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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Measurements of trace constituents from atmospheric infrared emission and absorption spectra, a feasibility study

The feasibility of detecting eight trace constituents (CH4, HCl, HF, HNO3, NH3, NO, NO2 and SO2) against the rest of the atmospheric background at various altitudes from infrared emission and absorption atmospheric spectra was studied. Line-by-line calculations and observational data were used to establish features that can be observed in the atmospheric spectrum due to each trace constituent. Model calculations were made for experimental conditions which approximately represent state of the art emission and absorption spectrometers.

Goldman, A.↗
DOE OSTI2020

Emerging investigator series: influence of marine emissions and atmospheric processing on individual particle composition of summertime Arctic aerosol over the Bering Strait and Chukchi Sea

The Arctic is rapidly transforming due to sea ice loss, increasing shipping activity, and oil and gas development. Associated marine and combustion emissions influence atmospheric aerosol composition, impacting complex aerosol–cloud–climate feedbacks. To improve understanding of the sources and processes determining Arctic aerosol composition, atmospheric particles were collected aboard the Korean icebreaker R/V Araon cruising within the Bering Strait and Chukchi Sea during August 2016. Offline analyses of individual particles by microspectroscopic techniques, including scanning electron microscopy with energy dispersive X-ray spectroscopy and atomic force microscopy with infrared spectroscopy, provided information on particle size, morphology, and chemical composition. The most commonly observed particle types were sea spray aerosol (SSA), comprising ~60–90%, by number, of supermicron particles, and organic aerosol (OA), comprising ~50–90%, by number, of submicron particles. Sulfate and nitrate were internally mixed within both SSA and OA particles, consistent with particle multiphase reactions during atmospheric transport. Within the Bering Strait, SSA and OA particles were more aged, with greater number fractions of particles containing sulfate and/or nitrate, compared to particles collected over the Chukchi Sea. This is indicative of greater pollution influence within the Bering Strait from coastal and inland sources, while the Chukchi Sea is primarily influenced by marine sources.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1988

Calculation of space station infrared irradiance from atmosphere-induced emissions

The excitation mechanisms and radiance estimates over the 1 to 10 micron region for CO2(v), H2O(v), CO(v), OH(v), NO2(2B-2A) and N2(B3 pi - A3 sigma) are discussed. The infrared irradiance of the Space Station at an altitude of 460 km was estimated. The surface material was presumed to be non-carbonaceous and inert. The determined number densities of the various gases relevant to the Space Station from both ambient and outgassing sources are presented. A model for the production of and emission from the infrared active molecules was constructed that considers two classes of production processes: (1) gas phase excitation of molecules in the near Station environment by collision with ambient flux; and (2) surface processes that lead to molecular excitation. A composite spectrum of all major emitting species shows that the observed irradiance is non-uniform over the 1 to 8 micron region. The comparison of predicted irradiance with the zodiacal background indicates that the Space Station infrared background from atmosphere-induced emissions may be a problem of consequence.

Fraser, M. E.↗
NASA NTRS1978

Measurements of constituents of interest in the photochemistry of the ozone layer using infrared techniques

Infrared solar spectra and infrared atmospheric emission spectra were obtained from the ground, from aircraft and from balloons. The initial detection of most stratospheric molecules was achieved by the solar spectral technique because better resolution helps remove interference from other molecules. Because the sun is an intense source of radiation, the resolution which can be obtained with good signal-to-noise, is greater than with atmospheric emission spectroscopy. Data are generally taken using a method that enhances the number of molecules in the optical path i.e. at large solar zenith angles for solar spectra and at low elevation angles for atmospheric emission spectra. The search for molecules which are predicted to be present but which, the detection of a molecule known to be present from other measurement techniques but observed for the first time in infrared solar spectra, and some further data on the variability of HNO3 are discussed.

Murcray, D. G.↗
NASA NTRS1994

Topside observation of gravity waves

The AEPI (Atmospheric Emissions Photometric Imager) experiment on the ATLAS-1 shuttle mission (launched March 24, 1992) imaged the earth night airglow emission in O2 Atmospheric (0,0) bands, at 762.0 nm. Earthward views of O2 A bands show structure from gravity waves which exhibit extended horizontal structure with horizontal wavelenghts on the order of 50-100 km. These observations of the O2 A (0,0) bands are particularly interesting since in this wavelength the lower atmosphere absorbs all the earth-reflected emissions and most of the spectrally diffuse backgrounds. Herein we present observations of gravity waves using a topside airglow imaging technique.

Mende, S. B.↗
NASA NTRS2022

Wetland Emission and Atmospheric Sink Changes Explain Methane Growth in 2020

Atmospheric methane growth reached an exceptionally high rate of 15.1 ± 0.4 parts per billion per year in 2020 despite a probable decrease in anthropogenic methane emissions during COVID-19 lockdowns(1). Here we quantify changes in methane sources and in its atmospheric sink in 2020 compared with 2019. We find that, globally, total anthropogenic emissions decreased by 1.2 ± 0.1 teragrams of methane per year (Tg CH4 yr−1), fire emissions decreased by 6.5 ± 0.1 Tg CH4 yr−1 and wetland emissions increased by 6.0 ± 2.3 Tg CH4 yr−1. Tropospheric OH concentration decreased by 1.6 ± 0.2 per cent relative to 2019, mainly as a result of lower anthropogenic nitrogen oxide (NOx) emissions and associated lower free tropospheric ozone during pandemic lockdowns(2). From atmospheric inversions, we also infer that global net emissions increased by 6.9 ± 2.1 Tg CH4 yr−1 in 2020 relative to 2019, and global methane removal from reaction with OH decreased by 7.5 ± 0.8 Tg CH4 yr−1. Therefore, we attribute the methane growth rate anomaly in 2020 relative to 2019 to lower OH sink (53 ± 10 per cent) and higher natural emissions (47 ± 16 per cent), mostly from wetlands. In line with previous findings(3,4,) our results imply that wetland methane emissions are sensitive to a warmer and wetter climate and could act as a positive feedback mechanism in the future. Our study also suggests that nitrogen oxide emission trends need to be taken into account when implementing the global anthropogenic methane emissions reduction pledge(5).

Shushi Peng↗
NASA NTRS1990

Procedure for generating global atmospheric engine emissions data from future supersonic transport aircraft. The 1990 high speed civil transport studies

The input for global atmospheric chemistry models was generated for baseline High Speed Civil Transport (HSCT) configurations at Mach 1.6, 2.2, and 3.2. The input is supplied in the form of number of molecules of specific exhaust constituents injected into the atmosphere per year by latitude and by altitude (for 2-D codes). Seven exhaust constituents are currently supplied: NO, NO2, CO, CO2, H2O, SO2, and THC (Trace Hydrocarbons). An eighth input is also supplied, NO(x), the sum of NO and NO2. The number of molecules of a given constituent emitted per year is a function of the total fuel burned by a supersonic fleet and the emission index (EI) of the aircraft engine for the constituent in question. The EIs for an engine are supplied directly by the engine manufacturers. The annual fuel burn of a supersonic fleet is calculated from aircraft performance and economic criteria, both of which are strongly dependent on basic design parameters such as speed and range. The altitude and latitude distribution of the emission is determined based on 10 Intern. Air Transport Assoc. (IATA) regions chosen to define the worldwide route structure for future HSCT operations and the mission flight profiles.

Sohn, R. A.↗
NASA NTRS2004

Design of a Far-Infrared Spectrometer for Atmospheric Thermal Emission Measurements

Global measurements of far infrared emission from the upper troposphere are required to test models of cloud radiative forcing, water vapor continuum emission, and cooling rates. Spectra with adequate resolution can also be used for retrieving atmospheric temperature and humidity profiles, and yet there are few spectrally resolved measurements of outgoing longwave flux at wavelengths longer than 16 m. It has been difficult to make measurements in the far infrared due to the need for liquid-helium cooled detectors and large optics to achieve adequate sensitivity and bandwidth. We review design considerations for infrared Fourier transform spectrometers, including the dependence of system performance on basic system parameters, and discuss the prospects for achieving useful sensitivity from a satellite platform with a lightweight spectrometer using uncooled detectors.

Johnson, David G.↗
NASA NTRS1991

Interpretation of Voyager UVS observations of occultations by the atmosphere of Neptune

We propose to continue our investigation of the upper atmosphere of Neptune based primarily on the solar occultation measurements made by the Voyager Ultraviolet Spectrometer (UVS). The ultimate goal of this research is to understand the structure and composition of Neptune's upper atmosphere as encoded in the data base obtained by the UVS during the Voyager 2 encounter with Neptune. The UVS occultations provide information essential to studies of atmospheric composition and structure, energy balance, photochemistry, global transport, ionospheric structure, and airglow production mechanisms. In conjunction with other research in progress at the University of Arizona and by our colleagues at other institutions, we not only analyze and interpret individual measurements or observations by the UVS, but also construct models of the upper atmosphere which are consistent with all available data obtained by the UVS. We derive constraints from measurements of the atmospheric emissions and we combine these with constraints derived from the occultation measurements. Principal sources for the atmospheric emissions include dayglow, resonance scattering and, at long wavelengths, the reflected solar spectrum. On the dark side of the planet, a weak H Ly alpha emission is due to resonance scattering of the sky background and perhaps another source. Thus a wide range of physical processes are at work, and each provides its own constraints on the atmosphere.

Sandel, Bill R.↗
NASA NTRS1981

Remote sensing of sea surface temperature in the 3.7 micron CO2 band

The main sources of error in remote sensing of sea surface temperature are discussed. The interfering effects of reflected solar radiation, reflected thermal flux, clouds and haze and atmospheric attenuation are examined. The components of measured sea surface radiances, such as clear column radiance, surface emission, atmospheric emission, reflected thermal downward flux, and reflection of solar flux, are analytically presented. The use of the 3.7 micron region window to obtain the radiance to four percent accuracy is discussed. The advantages to be obtained by the use of narrow bandpass channels are assessed.

Chahine, M. T.↗
NASA NTRS1992

The 1990 high-speed civil transport studies. Summary report

This report contains the results of the Douglas Aircraft Company system studies related to High-Speed Civil Transports (HSCT's). The tasks were performed under an 18-month extension of NASA Langley Research Center Contract NAS1-18378. The system studies were conducted to assess the emission impact of HSCT's at design Mach numbers ranging from 1.6 to 3.2. In particular, engine cycles were assessed regarding community noise and atmospheric emissions impact, and a HSCT route structure was developed. The general results indicated the following: (1) in the Mach number range 1.6 to 2.5, the development of polymer composite and discontinuous reinforced alumnium materials is essential to ensure a minimum operational weight; (2) the HSCT route structure to minimize supersonic overland can be increased by innovative routing to avoid land masses; (3) at least two engine concepts show promise in achieving sideline stage 3 noise limits; (4) two promising low-NO(x) combustor concepts were identified; (5) the atmospheric emission impact on ozone could be significantly lower for Mach 1.6 operations than for Mach 3.2 operations; and (6) sonic boom minimization concepts are maturing at an encouraging rate.

Source record↗
DOE OSTI2025

Implementation and Evaluation of Emission‐Driven Land‐Atmosphere Coupled Simulation in E3SMv2.1

Emissions-driven (prognostic CO 2 ) simulations are essential for representing two-way carbon-climate feedback in Earth System Models. We present an emissions-driven land–atmosphere coupled biogeochemistry (BGC) configuration (BGCLNDATM_progCO2) in version 2.1 of the Energy Exascale Earth System Model (E3SMv2.1). This is the first E3SM configuration that performs land-atmosphere emission-hindcasts. Here, we document its implementation, evaluate the model's performance against observations and other models, and propose a structured evaluation protocol for such emissions-driven simulations. We conducted transient historical simulations (1850–2014) with BGCLNDATM_progCO2 and compare them to reference simulations—a land-atmosphere coupled simulation without BGC and a standalone land simulation with BGC, both using prescribed CO 2 concentrations—and to observations. BGCLNDATM_progCO2 overestimates atmospheric CO 2 concentrations by 11–23 ppm yet stays within the 40-ppm spread CMIP6 emission-driven models and retains physical climate properties comparable to the reference runs. The CO 2 biases are partly attributed to underrepresented oceanic CO 2 uptake and inadequate representations of some terrestrial processes. In general, introducing prognostic CO 2 did not change physical climate metrics at the global scale but had larger regional effects, particularly over land where spatially heterogeneous CO 2 and prognostic leaf area index influenced surface energy balance. Finally, we propose a general evaluation protocol including spin-up assessment, atmospheric CO 2 benchmarking, physical climate evaluation, and land biogeochemical analysis to support scientific rigor and facilitate inter-model comparisons. The new configuration lays the groundwork for future enhancements, including improved terrestrial biogeochemical processes, integrated marine biogeochemistry, and additional human–Earth system interactions. These developments advance E3SM toward fully coupled emissions-driven simulations, enabling more accurate carbon–climate feedback projections and informing mitigation policy by providing physically consistent carbon-budget metrics for mitigation scenarios.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1992

The 1990 high-speed civil transport studies

This summary report contains the results of the Douglas Aircraft Company system studies related to High-Speed Civil Transports (HSCT's). The tasks were performed under an 18-month extension of NASA Langley Research Center Contract NAS1-18378. The system studies were conducted to assess the emission impact of HSCT's at design Mach numbers ranging from 1.6 to 3.2. The tasks specifically addressed an HSCT market and economic assessment, development of supersonic route networks, and an atmospheric emissions scenario. The general results indicated: (1) market projections predict sufficient passenger traffic for the 2000 to 2025 time period to support a fleet of economically viable and environmentally compatible HSCT's; (2) the HSCT route structure to minimize supersonic overland traffic can be increased by innovative routing to avoid land masses; and (3) the atmospheric emission impact on ozone would be significantly lower for Mach 1.6 operations than for Mach 3.2 operations.

Source record↗
NASA NTRS1998

Infrared Measurements of Atmospheric Constituents

This research program studies atmospheric trace gas concentrations and altitude distributions, particularly for those gases that are important in stratospheric chemistry and radiative balance. Measurements are made with infrared remote sensing instruments, either ground based or balloon-borne. Most of the ground based instruments are part of the Network for Detection of Stratospheric Change (NDSC), including a very high spectral resolution solar absorption spectrometer at Mauna Loa Observatory and similar system at McMurdo Station, Antarctica (operated in collaboration with the New Zealand NIWA). Additionally, we are deriving stratospheric constituent data from the spectra obtained at the DOE Atmospheric Radiation Measurements (ARM) program's site in north-central Oklahoma. We have an atmospheric emission spectrometer system at the South Pole (with additional support from NSF), and an identical NSF support instrument at Eureka, NWT, Canada. Our balloon-borne instruments include a very high resolution solar absorption spectrometer system, a smaller, slightly lower resolution solar spectrometer system, a high resolution atmospheric emission spectrometer, and several medium resolution emission spectrometers (CAESRs) that are usually flown piggyback. During the past year, we participated in the MANTRA balloon flight from Saskatoon, Saskatchewan, with the high resolution solar spectrometer system. Several of our instruments were extensively compared to (UARS) Upper Atmosphere Research Satellite observations, and so provide a data set with known connections to UARS. In the longer term, the data can be used to relate UARS data to (EOS) Earth Observing System and (ADEOS) Advanced Airborne Earth Observing System.

Frank J Murcray↗
NASA NTRS1991

Spectroscopic inferences from HIS measurements of atmospheric thermal emission

Radiometrically accurate observations of the earth's emission spectrum from 3.8 to 16.6 microns have been made using the High-resolution Interferometer Sounder (HIS) to look downward from the NASA U2/ER2 aircraft or upward from the ground. These observations have been used to demonstrate the substantially improved vertical resolution of temperature and water vapor soundings derived from high resolution spectra (resolving power from 1800 to 3800), as compared to soundings from the low resolution filter radiometer observations used in current satellite sounders. The HIS observations have also demonstrated that Fourier Transform Infrared (FTIR) instruments are especially well suited to absolute emission measurements of broad spectral bands at high resolution. A fundamental advantage of FTIR instruments for accurate calibration is wavelength integrity, the same property which has made FTIR the standard for very high resolution absorption measurements. The long wavelength part of a HIS downwelling radiance spectrum is compared to a calculated spectrum. The calculation uses the AFGL HITRAN/86 line file and FASCOD2 line-by-line program with atmospheric state data from in situ measurements. In general, agreement between HIS and FASCOD2 spectra is remarkably good, a tribute to the current state of spectral line files and line-by-line codes. Reproducible differences between HIS observations and FASCOD2 line-by-line calculations lead to the following conclusions: (1) The FASCOD2 water vapor continuum in the longwave window region from 10 to 13 microns (750 to 1000 cm(exp -1)) gives reasonable agreement with radiance observations; (2) The model H2O continuum from 7 to 8 microns (1250 to 1425 cm(exp -2)) needs adjustment to reduce its contribution by about 60 percent; (3) CO2 absorption in the region from 13.1 to 14.3 microns (700 to 760 cm(exp -1)) is too small in the model; and (4) Water vapor line strengths in the region from 8.1 to 9.1 microns (1100 to 1230 cm(exp -1)) need to be increased about 30 percent.

Revercomb, H. E.↗
DOE OSTI2025

A Measurement of Atmospheric Circular Polarization with POLARBEAR

At millimeter wavelengths, the atmospheric emission is circularly polarized owing to the Zeeman splitting of molecular oxygen by the Earth's magnetic field. We report a measurement of the signal in the 150 GHz band using 3 yr of observational data with the POLARBEAR project. Nonidealities of a continuously rotating half-wave plate (HWP) partially convert circularly polarized light to linearly polarized light. While POLARBEAR detectors are sensitive to linear polarization, this effect makes them sensitive to circular polarization. Although this was not the intended use, we utilized this conversion to measure circular polarization. We reconstruct the azimuthal gradient of the circular polarization signal and measure its dependency from the scanning direction and the detector bandpass. We compare the signal with a simulation based on atmospheric emission theory, the detector bandpass, and the HWP leakage spectrum model. We find the ratio of the observed azimuthal slope to the simulated slope is 0.92 ± 0.01(stat) ± 0.07(sys). This ratio corresponds to a brightness temperature of 3.8 mK at the effective band center of 121.8 GHz and bandwidth of 3.5 GHz estimated from representative detector bandpass and the spectrum of Zeeman emission. This result validates our understanding of the instrument and reinforces the feasibility of measuring the circular polarization using the imperfection of continuously rotating HWP. Continuously rotating HWP is popular in ongoing and future cosmic microwave background experiments to modulate the polarized signal. This work shows a method for signal extraction and leakage subtraction that can help measure circular polarization in such experiments.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Evaluation of interactive and prescribed agricultural ammonia emissions for simulating atmospheric composition in CAM-chem

Abstract. Ammonia (NH3) plays a central role in the chemistry of inorganic secondary aerosols in the atmosphere. The largest emission sector for NH3 is agriculture, where NH3 is volatilized from livestock wastes and fertilized soils. Although the NH3 volatilization from soils is driven by the soil temperature and moisture, many atmospheric chemistry models prescribe the emission using yearly emission inventories and climatological seasonal variations. Here we evaluate an alternative approach where the NH3 emissions from agriculture are simulated interactively using the process model FANv2 (Flow of Agricultural Nitrogen, version 2) coupled to the Community Atmospheric Model with Chemistry (CAM-chem). We run a set of 6-year global simulations using the NH3 emission from FANv2 and three global emission inventories (EDGAR, CEDS and HTAP) and evaluate the model performance using a global set of multi-component (atmospheric NH3 and NH4+, and NH4+ wet deposition) in situ observations. Over East Asia, Europe and North America, the simulations with different emissions perform similarly when compared with the observed geographical patterns. The seasonal distributions of NH3 emissions differ between the inventories, and the comparison to observations suggests that both FANv2 and the inventories would benefit from more realistic timing of fertilizer applications. The largest differences between the simulations occur over data-scarce regions. In Africa, the emissions simulated by FANv2 are 200 %–300 % higher than in the inventories, and the available in situ observations from western and central Africa, as well as NH3 retrievals from the Infrared Atmospheric Sounding Interferometer (IASI) instrument, are consistent with the higher NH3 emissions as simulated by FANv2. Overall, in simulating ammonia and ammonium concentrations over regions with detailed regional emission inventories, the inventories based on these details (HTAP, CEDS) capture the atmospheric concentrations and their seasonal variability the best. However these inventories cannot capture the impact of meteorological variability on the emissions, nor can these inventories couple the emissions to the biogeochemical cycles and their changes with climate drivers. Finally, we show with sensitivity experiments that the simulated time-averaged nitrate concentration in air is sensitive to the temporal resolution of the NH3 emissions. Over the CASTNET monitoring network covering the US, resolving the NH3 emissions hourly instead monthly reduced the positive model bias from approximately 80 % to 60 % of the observed yearly mean nitrate concentration. This suggests that some of the commonly reported overestimation of aerosol nitrate over the US may be related to unresolved temporal variability in the NH3 emissions.

54 ENVIRONMENTAL SCIENCES↗