SEARCH · Engineering Papers
Results for “Cleaned”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Oxygen Atom Transfer to a Half-Sandwich Iridium Complex: Clean Oxidation Yielding a Molecular Product
Explore the source record for details and available documents.
Renewable-integrated flexible carbon capture: a synergistic path forward to clean energy future
Integration of renewables-assisted carbon capture with existing fossil power plants is an economical grid decarbonization technique and renewable intermittency solution.
Clean vehicles as an enabler for a clean electricity grid
Not Available
How clean is clean: a review of the social science of environmental cleanups
Not Available
Accelerating Hydrogen Research in New York to Support Deployment of Clean Energy and Clean Industry
This project purchased equipment to advance hydrogen technology research at the University at Buffalo. The equipment is installed in laboratories in the Departments of Chemical and Biological Engineering (CBE) and Materials Design and Innovation (MDI) at the University at Buffalo (UB).
Sandia Participated in the 3rd Annual Technology Forum of the U.S.-China Clean Energy Research Center - Clean Vehicles Consortium (CERC-CVC).
Abstract not provided.
Enhancement of Optical Efficiency of CSP Mirrors for Reducing O&M Cost via Near-Continuous Operation of Self-Cleaning Electrodynamic Screens (EDS). Final Report
Over the past decade, techno-economical advancements in solar energy systems, particularly the improvement in the conversion efficiency of PV modules made with mono-crystalline silicon solar cells from 12% to 20%, as well as the cost reduction in manufacturing by a factor of about 10%, have made it possible to achieve a levelized cost of electricity (LCOE) in PV plants that is comparable to, or less than, the cost of deriving electricity from fossil fuels. Operating PV plants in mid-latitude sun-belt regions, where the solar irradiance level is highest, provides a high annual energy-yield (kWh/kWp) due to two factors: (1) the availability of predictable high solar irradiance throughout the year with the fewest interruptions in solar flux from clouds and rain, and (2) the increased conversion efficiency of crystalline solar cells, as recombination loss has decreased with increased intensity of the sunlight that illuminates the silicon solar cells. Semi-arid and desert regions, however, are plagued by high atmospheric dust concentrations and frequent sand storms. The deposition of a layer of dust on the optical surfaces of solar collectors such as PV modules and concentrating mirrors reduces the transmission efficiency of sunlight that actually reaches the solar cells or receivers, resulting in high energy-yield soiling loss. There are two major cost components to operating a solar plant: (1) installation costs, and (2) operation-and-maintenance (O&M) costs. There is no fuel cost; hence operating a solar plant in a semi-arid or desert region provides high returns on investment if soiling losses are mitigated via efficient cleaning methods and optimized cleaning frequency. If solar collectors are not cleaned, the accumulation of dust layers on solar collectors may cause the operation of such plants in arid regions to become economically unviable. Washing solar collectors with water and detergent, as is most commonly done now, is an efficient method for cleaning. The conventional approach in utility-scale solar plants is to use a large truck with a water tank and pump system for spraying deionized water on the surface of the solar collectors. Robotic cleaning with brushes, used for many solar plants, requires lesser water for cleaning. The water consumed using semi-automated cleaning of PV modules in utility-scale solar plants is approximately 2 liters/m 2 per cleaning cycle. The total optical surface area of the solar collectors in 1 TW-scale solar installation will be more than 3 × 109 m 2 ; hence an enormous amount of water be needed for cleaning. There simply is not enough fresh water in the sun-belt areas of the world for predicted cleaning needs. In solar power plants, the estimated cost of cleaning solar collectors includes expenses related to the equipment used, labor, cost of transportation of water, the energy required for cleaning, plus ancillary costs whereas the cost of water is not considered. The water used is obtained from sources located close to plant sites, unmindful of the environmental and societal impact as the power plants are oftentimes located in regions that face severe drought. This practice is very similar to the cost calculations in deriving the levelized cost of electricity (LCOE) in conventional power plants based on burning fossil fuel such as coal and gas, while disregarding the cost of climate change and health effects. Unless a water-free or low-water cleaning method is established, the expansion of solar plants may lose public support in areas suffering long intervals of drought. The goal of this research project has been the development and application of the Electrodynamic Screen (EDS) as a means for a water-free, scalable cleaning process applicable to solar-power installations, including rooftop applications. We describe here the development of an EDS film-based cleaning process as an emerging method for use on PV modules, parabolic troughs, and heliostats. This report aims to show the feasibility of integrating or retrofitting EDS films onto the optical surfaces of solar collectors (both PV and CSP) while maintaining high transmission or reflection efficiency. The cleaning action provided by the EDS film is an active method to remove dust deposits by electrodynamic force. Current lab-scale prototype EDS films, retrofitted onto solar panels and mirrors, have shown to be capable of maintaining optical transmission or specular-reflection efficiencies higher than 90% of initial values under clean conditions. The optical surfaces of solar collectors laminated with EDS films can remove more than 90% of deposited dust when the EDS is activated for less than two minutes. As an electrodynamic dust removal process, the EDS film-based method is designed primarily for the removal of dust in solar installations located in semi-arid and desert areas, where the atmosphere is often dry and dusty and rainfall is infrequent. While EDS film application minimizes water consumption and facilitates cleaning as frequently as needed, it has limitations in removing contaminants such as soot, organic pollutants deposited as fine films on the surface, and bird droppings. The dust removal efficiency of the EDS is maximum at relative humidity RH is 40 to 50% and decreases at when RH > 65%. Many solar plant sites undergo diurnal and seasonal cycles of high ambient, early afternoon temperatures and an RH that reaches the dew point early in the morning. These variations in atmospheric conditions do not limit the operation of the EDS film. This report presents a brief review of the progress and the potential of EDS film technology for mitigating the impact of dust on solar collectors via water-free cleaning, as well as current technical challenges regarding efficiency and durability. Our experimental data on the performance of EDS films show that: (1) the dust-removal efficiency (DRE) can reach levels higher than 90%, (2) the specular reflectivity (SR) of EDS film-laminated second-surface mirrors reach levels in excess of 90%, (3) the specular reflectivity restoration (SRR) can exceed 90%, (4) the output-power restoration (OPR) of PV modules can exceed 95%, and (5) the optical transmission efficiency (TE) of the EDS films can be greater than 90%. Working with Sandia National Laboratories (NM), Corning Research and Development Corporation (NY), Eastman Kodak (NY), Tomark-Worthen Industries (NH), and EDS Chile SPA (Chile), we have produced EDS film-laminated PV modules and demonstrated their self-cleaning functions without requiring water. We have demonstrated that the operational range of EDS films will cover the expected ambient temperature of solar fields at RH cycling varying from 20 to 95% as long as the EDS films are activated in the RH range 20 to 50%. (Typical solar-field climates in deserts and semi-arid lands often reach near dew point in coastal areas.) Our experiments on the application of hydrophobic-fluorinated nanoparticle coatings on EDS film surfaces show that the EDS operational range can be extended to higher RH levels that approach the dew point. At Eastman Kodak, as one of our industrial partners, we were able to establish a process for manufacturing EDS films using flexographic printing of the electrodes onto transparent polymer films. This process utilizes an existing manufacturing line at Eastman Kodak that allows fabrication of medium-scale EDS films (26 cm × 30 cm). The manufacturing process has the capacity to produce EDS films at high production speeds. The medium-scale EDS films that have been printed at Kodak were evaluated in the lab at Boston University. The EDS films produced at Kodak were laminated at Tomark-Worthen using an industrial scale vacuum laminator to produce EDS film stacks, which can be affixed onto the optical surfaces of PV modules or concentrating mirrors. The EDS film stack consists of the EDS films that have Willow® Glass (WG) which has a thickness of 100 μm as the front surface. The WG sheets obtained from Corning Research and Development Corporation are customized in size and shape to cover the active area of the EDS films. The back surface of the EDS film stack is integrated onto the optical surface of the solar panel or mirror using optically clear adhesive (OCA) films or silicone adhesives. The OCA films (thickness 25 μm) are produced by 3M. The EDS film stacks have the architecture: WG/OCA/EDS Film/OCA/ over PV module or solar mirror. The power-supply units needed for activating the electrodes of the EDS film were designed and produced at Boston University. These power supply units provide three-phase, 1.2 kV voltage pulses at a very low current (micro-ampere) level and at a low frequency (≈ 5 Hz). The voltage pulses are applied to the electrodes in a sequence such that the train of pulses resembles a unidirectional traveling wave of electrical field on the surface of the EDS film. The dust particles on the surface become charged electrostatically and are levitated by the Coulomb force. The lateral sweeping action of the traveling electric field created by the three-phase voltages pulses then sweeps the dust off the surface. The energy consumed by the EDS electrodes is less than 0.2 Wh/m 2 /cleaning cycle, enabling energy-efficient restoration of output power (OPR) of PV module or specular reflectivity restoration (SRR) for solar mirrors. The EDS system consists of (1) an EDS film stack laminated onto the solar collectors, (2) connection of the EDS film to its power supply unit and (3) Interconnection of the power supply to PV modules or solar mirrors. Design, construction and assessment of field-testing units that have EDS stack laminated PV modules for evaluating the performance of the EDS films in solar fields is being carried out at BU. Our progress under this project, aimed at the advancement of EDS film technology, has reached DOE Technology Readiness Level (TRL) 6. Based on the extensive laboratory evaluations and limited field trials, as well as contacts with potential users, we believe that the technology has reached its commercial stage. We are conducting a cost analysis using the National Renewable Energy Laboratory (NREL) System Advisory Model (SAM) and are preparing for field trials of EDS films in different solar fields in the US, Chile, India and in the Middle East. A brief description of EDS film performance, construction and testing of the field-test unit, autonomous operation of the field-test unit for evaluating EDS performance in increasing energy yield, associated revenue savings, and water conservation is presented.
Method and apparatus for inducing turbulent flow of a processing chamber cleaning gas
Embodiments of the invention generally relate to apparatus and methods for cleaning chamber components using a cleaning plate. The cleaning plate is adapted to be positioned on a substrate support during a cleaning process, and includes a plurality of turbulence-inducing structures. The turbulence-inducing structures induce a turbulent flow of cleaning gas while the cleaning plate is rotated during a cleaning process. The cleaning plate increases the retention time of the cleaning gas near the showerhead during cleaning. Additionally, the cleaning plate reduces concentration gradients within the cleaning plate to provide a more effective clean. The method includes positioning a cleaning plate adjacent to a showerhead, and introducing cleaning gas to the space between the showerhead and the cleaning plate. A material deposited on the surface of the showerhead is then heated and vaporized in the presence of the cleaning gas, and then exhausted from the processing chamber.
Examining the effects of chemical cleaning, leaching, and partial dissolution on zinc and cadmium isotope fractionation in marine carbonates
The application of zinc (Zn) and cadmium (Cd) isotopes as palaeo-proxies in carbonate sediment is rapidly expanding due to their potential for tracing changes in biological productivity in the modern and past oceans. However, there are limited investigations into the chemical cleaning methods required to produce the most consistent and accurate data for these novel isotope systems. This could impact their use as palaeo-proxies to reconstruct ocean-atmosphere-climate interactions throughout Earth's history. To address this concern and expand the utility of the Zn and Cd stable isotope systems as palaeo-productivity tracers, the performance of two standard chemical cleaning protocols for acquiring robust and reliable Zn and Cd isotope datasets were assessed. These include (i) the Cd-cleaning method that uses a reductive step to selectively leach contaminating secondary iron (Fe)-manganese (Mn) (oxyhydr)oxide coatings from the carbonate surface, and an oxidative step that is used to remove post-depositional organic matter and sulphide precipitates; and (ii) the magnesium/calcium cleaning protocol that includes an oxidative step only, leaving secondary Fesingle bondMn (oxyhydr)oxide coatings largely intact. Well-preserved Holocene-, and Mesozoic-aged carbonate sediments were used to test the reliability of these two chemical cleaning methods. The Holocene samples comprised not only aliquots of bulk sediment, but also individual species of planktic and benthic foraminifera. Our results show that the best practice chemical cleaning method for retrieving consistent and accurate Zn and Cd isotope, and Zn/Ca and Cd/Ca datasets for carbonate sediments, requires both reductive and oxidative cleaning following the Cd-cleaning method. This differs from most methodological approaches applied to date that remove the reductive step from the chemical cleaning protocol and apply an oxidative step only, or no chemical cleaning at all. Inclusion of the reductive step in the chemical cleaning method typically shifts δ 66 Zn by ~0.1‰ lower and δ 114 Cd by 0.3‰ higher in the solid phase, while Zn/Ca and Cd/Ca typically decrease 2-fold. The benthic foraminifera, C. wuellerstorfi, that live in ocean bottom waters where the seawater Zn and Cd isotope composition is homogeneous display evidence of Zn and Cd isotope fractionation between seawater and carbonate on the order of 0.08 ± 0.08‰ (2SE, n = 4) and -0.25 ± 0.13‰ (2SE, n = 4), respectively, in agreement with experimental constraints. Furthermore, evidence of Zn isotope fractionation effects are recorded in a naturally-dissolved carbonate sediment, together with laboratory-controlled carbonate dissolution experiments. Based on these results, we recommend the Cd-cleaning method and the application of Zn and Cd isotope fractionation factors to accurately reconstruct past seawater Zn and Cd isotope compositions from carbonate sediments.
Public-Private roundtables at the fourth Clean Energy Ministerial, 17-18 April 2013, New Delhi, India
The Clean Energy Ministerial (CEM) is a high-level global forum to share best practices and promote policies and programs that advance clean energy technologies and accelerate the transition to a global clean energy economy. The CEM works to increase energy efficiency, expand clean energy supply, and enhance clean energy access worldwide. To achieve these goals, the CEM pursues a three-part strategy that includes high-level policy dialogue, technical cooperation, and engagement with the private sector and other stakeholders. Each year, energy ministers and other high-level delegates from the 23 participating CEM governments come together to discuss clean energy, review clean energy progress, and identify tangible next steps to accelerate the clean energy transition. The U.S. Department of Energy, which played a crucial role in launching the CEM, hosted the first annual meeting of energy ministers in Washington, DC, in June 2010. The United Arab Emirates hosted the second Clean Energy Ministerial in 2011, and the United Kingdom hosted the third Clean Energy Ministerial in 2012. In April 2013, India hosted the fourth Clean Energy Ministerial (CEM4) in New Delhi. Key insights from CEM4 are summarized in the report. It captures the ideas and recommendations of the government and private sector leaders who participated in the discussions on six discussion topics: reducing soft costs of solar PV; energy management systems; renewables policy and finance; clean vehicle adoption; mini-grid development; and power systems in emerging economies.
Automated detection of photovoltaic cleaning events: A performance comparison of techniques as applied to a broad set of labeled photovoltaic data sets
Extracting accurate soiling loss information from photovoltaic (PV) production data first requires segmenting the time series data per natural or manually occurring cleaning events. Maintenance logs are often incomplete, rain data are often unavailable, and the debate on rain thresholds for cleaning and dew or wind cleanings is still ongoing. The present work aims to overtake these issues by improving automated methods to detect these cleaning events and therefore improve extraction of soiling loss information. Time series power production data from 22 PV inverters were labeled for natural or manually occurring cleaning events. The data sets were carefully selected to include varying degrees of soiling, cleaning events, and noise. Several algorithms, including filtering logic and change point detection, were examined for efficacy at detecting the labeled cleanings. All the methods introduced except for changepoint detection showed significant improvement at detecting the labeled cleaning events per the mean F 1 score. Furthermore, the highest performing cleaning detection algorithm achieved an absolute increase in the mean F 1 score of 43% over the default version of the RdTools stochastic rate and recovery (SRR) algorithm. The highest performing algorithm included irradiance filtering and a cleaning detection threshold, adjusted based on the 40-day centered rolling median of the absolute day-to-day deviations in the daily performance index (PI). Furthermore, these improvements are promising as cleaning detection is an essential step in the automated analysis of PV soiling.
Clean Energy Microgrids: Considerations for State Energy Offices and Public Utility Commissions to Increase Resilience, Reduce Emissions, and Improve Affordability
In fall 2019, the National Association of Regulatory Utility Commissioners (NARUC) and the National Association of State Energy Officials (NASEO) initiated a joint Microgrids State Working Group (MSWG), funded by the U.S. Department of Energy (DOE) Office of Electricity (OE). The MSWG aims to bring together NARUC and NASEO members to explore the capabilities, costs, and benefits of microgrids; discuss barriers to microgrid development; and develop strategies to plan, finance, and deploy microgrids to improve resilience. This report, Clean Energy Microgrids: Considerations for State Energy Offices and Public Utility Commissions to Increase Resilience, Reduce Emissions, and Improve Affordability, focuses specifically on how clean energy microgrids can achieve both resilience and clean energy benefits. The paper provides an overview of the challenges faced by clean energy microgrids, outlines benefits that clean energy microgrids can provide, and details economic and cost considerations for the development of clean energy microgrid projects. Outlined in the paper are the necessary technological components of a clean energy microgrid, including generation, storage, energy efficiency measures, and smart controls. Current technologies are highlighted, along with potential configurations of clean technologies that are approaching cost competitiveness with commercially available options. The paper concludes with both policy and regulatory considerations for State Energy Offices and Public Utility Commissions to enhance the development and deployment of clean energy microgrids. Although it touches on the clean energy microgrids’ role in integrating distributed energy resources (DERs) into the larger grid, this is not the focus of this paper.
A Review of Clean Electricity Policies—From Countries to Utilities
Due to the heavy stress on environmental deterioration and the excessive consumption of fossil resources, the transition of global energy from fossil fuel energy to clean energy has significantly accelerated in recent years. The power industry and policymakers in almost all countries are focusing on clean energy development. Thanks to progressive clean energy policies, significant progress in clean energy integration and greenhouse gas reduction has been achieved around the world. However, due to the differences in economic structures, clean energy distributions, and development models, clean energy policy scope, focus, and coverage vary between different countries, states, and utilities. This paper aims at providing a policy review for readers to easily obtain clean energy policy information on various clean energies in the U.S. and some other countries. Firstly, this paper reviews and compares some countries’ clean energy policies on electricity. Then, taking the U.S. as an example, this paper introduces the clean energy policies of some representative states and utilities in the U.S in perspectives of renewable energies, electric vehicles, and energy storage.
Glass-particle adhesion-force-distribution on clean (laboratory) and contaminated (outdoor) surfaces
This article explores whether laboratory-clean samples are representative of real outdoor surfaces – often covered in dust and other contaminants – with respect to adhesion properties, which ultimately affect particle resuspension. In this study, Atomic Force Microscopy (AFM) was used to measure the adhesion force between a clean, smooth glass particle (5 µm in diameter) and two glass slides, one prepared according to common laboratory practices (hereafter, clean glass) and a second one left outdoors for six weeks (hereafter, contaminated glass). It was found that the adhesion force distribution was bimodal for the clean glass while it showed three peaks for the contaminated glass. For both surfaces, the adhesion force showed a peak at very low adhesion values (< 100 nN) representing 1.2% of the measurements for the clean glass and 58% for the contaminated glass. This low-adhesion peak is important because it represents the particles that would be resuspended first even in light winds. The low adhesion-force measurements were associated with the presence of contaminants on the surface. Another notable difference between the adhesion force distributions was a long tail at high adhesion forces for clean glass (up to ~1900 nN) and the absence of the tail for the contaminated glass, which had a maximum adhesion force of 950 nN. The mean adhesion force on the contaminated glass was also lower than on the clean glass (206 ± 240 nN vs. 516 ± 354 nN). These observations indicate that the adhesion force distribution between a 5-µm smooth and clean glass sphere and the outdoor contaminated glass surface is quite different from that of the clean glass surface. Hence, one should be cautious when using adhesion force measurements from clean surfaces to estimate particle resuspension from outdoor surfaces.
Clean Energy Innovation Ecosystems Discovery - Measuring Innovation Through Data Analytics (MIDAS)
As part of the Mission Innovation rollout at the Paris COP 21, 20 countries announced to double their R&D budgets over 5 years to accelerate lab-to-market clean energy innovations. These innovations must address technical urgency and navigate complex institutional, social and financial environments. To inform budget and program development, policymakers need to understand existing clean energy innovation ecosystems (IE) and their characteristics at the local, state, and regional levels within the US. Researchers at ORNL have implemented a ground-breaking application of natural language processing, link analysis, and other computational techniques to transform text and numerical data into metrics on clean energy innovation activity and geography. The 'Measuring Innovation through Data Analytics' (MIDAS) application uses data to determine where clean energy innovation ecosystems exist and the underlying scoring algorithm "ranks" the strength of the ecosystem for several clean energy technologies. The selection of the data sources is driven by the fact that a clean energy IE can be identified as an intersection of nascent clean technology efforts and financing mechanisms and related large companies located in a geographically concentrated area with an enabling environment to encourage commercialization and networking assets to facilitate communication. MIDAS is a machine-assisted methodology that provides the user with a replicable method to rapidly identify, quantify and characterize clean energy innovation ecosystems. This software application and the underlying datasets have the potential to address many important policy questions. The initial broad list of U.S. clean energy ecosystems, with geographic area, technology focus, and list and types of involved organizations can help describe regional tech activities and capabilities. Other potential applications include understanding the effect of private sector investments on ecosystem activity, and trends analysis.
Corrosion Testing of Carbon Steel Exposed to Sludge Heel Chemical Cleaning Solutions - 16109
As efforts continue to treat and dispose of millions of gallons of legacy radioactive materials from the production of nuclear weapons, non-compliant waste storage tanks will gradually be emptied of the bulk waste volume leaving heel materials requiring removal prior to tank closure. The waste heel slurries are distributed on the floor of large, million gallon tanks, which frequently contain numerous obstructions that limit the effectiveness of mechanical removal methods. As a result, chemical cleaning methods are needed for the effective removal of the heels as well as chemical scales that are present on the tank walls and other interior surfaces. Two tank cleaning technologies have already been implemented at the Savannah River Site (SRS): Low Temperature Aluminum Dissolution (LTAD) and Bulk Oxalic Acid Cleaning (BOAC). Recent chemical cleaning efforts on SRS Tank 12 were very successful with regard to bulk sludge heel (especially for Al, Fe, and U phases) and beta/gamma radionuclide removal. Although chemical cleaning using these technologies has been shown to be effective, no disposition path has been identified for oxalate added during BOAC, and insoluble oxalate salts are accumulating within the SRS tank farm and waste processing facilities (evaporators, etc.). Extensive sludge washing is also required to remove moderately soluble sodium oxalate salts prior to sludge vitrification in the SRS Defense Waste Processing Facility (DWPF). As a result, oxalate additions to the tank farm need to be minimized by the use of supplementary acids to assist sludge removal in OA or the use of other cleaning reagents or processing strategies. Previous SRNL testing revealed the importance of pH control for BOAC and recommended the use of a supplementary acid (dilute HNO{sub 3}) with OA to minimize oxalate additions. Primary drivers in SRS Tank Closure Performance Assessments, which evaluate the fate and impact of tank sludge residuals on a geological timescale, are the removal of alpha emitting radionuclides present at low concentrations such as Pu, Am, and Np, which are not highly soluble in currently utilized chemical cleaning reagents. Scoping studies conducted at SRNL revealed promising methods to dissolve the actinides within the HLW tank heels. Oxidation of the actinides with permanganate in either strong caustic (10 M NaOH) or dilute acidic (0.2 M HNO{sub 3}) solutions was shown to result in dissolution of oxy/hydroxide phases of these metals in the absence of major sludge phases. The waste tanks at SRS and Hanford are constructed of carbon steel. Carbon steel corrodes rapidly in most acidic and/or oxidizing environments. Previous electrochemical corrosion testing indicated that the corrosion rates in dilute HNO{sub 3} with OA may result in manageable corrosion rates, over short exposure periods. Additional corrosion testing was performed to provide data for the nitric acid/OA blend as well as the acid/permanganate and caustic permanganate based chemical cleaning solutions. Corrosion rates from the passive coupon tests for the nitric acid/oxalic acid blend were significantly greater than those observed previously with the electrochemical testing. This result may be due to simultaneous electrochemical and chemical dissolution of the steel. The corrosion rate data from the coupon tests in the nitric acid/oxalic acid blend were evaluated to determine the degree of potential structural damage. The corrosion rates, although relatively high, would not be expected to cause damage that would reduce the capacity of the tank primary wall if the process is completed within a month. The corrosivity of sodium permanganate in four proposed cleaning solutions, 1 nitric acid solution and 3 sodium hydroxide solutions, was studied by electrochemical methods at room temperature. The corrosion rates were significantly less aggressive than in the nitric acid/oxalic acid blend corrosion tests. Passive coupon tests needs to be performed in these solutions to ensure that chemical dissolution of the metal is not occurring simultaneously. (authors)