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NASA NTRS2010

Acute and Chronic Exposure to CO2 in Space Flight

Spacecraft and space stations, similar to other habitable confined spaces such as submarines, need to provide a breathable atmosphere for their inhabitants. The inevitable production of CO2 during respiration necessitates life support systems that "scrub" the atmosphere and lower CO2 levels. Due to operational limitations associated with space flight (limited mass, volume, power, and consumables) CO2 is not scrubbed down to its terrestrial equivalent of 0.03% CO2 (ppCO2 of 0.23 mmHg), but is kept below 0.7% (ppCO2 of 5.3 mmHg), a level established in NASA s 180-day mission Spacecraft Maximum Allowable Concentration (SMAC) to be safe and unlikely to cause symptoms. Reports of space flight crewmembers becoming symptomatic with headaches, fatigue, and malaise at levels below those known to cause such symptoms terrestrially has prompted studies measuring the levels of CO2 on both the space shuttle and the space station. Data from cabin atmosphere sampling were collected on space shuttle missions STS-113, STS-122, STS-123, and International Space Station Expeditions 12-15 and 17, and the measured CO2 levels were then correlated to symptoms reported by the crew. The results indicate that a correlation exists between CO2 levels and symptomatology, however causality cannot be established at this time. While the short-term effects of elevated CO2 exposure are well known terrestrially, less is known regarding potential long-term effects of prolonged exposure to a CO2-rich environment or how the physiological changes caused by microgravity may interact with such exposures. Other challenges include limitations in the CO2 monitors used, lack of convection in the microgravity environment, and formation of localized CO2 pockets. As it is unclear if the unique environment of space increases sensitivity to CO2 or if other confounding factors are present, further research is planned to elucidate these points. At the same time, efforts are underway to update the SMAC to a lower level

Alexander, D.↗

NASA NTRS2000

BOREAS AFM-2 Wyoming King Air 1994 Aircraft Sounding Data

The BOREAS AFM-2 team used the University of Wyoming King Air aircraft during IFCs 1, 2, and 3 in 1994 to collected pass-by-pass fluxes (and many other statistics) for the large number of level (constant altitude), straight-line passes used in a variety of flight patterns over the SSA and NSA and areas along the transect between these study areas. The data described here form a second set, namely soundings that were incorporated into nearly every research flight by the King Air in 1994. These soundings generally went from near the surface to above the inversion layer. Most were flown immediately after takeoff or immediately after finishing the last flux pattern of that particular day's flights. The parameters that were measured include wind direction, wind speed, west wind component (u), south wind component (v), static pressure, air dry bulb temperature, potential temperature, dewpoint, temperature, water vapor mixing ratio, and CO2 concentration. Data on the aircraft's location, attitude, and altitude during data collection are also provided. These data are stored in tabular ASCH files. The data files are available on a CD-ROM (see document number 20010000884) or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Kelly, Robert D.↗

NASA NTRS1997

The effects of atmospheric [CO2] on carbon isotope fractionation and magnesium incorporation into biogenic marine calcite

The influences of atmospheric carbon dioxide on the fractionation of carbon isotopes and the magnesium incorporation into biogenic marine calcite were investigated using samples of the calcareous alga Amphiroa and benthic foraminifer Sorites grown in the Biosphere 2 Ocean system under variable atmospheric CO2 concentrations (approximately 500 to 1200 ppm). Carbon isotope fractionation was studied in both the organic matter and the skeletal carbonate. Magnesium analysis was to be performed on the carbonate removed during decalcification. These data have not been collected due to technical problems. Carbon isotope data from Amphiroa yields a linear relation between [CO2] and Delta(sup 13)C(sub Corg)values suggesting that the fractionation of carbon isotopes during photosynthesis is positively correlated with atmospheric [CO2]. [CO2] and Delta(sup 13)C(sub Corg) values for Sorites produce a relation that is best described by a hyperbolic function where Delta(sup 13)C(sub Corg) values increase between 300 and 700 ppm and decrease from 700 to 1200 ppm. Further investigation of this relation and Sorites physiology is needed.

Vieira, Veronica↗

NASA NTRS2000

BOREAS TF-11 SSA-Fen Soil Surface CO2 Flux Data

The BOREAS TF-11 team gathered a variety of data to complement its tower flux measurements collected at the SSA-Fen site. These data are soil surface CO 2 flux data at the SSA-Fen site from 27- May-1994 to 23-Sep-1994 and from 13-May-1995 to 03-Oct-1995. A portable gas exchange system was used to make these measurements. The data are stored in tabular ASCII files.

Arkebauer, Timothy J.↗

NASA NTRS2002

NASA/DERA Collaborative Program

This report is an interim report. The work reported are the results from the combustor testing, the first phase of testing in the DERA/NASA collaborative program. A program of work was developed by DERA and NASA utilizing specialist facilities within the UK, and specialist measurement techniques developed within the U.S. Under a Memorandum of Understanding (MoU) between the UK and U.S. governments, the joint UK/U.S. funded program commenced. The objective of the program was to make combustor and engine exit plane emissions measurements, including particulate and sulphur measurements, for kerosene fuels with different sulphur levels. The combustor test program was performed in August/September 2000. Although probe issues complicated the test program, a consistent set of data, including CO, NO(x), NO, NO2, CO2, O2, smoke number, particulate number density and size distribution, SO2, SO3 and HONO were collected at the exit plane of the DERA TRACE engine combustor. A second probe was utilized to measure spatial location of CO, NO(x), NO, NO2 and CO2 concentrations. Data are therefore available for development of aerosol, particulate and aerosol precursor chemistry sub-models for inclusion into CFD. Inlet boundary conditions have been derived at the exit of the combustion system for the modelling of the DERA TRACE engine. The second phase of the program is to perform identical measurements at the engine exit, to allow a full data set to be available. This will be performed in July 2001 at the Glenn test facility, DERA Pyestock.

Whitefield, Phillip D.↗

NASA NTRS2016

Constraining Hesperian martian PCO2 from mineral analysis at Gale crater

Carbon dioxide is an essential atmospheric component in martian climate models that attempt to reconcile a faint young sun with planet-wide evidence of liquid water at the planets surface in the Noachian and Early Hesperian. Current estimates of ancient martian CO2 levels, derived from global inventories of carbon, and orbital detections of Noachian and Early Hesperian clay mineral-bearing terrains indicate CO2 levels that are unable to support warm and wet conditions. These estimates are subject to various sources of uncertainty however. Mineral and contextual sedimentary environmental data collected by the Mars Science Laboratory rover Curiosity in Gale Crater provide a more direct means of estimating the atmospheric partial pressure of CO2 (PCO2) coinciding with a long-lived lake system in Gale crater at ~3.5 Ga. Results from a reaction-transport model, which simulates mineralogy observed within the Sheepbed member at Yellowknife Bay by coupling mineral equilibria with carbonate precipitation kinetics and rates of sedimentation, indicate atmospheric PCO2 levels in the 10’s mbar range. At such low PCO2 levels, climate models are unable to warm Hesperian Mars anywhere near the freezing point of water and other gases are required to raise atmospheric pressure to prevent lakes from boiling away. Thus, lacustrine features of Gale formed in a cold environment by a mechanism yet to be determined, or the climate models still lack an essential component that would serve to elevate surface temperatures, at least temporally and/or locally, on Hesperian Mars. Our results also impose restrictions on the potential role of atmospheric CO2 in inferred warmer conditions of the Noachian.

Bristow, T. F.↗

NASA NTRS1977

CO2 and humidity removal system for extended Shuttle missions - CO2, H2O, and trace contaminant equilibrium testing

The equilibrium relationships for the co-adsorption of CO2 and H2O on an amine coated acrylic ester are presented. The equilibrium data collection and reduction techniques are discussed. Based on the equilibrium relationship, other modes of operation of systems containing HS-C are discussed and specific space applications for HS-C are presented. Equilibrium data for 10 compounds which are found as trace contaminants in closed environments are also presented.

Davis, S. H.↗

NASA NTRS2006

Tracking the Martian CO2 Polar Ice Caps in Infrared Images

Researchers at NASA s Jet Propulsion Laboratory have developed a method for automatically tracking the polar caps on Mars as they advance and recede each year (see figure). The seasonal Mars polar caps are composed mainly of CO2 ice and are therefore cold enough to stand out clearly in infrared data collected by the Thermal Emission Imaging System (THEMIS) onboard the Mars Odyssey spacecraft. The Bimodal Image Temperature (BIT) histogram analysis algorithm analyzes raw, uncalibrated data to identify images that contain both "cold" ("polar cap") and "warm" ("not polar cap") pixels. The algorithm dynamically identifies the temperature that separates these two regions. This flexibility is critical, because in the absence of any calibration, the threshold temperature can vary significantly from image to image. Using the identified threshold, the algorithm classifies each pixel in the image as "polar cap" or "not polar cap," then identifies the image row that contains the spatial transition from "polar cap" to "not polar cap." While this method is useful for analyzing data that has already been returned by THEMIS, it has even more significance with respect to data that has not yet been collected. Instead of seeking the polar cap only in specific, targeted images, the simplicity and efficiency of this method makes it feasible for direct, onboard use. That is, THEMIS could continuously monitor its observations for any detections of the polar-cap edge, producing detections over a wide range of spatial and temporal conditions. This effort can greatly contribute to our understanding of long-term climatic change on Mars.

Wagstaff, Kiri L.↗

NASA NTRS1984

The Joint Airport Weather Studies Project - Current analysis highlights in the aviation safety context

The principal objective of the Joint Airport Weather Studies Project was to obtain high-resolution velocity, turbulence, and thermodynamic data on a convective outflow called a microburst, an intense downdraft and resulting horizontal outflow near the surface. Data collection occurred during the summer of 1982 near Denver, CO. Data sensors included three pulsed-microwave Doppler and two pulsed CO2 lidar radars, along with 27 Portable Automated Mesonet surface weather stations, the FAA's low-level-wind-shear alert system (LLWSAS), and five instrumented research aircraft. Convective storms occurred on 75 of 91 operational days, with Doppler data being collected on at least 70 microbursts. Analyses reported included a thorough examination of microburst-climatology statistics, the capability of the LLWSAS to detect adequately and accurately the presence of low-altitude wind shear danger to aircraft, the capability of a terminal Doppler radar system development to provide improved wind-shear detection and warning, and progress toward improved wind-shear training for pilots.

Mccarthy, J.↗

NASA NTRS1972

C14-radiorespirometry system for astronaut medical monitoring.

A C14-CO2 radiorespirometry-computer system for monitoring human metabolism during space missions is described. Data collection using this apparatus is an effective 'real time' system allowing rapid, low-cost data processing which is ideal for telemetering signals from spacecraft to earth.

Feller, D. D.↗

NASA NTRS2006

A Ground-Based 2-Micron DIAL System to Profile Tropospheric CO2 and Aerosol Distributions for Atmospheric Studies

System will operate at a temperature insensitive CO2 line (2050.967 nm) with side-line tuning and off-set locking. Demonstrated an order of magnitude improvement in laser line locking needed for high precision measurements, side-line operation, and simultaneously double pulsing and line locking. Detector testing of phototransistor has demonstrated sensitivity to aerosol features over long distances in the atmosphere and resolve features approx. 100m. Optical systems that collect light onto small area detectors work well. Receiver optical designs are being optimized and data acquisition systems developed. CO2 line parameter characterization in progress In situ sensor calibration in progress for validation of DIAL CO2 system.

Ismail, Syed↗

NASA NTRS2000

BOREAS TGB-3 Plant Species Composition Data over the NSA Fen

The BOReal Ecosystem-Atmosphere Study Trace Gas Biogeochemistry (BOREAS TGB-3) team collected several data sets that contributed to understanding the measured trace gas fluxes over sites in the Northern Study Area (NSA). This data set contains information about the composition of plant species that were within the collars used to measure Net Ecosystem Exchange of CO2 (NEE). The species composition was identified to understand the differences in NEE among the various plant communities in the NSA fen. The data were collected in July of 1994 and 1996. The data are contained in comma-delimited, ASCII files.

Bubier, Jill L.↗

NASA NTRS1994

Carbon dioxide and water vapor production at rest and during exercise. A report on data collection for the Crew and Thermal Systems Division

The current environmental control device in the shuttle uses lithium hydroxide (LiOH) filter canisters to remove carbon dioxide (CO2) from the cabin air, requiring several bulky filter canisters that can only be used once and must be changed frequently. To alleviate a stowage problem and decrease launch weight, the Crew and Thermal Systems Division (CTSD) at the NASA Johnson Space Center has been researching a system to be used on future shuttle missions. This system uses two beds of solid amine material to absorb CO2 and water, later desorbing them to space vacuum. In this way the air scrubbing medium is regenerable and reusable. To identify the efficacy of this regenerable CO2 removal system (RCRS), CTSD began investigations in the shuttle mockup. The purpose of this investigation was to support the CTSD program by determining mean levels of carbon dioxide and water vapor production in normal, healthy males and females age-matched with the astronaut corps. Subjects' responses were measured at rest and during exercise at intensity levels equivalent to normal shuttle operation activities. The results were used to assess the adjustments made to RCRS and are reported as a reference for future investigations in shuttle environmental control.

Lee, Stuart M. C.↗

NASA NTRS1989

Estimations of ABL fluxes and other turbulence parameters from Doppler lidar data

Techniques for extraction boundary layer parameters from measurements of a short-pulse CO2 Doppler lidar are described. The measurements are those collected during the First International Satellites Land Surface Climatology Project (ISLSCP) Field Experiment (FIFE). By continuously operating the lidar for about an hour, stable statistics of the radial velocities can be extracted. Assuming that the turbulence is horizontally homogeneous, the mean wind, its standard deviations, and the momentum fluxes were estimated. Spectral analysis of the radial velocities is also performed from which, by examining the amplitude of the power spectrum at the inertial range, the kinetic energy dissipation was deduced. Finally, using the statistical form of the Navier-Stokes equations, the surface heat flux is derived as the residual balance between the vertical gradient of the third moment of the vertical velocity and the kinetic energy dissipation. Combining many measurements would normally reduce the error provided that, it is unbiased and uncorrelated. The nature of some of the algorithms however, is such that, biased and correlated errors may be generated even though the raw measurements are not. Data processing procedures were developed that eliminate bias and minimize error correlation. Once bias and error correlations are accounted for, the large sample size is shown to reduce the errors substantially. The principal features of the derived turbulence statistics for two case studied are presented.

Gal-Chen, Tzvi↗

NASA NTRS1985

Microanalysis of dissolved iron and phosphate in pore waters of hypersaline sediment

Diurnal fluctuations of reduced iron concentrations, expected to occur in reduced sediments in the photic zone, were studied. Iron concentration was compared to O2-H2S, a microcanalysis of sulfate reduction was performed, as well as an examination of diurnal concentration of dissolved phosphate and changes in interstitial CO2. The iron profiles suggest a strong correlation between iron remobilization and processes occurring in the light. Phosphate profiles suggest the removal of phosphate is strongly correlated with precipitation of oxidized iron in the upper 2 mm to 5 mm of the sediments. Pore water CO2 concentrations and carbon isotope ratios are presented. These data are from the analyses of minisediment cores collected from the 42 per mil salt pond and incubated in the laboratory under light and dark conditions.

Haddad, R.↗

NASA NTRS2007

The Orbiting Carbon Observatory Mission: Watching the Earth Breathe Mapping CO2 from Space

Approach: Collect spatially resolved, high resolution spectroscopic observations of CO2 and O2 absorption in reflected sunlight. Use these data to resolve spatial and temporal variations in the column averaged CO2 dry air mole fraction, X(sub CO2) over the sunlit hemisphere. Employ independent calibration and validation approaches to produce X(sub CO2) estimates with random errors and biases no larger than 1-2 ppm (0.3-0.5%) on regional scales at monthly intervals.

three channel grating spectrometry↗

NASA NTRSDate not supplied

RadLab and the Environmental Data Application Dashboard: Graphical and Programming Interfaces for Interrogation of Space Telemetry Data

Sensors on the International Space Station (ISS) and multiple spacecraft elsewhere in Earth orbit and in deep space continuously monitor and collect environmental data, transmitting this information back to Earth. These data include ionizing radiation and, on the ISS, CO2, relative humidity levels, and temperature, and are of great importance to space biology research. Ionizing radiation in particular has been established in ground-based experiments as being correlated with increased risk of carcinogenesis and cardiovascular and neurological effects. Looking ahead to future long duration crewed missions beyond low Earth orbit, the ability to study how factors including CO2 levels, light cycle, temperature modulate the response to ionizing radiation and microgravity is essential. To date, access to these data has been fragmented across space agencies, spacecraft, and databases. To address this issue, NASA’s Open Science Data Repository (osdr.nasa.gov) has developed two Web applications: the Environmental Data Application (EDA) and a radiation-specific RadLab. Each consists of an API (application programming interface) and an associated GUI (graphical user interface) that provide single points of access to the data. To date, OSDR has focused on the sensors from payloads and radiation detectors located on the ISS. The Web applications process telemetry information and associated data, such as spacecraft location and orientation, from multiple international databases. The applications’ request syntax enables users to interrogate these data by craft, sensor type, time range, radiation type (galactic cosmic rays, solar particle events, the contribution of the South Atlantic Anomaly), facilitating arbitrary comparisons of original source data at varying time resolutions. The applications provide programmatic access for use in computational pipelines and GUIs for data visualization and exploration, making these data FAIR (Findable, Accessible, Interoperable, and Reusable), complementing the biological data contained in OSDR, and providing the space science community with a valuable resource for scientific analyses.

radiation↗

NASA NTRS2001

An Assessment of the Ability of Potential Space-Borne Instruments to Resolve Spatial and Temporal Variability of Atmospheric Carbon Dioxide

Mounting concern regarding the possibility that increasing carbon dioxide concentrations will initiate climate change has stimulated interest in the feasibility of measuring CO2 mixing ratios from satellites. Currently, the most comprehensive set of atmospheric CO2 data is from the NOAA CMDL cooperative air sampling network, consisting of more than 40 sites where flasks of air are collected approximately weekly. Sporadic observations in the troposphere and stratosphere from airborne in situ and flask samplers are also available. Although the surface network is extensive, there is a dearth of data in the Southern Hemisphere and most of the stations were intentionally placed in remote areas, far from major sources. Sufficiently precise satellite observations with adequate spatial and temporal resolution would substantially increase our knowledge of the atmospheric CO2 distribution and would undoubtedly lead to improved understanding of the global carbon budget. We use a 3-D chemical transport model to investigate the ability of potential satellite instruments with a variety of orbits, horizontal resolution and vertical weighting functions to capture the variation in the modeled CO2 fields. The model is driven by analyzed winds from the Goddard Data Assimilation Office. Simulated CO2 fields are compared with existing surface and aircraft data, and the effects of the model convection scheme and representation of the planetary boundary layer are considered.

Andrews, Arlyn E.↗