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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Integrating Contaminant Source Indicators, Water Quality Measures, and Ecotoxicity to Characterize Contaminant Mixtures and Per- and Polyfluoroalkyl Substance (PFAS) Variability in an Urban Watershed

Thousands of chemical contaminants threaten watersheds but are time and cost prohibitive to monitor. Identifying their sources, transport, and ecological risk is limited in heterogeneous urban watersheds. We present an integrative watershed approach using source-specific indicator compounds, common water quality measures, and ecotoxicity assays to examine the distribution of contaminant mixtures in an urbanized watershed. Indicator compound concentrations were temporally and spatially distributed for treated/untreated sewage (sucralose, artificial sweetener), road runoff (diphenyl-guanidine [DPG] and 6PPD-quinone [6PPD-Q], automobile tire additives), and lawncare runoff (aminomethanephosphonic acid (AMPA), major degradant of the herbicide glyphosate). Sucralose was predominately sourced from treated wastewater; measurable concentrations in tributaries indicated raw sewage inputs. DPG and 6PPD-Q concentrations correlated to road density during base flow and were elevated during stormflow. AMPA was measurable spring through fall, especially where lawns were dense. When specific sources dominated flow, water quality measures correlated with wastewater (sulfate, potassium, chloride, and sodium) and road runoff (chromium and lead) indicators. The limited behavioral toxicity observed in exposed zebrafish (Danio rerio) (18%) was not well explained by source-indicators. PFAS concentrations were highly variable spatially but not well explained by our source-specific indicator compounds. Here, more costly compound-specific monitoring may be necessary when multiple sources exist or when unexpected toxicity trends occur.

computer simulations↗

Hybrid Sorbents for 129 I Capture from Contaminated Groundwater

Radioiodine ( 129 I) poses a risk to the environment due to its long half-life, toxicity, and mobility. It is found at the U.S. Department of Energy Hanford Site due to legacy releases of nuclear wastes to the subsurface where 129 I is predominantly present as iodate (IO 3 – ). To date, a cost-effective and scalable cleanup technology for 129 I has not been identified, with hydraulic containment implemented as the remedial approach. Here, novel high-performing sorbents for 129 I remediation with the capacity to reduce 129 I concentrations to or below the US Environmental Protection Agency (EPA) drinking water standard and procedures to deploy them in an ex-situ pump and treat (P&T) system are introduced. Furthermore, this includes implementation of hybridized polyacrylonitrile (PAN) beads for ex-situ remediation of IO 3 – -contaminated groundwater for the first time. Iron (Fe) oxyhydroxide and bismuth (Bi) oxyhydroxide sorbents were deployed on silica substrates or encapsulated in porous PAN beads. In addition, Fe–, cerium (Ce)–, and Bi–oxyhydroxides were encapsulated with anion-exchange resins. The PAN–bismuth oxyhydroxide and PAN–ferrihydrite composites along with Fe- and Ce-based hybrid anion-exchange resins performed well in batch sorption experiments with distribution coefficients for IO 3 – of >1000 mL/g and rapid removal kinetics. Of the tested materials, the Ce-based hybrid anion-exchange resin was the most efficient for removal of IO 3 – from Hanford groundwater in a column system, with 50% breakthrough occurring at 324 pore volumes. The functional amine groups on the parent resin and amount of active sorbent in the resin can be customized to improve the iodine loading capacity. These results highlight the potential for IO 3 – remediation by hybrid sorbents and represent a benchmark for the implementation of commercially available materials to meet EPA standards for cleanup of 129 I in a large-scale P&T system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Approaches for effective negative pressure isolation space control to minimize airborne transmission of contaminants in residential homes

Controlling airborne transmission of contaminants including respired viruses such as SARS-CoV-2 is necessary to protect occupants living in the same house with a contagious person. The effectiveness of interventions requiring minor efforts that create a negative pressure isolation zone (IZ) for a contagious person has yet to be systematically tested for residential homes. In this study, ASHRAE Standard 170, which offers guidance for negative pressure isolation space control in healthcare facilities, was used in developing practical and attainable recommendations for residential single-family homes. The relative effectiveness of several control strategies was evaluated through experimentally conducting 17 different test cases in a manufactured single-family house laboratory. These cases were designed based on various heating, ventilation and air-conditioning (HVAC) operating scenarios, intervention measures including closing the IZ door and/or sealing over supply and return air grilles in the IZ, and utilization of bathroom exhaust or portable window fans for pressure control. Four out of 17 test cases were identified as having the potential for strong containment with adequate depressurization in the IZ. The most effective IZ depressurization was achieved through continuously operating the exhaust fan in the bathroom attached to the IZ, by installing a portable window fan that extracted air out of the IZ, and a portable room air conditioner with the AC unit exhaust duct installed in one of the IZ windows.

Construction & Building Technology↗

On Estimation of Contamination from Hydrogen Cyanide in Carbon Monoxide Line-intensity Mapping

Line-intensity mapping surveys probe large-scale structure through spatial variations in molecular line emission from a population of unresolved cosmological sources. Future such surveys of carbon monoxide line emission, specifically the CO(1-0) line, face potential contamination from a disjointed population of sources emitting in a hydrogen cyanide emission line, HCN(1-0). This paper explores the potential range of the strength of HCN emission and its effect on the CO auto power spectrum, using simulations with an empirical model of the CO/HCN–halo connection. We find that effects on the observed CO power spectrum depend on modeling assumptions but are very small for our fiducial model, which is based on current understanding of the galaxy–halo connection. Given the fiducial model, we expect the bias in overall CO detection significance due to HCN to be less than 1%.

79 ASTRONOMY AND ASTROPHYSICS↗

Spacecraft contamination investigation by direct simulation Monte Carlo - Contamination on UARS/HALOE

A three-dimensional version of the direct simulation Monte Carlo method is adapted to study the contamination environment surrounding a highly detailed model of the Upper Atmosphere Research Satellite, with the ultimate goal of estimating the cumulative level of molecular deposits on critical optical surfaces of the Halogen Occultation Experiment. Emphasis is placed on describing the development of preprocessing codes that simplify the incorporation of geometry and outgassing data into the main run code. A novel use of parallel processing software allows use of multiple processors to solve different regions of the overall flowfield. Initial results relating to contaminant cloud structure, cloud composition, and statistics of simulated molecules impinging on the Halogen Occultation telescope's aperture plane are presented, along with data related to code performance.

Rault, Didier F. G.↗

Earth contamination free sample acquisition from an Earth Contaminated Spacecraft

The paper describes the first step in the feasibility demonstration of a novel low cost Mars Sample Return Transfer Sequence (STS) that does not require cleaning and sterilization of the entire spacecraft. The proposed STS relies on ability to collect (and in the future deliver to Earth) Earth-contamination-free samples from a spacecraft that was cleaned only to the levels achieved on the Pathfinder.

contamination sampling↗

Contaminant Transport Parameters for the Groundwater Flow and Contaminant Transport Model of Corrective Action Units 101 and 102: Central and Western Pahute Mesa, Nye County, Nevada, Revision 1

This document presents a summary and framework of available transport data and other information directly relevant to the development of the groundwater transport model for Central and Western Pahute Mesa (PM) corrective action units (CAU). This model is referred to as the “PM CAU transport model” in this document. Central and Western PM are two areas of the Nevada National Security Site (NNSS) that historically were used for underground nuclear testing. These nuclear tests resulted in groundwater contamination in the vicinity of the underground test areas. As a result, the U.S. Department of Energy (DOE), Environmental Management (EM) Nevada Program is currently conducting a corrective action investigation (CAI) of the PM underground test areas. This work is a part of the Underground Test Area (UGTA) Activity in accordance with the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Groundwater Contamination, Subsurface Processes, and Remediation Methods: Overview of the Special Issue of Water on Groundwater Contamination and Remediation

This special issue of Water brings together ten studies on groundwater contamination and remediation. Common themes include practical techniques for plume identification and delineation, the central role of subsurface processes, the pervasiveness of non-Fickian transport, and the importance of bacterial communities in the broader context of biogeochemistry.

Mays, David↗

Space station contamination study: Assessment of contaminant spectral brightness

The results presented show that spectral emissions which arise as a result of vehicle-ambient atmospheric interactions are significant and can become competitive with the natural zodiacal background up to altitudes as high as 400 km for the Vacuun Ultraviolet (VUV) and Visible Infrared Spectra (VIS) for the worst case conditions used. The empirical database on the induced environment of space vehicles is very sparse, and these results are based on a number of assumptions and cannot be regarded as definitive at the present time. Since the technique for doing calculations of this kind was developed in its preliminary form for the purpose of this study, a list of greatly improved estimates are provided of the contamination irradiances. Tasks which are considered most important in order to achieve a higher confidence level for the preliminary conclusions drawn are provided.

Torr, D. G.↗