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At least 55 records · Page 3

Comparison of OARE Accelerometer Data with Dopant Distribution in Se-Doped GaAs Crystals Grown During USML-1

Experiments were conducted in the crystal growth furnace (CGF) during the first United States Microgravity Laboratory (USML-1), the STS-50 flight of the Space Shuttle Columbia, to determine the segregation behavior of selenium in bulk GaAs in a microgravity environment. After the flight, the selenium-doped GaAs crystals were sectioned, polished, and analyzed to determine the free carrier concentration as a function of position, One of the two crystals initially exhibited an axial concentration profile indicative of diffusion controlled growth, but this profile then changed to that predicted for a complete mixing type growth. An analytical model, proposed by Naumann [R.J. Naumann, J. Crystal Growth 142 (1994) 253], was utilized to predict the maximum allowable microgravity disturbances transverse to the growth direction during the two different translation rates used for each of the experiments. The predicted allowable acceleration levels were 4.86 microgram for the 2.5 micrometers/s furnace translation rate and 38.9 microgram for the 5.0 micrometers/s rate. These predicted values were compared to the Orbital Acceleration Research Experiment (OARE) accelerometer data recorded during the crystal growth periods for these experiments. Based on the analysis of the OARE acceleration data and utilizing the predictions from the analytical model, it is concluded that the change in segregation behavior was not caused by any acceleration events in the microgravity environment.

Moskowitz, Milton E.↗

Rate and time dependent failure of structural adhesives

Studies on two adhesives (Metlbond 1113 and 1113-2) identified as having important applications in the bonding of composite materials are presented. A testing program to ascertain stress-strain, strain-rate, time, yield, and/or failure behavior of these materials in bulk form using uniaxial tensile constant strain-rate, creep, and relaxation tests is described. The stress-strain behavior of each material is shown to be significantly rate dependent. A rate dependent stress whitening (crazing) phenomenon occurs prior to either yield or fracture. A region of linear elasticity, a region of viscoelasticity, and the onset of yielding are identified in the stress-strain behavior. The linear elastic limit and the yield point are shown to be rate dependent and agree well with an empirical equation proposed by Ludwik. A creep to failure phenomenon is shown to exist and is correlated with a delayed yield equation proposed by Crochet. Analytical predictions based on a modified Bingham model are shown to agree well with experimental stress-strain strain-rate data. Analytical predictions based on a modified Ramberg-Osgood equation are also shown for comparison purposes.

Brinson, H. F.↗

Experiments to investigate particulate materials in reduced gravity fields

Study investigates agglomeration and macroscopic behavior in reduced gravity fields of particles of known properties by measuring and correlating thermal and acoustical properties of particulate materials. Experiment evaluations provide a basis for a particle behavior theory and measure bulk properties of particulate materials in reduced gravity.

Bowden, M.↗

Failure criteria for viscoelastic materials

Research projects concerned with developing a theory of fracture of materials are discussed. The effects of the geometry of the structure and the loads acting on the structure as they influence the failure process are analyzed. The effects of the viscoelastic deformation characteristics of the bulk elastomer on failure behavior are examined. Additional material parameters which control the fracture process are identified.

Knauss, W. G.↗

Consecutive plate acoustic suppressor apparatus and methods

An apparatus and method for suppressing acoustic noise utilizes consecutive plates, closely spaced to each other so as to exploit dissipation associated with sound propagation in narrow channels to optimize the acoustic resistance at a liner surface. The closely spaced plates can be utilized as high temperature structural materials for jet engines by constructing the plates from composite materials. Geometries of the plates, such as plate depth, shape, thickness, inter-plate spacing, arrangement, etc., can be selected to achieve bulk material-like behavior.

Doychak, Joseph↗

On accurate determination of contact angle

Methods are proposed that exploit a microgravity environment to obtain highly accurate measurement of contact angle. These methods, which are based on our earlier mathematical results, do not require detailed measurement of a liquid free-surface, as they incorporate discontinuous or nearly-discontinuous behavior of the liquid bulk in certain container geometries. Physical testing is planned in the forthcoming IML-2 space flight and in related preparatory ground-based experiments.

Concus, P.↗

Estimating the Size and Timing of Maximum Amplitude for Cycle 23 from Its Early Cycle Behavior

On the basis of the lowest observed smoothed monthly mean sunspot number, cycle 23 appears to have conventionally begun in May 1996, in conjunction with the first appearance of a new cycle, high-latitude spot-group. Such behavior, however, is considered rather unusual, since, previously (based upon the data- available cycles 12-22), the first appearance of a new cycle, high-latitude spot- group has always preceded conventional onset by at least 3 months. Furthermore, accepting May 1996 as the official start for cycle 23 poses a dilemma regarding its projected size and timing of maximum amplitude. Specifically, from the max-min and amplitude-period relationships we infer that cycle 23 should be above average in size and a fast riser, with maximum amplitude occurring before May 2000 (being in agreement with projections for cycle 23 based on precursor information), yet from its initial languid rate of rise (during the first 6 months of the cycle) we infer that it should be below average in size and a slow riser, with maximum amplitude occurring after May 2000. The dilemma vanishes, however, when we use a slightly later-occurring onset. For example, using August 1996, a date associated with a local secondary minimum prior to the rapid rise that began shortly thereafter (in early 1997), we infer that cycle 23's rate of rise is above that for the mean of cycles 1-22, the mean of cycles 10-22 (the modern era cycles), the mean of the modern era'fast risers,' and the largest of the modern era 'slow risers' (i.e., cycle 20), thereby, suggesting that cycle 23 will be both fast-rising and above average in size, peaking before August 2000. Additionally, presuming cycle 23 to be a well- behaved fast-rising cycle (regardless of whichever onset date is used), we also infer that its maximum amplitude likely will measure about 144.0 q+/- 28.8 (from the general behavior found for the bulk of modern era fast risers; i.e., 5 of 7 have had their maximum amplitude to lie within 20% of the mean curve for modern era fast risers). It is apparent, then, that sunspot number growth during 1998 will prove crucial for correctly establishing the size and shape of cycle 23.

Wilson, Robert M.↗

Consecutive Plate Acoustic Suppressor Apparatus and Methods

An apparatus and method for suppressing acoustic noise utilizes consecutive plates, closely spaced to each other so as to exploit dissipation associated with sound propagation in narrow channels to optimize the acoustic resistance at a liner surface. The closely spaced plates can be utilized as high temperature structural materials for jet engines by constructing the plates from composite materials. Geometries of the plates, such as plate depth, shape, thickness, inter-plate spacing, arrangement, etc., can be selected to achieve bulk material-like behavior.

Doychak, Joseph↗

Buoyancy and Pressure Effects on Bulk Metal-Oxygen Reactions

The combustion behavior of metal-oxygen reactions if a weakly buoyant environment is studied to understand the rate-controlling mechanisms in the homogeneous and heterogeneous combustion of bulk metals. Cylindrical titanium and magnesium specimens are ignited in pure-oxygen at pressures ranging from 0.1 to 4.0 atm. Reduced gravity is obtained from an aircraft flying parabolic trajectories. A weakly buoyant environment is generated at low pressures under normal gravity and also at 1 atm under reduced gravity (0.01g). The similarity between these two experimental conditions comes from the p(exp 2)g buoyancy scale extracted from the Grashof number. Lower propagation rates of the molten interface on titanium samples are found at progressively lower pressures at 1 g. These rates are compared to theoretical results from heat conduction analyses with a diffusion/convection controlled reaction. The close agreement found between experimental and theoretical values indicate the importance values indicate the importance of natural convection enhanced oxygen transport on combustion rates. For magnesium, progressively longer burning times are experienced at lower pressures and 1 g. Under reduced gravity conditions at 1 atm, a burning time twice as long as in 1 g is exhibited. However, in this case, the validity of the p(exp 2)g buoyancy scale remains untested due to the inability to obtain steady gas-phase burning of the magnesium sample at 0.1 atm. Nevertheless, longer burning times and larger flame standoff distance at low pressures and at low gravity points to a diffusion/convection controlled reaction.

Abbud-Madrid, A.↗

The viscoelastic behavior of notched glassy polymers

In the bulk, glassy polymers exhibit a nonlinear viscoelastic response during deformation. Stress or strain induced damage (i.e. crazing, microshear banding) results in the production of nonrecoverable work and observed nonlinearity. Stress or strain dependent shift factors have been used to mathematically model the mechanical behavior of these polymers. Glassy polymers that have been notched, may exhibit very different load displacement response compared to the same material under bulk deformation. If a sharp notch is introduced into the body then loaded, the load displacement trace may appear to be single-valued in the absence of viscoelasticity and crack growth. This suggests the volume of damaged material is small compared to the overall dimensions of the specimen. The ability to produce a single-valued load-load-line displacement trace through the use of the Correspondence Principle may prove to be useful for fracture of viscoelastic materials.

Crook, R. A.↗

Advances in the theory and application of BSF cells

A study to determine the influence of fabrication processes and bulk material properties on the behavior of back surface field (BSF) cells is reported. It is concluded that a photovoltage is generated at the p(+), p back junction of the cell. The concept of majority carrier collection is proposed as a possible mechanism for this generation. Advantages accruing to the advent of BSF cells are outlined.

Mandelkorn, J.↗

A Study of Nucleate Boiling with Forced Convection in Microgravity

The ultimate objective of basic studies of flow boiling in microgravity is to improve the understanding of the processes involved, as manifested by the ability to predict its behavior. This is not yet the case for boiling heat transfer even in earth gravity, despite the considerable research activity over the past 30 years. The elements that constitute the nucleate boiling process - nucleation, growth, motion, and collapse of the vapor bubbles (if the bulk liquid is subcooled) - are common to both pool and flow boiling. It is well known that the imposition of bulk liquid motion affects the vapor bubble behavior relative to pool boiling, but does not appear to significantly influence the heat transfer. Indeed, it has been recommended in the past that empirical correlations or experimental data of pool boiling be used for design purposes with forced convection nucleate boiling. It is anticipated that such will most certainly not be possible for boiling in microgravity, based on observations made with pool boiling in microgravity. In earth gravity buoyancy will act to remove the vapor bubbles from the vicinity of the heater surface regardless of how much the imposed bulk velocity is reduced, depending, of course, on the geometry of the system. Vapor bubbles have been observed to dramatically increase in size in pool boiling in microgravity, and the heat flux at which dryout took place was reduced considerably below what is generally termed the critical heat flux (CHF) in earth gravity, depending on the bulk liquid subcooling. However, at heat flux levels below dryout, the nucleate pool boiling process was enhanced considerably over that in earth gravity, in spite of the large vapor bubbles formed in microgravity and perhaps as a consequence. These large vapor bubbles tended to remain in the vicinity of the heater surface, and the enhanced heat transfer appeared to be associated with the presence of what variously has been referred to as a liquid microlayer between the bubble and the heater surface. The enhancement of the boiling process with low velocities in earth gravity for those orientations producing the formation of a liquid macrolayer described above, accompanied by "sliding" vapor bubbles, has been demonstrated. The enhancement was presented as a function of orientation, subcooling, and heated length, while a criterion for the heat transfer for mixed natural/forced convection nucleate boiling was given previously. A major unknown in the prediction and application of flow boiling heat transfer in microgravity is the upper limit of the heat flux for the onset of dryout (or critical heat flux - CHF), for given conditions of fluid-heater surfaces, including geometry, system pressure and bulk liquid subcooling. It is clearly understood that the behavior in microgravity will be no different than on earth with sufficiently high flow velocities, and would require no space experimentation. However, the boundary at which this takes place is still an unknown. Previous results of CHF measurements were presented for low velocity flow boiling at various orientations in earth gravity as a function of flow velocity and bulk liquid subcooling, along with preliminary measurements of bubble residence times on a flat heater surface. This showed promise as a parameter to be used in modeling the CHF, both in earth gravity and in microgravity. The objective of the work here is to draw attention to and show results of current modeling efforts for the CHF, with low velocities in earth gravity at different orientations and subcoolings. Many geometrical possibilities for a heater surface exist in flowing boiling, with boiling on the inner and outer surfaces of tubes perhaps being the most common. If the vapor bubble residence time on and departure size from the heater surface bear a relationship to the CHF, as results to be given indicate, it is important that visualization of and access to vapor bubble growth be conveniently available for research purposes. In addition, it is desirable to reduce the number of variables as much as possible in a fundamental study. These considerations dictated the use of a flat heater surface, which is rectangular in shape, 1.91 cm by 3.81 cm (0.75 x 1.5 inches), consisting either of a 400 Angstrom thick semi-transparent gold film sputtered on a quartz substrate which serves simultaneously as a heater and a resistance thermometer, or a copper substrate of the same size. The heater substrate is a disc which can be rotated so that the heated length in the flow direction can be changed from 1.91 to 3.81 cm (0.75 to 1.5 inches). The fluid is R-113, and the velocities can be varied between 0.5 cm/s and 60 cm/s. For a sufficiently low velocity the CHF can be modeled reasonably well at various orientations by the correlation for pool boiling corrected for the influence of bulk liquid subcooling, multiplied by the square root of q, the angle relative to horizontal. This arises from equating buoyancy and drag forces in the inverted positions where the vapor bubbles are held against the heater surface as they slide. A distortion of the measurements relative to pool boiling occurs as the flow velocity increases. In modeling this effect at different levels of subcooling it appeared appropriate to estimate the volumetric rate of vapor generation, using measurements of bubble frequency (or residence time), void fraction and average bubble boundary layer thickness. These were determined with the use of a platinum hot wire probe 0.025 mm in diameter by 1.3 mm long, applying a constant current to distinguish between contact with liquid or vapor. Two-dimensional spatial variations are obtained with a special mechanism to resolve displacements in increments of 0.025 mm. From such measurements it was determined that the fraction of the surface heat transfer resulting in evaporation varies inversely with the subcooling correction factor for the CHF. The measured inverse bubble residence time is normalized relative to that predicted for an infinite horizontal flat plate at the CHF, and is correlated well with the CHF normalized relative to that for pool boiling, for various orientation angles and subcooling levels. This correspondence is then combined with a normalizing factor for the energy flux leaving the heater surface at the CHF and the computed bubble radius at departure, determined from the balance between the outward velocity of the interface due to evaporation and the buoyance induced velocity of the center of mass of the bubble. The product of the CHF and the corresponding residence time was determined to be a constant for all orientations at a given bulk flow velocity and liquid subcooling, and must be determined empirically for each velocity and subcooling at present. It then becomes possible to predict the CHF for the different orientations, velocities, and subcoolings. These are compared with normalized measurements of the CHF for velocities ranging from 4 cm/s to 55 cm/s, subcoolings from 2.8 to 22.2 K, over orientations angles of 360 degrees.

Merte, Herman, Jr.↗

An investigation of environmental influence on the creep behavior of a low pressure plasma sprayed NiCoCrAlY alloy

Low pressure sprayed MCrAlY overlay coatings are currently being used on advanced single crystal superalloy blades for gas turbine engines. Many studies were made on the influence of coatings on the mechanical properties of superalloys in oxidizing or hot-corroding environments, but very few on the properties of the bulk coating alloy itself. The creep behavior of a typical NiCoCrAlY alloyd (PWA 276) was studied in air and vacuum. The as-received low pressure plasma sprayed NiCoCrAlY plates were heat treated for 4 h at 1080 C followed by 32 h at 870 C, the heat treatment applied to coated superalloy parts. Standard creep specimens 12.7 mm long and 3.2 mm in diameter were then machined. Constant load creep-rupture tests were performed in air and vacuum at 650, 850, and 1050 C and various initial stresses. In addition, some specimens were preoxidized at 1050 C for 100 h prior to testing. Results are briefly discussed.

Hebsur, M. G.↗

Structure property behavior of polyimide siloxane segmented copolymers

Procedures were developed for preparing soluble fully imidized polyimide-polydimethyl siloxane segmented copolymers of wide ranging compositions. At low siloxane levels, the materails behave as modified polyimides. At higher concentrations, the materials are analogous to thermoplastic elastomers. Characterization by dynamic mechanical and thermal analysis methods will be reported along with an assesment of the bulk mechanical properties and the surface behavior. The surface behavior is particularly interesting since the materials can be tailored to have siloxane surfaces even at rather low siloxane contents. This influences a number of properties such as the coefficient of friction and, importanly, the degradation of these materials under aggressive oxygen environments (e.g., atomic oxygen, oxygen plasma).

Arnold, C. A.↗

Elastic constant versus temperature behavior of three hardened maraging steels

Elastic constants of three maraging steels were determined by measuring ultrasonic velocities. Annealed steels show slightly lower bulk moduli and considerably lower shear moduli than hardened steels. All the elastic constants (Young's modulus, shear modulus, bulk modulus and Poisson's ratio) show regular temperature behavior between 76 and 400 K. Young's modulus and the shear modulus increase with increasing yield strength, but the bulk modulus and Poisson's ratio are relatively unchanged. Elastic anisotropy is quite small.

Ledbetter, H. M.↗

Extensional Flow of Bulk Polymers

A study was made of the behavior of polyisobutylene under motion at a constant stretch history for both strip biaxial extensional flow and simple extensional flow. Steady-state non-Newtonian viscosities were observed at various constant stretch histories. Newtonian viscosities for both strip biaxial and simple extensional flow were found to be in agreement with the classical theory. The results of the study provide an essential part of the experimental background necessary for the development of a new general stress-strain-time relation for uncrosslinked and lightly crosslinked polymers.

Peng, T. J.↗

Mechanical Properties of Air Plasma Sprayed Environmental Barrier Coating (EBC) Materials

Development work in Environmental Barrier Coatings (EBCs) for Ceramic Matrix Composites (CMCs) has focused considerably on the identification of materials systems and coating architectures to meet application needs. The evolution of these systems has occurred so quickly that modeling efforts and requisite data for modeling lag considerably behind development. Materials property data exists for many systems in the bulk form, but the effects of deposition on the critical properties of strength and fracture behavior are not well studied. We have plasma sprayed bulk samples of baseline EBC materials (silicon, ytterbium disilicate) and tested the mechanical properties of these materials to elicit differences in strength and toughness. We have also endeavored to assess the mixed-mode fracture resistance, Gc, of silicon in a baseline EBC applied to SiCSiC CMC via four point bend test. These results are compared to previously determined properties of the comparable bulk material.

Ceramic Matrix Composites (CMC's)↗

Effect of shock pressure on the structure and superconducting properties of Y-Ba-Cu-O in explosively fabricated bulk metal-matrix composites

While it is now well established that copper-oxide-based power, or virtually any other ceramic superconductor powder, can be consolidated and encapsulated within a metal matrix by explosive consolidation, the erratic superconductivity following fabrication has posed a major problem for bulk applications. The nature of this behavior was found to arise from microstructural damage created in the shock wave front, and the residual degradation in superconductivity was demonstrated to be directly related to the peak shock pressure. The explosively fabricated or shock loaded YBa2Cu3Ox examples exhibit drastically altered rho (or R) - T curves. The deterioration in superconductivity is even more noticeable in the measurement of ac magnetic susceptibility and flux exclusion or shielding fraction which is also reduced in proportion to increasing peak shock pressure. The high frequency surface resistance (in the GHz range) is also correspondingly compromised in explosively fabricated, bulk metal-matrix composites based on YBa2Cu3O7. Transmission electron microscopy (including lattice imaging techniques) is being applied in an effort to elucidate the fundamental (microstructural) nature of the shock-induced degradation of superconductivity and normal state conductivity. One focus of TEM observations has assumed that oxygen displaced from b-chains rather than oxygen-vacancy disorder in the basal plane of oxygen deficient YBa2Cu3Ox may be a prime mechanism. Shock-wave displaced oxygen may also be locked into new positions or interstitial clusters or chemically bound to displaced metal (possibly copper) atoms to form precipitates, or such displacements may cause the equivalent of local lattice cell changes as a result of stoichiometric changes. While the shock-induced suppression of T(sub c) is not desirable in the explosive fabrication of bulk metal-matrix superconductors, it may be turned into an advantage if the atomic-scale distortion can be understood and controlled as local flux pinning sites.

Murr, L. E.↗