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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Optimal Design and Operation of a Solvent-Sorbent Hybrid Capture Process for Minimizing the Cost of High Capture

High capture can cause a significant increase in energy penalty if the appropriate technology/technologies are not utilized. The optimal technology for bulk capture is not necessarily the optimal technology for polishing capture (i.e., high extent of capture from the flue gas with very low partial pressure of CO2). This work investigates the use of MEA for bulk capture with the polishing capture being accomplished by a functionalized metal organic framework (MOF).

Kasturi, Pooja↗
NASA NTRS1994

Nondestructive time-of-capture, location and velocity sensing in intact capture

Velocity sensing of hypervelocity particles was a significant field of interest from the 1960s to 1970s. Generically, velocity sensing has been approached by either of two methods: first, detecting direct plasma or light emissions onto a solid surface, or second, performing time-of-flight by film penetration, or by detecting charged particles passing a static electric field. Impact plasma techniques required the destruction of the particles. Multiple-film penetrations were also destructive, especially for small particles. There is a need for an integrated, reliable, and simple location and velocity sensor compatible to our intact capture underdense medium without contributing additional damage to the captured particle. Since cometary dust, like cosmic dust, is essentially randomly distributed, knowing the time of the dust capture and the location of the capture on the collector permits the identification of the specific dust particle captured. Velocity information helps to determine the trajectory of the dust particle. Our discovery of a very suitable acoustic sensor and fruitful experimental results have led to the realization of a flight velocity sensor with intact capture underdense media.

Tsou, Peter↗
DOE OSTI2015

DEVELOPMENT OF A NOVEL GAS PRESSURIZED STRIPPING (GPS)-BASED TECHNOLOGY FOR CO 2 CAPTURE FROM POST-COMBUSTION FLUE GASES Topical Report: Techno-Economic Analysis of GPS-based Technology for CO 2 Capture

This topical report presents the techno-economic analysis, conducted by Carbon Capture Scientific, LLC (CCS) and Nexant, for a nominal 550 MWe supercritical pulverized coal (PC) power plant utilizing CCS patented Gas Pressurized Stripping (GPS) technology for post-combustion carbon capture (PCC). Illinois No. 6 coal is used as fuel. Because of the difference in performance between the GPS-based PCC and the MEA-based CO2 absorption technology, the net power output of this plant is not exactly 550 MWe. DOE/NETL Case 11 supercritical PC plant without CO2 capture and Case 12 supercritical PC plant with benchmark MEA-based CO2 capture are chosen as references. In order to include CO2 compression process for the baseline case, CCS independently evaluated the generic 30 wt% MEA-based PCC process together with the CO2 compression section. The net power produced in the supercritical PC plant with GPS-based PCC is 647 MW, greater than the MEA-based design. The levelized cost of electricity (LCOE) over a 20-year period is adopted to assess techno-economic performance. The LCOE for the supercritical PC plant with GPS-based PCC, not considering CO2 transport, storage and monitoring (TS&M), is 97.4 mills/kWh, or 152% of the Case 11 supercritical PC plant without CO2 capture, equivalent to $39.6/tonne for the cost of CO2 capture. GPS-based PCC is also significantly superior to the generic MEA-based PCC with CO2 compression section, whose LCOE is as high as 109.6 mills/kWh.

Chen, Shiaoguo↗
DOE OSTI2017

Packet Capture Solutions: PcapDB Benchmark for High-Bandwidth Capture, Storage, and Searching

PcapDB stands alone when looking at the overall field of competitors, from the cost-effective COTS hardware, to the efficient utilization of disk space that enables a longer packet history. A scalable, 100GbE-enabled system that indexes every packet and indexes flow data without complicated load-balancing requirements. The Transport Layer search and indexing approach led to patent-pending flow indexing technology, providing a specialized database system specifically optimized around providing fast flow searches. While there are a plethora of options in network packet capture, there are very few that are able to effectively manage capture rates of more than 10 Gb/s, distributed capture and querying, and a responsive user interface. By far, the primary competitor in the market place is Endace and DeepSee; in addition to meeting the technical requirements we set out in this document, they provide technical support and a fully 'appliance like' system. In terms of cost, however, our experience has been that the yearly maintenance charges alone outstrip the entire hardware cost of solutions like PcapDB. Investment in cyber security research and development is a large part of what has enabled us to build the base of knowlegable workers needed to defend government resources in the rapidly evolving cyber security landscape. We believe projects like Bro, WireCap, and Farm do more than just fill temporary gaps in our capabilities. They give allow us to build the firm foundation needed to tackle the next generation of cyber challenges. PcapDB was built with loftier ambitions than simply solving the packet capture of a single lab site, but instead to provide a robust, scaleable packet capture solution to the DOE complex and beyond.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗
DOE OSTI2021

Integrated Capture and Conversion of CO 2 to Methane Using a Water-lean, Post-Combustion CO 2 Capture Solvent

Integrated Carbon Capture and Conversion of CO 2 into materials (IC3M) is an attractive solution to meet the global energy demand, reduce our dependence on fossil fuels and lower CO 2 emissions. In this work, using a water-lean post combustion capture solvent, (N-(2-ethoxyethyl)-3-morpholinopropan-1-amine) (2-EEMPA), >90% conversion of captured CO2 to hydrocarbons, mostly methane, is achieved in the presence of a heterogenous Ru catalysts under relatively mild reaction conditions (170 °C and <15 bar H 2 pressure). The catalytic performance was better in 2-EEMPA than aqueous 5M monoethanol amine (MEA). Operando NMR study showed in-situ formation of N-formamide intermediate, which underwent further hydrogenation to form methane and other higher hydrocarbons. The technoeconomic analyses (TEA) showed that the proposed integrated process can potentially improve the thermal efficiency by 5% and reduce the total capital investment and minimum synthetic natural gas (SNG) selling price by 32% and 12% respectively compared to conventional Sabatier process, highlighting the energetic and economic benefits of integrated capture and conversion. Methane derived from CO 2 and renewable H 2 source is an attractive fuel, and it has a great potential as a renewable hydrogen carrier as an environmentally responsible carbon capture and utilization approach.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Determination of CO 2 capture during accelerated carbonation of engineered cementitious composite pastes by thermogravimetry

The concerns about greenhouse gas emissions have triggered investigations among the scientific community. The accelerated carbonation curing has been used as a tool to capture CO 2 at early stages of cement-based material fabrication. In a previous study, the authors quantified the amount of CO 2 captured in portland cement pastes by thermal analysis, at high relative humidity precure conditions. In the present work, the authors quantified the amount of CO 2 captured in binary pastes derived from engineered cementitious composites (ECC), a family of composites worldwide used, whose one of their features is the precure at low relative humidity conditions. Two types of ECC pastes (1.2 and 2.2) were submitted to 4 h and 24 h of accelerated carbonation after 24 h of initial hydration. Using thermogravimetry and derivative thermogravimetry, the amounts of captured CO 2 and respective carbonation degrees were quantified. Furthermore, the results showed that ECC paste 1.2 presented the highest values of captured CO 2 and carbonation degree, considering all reactive components. In contrast, ECC paste 2.2 presented the highest values of these two parameters, when considering only portland cement as reactive component. For both pastes, the hydration degrees of the carbonated samples were higher than those of the non-carbonated references, indicating that in the used operating conditions, carbonation enhances ECC paste hydration.

42 ENGINEERING↗
DOE OSTI2021

Performance of a Natural Gas Solid Oxide Fuel Cell System With and Without Carbon Capture

The fuel cell program at the United States Department of Energy (DOE) National Energy Technology Laboratory (NETL) is focused on the development of low-cost, highly efficient, and reliable fossil-fuel-based solid oxide fuel cell (SOFC) power systems that can generate environmentally-friendly electric power with at least 90 percent carbon capture. NETL’s SOFC technology development roadmap is aligned with near-term market opportunities in the distributed generation sector to validate and advance the technology while paving the way for utility-scale natural gas (NG)- and coal-derived synthesis gas-fueled applications via progressively larger system demonstrations. The present study represents a part of a series of system evaluations being carried out at NETL to aid in prioritizing technological advances along research pathways to the realization of utility-scale SOFC systems, a transformational goal of the fuel cell program. In particular, the system performance of utility-scale NG fuel cell (NGFC) systems with and without carbon dioxide (CO2) capture is presented. The NGFC system analyzed features an external auto-thermal reformer (ATR) feeding the fuel to the SOFC system consisting of planar anode-supported SOFC with separated anode and cathode off-gas streams. In systems with CO2 capture, an air separation unit (ASU) is used to provide the oxygen for the ATR and for the combustion of unutilized fuel in the SOFC anode exhaust along with a CO2 purification unit to provide a nearly pure CO2 stream suitable for transport for usage in enhanced oil recovery operations or for storage in underground saline formations. Remaining thermal energy in the exhaust gases is recovered in a bottoming steam Rankine cycle while supplying any process heat requirements. A reduced order model (ROM) developed at the Pacific Northwest National Laboratory (PNNL) is used to predict the SOFC performance. The ROM, while being computationally effective for system studies, provides other detailed information about the state of the stack, such as the internal temperature gradient, generally not available from simple performance models often used to represent the SOFC. Such additional information can be important in system optimization studies to preclude operation under off-design conditions that can adversely impact overall system reliability. The NGFC system performance was analyzed by varying salient system parameters, including the percent of internal (to the SOFC module) NG reformation—ranging from 0 to 100 percent—fuel utilization, and current density. The impact of advances in underlying SOFC technology on electrical performance was also explored.

solid oxide fuel cell (SOFC), natural gas fuel cel↗
DOE OSTI2025

Beta-Amino Carboxylate (BAC) non-aqueous physical solvents for enhanced CO2 separations in pre-combustion carbon capture, industrial CO 2 capture, and biogas upgrading processes

Novel beta-amino carboxylate (BAC) solvents have been synthesized and tested to efficiently capture carbon dioxide (CO 2 ) from process gas streams with CO 2 partial pressure intermediate between pre-combustion and post-combustion capture. The BAC solvents have molecular structures characterized by alkyl-substituted amides or esters containing a secondary amine functional group on the second carbon from the carbonyl carbon (referred to as the beta “β” carbon). The ester or amide functional group combined with optimal steric crowding around the amine nitrogen by proximate alkyl groups are tailored to modify the strength of CO 2 binding in the solvent. The solvents possess high CO 2 solubilities and high gas selectivity including good CO 2 /H 2 O selectivity and can be utilized for CO 2 absorption over a range of partial pressures. Due to low volatility, many of the solvents can be operated at or above ambient temperature which eliminates solvent chilling and allows regeneration using low grade waste heat. These novel solvents offer an opportunity for efficient carbon capture for a range of applications including biogas upgrading, hydrogen production, and pre-combustion carbon capture.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Full-scale FEED Study for Retrofitting the Prairie State Generating Station with an 816 MWe Capture Plant using Mitsubishi Heavy Industries Post-Combustion CO 2 Capture Technology

A full front-end engineering design (FEED) study to for a carbon capture system for Unit #2 (816 MWe) at the Prairie State Generating Company’s (PSGC) Energy Campus in Marissa, IL based on the KM CDR Process CO 2 capture technology from Mitsubishi Heavy Industries (MHI) using their proprietary solvent KS-21TM. If built this carbon capture plant would be the world's largest to date. The cost of capture of 100 percent of the plant emissions was calculated to be $43.42 per metric tonne of CO 2 based on levelized costs for 30 years of operation (85% capacity factor), and includes Interest on Debt and Return on Equity During Operation.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2019

Laser Capture Microdissection–Liquid Vortex Capture Mass Spectrometry Metabolic Profiling of Single Onion Epidermis and Microalgae Cells

Laser capture microdissection is a valuable technique in individually isolating single cells whether in tissue networks or deposited from a cell suspension. New developments have enabled coupling of laser capture microdissection with mass spectrometry via liquid vortex capture sampling probe. This enables online metabolic profiling of sectioned cells. Here, we describe the protocol used to deposit, isolate, and individually chemically characterize single Allium cepa and Chlamydomonas reinhardtii cells by laser capture microdissection–liquid vortex capture mass spectrometry.

Cahill, John F.↗
DOE OSTI2017

Porous Organic Polymers for Post-Combustion Carbon Capture

One of the most pressing environmental concerns of our age is the escalating level of atmospheric CO 2 . Intensive efforts have been made to investigate advanced porous materials, especially porous organic polymers (POPs), as one type of the most promising candidates for carbon capture due to their extremely high porosity, structural diversity, and physicochemical stability. This review provides a critical and in-depth analysis of recent POP research as it pertains to carbon capture. The definitions and terminologies commonly used to evaluate the performance of POPs for carbon capture, including CO 2 capacity, enthalpy, selectivity, and regeneration strategies, are summarized. A detailed correlation study between the structural and chemical features of POPs and their adsorption capacities is discussed, mainly focusing on the physical interactions and chemical reactions. Lastly, a concise outlook for utilizing POPs for carbon capture is discussed, noting areas in which further work is needed to develop the next-generation POPs for practical applications

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2018

Modeling and simulation of CO 2 capture using semipermeable elastic microcapsules

Very high rates of CO2 absorption have been demonstrated using semipermeable microcapsules filled with environmentally benign sodium carbonate solutions (Vericella et al., Nature communications 6, 2015). However, such capsules have also exhibited several traits, including water loss/uptake, elastic swelling and buckling, and precipitation of solids, which make them more complicated to engineer as a carbon capture material. To address this, a mechanistic model for mass transfer and chemical reaction has been developed, which accounts for these behaviors, and can be used as a predictive tool to explore capsule performance under different CO2 capture scenarios. The model uses a modified film theory to describe CO2 and H2O mass transfer rates, a concentration based description of vapor-liquid-solid equilibrium inside the capsule, and an elastic description of the capsule shell. Model predictions compare favorably to literature data for precipitating carbonates, as well as recent data for microcapsule CO2 absorption. The model was used to assess practical issues of capsule water transfer during a temperature swing CO2 absorption/desorption cycle. Model predictions indicate that capsules filled with high weight percent, precipitating sodium carbonate solution could be significantly or completely dehydrated during CO2 absorption. Subsequent rehydration of lean capsules at elevated temperature showed strong sensitivity to both gas humidity, and capsule shell elasticity.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2015

Novel Application of Carbonate Fuel Cell for Capturing Carbon Dioxide from Flue Gas Streams

To address concerns about climate change resulting from emission of CO2 by coal-fueled power plants, FuelCell Energy, Inc. has developed the Combined Electric Power and Carbon-dioxide Separation (CEPACS) system concept. The CEPACS system utilizes Electrochemical Membrane (ECM) technology derived from the Company’s Direct FuelCell® products. The system separates the CO2 from the flue gas of other plants and produces electric power using a supplementary fuel. FCE is currently evaluating the use of ECM to cost effectively separate CO2 from the flue gas of Pulverized Coal (PC) power plants under a U.S. Department of Energy contract. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from the flue gas with no more than 35% increase in the cost of electricity. The project activities include: 1) laboratory scale operational and performance tests of a membrane assembly, 2) performance tests of the membrane to evaluate the effects of impurities present in the coal plant flue gas, in collaboration with Pacific Northwest National Laboratory, 3) techno-economic analysis for an ECM-based CO2 capture system applied to a 550 MW existing PC plant, in partnership with URS Corporation, and 4) bench scale (11.7 m2 area) testing of an ECM-based CO2 separation and purification system.

CO2 separation, Carbon capture, electrochemical me↗
DOE OSTI2017

Highly Efficient Carbon Monoxide Capture by Carbanion-Functionalized Ionic Liquids through C-Site Interactions

A novel method for the highly efficient and reversible capture of CO in carbanion-functionalized ionic liquids (ILs) by a C-site interaction is reported. Because of its supernucleophilicity, the carbanion in ILs could absorb CO efficiently. As a result, a relatively high absorption capacity for CO (up to 0.046 mol mol -1 ) was achieved under ambient conditions, compared with CO solubility in a commonly used IL [Bmim][Tf 2 N] (2×10 -3 mol mol -1 ). The results of quantum mechanical calculations and spectroscopic investigation confirmed that the chemical interaction between the C-site in the carbanion and CO resulted in the superior CO absorption capacities. In addition, the subsequent conversion of captured CO into valuable chemicals with good reactivity was also realized through the alkoxycarbonylation reaction under mild conditions. Highly efficient CO absorption by carbanion-functionalized ILs provides a new way of separating and converting CO.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Directly Spun Epoxy-Crosslinked Polyethylenimine Fiber Sorbents for Direct Air Capture and Postcombustion Capture of CO 2

A novel, directly injected solid fiber sorbent is synthesized from a solvent-stable, epoxy-crosslinked basic immobilized amine sorbent (BIAS) for CO 2 capture. Leach resistance of the BIAS organics toward 1-methyl-2-pyrrolidone/H 2 O (90/10, fiber solvent) reaches near 100% at the expense of CO 2 capture and is achieved by increasing the extent of crosslinking. The optimized fiber sorbent, prepared with an N,N-diglycidyl-4-glycidyloxyaniline/polyethylenimine (PEI)-0.35/1 wt. ratio, retains 79.2% of PEI and captures 0.37 (direct air capture [DAC]) and 0.67 (postcombustion) mmol CO 2 g-fiber -1 . A nonoptimized prototype hollow fiber exhibits a stable 0.2 mmol CO 2 g-fiber -1 during DAC cycling and is assembled into a ten-fiber module. In conclusion, these results demonstrate a large step toward practical application of this material.

42 ENGINEERING↗