A study of the application of microwave techniques to the measurement of solid propellant burning rates Final report
Utilization of Doppler microwave interferometer for measuring solid propellant burning rates
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Utilization of Doppler microwave interferometer for measuring solid propellant burning rates
An analytical model of the steady-state burning of composite solid propellants is presented. An improved burning rate model is achieved by incorporating an improved AP monopropellant model, a separate energy balance for the binder in which a portion of the diffusion flame is used to heat the binder, proper use of the binder regression rate in the model, and a model for the combustion of the energetic binder component of CMDB propellants. Also, an improved correlation and model of aluminum agglomeration is developed which properly describes compositional trends.
Microwave techniques for measurement of solid rocket propellant burning rates
Using the theory of gas dynamics and heat transfer from a turbulent gas flow to the burning surface of propellant along a permeable wall, an explicit expression is derived to predict the burning rate of the solid propellant with crossflow. Results of the calculation have been compared with experimental data and proved to be correct.
Temperature at which predecomposition or decomposition of ammonium perchlorate occurs, changed by perchlorate surface treatment and reflected in burning rate of propellant containing perchlorate
The relationships among excursions of mean chamber pressure, high frequency pressure oscillations and accelerations associated with tangential mode combustion instability are considered. A data reduction procedure was devised to utilize the precise pressure time data as input to a numerical solution of the chamber mass balance relationships. The results indicate that both elevated burning rate induced by the tangential wave motions and variable nozzle blockage due to passage of vortical flow through the nozzle throat must act together to generate the large mean pressure peaks observed in the tests. There is strong correlation between the amplitude of wave motions and the level of mean pressure rise. Evidence for the presence of traveling tangential waves at the time of the D.C. shift was found by use of dual Kistler pressure transducers mounted at the head end of the burner. A very unusual frequency history was found to accompany the high amplitude disturbances. This was consistent from test to test and may represent an additional source of information regarding the complicated flow combustion interactions within the propellant burning zone.
Combustion of methanol, ethanol, propanol-1, n-pentane, n-heptane, and n-decane was observed in air under natural convection conditions, at pressures up to 100 atm. The droplets were simulated by porous spheres, with diameters in the range from 0.63 to 1.90 cm. The pressure levels of the tests were high enough so that near-critical combustion was observed for methanol and ethanol. Due to the high pressures, the phase-equilibrium models of the analysis included both the conventional low-pressure approach as well as high-pressure versions, allowing for real gas effects and the solubility of combustion-product gases in the liquid phase. The burning-rate predictions of the various theories were similar, and in fair agreement with the data. The high-pressure theory gave the best prediction for the liquid-surface temperatures of ethanol and propanol-1 at high pressure. The experiments indicated the approach of critical burning conditions for methanol and ethanol at pressures on the order of 80 to 100 atm, which was in good agreement with the predictions of both the low- and high-pressure analysis.
Flame spread over solid fuels is a canonical problem in fire science, due to its direct implications on material flammability and importance in fire development. Flames in a microgravity environment can behave very differently than on Earth, posing additional risks for spaceflight life safety. Sub-atmospheric pressures in ground-based experiments have been proposed to approximately replicate the burning behavior of solid fuels in reduced gravity conditions because of similar effects on heat and mass transfer mechanisms from the flame to the solid. In opposed-flow flame spread, the solid fuel is heated by the flame ahead of its leading edge, and this process is strongly affected by the ambient conditions. In this work, we consider flames spreading over flat thin acrylic samples exposed to a forced flow of 20 cm/s, and pressures between 30 and 100 kPa. When radiation losses and chemical kinetic effects are neglected, experimental and theoretical results suggest an independence of the spread rate on pressure. However, the spread rate shows a decreasing trend with lower pressure in the range 30-60 kPa. The mass burning rate, calculated from the samples weight measured before and after the experiments, shows a similar trend. The flame length, on the other hand, shows a non-monotonic behavior, reaching a maximum at 60 kPa. Additionally, gas emissions measured during the experiments are used to estimate the heat release rate of the spreading flames. The comparison of the heat release rate obtained from the measured emissions and the estimated mass burning rates, suggests that chemical kinetics is not driving the decrease in flame spread observed at low pressures, whereas radiation losses could be responsible in analogy to what has been observed in micro and partial gravity studies. These results could provide more information to guide future Earth-based material flammability testing for spacecraft applications.
The burning behavior of pressed binderless HMX laterally confined in 6.4 mm i.d. steel cases was measured over the pressure range 1.45 to 338 MPa in a constant pressure strand burner. The measured regression rates are compared to those reported previously for unconfined samples. It is shown that lateral confinement results in a several-fold decrease in the regression rate for the coarse particle size HMX above the transition to super fast regression. For class E samples, confinement shifts the transition to super fast regression from low pressure to high pressure. These results are interpreted in terms of the previously proposed progressive deconsolidation mechanism. Preliminary holographic photography and closed bomb tests are also described. Theoretical one dimensional modeling calculations were carried out to predict the expected flame height (particle burn out distance) as a function of particle size and pressure for binderless HMX burning by a progressive deconsolidation mechanism.
Kinetics and energetics of condensed phase thermal decomposition reactions of ammonium perchlorate composite propellants analyzed, using differential scanning calorimetry
New theoretical method for prediction of erosive burning characteristics of solid propellant, using known ballistic and thermodynamic data only, is presented. Method is based on modified Lenoir-Robillard formula, and is applicable for composite and double base propellants, with or without negative erosion effect. Method is confirmed using experimental data of numerous authors.
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Combustibility tester fits into a sealed chamber so that tests may be performed under controlled atmospheric pressure and compostion. Support frame allows rotation of the test sample so that ignition combustion may be tested in various orientations from horizontal to vertical.
Combustion characteristics and safety factors for hydrogen diffusion flames in flare stack operations
Steady-state combustion modeling of composite solid propellants is discussed with emphasis on the Beckstead-Derr-Price (BDP) model. The BDP model and some revisions are considered with respect to the analysis of monomodal ammonium perchlorate/inert binder propellants: topics examined include continuity relations, surface area relations, characteristic surface dimension, flame heights, and energy balance. Application of the BDP model to more complicated propellants containing multiple active ingredients is described. These propellants include multimodal, mixed oxidizer, active binder, aluminized, catalyzed, and nitramine propellants. Example cases of modeling (with comparison to experimental data) are presented, and strengths and weaknesses of current modeling approaches are evaluated.
The effect of the final mixing time on quality of smokeless AP/HTPB propellant with bimodal AP was examined. Identical ingredients were mixed for various intervals, cast in a circular tube, then fired in a static test. Mechanical properties were measured and initial moduli were calculated from the initial slope of the S-N curves. A theoretical model was developed using the data to quantitatively configure a quality control procedure. A minimum time for mixing fine and coarse AP particles was identified and was approximated to within a factor of two or three using a viscous dispersion time and the surface areas of the particles. The model could be improved by considering settling time and particle size distribution effects.