values. The results were reported at the AAS (Sourlas, Yu, van Dyk, Kashyap, and Drake, 2000, BAAS 196, v32, #54.02), and at the conference on Statistical Challenges in Modem Astronomy (Sourlas, van Dyk, Kashyap, Drake, and Pease, 2003, SCMA 111, Eds. E.D.Feigelson, G.J.Babu, New York:Springer, p489-490). We also described the limitations of one of the most egregiously misused and misapplied statistical tests in astrophysical literature, the F-test for verifying model components (Protassov, van Dyk, Connors, Kashyap, and Siemiginowska, 2002, ApJ, 571,545). Indeed, a search through the ApJ archives turned up 170 papers in the 5 previous years that used the F-test explicitly in some form or the other, and with the vast majority of them not using it correctly! Indeed, looking at just 4 issues of the ApJ in 2001, we found 13 instances of its use, of which nine were demonstrably incorrect. Clearly, it is difficult to understate the importance of this issue. We also worked on speeding up Bayes Blocks and Sparse Bayes Blocks algorithms to make them more tractable for large searches. We also supported staistics students and postdocs in both explicit physics- model-based (spectra with tens of thousands of atomic lines) and "model-free" -- i.e. non-parametric or semi-parametric -- algorithms. Work on using more of the latter is just beginning; while using multi-scale methods for Poisson imaging has come to hition. In fact, "An Image Restoration Technique with Error Estimates", by D. Esch, A. Connors, M. Karovska, and D. van Dyk, was published by ApJ (Esch et a1.2004, ApJ, 610, 1213). The code has been delivered to M. Karovska for CXC; and is available for beta-testing upon request. The other large project we worked on was on the self-consistent modeling of logN-logs curves in the Poisson limit. logN-logs curves are a fundamental tool in the study of source populations, luminosity functions, and cosmological parameters. However, their determination is hampered by statistical effects such as the Eddington bias, incompleteness due to detection efficiency, faint source flux fluctuations, etc. We have develed a new and powerful method using the full Poisson machinery that allows us to model the logN-logs distribution of X-ray sources in a self-consistent manner. Because we properly account for all the above statistical effects, our modeling is valid over the full range of the data, and not just for strong sources, as is normally done. Using a Bayesian approach and modeling the fluxes with known functional forms such as simple or broken power-laws, and conditioning the expected photon counts on the fluxes, the background contamination, effective area, detector vignetting, and detection probability, we can delve deeply into the low counts regime and extend the usefulness of medium sensitivity surveys such as ChAMP by orders of magnitude. The built-in flexibility of the algorithm also allows a simultaneous analysis of multiple datasets. We have applied this analysis to a set a Chandra observations (Sourlas, Kashyap, Zezas, van Dyk, 2004, HEAD #8, #16.32)

Scargle, Jeffrey D.↗

Observations of Type I X-ray Bursts from GS 1826-238 with RXTE

The analysis of the XMM data is complete. Additional RXTE data were used to determine the underlying continuum of the XMM spectra. A few spectral lines (with low significance) are present in the XMM-Newton data of the Type I bursts of GS 1826-238. In spite of numerous efforts, we cannot identify these lines; perhaps they are not real. The bottom line is that we are unable to determine the gravitational redshift from the surface of the neutron star in GS 1826-238. A gravitational redshift was earlier reported using spectra of Type I bursts observed with XMM-Newton from EX0 0748-676 (Cottam et al., Nature). However, renewed observations by Cottam et al. of EX0 0748-676 with XMM-Newton do not confirm their earlier results. Our adopted Co-I Mario Mendez is presently working on a paper which finalizes our conclusions for GS 1826-238.

Lewin, Walter↗

Testing the Hypothesis of Young Martian Volcanism: Studies of the Tharsis Volcanoes and Adjacent Lava Plains

We experienced much success in reaching our stated goals in our original MDAP proposal. Our work made substantial contributions towards an integrated understanding of the counting and calibration of crater data on Mars, and changing nature of the Martian surface influenced by craters, water, and wind, and their general relationship to Martian geothermal history. We accomplished this while being to responsive to the rapid changes in the field brought about by several key NASA missions that returned data during the life of the grant. Our integrated effort included three stages: The first major area of research (Crater Count Research) was conducted by Jennifer Grier (P.I.), Lazslo Keszthelyi (Collaborator), William Hartmann (Collaborator), with assistance from Dan Berman (Graduate student) and concerned the mapping and the collection of crater count data on various Martian terrains. The second major area of study (Absolute Age Calibration) was conducted by William Bottke (Co-I) at SWRI, and concerned constraining the nature of the Moon and Mars impactor populations to create better absolute age calibrations for counted areas. The third major area of study was the integration and leverage of this effort with ongoing related Mars crater work at PSI (Integrated and Continuing Studies - Older Volcanoes), headed by David Crown (PSI Scientist), assisted by Les Bleamaster (PSI Scientist) and Dan Berman (Graduate Student).

Grier, Jennifer A.↗

Modelling the Neutral Atmosphere and Plasma Environment of Saturn

The first year of this contract has resulted in two publications with the P.I. and co-I Jurac as lead authors and two publications where these team members are co-authors. These papers discuss modeling work undertaken in preparation for Cassini; the goal was to summarize our current best knowledge of the ion and neutrals sources and distributions. One of the major goals of this project is to improve models of the plasma and neutral environment near Saturn. The paper "A self-consistent model of plasma and neutrals at Saturn: Neutral cloud morphology" [Jurac and Richardson, 20051 presents results on the neutral clouds near Saturn using a model which for the first times treats the ions and neutrals self-consistently. We also for the first time include a directly sputtered H source. The Voyager and HST observations are used as model constraints. The neutral source is adjusted to give a good match to the HST observations of OH. For this initial run the ion parameters from Richardson et al. are used; charge exchange with ions is a major neutral loss process. The neutral profile derived from the model is then used in a model of plasma transport and chemistry (with the plasma diffusion rate the only free parameter). This model gives new values of the ion composition which are then fed back into the neutral model. This iteration continues until the values converge.

Richardson, John D.↗

Discrete X-Ray Sources Between M81 and NGC3077

Analysis is now complete on the XMM-Newton and Chandra/HRC fields for the interaction region between M81 and NGC 3077. In addition, we have recently obtained ground-based optical data (KPNO 4-meter mosaic and CFHT 12K) for 2 regions of this field: one region near the edge of the D25 ellipse of M81 and a second region containing NGC 3077 and the furthest end of the HI bridge. Durrell et at. (private communication) find many young star clusters within the HI bridge, and we are in the process of performing the astrometric corrections to look for young stellar counterparts to the X-ray sources. We plan to present our results at the January 2006 AAS meeting in Washington, D.C., and are preparing a paper for submission to MNRAS in the near future with Co-Is M. Ward (U. Durham), T. Roberts (U. Leicester), A. Prestwich (CfA), A. Zezas (CfA), P. Durrell (Youngstown State), and Megan DeCesar (PSU).

Kilgard, Roy E.↗

Comments about "Earth 3.0"

Dr. Christopher P. McKay, Planetary Scientist with the Space Science Division of NASA Ames. Chris received his Ph.D. in AstroGeophysics from the University of Colorado in 1982 and has been a research scientist with the NASA Ames Research Center since that time. His current research focuses on the evolution of the solar system and the origin of life. He is also actively involved in planning for future Mars missions including human exploration. Chris been involved in research in Mars-like environments on Earth, traveling to the Antarctic dry valleys, Siberia, the Canadian Arctic, and the Atacama desert to study life in these Mars-like environments. His was a co-I on the Titan Huygen s probe in 2005, the Mars Phoenix lander mission for 2007, and the Mars Science Lander mission for 2009.

Dator, Jim↗

Phoenix - the First Mars Scout Mission

As the first of the new Mars Scouts missions, the Phoenix project was selected by NASA in August of 2003. Four years later, almost to the day, Phoenix was launched from Cape Canaveral Air Station and successfully injected into an interplanetary trajectory on its way to Mars. This paper will highlight some of the key changes since the 2006 IEEE paper of the same name, as well as activities, challenges and problems encountered on the way to the launch pad. Phoenix Follows the water responding directly to the recently published data from Dr. William Boynton, PI (and Phoenix co-I) of the Mars Odyssey Gamma Ray Spectrometer (GRS). GRS data indicate extremely large quantities of water ice (up to 50% by mass) within the upper 50 cm of the northern polar regolith. Phoenix will land within the north polar region at 68.2 N, 233.4 W identified by GRS to harbor near surface water ice and provide in-situ confirmation of this extraordinary find. Our mission will investigate water in all its phases, and will investigate the history of water as evidenced in the soil characteristics that will be carefully examined by the powerful suite of onboard instrumentation. Access to the critical subsurface region expected to contain this information is made possible by a third generation robotic arm capable of excavating the expected Martian regolith to a depth of 1m. Phoenix has four primary science objectives: 1) Determine the polar climate and weather, interaction with the surface, and composition of the lower atmosphere around 70 N for at least 90 sols focusing on water, ice, dust, noble gases, and CO2. Determine the atmospheric characteristics during descent through the atmosphere. 2) Characterize the geomorphology and active processes shaping the northern plains and the physical properties of the near surface regolith focusing on the role of water. 3) Determine the aqueous mineralogy and chemistry as well as the adsorbed gases and organic content of the regolith. Verify the Odyssey discovery of near-surface ice. 4) Characterize the history of water, ice, and the polar 1 1-4244-1488-1/08/$25.00 2008 IEEE 2 IEEEAC paper#1579, Version 1, Updated 2008:01:09 climate. Determine the past and present biological potential of the surface and subsurface environments.

Mars exploration↗

Liquid Water on Enceladus from Observations of Ammonia and Ar-40 in the Plume

Jets of water ice from surface fractures near the south pole of Saturn's icy moon Enceladus produce a plume of gas and particles. The source of the jets may be a liquid water region under the ice shell-as suggested most recently by the discovery of salts in E-ring particles derived from the plume-or warm ice that is heated, causing dissociation of clathrate hydrates. Here we report that ammonia is present in the plume, along with various organic compounds, deuterium and, very probably, Ar-40. The presence of ammonia provides strong evidence for the existence of at least some liquid water, given that temperatures in excess of 180 K have been measured near the fractures from which the jets emanate. We conclude, from the overall composition of the material, that the plume derives from both a liquid reservoir (or from ice that in recent geological time has been in contact with such a reservoir) as well as from degassing, volatile-charged ice. As part of a general comprehensive review of the midsize saturnian satellites at the conclusion of the prime Cassini mission, PI McKinnon and co-I Barr contributed to three review chapters.

Waite, J. H., Jr.↗

Put X-Ray Polarimetry on the MAP!

With Prof. R. Novick and others at the Columbia Astrophysics Laboratory I help found the field of X-ray polarimetry in the early 1970s. Currently I have more experience with the design, construction, calibration, and space flight of such instruments than anyone on the planet. The early probing beginnings saw only one definitive measurement (that of the integrated low-energy X-ray emission from the Crab Nebula sans pulsar) and a number of upper limits. The limited success did nevertheless inspire a number of detailed theoretical calculations, concentrating at first on neutron stars and black holes showing how precise measurements (e.g. degree of polarization and position angle as a function of pulse phase) would provide definitive limitations on otherwise equally plausible theoretical models. Over time the theoretical foundation has grown (e.g. the proceedings of the X-Ray Polarimetry Workshop held at SLAC in 2004). I will outline these foundations. It is important to understand the history of X-ray polarimetry beyond the early excitement. A polarimeter was at the focus of the original Einstein mission but was dropped during the restructuring. A polarimeter was successfully proposed (R. Novick PI, I was a Co-I) and built for the original Spectrum-X mission. During the years before the cancellation of Spectrum-X, the potential flight of this device stood in the way of other space flights for polarimeters --- "let us wait and see what it finds". This was unfortunate as there were a number of reasons why that polarimeter should not have been flown on the mission. Perhaps the most significant (but not only) reason was that a shared focal plane provided very little observing time. This is an extremely important point in considering the Roadmap. It is doubtful that there many 100%-polarized sources and so the "signal" is more typically a small fraction of the source flux. Thus, the source itself provides a substantial background, making continuum polarimetry even more difficult than narrow-line spectroscopy. X-ray polarimetry thus requires a dedicated mission that can, without programmatic pressures from other instruments/users, devote the integration time to perform meaningful measurements. The recently cancelled GEMS might have been such a mission. At least it was dedicated to polarimetry. Performing meaningful measurements is not going to be easy. In part because of the long hiatus and lack of experience, there appears to be too much pressure to "sell" polarimetry missions by the number of sources for which one might answer the simple question is, or is not, the integrated and time averaged emission from the source polarized at some confidence level? This was a fine question for the 1970 s but, I maintain, it is not today. One simply doesn't want to measure the time averaged polarization of the Crab s pulsar, but one wants to know the polarization as a function of energy and pulse phase to compare, e.g. to optical and radio measurements which divide even the primary pulse into dozens of phase bins. Such observations can distinguish amongst competing theories for the pulsed emission. The Roadmap should define what meaningful experiments are. I will pose some suggestions. Note that , because X-rays are usually believed originate in either non-thermal or highly aspherical situations we expect X-ray polarimetry to be much more important and rich in astrophysical information as opposed to the visible, where starlight often dominates the emission. One has often dreamt about an instrument that does polarimetry whilst it does other things, and I will discuss this. Even in this case, one needs to realize that the observing time will be driven by the polarimetry, otherwise no useful polarization measurements will be made. Finally, I will discuss some misconceptions that have appeared in the literature and at conferences which indicate to me that certain fundamental principles of polarimeter design and performance are not clearly understoodt is important for the Roadmap that we understand these principles and not advocate instruments that will not (or even worse cannot) accomplish the promised scientific return. I will discuss these principles.

Weisskopf, Martin C.↗

UASs Optimization - An evaluation of multiple mode vehicles in monitoring and communication

This presentation will describe the author's experience as Co-I in the NASA/USFS Project: "Strategic Tac Radio and Tac Overwatch (STRATO): Last Mile Communications and Realtime Observation Stratospheric Platforms for wildland fire". This project utilizes an uncrewed Stratospheric (> 70Kft) lighter than air Uninhabited Aerial System (UAS), carries 50 Kg of sensor and communications equipment, and remains on station over a wildfire for up to 30 days. The air vehicle is capable of in excess of 180 days on station, but while the full duration capabilities were not utilized in this project, they could, and would, be used in monitoring a feature like a volcano. In addition to duration, the ability of these Stratospheric Platforms to persistently monitor an area, while carrying "smart" sensors - generating information products, rather than just data - is game changing. Utilizing technologies such as LoRa, the platform can now be the nexus of an ad-hoc sensor web, receiving LoRa based data from low power in-situ sensors in the area being monitored, combining it with high fidelity information gained from on-board sensors, and sending the information product to a remote research facility, using Satellite communication, in real time. The author will relate the evolution of information collection, derivation and delivery mechanisms in the entire range of NASA's UAS fleet, to today's world, where information products conventionally derived in desk top computational environments, and made available to the Science Community in weeks or months, are now being generated and delivered in near real time.

UASs↗

NASA’s Student Airborne Science Activation for Minority Serving Institutions: Inaugural Program, Educational Outcomes, and Lessons Learned

The NASA Student Airborne Science Activation (SaSa) for Minority Serving Institutions (MSIs) held its inaugural summer research program for early career undergraduates interested in the Geosciences. SaSa is a NASA Science Activation funded 8-week summer internship program. Twenty-four first- and second-year undergraduates from MSIs across the U.S. participated in the summer program - June 6 to July 29, 2022. Students had the opportunity to gain hands-on research experience in all components of an airborne science campaign including flying on-board a NASA research aircraft to collect atmospheric measurements. Students conducted independent research projects related to the atmosphere, ocean, and geosciences that feed into NASA’s broader Earth Science Division’s and Decadal Survey goals using air quality, meteorological, and oceanic measurements from surface, airborne, and satellite-based observations. The program split its time between partner institution, University of Maryland Baltimore County and NASA’s Wallops Flight Facility in Wallops Island, Virginia. Students also made site visits at partner institutions, including: Hampton University, University of Maryland Eastern Shore, Morgan State University, Howard University, and Coppin State University and attended lectures from visiting faculty and NASA Subject Matter Experts. Students were guided on their research projects by near-peer graduate mentors, SaSa program leadership, co-Is at partner institutions, and NASA scientists to address two major research themes: 1) how human-caused air pollution has human and environmental implications, and 2) how large-scale meteorological factors influence local weather conditions. Students sorted into research groups, based on sub-discipline areas in the Geosciences, including: “Clouds, Aerosols and Radiation”, “Meteorology and Planetary Boundary Layer”, “Air Quality: Particle Pollution and Trace Gases”, and “Air-Water-Land Interface”. Their research was presented as 3-minute lightning talks and in-person poster presentations at a close-out event at NASA Goddard Space Flight Center in Greenbelt, Maryland. The students’ inter- and trans-disciplinary research experiences centered in the use of multiple ground, airborne, and satellite remote sensing NASA Earth Science Division assets. Providing a unique experience aligned to recognize the societal benefits that NASA contributes in the areas of resource management, air quality monitoring and policy decisions, energy and weather predictions, and research on the Earth’s climate. The SaSa program aims to increase the number of students from MSIs that identify as underrepresented or underserved individuals in the Geosciences discipline, Earth System Science graduate programs, and the NASA workforce. A summary of the summer research program, educational, scientific, and programmatic outcomes, as well as lessons learned will be presented.

NASA↗

DOE new players Carbon cycle (2016-2021)

The overarching scientific goals of our multidisciplinary grant was to further expand understanding about the key microorganisms (players), metabolic strategies (processes), and interspecies relationships (interactions) involved in the formation and oxidation of methane in the environment. This research applied novel environmental metagenomics, transcriptomics, and proteomic techniques, state-of-the-art analytical imaging, stable isotope geochemistry, and reaction-transport modeling to address these goals and develop an ‘ecosystems level’ understanding of the factors which regulate microbial methane cycling in anoxic sedimentary ecosystems. For decades, it was believed that the obligate step in methanogenesis catalyzed by methyl coenzyme M reductase (Mcr) was limited to a specific branch of the archaeal Domain, formerly known as the Euryarchaeota. Less than a decade ago co-I Tyson’s team published a surprising metagenomic-based discovery of divergent Mcr genes in a novel uncultured phylum (Bathyarchaeota), catalyzing a major shift in thinking about the diversity of microorganisms that encode the potential for methane (or higher alkane) metabolism in anoxic environments (Evans et al., 2015). In our work here, we further expand on the groups of archaea harboring the genomic potential for methane or hydrocarbon metabolism using environmental metagenomics and new gene targeted bioinformatics techniques. We additionally advanced understanding about the terminal electron acceptors and metabolic potential supporting the anaerobic oxidation of methane (AOM) in terrestrial ecosystems, specifically focused on new lineages of ANME archaea capable of respiring manganese oxides with methane presumably using large extracellular multi-heme cytochrome complexes. New details about specific syntrophic mechanisms underlying the exchange of electrons during sulfate-coupled methane oxidation between ANME-2 archaea and their sulfate-reducing bacterial partners were also elucidated as part of this funded project. Through a series of experimental ‘omics and single cell stable isotope probing studies with incubated environmental sediment samples and a cultured model electrogenic microorganism combined with model-based predictions. Combined, this work provides strong support for the hypothesis of direct interspecies electron transfer (DIET) is the dominant syntrophic mechanism controlling the anaerobic oxidation of methane with sulfate over other proposed mechanisms and additionally illustrates important spatial constraints and the underlying physico-chemical factors influencing AOM syntrophic consortia structure for DIET and extracellular metal respiration. This collaborative multi-institutional project successfully advanced several of our milestone goals including the identification of new microbial players containing methyl coenzyme M reductases hypothesized to be central to methane or hydrocarbon cycling in anoxic environments and enhancing fundamental knowledge about the role extracellular electron transfer plays in the ecophysiology of methanotrophic archaea respiring metal oxides and in the physical and metabolic structuring of syntrophic interactions in methane-rich sedimentary ecosystems.

03 NATURAL GAS↗

Materials Data on YCo2 by Materials Project

YCo2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Y is bonded in a 12-coordinate geometry to twelve equivalent Co atoms. All Y–Co bond lengths are 2.96 Å. Co is bonded to six equivalent Y and six equivalent Co atoms to form a mixture of edge, face, and corner-sharing CoY6Co6 cuboctahedra. All Co–Co bond lengths are 2.52 Å.

36 MATERIALS SCIENCE↗

Materials Data on YCo3 by Materials Project

YCo3 crystallizes in the trigonal R-3m space group. The structure is three-dimensional. there are two inequivalent Y sites. In the first Y site, Y is bonded in a 12-coordinate geometry to twelve Co atoms. There are a spread of Y–Co bond distances ranging from 2.88–3.10 Å. In the second Y site, Y is bonded in a 6-coordinate geometry to eighteen Co atoms. There are six shorter (2.88 Å) and twelve longer (3.18 Å) Y–Co bond lengths. There are three inequivalent Co sites. In the first Co site, Co is bonded to five Y and seven Co atoms to form a mixture of edge, face, and corner-sharing CoY5Co7 cuboctahedra. There are a spread of Co–Co bond distances ranging from 2.42–2.54 Å. In the second Co site, Co is bonded to six equivalent Y and six equivalent Co atoms to form CoY6Co6 cuboctahedra that share corners with twelve equivalent CoY5Co7 cuboctahedra, edges with six equivalent CoY6Co6 cuboctahedra, and faces with eighteen equivalent CoY5Co7 cuboctahedra. In the third Co site, Co is bonded in a 12-coordinate geometry to three equivalent Y and six equivalent Co atoms.

36 MATERIALS SCIENCE↗