A pocket model for aluminum agglomeration in composite propellants
Previously cited in issue 19, p. 3327, Accession no. A81-40960
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Previously cited in issue 19, p. 3327, Accession no. A81-40960
Proof for the existence of a single Poisson's ratio function in isotropic linear viscoelastic materials is presented. An in-depth discussion is given of three dimensional viscoelastic material properties and their relationships to linear isotropic and orthotropic viscoelastic materials. A discussion of the alternate invariant definition as used by Abaqus and how it relates to the form used by Dr. S. Peng is presented.
The basic principles underlying propulsion by rocket motor are examined together with the configuration of a solid propellant motor. Solid propellants and their preparation are discussed, giving attention to homogeneous propellants, composite propellants, energetic considerations in choosing a solid propellant, the processing of composite propellants, and some examples of new developments. The performance of solid propellants is investigated, taking into account characteristics velocity, the specific impulse, and performance calculations. Aspects of propellant development considered include nonperformance requirements for solid propellants, the approach to development, propellant mechanical properties, and future trends.
Results of casting studies are reviewed so as to define the viscosity criteria insuring the fabrication of defect-free grains. The rheology of uncured propellants is analyzed showing that a realistic assessment of a propellant's flow properties must include measurement of viscosity as a function of shear stress and time after curing agent. Methods for measuring propellant viscosity are discussed, with particular attention given to the Haake-Rotovisko rotational viscometer. The effects of propellant compositional and processing variables on apparent viscosity are examined, as are results relating rheological behavior to grain defect formation during casting.
An analytical model is developed for the linearized velocity-coupled combustion response function. The model treats elements of response to perturbations in pressure, in composition due to the heterogeneity of composite propellants, and in crossflow velocity. The effects of AP particle size are accounted for in terms of effects on controlling ballistics properties and in terms of fluctuations in propellant composition. There are two facets of the crossflow problem: the effect of crossflow velocity on the various response elements, and the response to velocity perturbations. Both are dealt with in this paper. Important trends derived from series of parametric computations are described.
Composite solid propellants surface structure and profile characteristics burning with various oxidizers and polyurethane binder by scanning electron microscopy
A solid propellant composition of improved efficiency is described which includes an oxidizer containing ammonium perchlorate, and a powered metal fuel, preferably aluminum or beryllium, in the form of a composite. The metal fuel is contained in the crystalline lattice framework of the oxidizer, as well as within the oxidizer particles, and is disposed in the interstices between the oxidizer particles of the composition. The propellant composition is produced by a process comprising the crystallization of ammonium perchlorate in water, in the presence of finely divided aluminum or beryllium. A suitable binder is incorporated in the propellant composition to bind the individual particles of metal with the particles of oxidizer containing occluded metal.
In a study conducted to evaluate flow parameters of uncured solid composite propellants during motor casting, two motors (1.8M-lb grain wt) were cast with a PBAN propellant exhibiting good flow characteristics in a 260-in. dia solid rocket motor. Attention is given to the effects of propellant compositional and processing variables on apparent viscosity as they pertain to rheological behavior and grain defect formation during casting. It is noted that optimized flow behavior is impaired with solid propellant loading. Non-Newtonian pseudoplastic flow is observed, which is dependent upon applied shear stress and the age of the uncured propellant.
Performance of composite solid propellant at simulated high altitudes
Extinction model of composite solid propellant combustion including wall and flame heat release zones
Flame spreading over surface of igniting composite solid propellant constituents
Suitability of thermoplastic rubbers as binder for composite solid propellant
Steady state acceleration effects on combustion characteristics of aluminized composite solid propellant
A computerized mathematical model of the combustion response function of composite solid propellants was developed with particular attention to the contributions of the solid phase heterogeneity. The one-dimensional model treats the solid phase as alternating layers of ammonium perchlorate and binder, with an exothermic melt layer at the surface. Solution of the Fourier heat equation in the solid provides temperature and heat flux distributions with space and time. The problem is solved by conserving the heat flux at the surface from that produced by a suitable model of the gas phase. An approximation of the BDP flame model is utilized to represent the gas phase. By the use of several reasonable assumptions, it is found that a significant portion of the problem can be solved in closed form. A method is presented by which the model can be applied to tetramodal particle size distributions. A computerized steady-state version of the model was completed, which served to validate the various approximations and lay a foundation for the combustion response modeling. The combustion response modeling was completed in a form which does not require an iterative solution, and some preliminary results were acquired.
Solid propellant composition and rocket motor design effect on plasma microwave and visible light attenuation emitted by exhaust
Composite solid propellant flame microstructure determinations
A mathematical model is developed to predict burn rate augmentation due to strain in a composite solid propellant. The model assumes the effect is due to the ability of the flame to penetrate the small fissures and voids that form when a propellant is strained. The number and size of these fissures is obtained by applying a flaw propagation analysis to randomly distributed flaws that form when the binder-oxidizer particle bonds break under stress. A flame height is calculated with Summerfield's burn rate equation and is used to compute the burn rate augmentation based upon the additional burn area created when the flame penetrates the fissures. Comparisons are made with data obtained from published sources. The existence of threshold pressure and strains, above which augmentation occurs, is verified although the model predicts a lower threshold pressure and higher threshold strain than expected. Further results and applications of the model are discussed.
Contributions to the evolution of solid-propellant rocketry have come from a variety of sources. World War II research on large solids enabled one company to capitalize on work in the area of castable double-base propellants. Separate development of castable composite propellants led to production of Polaris and Minuteman powerplants. Pivotal to the development of these missiles were Edward Hall's advocacy of the Minuteman missile within the Air Force and contract funding to resolve problems. The discovery that adding large amounts of aluminum significantly increased the specific impulse of a castable composite propellant further aided large-missile technology. These separate lines of research led to the development of large solid-propellant motors and boosters. Many more discoveries went into the development of large solid-propellant motors. Ammonium perchlorate replaced potassium perchlorate as an oxidizer in the late 1940's, and binders were developed. Discoveries important in the evolution of large solid-propellant motors appear to have resulted from innovators' education and skills, an exposure to contemporary problems, an awareness of theory but a willingness not to let it dictate empirical investigations, and proper empirical techniques. Other important contributions are the adequate funding and exchange of information. However, many questions remain about these and other innovations.