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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Density and optical properties of SPARCS plumes

Propellant gases emitted by attitude control systems such as SPARCS (Solar Pointing Aerobee Rocket Control System) and possible interference with experiments aboard the payloads are discussed. The optical properties of seven actual and potential gases emitted by propellant systems (CF4, N2H4, NH3, N2, CO2, Ar, and He) are presented. A compilation of absorption coefficients from 1 Angstrom to 50 microns and a summary of fluorescent spectra and efficiencies are provided. Since Freon-14 (CF4) is of primary importance to SPARCS, an experimental search for the fluorescent spectrum of CF4 was performed by exciting the gas with 920 Angstrom UV photons. The result was compared with an electron impact induced spectrum of CF4, and conclusions drawn about the nature of the radiating species. A detailed study of the CF4 flow fields and plume densities for typical SPARCS controlled payloads was made using gas dynamic codes which included the effects of vehicle shading and condensation. The importance of the optical properties of CF4 plumes was investigated and it is concluded that absorption is negligible but fluoresence may be significant in some cases.

Brown, W. A.↗
NASA NTRS1975

A comparison of measured and predicted sphere shock shapes in hypersonic flows with density ratios from 4 to 19

Measured shock shapes are presented for sphere and hemisphere models in helium, air, CF4, C2F6, and CO2 test gases, corresponding to normal-shock density ratios (primary factor governing shock detachment distance of blunt bodies at hypersonic speeds) from 4 to 19. These shock shapes were obtained in three facilities capable of generating the high density ratios experienced during planetary entry at hypersonic conditions; namely, the 6-inch expansion tube, with hypersonic CF4 tunnel, and pilot CF4 Mach 6 tunnel (with CF4 replaced by C2F6). Measured results are compared with several inviscid perfect-gas shock shape predictions, in which an effective ratio of specific heats is used as input, and with real-gas predictions which include effects of a laminar viscous layer and thermochemical nonequilibrium.

Miller, C. G., III↗
NASA NTRS1984

Real-gas simulation for the Shuttle Orbiter and planetary entry configurations including flight results

By testing configurations in a gas (like CF4) which can produce high normal-shock density ratios, such as those encountered during hypersonic entry, certain aspects of real-gas effects can be simulated. Results from force-moment, shock-shape and oil flow visualization tests are presented for both the Shuttle Orbiter and a 45 deg sphere-cone in CF4 and air at M = 6, and comparisons are made with flight results. Pitching-moment coefficients measured on a Shuttle Orbiter model in CF4 showed a nose-up increment, compared with air results, that was almost identical to the difference between preflight predictions and flight in the high hypersonic regime. The drag coefficient measured in CF4 on the 45 deg sphere-cone, which is the same configuration used on the forebody of the Pioneer Venus entry vehicles, showed excellent agreement with flight data at M = 6.

Calloway, R. L.↗
NASA NTRS1996

Computational Study of a McDonnell Douglas Single-Stage-to-Orbit Vehicle Concept for Aerodynamic Analysis

This paper presents the results of a computational flow analysis of the McDonnell Douglas single-stage-to-orbit vehicle concept designated as the 24U. This study was made to determine the aerodynamic characteristics of the vehicle with and without body flaps over an angle of attack range of 20-40 deg. Computations were made at a flight Mach number of 20 at 200,000 ft. altitude with equilibrium air, and a Mach number of 6 with CF4 gas. The software package FELISA (Finite Element Langley imperial College Sawansea Ames) was used for all the computations. The FELISA software consists of unstructured surface and volume grid generators, and inviscid flow solvers with (1) perfect gas option for subsonic, transonic, and low supersonic speeds, and (2) perfect gas, equilibrium air, and CF4 options for hypersonic speeds. The hypersonic flow solvers with equilibrium air and CF4 options were used in the present studies. Results are compared with other computational results and hypersonic CF4 tunnel test data.

Prabhu, Ramadas K.↗
DOE OSTI2026

Uniform Whole Wafer Anisotropic Etching of Structural Ta Thin Films

Tantalum (Ta) has promise as a structural material for micromechanical sensors and actuators. Anisotropic etching of alpha (α) phase Ta is required for micromachining applications. Uniform thickness and etch across a full wafer are desirable features. An experimental investigation is conducted to study plasma etching rate and anisotropy in etching α -Ta in relation to pressure and gas flow ratio. A comparatively low toxicity gas, carbon tetrafluoride (CF4), and argon (Ar) are used. Spectrometry by optical emission spectrometry (OES) and residual gas analysis (RGA) are employed to characterize the plasma to gain insight into the etch mechanisms. At low flow, the etch rate is slow due to an inadequate supply of the etching gas, CF4. The etch rate is also slowed at high flow due to a reduced CF4 residence time. Flow and pressure conditions to achieve a good etch rate and vertical sidewalls are identified and explained by means of a full factorial experiment coupled with emission spectra. Finally, with these conditions, uniform etching of 2.5 μm thick α-Ta across a 4-inch wafer is demonstrated.

36 MATERIALS SCIENCE↗
NASA NTRS1979

Holographic flow visualization at NASA Langley

Holographic flow visualization systems at two NASA Langley facilities, a hypersonic blow-down tunnel using CF4 gas and an expansion tube with very short test time, are described. A pulsed ruby laser is used at a CF4 tunnel for single pulse holography, double pulse with several minutes between exposures, and dual plate holographic interferometry. Shadowgraph, schlieren, and interferograms are reconstructed from the holograms in a separate reconstruction lab. At the expansion tube the short run time of 200 microseconds requires precise triggering of its double pulsed ruby laser. With double pulse capability of 20 to 1200 microseconds pulse separation, one pulse can occur before and one later after flow is established to obtain fringe free background interferograms (perfect infinite fringe) or both pulses can occur during flow in order to study flow instabilities. Holograms are reconstructed at the expansion tube with an in-place setup which makes use of a high power CW Argon laser and common optics for both recording and reconstructing the holograms. The holographic systems at the CF4 tunnel and expansion tube are operated routinely for flow visualization by tunnel technicians. Typical flow visualization photographs from both facilities are presented.

Burner, A. W.↗
NASA NTRS1979

Industrial ion source technology

In reactive ion etching of Si, varying amounts of O2 were added to the CF4 background. The experimental results indicated an etch rate less than that for Ar up to an O2 partial pressure of about .00006 Torr. Above this O2 pressure, the etch rate with CF4 exceeded that with Ar alone. For comparison the random arrival rate of O2 was approximately equal to the ion arrival rate at a partial pressure of about .00002 Torr. There were also ion source and ion pressure gauge maintenance problems as a result of the use of CF4. Large scale (4 sq cm) texturing of Si was accomplished using both Cu and stainless steel seed. The most effective seeding method for this texturing was to surround the sample with large inclined planes. Designing, fabricating, and testing a 200 sq cm rectangular beam ion source was emphasized. The design current density was 6 mA/sq cm with 500 eV argon ions, although power supply limitations permitted operation to only 2 mA/sq cm. The use of multiple rectangular beam ion sources for continuous processing of wider areas than would be possible with a single source was also studied. In all cases investigated, the most uniform coverage was obtained with 0 to 2 cm beam overlay. The maximum departure from uniform processing at optimum beam overlap was found to be +15%.

Kaufman, H. R.↗
NASA NTRS1985

Experimental aerodynamic coefficients on a Shuttle-like vehicle at Mach 6 and 10 and comparison to prediction

Aerodynamic coefficients measured for an Orbiter-like configuration are presented for a range of angle of attack from 15 deg to 45 deg at Mach 6 and 10. The low-gamma aspect of a real gas on aerodynamic characteristics and shock detachment distance were simulated by testing this configuration in Mach 6 air (freestream gamma equal to 1.4) and Mach 6 CF4 (freestream gamma equal to 1.17). The effects of Mach number, Reynolds number, and gamma on these measurements are examined and comparisons made to an inviscid flowfield computer code known as HALIS. Pitching-moment coefficients measured in CF4 revealed a nose-up increment when compared with measurements in perfect air, indicative of real-gas effects. In general, the HALIS code accurately predicted the measured aerodynamic coefficients in air and CF4.

Micol, J. R.↗
NASA NTRS2001

The Importance of Optical Pathlength Control for Plasma Absorption Measurements

An inductively coupled GEC Cell with modified viewing ports has been used to measure in-situ absorption in CF4 plasmas via Fourier Transform Infrared Spectroscopy, and the results compared to those obtained in a standard viewport configuration. The viewing ports were modified so that the window boundary is inside, rather than outside, of the GEC cell. Because the absorption obtained is a spatially integrated absorption, measurements made represent an averaging of absorbing species inside and outside of the plasma. This modification is made to reduce this spatial averaging and thus allow a more accurate estimation of neutral species concentrations and temperatures within the plasmas. By reducing this pathlength, we find that the apparent CF4 consumption increases from 65% to 95% and the apparent vibrational temperature of CF4 rises by 50-75 K. The apparent fraction of etch product SiF4 decreases from 4% to 2%. The data suggests that these density changes may be due to significant temperature gradients between the plasma and chamber viewports.

Cruden, Brett A.↗
NASA NTRS2001

Ion Energy and Ion Flux Distributions of CF4/Ar/O2 Inductively Coupled Plasmas in a GEC Cell

Knowledge of ion kinetics in plasma processing gas mixtures, such as CF4:Ar:O2, is important for understanding plasma assisted etching and deposition of materials. Ion energies and ion fluxes were measured in this mixture for 80:10:10, 60:20:20, and 40:30:30 mixture ratios in the pressure range of 10-50 mTorr, and at 200 and 300 W of RF power. Ions from plasma, sampled through a 10 micron orifice in the center of the lower plane electrode, were energy and mass analyzed by a combination of electrostatic energy and quadrupole mass filters. CFx(+) (x = 1 - 3), F2(+), F(+), C(+) from CF4, Ar(+) from Ar, and O2(+) and O(+) from O2, and by-product ions SiFx(+)(x = 1 - 3) from etching of quartz coupling window, COFx(+)(x = 1 - 3), CO(+), CO2(+), and OF(+) were detected. In all conditions ion flux decreases with increase of pressure but increase with increase of RF power. Ar(+) signal decreases with increase of pressure while CF3(+), which is the dominant ion at all conditions, increases with increase in pressure. The loss mechanism for Ar(+) and increase of CF3(+) is due to large cross section for Ar(+) + CF4 yields Ar + CF3(+) + F. Ion energies, which range from 15-25 eV depending on plasma operating conditions, are nearly Gaussian. By-product ion signals are higher at lower pressures indicating stronger plasma interaction with quartz window.

Rao, M. V. V. S.↗
NASA NTRS2004

An Inviscid Computational Study of the Space Shuttle Orbiter and Several Damaged Configurations

Inviscid aerodynamic characteristics of the Space Shuttle Orbiter were computed in support of the Columbia Accident Investigation. The unstructured grid software FELISA was used and computations were done using freestream conditions corresponding to those in the NASA Langley 20-Inch Mach 6 CF4 tunnel test section. The angle of attack was held constant at 40 degrees. The baseline (undamaged) configuration and a large number of damaged configurations of the Orbiter were studied. Most of the computations were done on a half model. However, one set of computations was done using the full-model to study the effect of sideslip. The differences in the aerodynamic coefficients for the damaged and the baseline configurations were computed. Simultaneously with the computation reported here, tests were being done on a scale model of the Orbiter in the 20-Inch Mach 6 CF4 tunnel to measure the deltas . The present computations complemented the CF4 tunnel test, and provided aerodynamic coefficients of the Orbiter as well as its components. Further, they also provided details of the flow field.

Prabhu, Ramadas K.↗
NASA NTRS2005

Holographic Flow Visualization at NASA Langley

Holographic flow visualization systems at two NASA Langley facilities, a hypersonic blow-down tunnel using CF4 gas and an expansion tube with very short test time, are described. A pulsed ruby laser is used at a CF4 tunnel for single pulse holography, double pulse with several minutes between exposures, and dual plate holographic interferometry. Shadow-graph, schlieren, and interferograms are reconstructed from the holograms in a separate reconstruction lab. At the expansion tube the short run time of 200 microseconds requires precise triggering of its double pulsed ruby laser. With pulse separation, one pulse can occur before and one after flow is established to obtain fringe free background interferograms (perfect infinite fringe) or both pulses can occur during flow in order to study flow instabilities. Holograms are reconstructed at the expansion tube with an in-place setup which makes use of a high power CW Argon laser and common optics for both recording and reconstructing the holograms. The holographic systems at the CF4 tunnel and expansion tube are operated routinely for flow visualization by tunnel technicians. Typical flow visualization photographs from both facilities are presented.

Burner, A. W.↗
NASA NTRS1973

Thermodynamic and transport properties of gaseous tetrafluoromethane in chemical equilibrium

Equations and in computer code are presented for the thermodynamic and transport properties of gaseous, undissociated tetrafluoromethane (CF4) in chemical equilibrium. The computer code calculates the thermodynamic and transport properties of CF4 when given any two of five thermodynamic variables (entropy, temperature, volume, pressure, and enthalpy). Equilibrium thermodynamic and transport property data are tabulated and pressure-enthalpy diagrams are presented.

Hunt, J. L.↗
NASA NTRS1973

Evaluation of Raman scattering as a sensor of temperature and molecular density

The performance of the Raman scattering technique for the remote monitoring of temperature and molecular number density in various wind tunnel and engine testing facilities has been experimentally evaluated. Temperature measurements were made by monitoring the pure rotational spectrum of nitrogen and the rotational branch separations of nu2 of CF4 for temperatures in the range 300 to 1000 K. These measurements yielded an average error of 2.6 and 7.6%, respectively, for temperature measurements at pressures near 1 atm. Molecular number density measurements with 20% error could be made at densities as low as 3.5 times 10 to the 22-nd power per cu m by monitoring the 6 to 8 rotational transition of nitrogen, 3.5 times 10 to the 23-rd power per cu m by monitoring the Q-branch of the fundamental vibrational transition of nitrogen, and 7 times 10 to the 22-nd power per cu m by monitoring the nu1 fundamental vibrational transition of CF4.

Bandy, A. R.↗
NASA NTRS1977

Thermodynamic properties of gaseous fluorocarbons and isentropic equilibrium expansions of two binary mixtures of fluorocarbons and argon

Equations and computer code are given for the thermodynamic properties of gaseous fluorocarbons in chemical equilibrium. In addition, isentropic equilibrium expansions of two binary mixtures of fluorocarbons and argon are included. The computer code calculates the equilibrium thermodynamic properties and, in some cases, the transport properties for the following fluorocarbons: CCl2F, CCl2F2, CBrF3, CF4, CHCl2F, CHF3, CCL2F-CCl2F, CCLF2-CClF2, CF3-CF3, and C4F8. Equilibrium thermodynamic properties are tabulated for six of the fluorocarbons(CCl3F, CCL2F2, CBrF3, CF4, CF3-CF3, and C4F8) and pressure-enthalpy diagrams are presented for CBrF3.

Talcott, N. A., Jr.↗
NASA NTRS1982

Experimental investigation of gamma effects on heat transfer to a 0.006 scale Shuttle Orbiter at Mach 6

Real-gas effects on heating to the windward centerline of the Shuttle Orbiter and shock shape were simulated by testing a 0.006-scale Orbiter model in Mach 6 air and CF4 flows. The range of free-stream Reynolds number, based on model length, was 0.4 x 10 to the 6th to 5.3 x 10 to the 6th for air, resulting in laminar and turbulent heating. The Reynolds number for CF4 was 0.3 x 10 to the 6th and gamma was equal to 1.13, corresponding to a normal shock density ratio of 12 as compared to 5.25 in air. Angle of attack was varied from 15 deg to 45 deg in 5 deg increments. Centerline heating distributions were compared for the two gases, and to Mach 8 wind-tunnel data, predictions, and flight (STS-1 and STS-2) data. The present results revealed a significant increase in heating with increasing density ratio and decreasing Reynolds number at the lower angles of attack; the effects of density ratio and Reynolds number diminished with increasing angle of attack and were relatively small at the angles of attack for the hypersonic portion of Space Shuttle Orbiter flights STS-1 and STS-2. Wind-tunnel and flight heating distributions were in relatively good agreement, and the present heating rates in air were accurately predicted by a local infinite swept cylinder analysis.

Miller, C. G.↗
NASA NTRS1983

An experimental investigation of control surface effectiveness and real-gas simulation for biconics

Aerodynamic coefficients, pressure distributions, and oil-flow patterns measured on spherically blunted, 13 degrees/7 degrees on-axis and bent biconics at Mach 6 and 10 in air are compared. Angle of attack, referenced to the axis of the aft cone, was varied from zero to 40 degrees. The effect of deflection of base-mounted flaps on aerodynamic characteristics was examined at Mach 10. Real-gas effects on aerodynamic coefficients, pressure distributions and shock detachment distance were simulated by testing the biconic models in Mach 6 air and Mach 6 CF4 flows. (Density ratio equal to 5.3 for air and 12 for CF4.) The on-axis biconic is stable but cannot be trimmed at angles of attack above zero with the assumed center of gravity and flap configuration. Flaps on the bent biconic produced a stable and trim configuration for angles of attack from zero to 23 degrees. A significant effect of density ratio on aerodynamic coefficients, pressure distribution, and shock detachment distance was observed.

Miller, C. G.↗
NASA NTRS1986

A comparison of computed and measured aerodynamic characteristics of a proposed aeroassist flight experiment configuration

The use of experimental or computed data to evaluate the performance of aeroassist orbital transfer vehicles (AOTVs) is discussed. Aerodynamic and surface pressure data are derived from computed flowfield solutions (the HALIS inviscid flowfield code), the Newtonian theory, and ground-based, wind tunnel studies (hypersonic He tunnel, 31-inch Mach 10 tunnel, and a hypersonic CF4 tunnel). The wind tunnel and HALIS models were tested at angles-of-attack that ranged from -10 to 10 deg. The effects of the ellipticity of the nose, the radius of the circular arc, and the angle through which the arc passes on the aerodynamic characteristics of the vehicles are examined. It is observed that the HALIS and CF4 tunnel generated surface pressure on the AOTVs produced the most useful aerodynamic data. Good correlation is obtained for the experimental and computational data; however, the Newtonian results do not correspond to the tunnel/HALIS data.

Weilmuenster, K. J.↗