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At least 55 records · Page 3

Wetland Emission and Atmospheric Sink Changes Explain Methane Growth in 2020

Atmospheric methane growth reached an exceptionally high rate of 15.1 ± 0.4 parts per billion per year in 2020 despite a probable decrease in anthropogenic methane emissions during COVID-19 lockdowns(1). Here we quantify changes in methane sources and in its atmospheric sink in 2020 compared with 2019. We find that, globally, total anthropogenic emissions decreased by 1.2 ± 0.1 teragrams of methane per year (Tg CH4 yr−1), fire emissions decreased by 6.5 ± 0.1 Tg CH4 yr−1 and wetland emissions increased by 6.0 ± 2.3 Tg CH4 yr−1. Tropospheric OH concentration decreased by 1.6 ± 0.2 per cent relative to 2019, mainly as a result of lower anthropogenic nitrogen oxide (NOx) emissions and associated lower free tropospheric ozone during pandemic lockdowns(2). From atmospheric inversions, we also infer that global net emissions increased by 6.9 ± 2.1 Tg CH4 yr−1 in 2020 relative to 2019, and global methane removal from reaction with OH decreased by 7.5 ± 0.8 Tg CH4 yr−1. Therefore, we attribute the methane growth rate anomaly in 2020 relative to 2019 to lower OH sink (53 ± 10 per cent) and higher natural emissions (47 ± 16 per cent), mostly from wetlands. In line with previous findings(3,4,) our results imply that wetland methane emissions are sensitive to a warmer and wetter climate and could act as a positive feedback mechanism in the future. Our study also suggests that nitrogen oxide emission trends need to be taken into account when implementing the global anthropogenic methane emissions reduction pledge(5).

Shushi Peng

Procedure for generating global atmospheric engine emissions data from future supersonic transport aircraft. The 1990 high speed civil transport studies

The input for global atmospheric chemistry models was generated for baseline High Speed Civil Transport (HSCT) configurations at Mach 1.6, 2.2, and 3.2. The input is supplied in the form of number of molecules of specific exhaust constituents injected into the atmosphere per year by latitude and by altitude (for 2-D codes). Seven exhaust constituents are currently supplied: NO, NO2, CO, CO2, H2O, SO2, and THC (Trace Hydrocarbons). An eighth input is also supplied, NO(x), the sum of NO and NO2. The number of molecules of a given constituent emitted per year is a function of the total fuel burned by a supersonic fleet and the emission index (EI) of the aircraft engine for the constituent in question. The EIs for an engine are supplied directly by the engine manufacturers. The annual fuel burn of a supersonic fleet is calculated from aircraft performance and economic criteria, both of which are strongly dependent on basic design parameters such as speed and range. The altitude and latitude distribution of the emission is determined based on 10 Intern. Air Transport Assoc. (IATA) regions chosen to define the worldwide route structure for future HSCT operations and the mission flight profiles.

Sohn, R. A.

Design of a Far-Infrared Spectrometer for Atmospheric Thermal Emission Measurements

Global measurements of far infrared emission from the upper troposphere are required to test models of cloud radiative forcing, water vapor continuum emission, and cooling rates. Spectra with adequate resolution can also be used for retrieving atmospheric temperature and humidity profiles, and yet there are few spectrally resolved measurements of outgoing longwave flux at wavelengths longer than 16 m. It has been difficult to make measurements in the far infrared due to the need for liquid-helium cooled detectors and large optics to achieve adequate sensitivity and bandwidth. We review design considerations for infrared Fourier transform spectrometers, including the dependence of system performance on basic system parameters, and discuss the prospects for achieving useful sensitivity from a satellite platform with a lightweight spectrometer using uncooled detectors.

Johnson, David G.

Interpretation of Voyager UVS observations of occultations by the atmosphere of Neptune

We propose to continue our investigation of the upper atmosphere of Neptune based primarily on the solar occultation measurements made by the Voyager Ultraviolet Spectrometer (UVS). The ultimate goal of this research is to understand the structure and composition of Neptune's upper atmosphere as encoded in the data base obtained by the UVS during the Voyager 2 encounter with Neptune. The UVS occultations provide information essential to studies of atmospheric composition and structure, energy balance, photochemistry, global transport, ionospheric structure, and airglow production mechanisms. In conjunction with other research in progress at the University of Arizona and by our colleagues at other institutions, we not only analyze and interpret individual measurements or observations by the UVS, but also construct models of the upper atmosphere which are consistent with all available data obtained by the UVS. We derive constraints from measurements of the atmospheric emissions and we combine these with constraints derived from the occultation measurements. Principal sources for the atmospheric emissions include dayglow, resonance scattering and, at long wavelengths, the reflected solar spectrum. On the dark side of the planet, a weak H Ly alpha emission is due to resonance scattering of the sky background and perhaps another source. Thus a wide range of physical processes are at work, and each provides its own constraints on the atmosphere.

Sandel, Bill R.

Remote sensing of sea surface temperature in the 3.7 micron CO2 band

The main sources of error in remote sensing of sea surface temperature are discussed. The interfering effects of reflected solar radiation, reflected thermal flux, clouds and haze and atmospheric attenuation are examined. The components of measured sea surface radiances, such as clear column radiance, surface emission, atmospheric emission, reflected thermal downward flux, and reflection of solar flux, are analytically presented. The use of the 3.7 micron region window to obtain the radiance to four percent accuracy is discussed. The advantages to be obtained by the use of narrow bandpass channels are assessed.

Chahine, M. T.

The 1990 high-speed civil transport studies. Summary report

This report contains the results of the Douglas Aircraft Company system studies related to High-Speed Civil Transports (HSCT's). The tasks were performed under an 18-month extension of NASA Langley Research Center Contract NAS1-18378. The system studies were conducted to assess the emission impact of HSCT's at design Mach numbers ranging from 1.6 to 3.2. In particular, engine cycles were assessed regarding community noise and atmospheric emissions impact, and a HSCT route structure was developed. The general results indicated the following: (1) in the Mach number range 1.6 to 2.5, the development of polymer composite and discontinuous reinforced alumnium materials is essential to ensure a minimum operational weight; (2) the HSCT route structure to minimize supersonic overland can be increased by innovative routing to avoid land masses; (3) at least two engine concepts show promise in achieving sideline stage 3 noise limits; (4) two promising low-NO(x) combustor concepts were identified; (5) the atmospheric emission impact on ozone could be significantly lower for Mach 1.6 operations than for Mach 3.2 operations; and (6) sonic boom minimization concepts are maturing at an encouraging rate.

Source record

Implementation and Evaluation of Emission‐Driven Land‐Atmosphere Coupled Simulation in E3SMv2.1

Emissions-driven (prognostic CO 2 ) simulations are essential for representing two-way carbon-climate feedback in Earth System Models. We present an emissions-driven land–atmosphere coupled biogeochemistry (BGC) configuration (BGCLNDATM_progCO2) in version 2.1 of the Energy Exascale Earth System Model (E3SMv2.1). This is the first E3SM configuration that performs land-atmosphere emission-hindcasts. Here, we document its implementation, evaluate the model's performance against observations and other models, and propose a structured evaluation protocol for such emissions-driven simulations. We conducted transient historical simulations (1850–2014) with BGCLNDATM_progCO2 and compare them to reference simulations—a land-atmosphere coupled simulation without BGC and a standalone land simulation with BGC, both using prescribed CO 2 concentrations—and to observations. BGCLNDATM_progCO2 overestimates atmospheric CO 2 concentrations by 11–23 ppm yet stays within the 40-ppm spread CMIP6 emission-driven models and retains physical climate properties comparable to the reference runs. The CO 2 biases are partly attributed to underrepresented oceanic CO 2 uptake and inadequate representations of some terrestrial processes. In general, introducing prognostic CO 2 did not change physical climate metrics at the global scale but had larger regional effects, particularly over land where spatially heterogeneous CO 2 and prognostic leaf area index influenced surface energy balance. Finally, we propose a general evaluation protocol including spin-up assessment, atmospheric CO 2 benchmarking, physical climate evaluation, and land biogeochemical analysis to support scientific rigor and facilitate inter-model comparisons. The new configuration lays the groundwork for future enhancements, including improved terrestrial biogeochemical processes, integrated marine biogeochemistry, and additional human–Earth system interactions. These developments advance E3SM toward fully coupled emissions-driven simulations, enabling more accurate carbon–climate feedback projections and informing mitigation policy by providing physically consistent carbon-budget metrics for mitigation scenarios.

54 ENVIRONMENTAL SCIENCES

The 1990 high-speed civil transport studies

This summary report contains the results of the Douglas Aircraft Company system studies related to High-Speed Civil Transports (HSCT's). The tasks were performed under an 18-month extension of NASA Langley Research Center Contract NAS1-18378. The system studies were conducted to assess the emission impact of HSCT's at design Mach numbers ranging from 1.6 to 3.2. The tasks specifically addressed an HSCT market and economic assessment, development of supersonic route networks, and an atmospheric emissions scenario. The general results indicated: (1) market projections predict sufficient passenger traffic for the 2000 to 2025 time period to support a fleet of economically viable and environmentally compatible HSCT's; (2) the HSCT route structure to minimize supersonic overland traffic can be increased by innovative routing to avoid land masses; and (3) the atmospheric emission impact on ozone would be significantly lower for Mach 1.6 operations than for Mach 3.2 operations.

Source record

Infrared Measurements of Atmospheric Constituents

This research program studies atmospheric trace gas concentrations and altitude distributions, particularly for those gases that are important in stratospheric chemistry and radiative balance. Measurements are made with infrared remote sensing instruments, either ground based or balloon-borne. Most of the ground based instruments are part of the Network for Detection of Stratospheric Change (NDSC), including a very high spectral resolution solar absorption spectrometer at Mauna Loa Observatory and similar system at McMurdo Station, Antarctica (operated in collaboration with the New Zealand NIWA). Additionally, we are deriving stratospheric constituent data from the spectra obtained at the DOE Atmospheric Radiation Measurements (ARM) program's site in north-central Oklahoma. We have an atmospheric emission spectrometer system at the South Pole (with additional support from NSF), and an identical NSF support instrument at Eureka, NWT, Canada. Our balloon-borne instruments include a very high resolution solar absorption spectrometer system, a smaller, slightly lower resolution solar spectrometer system, a high resolution atmospheric emission spectrometer, and several medium resolution emission spectrometers (CAESRs) that are usually flown piggyback. During the past year, we participated in the MANTRA balloon flight from Saskatoon, Saskatchewan, with the high resolution solar spectrometer system. Several of our instruments were extensively compared to (UARS) Upper Atmosphere Research Satellite observations, and so provide a data set with known connections to UARS. In the longer term, the data can be used to relate UARS data to (EOS) Earth Observing System and (ADEOS) Advanced Airborne Earth Observing System.

Frank J Murcray

Spectroscopic inferences from HIS measurements of atmospheric thermal emission

Radiometrically accurate observations of the earth's emission spectrum from 3.8 to 16.6 microns have been made using the High-resolution Interferometer Sounder (HIS) to look downward from the NASA U2/ER2 aircraft or upward from the ground. These observations have been used to demonstrate the substantially improved vertical resolution of temperature and water vapor soundings derived from high resolution spectra (resolving power from 1800 to 3800), as compared to soundings from the low resolution filter radiometer observations used in current satellite sounders. The HIS observations have also demonstrated that Fourier Transform Infrared (FTIR) instruments are especially well suited to absolute emission measurements of broad spectral bands at high resolution. A fundamental advantage of FTIR instruments for accurate calibration is wavelength integrity, the same property which has made FTIR the standard for very high resolution absorption measurements. The long wavelength part of a HIS downwelling radiance spectrum is compared to a calculated spectrum. The calculation uses the AFGL HITRAN/86 line file and FASCOD2 line-by-line program with atmospheric state data from in situ measurements. In general, agreement between HIS and FASCOD2 spectra is remarkably good, a tribute to the current state of spectral line files and line-by-line codes. Reproducible differences between HIS observations and FASCOD2 line-by-line calculations lead to the following conclusions: (1) The FASCOD2 water vapor continuum in the longwave window region from 10 to 13 microns (750 to 1000 cm(exp -1)) gives reasonable agreement with radiance observations; (2) The model H2O continuum from 7 to 8 microns (1250 to 1425 cm(exp -2)) needs adjustment to reduce its contribution by about 60 percent; (3) CO2 absorption in the region from 13.1 to 14.3 microns (700 to 760 cm(exp -1)) is too small in the model; and (4) Water vapor line strengths in the region from 8.1 to 9.1 microns (1100 to 1230 cm(exp -1)) need to be increased about 30 percent.

Revercomb, H. E.

A Measurement of Atmospheric Circular Polarization with POLARBEAR

At millimeter wavelengths, the atmospheric emission is circularly polarized owing to the Zeeman splitting of molecular oxygen by the Earth's magnetic field. We report a measurement of the signal in the 150 GHz band using 3 yr of observational data with the POLARBEAR project. Nonidealities of a continuously rotating half-wave plate (HWP) partially convert circularly polarized light to linearly polarized light. While POLARBEAR detectors are sensitive to linear polarization, this effect makes them sensitive to circular polarization. Although this was not the intended use, we utilized this conversion to measure circular polarization. We reconstruct the azimuthal gradient of the circular polarization signal and measure its dependency from the scanning direction and the detector bandpass. We compare the signal with a simulation based on atmospheric emission theory, the detector bandpass, and the HWP leakage spectrum model. We find the ratio of the observed azimuthal slope to the simulated slope is 0.92 ± 0.01(stat) ± 0.07(sys). This ratio corresponds to a brightness temperature of 3.8 mK at the effective band center of 121.8 GHz and bandwidth of 3.5 GHz estimated from representative detector bandpass and the spectrum of Zeeman emission. This result validates our understanding of the instrument and reinforces the feasibility of measuring the circular polarization using the imperfection of continuously rotating HWP. Continuously rotating HWP is popular in ongoing and future cosmic microwave background experiments to modulate the polarized signal. This work shows a method for signal extraction and leakage subtraction that can help measure circular polarization in such experiments.

79 ASTRONOMY AND ASTROPHYSICS

Zodiacal light surface brightness measurements by Atmosphere Explorer-C

The visible airglow photometer on the Atmosphere Explorer-C satellite has been used to map the zodiacal light surface brightness at the wavelengths monitored by the instrument: 3371, 4278, 5200, 5577, 6300, and 7319 A. The study constitutes a survey over this wavelength range, covering most of the celestial sphere from altitudes above the atmospheric emissions and free from atmospheric scattering and attenuation. The intensity variations reveal enhancements near elongations of 130 deg and possibly near 60 deg at all wavelengths. The intensity of the zodiacal light near the ecliptic pole is found to be about 30 S10 units. The color ratio with respect to the sun is found to be redder than the sun (0.7) at all elongations.

Torr, M. R.

Atmospheric infrared emission of ClONO2 observed by a balloon-borne Fourier spectrometer

ClONO2 was observed in high-resolution infrared emission spectra obtained on Nov. 6, 1984, by a balloon-borne Fourier spectrometer. The observations took place near 0300 LT at a latitude of 35 N. Spectral simulations are used to determine the mixing ratios of ClONO2. This analysis incorporates line by line calculations and new ClONO2 cross sections measured in the laboratory at 223 K. The inferred mixing ratios of ClONO2 are 1.3 + or - 0.45 ppb and 0.98 + or - 0.35 ppb at 14 and 34 mbar. One-dimensional photochemical model predictions are compared to the observations. The ClONO2 mixing ratio at 34 mbar appears to be larger than theory, while there is agreement at 14 mbar.

Massie, S. T.

Aerosols in Atmospheric Chemistry and Biogeochemical Cycles of Nutrients

Atmospheric aerosols have complex and variable compositions and properties.While scientific interest is centered on the health and climatic effects of atmospheric aerosols, insufficient attention is given to their involvement in multiphase chemistry that alters their contribution as carriers of nutrients in ecosystems. However, there is experimental proof that the nutrient equilibria of both land and marine ecosystems have been disturbed during the Anthropocene period. This review study first summarizes our current understanding of aerosol chemical processing in the atmosphere as relevant to biogeochemical cycles. Then it binds together results of recent modeling studies based on laboratory and field experiments, focusing on the organic and dust components of aerosols that account for multiphase chemistry, aerosol ageing in the atmosphere, nutrient (N, P, Fe) emissions, atmospheric transport, transformation and deposition. The human-driven contribution to atmospheric deposition of these nutrients, derived by global simulations using past and future anthropogenic emissions of pollutants, is put into perspective with regard to potential changes in nutrient limitations and biodiversity. Atmospheric deposition of nutrients has been suggested to result in human-induced ecosystem limitations with regard to specific nutrients. Such modifications favor the development of certain species against others and affect the overall functioning of ecosystems. Organic forms of nutrients are found to contribute to the atmospheric deposition of the nutrients N, P and Fe by 20%-40%, 35%-45% and 7%-18%, respectively. These have the potential to be key components of the biogeochemical cycles since there is initial proof of their bioavailability to ecosystems. Bioaerosols have been found to make a significant contribution to atmospheric sources of N and P, indicating potentially significant interactions between terrestrial and marine ecosystems. These results deserve further experimental and modeling studies to reduce uncertainties and understand the feedbacks induced by atmospheric deposition of nutrients to ecosystems.

dust

The Global Methane Budget 2000–2017

Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH4 continue to increase, making CH4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO2). The relative importance of CH4 compared to CO2 depends on its shorter atmospheric lifetime, stronger warming potential, and variations in atmospheric growth rate over the past decade, the causes of which are still debated. Two major challenges in reducing uncertainties in the atmospheric growth rate arise from the variety of geographically overlapping CH4 sources and from the destruction of CH4 by short-lived hydroxyl radicals (OH). To address these challenges, we have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottom-up estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations). For the 2008–2017 decade, global methane emissions are estimated by atmospheric inversions (a top-down approach) to be 576 Tg CH4/yr (range 550–594, corresponding to the minimum and maximum estimates of the model ensemble). Of this total, 359 Tg CH4/yr or ∼ 60 % is attributed to anthropogenic sources, that is emissions caused by direct human activity (i.e. anthropogenic emissions; range 336–376 Tg CH4/yr or 50 %–65 %). The mean annual total emission for the new decade (2008–2017) is 29 Tg CH4/yr larger than our estimate for the previous decade (2000–2009), and 24 Tg CH4/yr larger than the one reported in the previous budget for 2003–2012 (Saunois et al., 2016). Since 2012, global CH4 emissions have been tracking the warmest scenarios assessed by the Intergovernmental Panel on Climate Change. Bottom-up methods suggest almost 30 % larger global emissions (737 Tg CH4/yr, range 594–881) than top-down inversion methods. Indeed, bottom-up estimates for natural sources such as natural wetlands, other inland water systems, and geological sources are higher than top-down estimates. The atmospheric constraints on the top-down budget suggest that at least some of these bottom-up emissions are overestimated. The latitudinal distribution of atmospheric observation-based emissions indicates a predominance of tropical emissions (∼ 65 % of the global budget, < 30° N) compared to mid-latitudes (∼ 30 %, 30–60° N) and high northern latitudes (∼ 4 %, 60–90° N). The most important source of uncertainty in the methane budget is attributable to natural emissions, especially those from wetlands and other inland waters. Some of our global source estimates are smaller than those in previously published budgets (Saunois et al., 2016; Kirschke et al., 2013). In particular wetland emissions are about 35 Tg CH4/yr lower due to improved partition wetlands and other inland waters. Emissions from geological sources and wild animals are also found to be smaller by 7 Tg CH4/yr by 8 Tg CH4/yr, respectively. However, the overall discrepancy between bottom-up and top-down estimates has been reduced by only 5 % compared to Saunois et al. (2016), due to a higher estimate of emissions from inland waters, highlighting the need for more detailed research on emissions factors. Priorities for improving the methane budget include (i) a global, high-resolution map of water-saturated soils and inundated areas emitting methane based on a robust classification of different types of emitting habitats; (ii) further development of process-based models for inland-water emissions; (iii) intensification of methane observations at local scales (e.g., FLUXNET-CH4 measurements) and urban-scale monitoring to constrain bottom-up land surface models, and at regional scales (surface networks and satellites) to constrain atmospheric inversions; (iv) improvements of transport models and the representation of photochemical sinks in top-down inversions; and (v) development of a 3D variational inversion system using isotopic and/or co-emitted species such as ethane to improve source partitioning.

methane budget

Global Impacts of Marine Methanethiol Emissions and Chemistry in the Atmosphere

Oceanic emissions of dimethyl sulfide (DMS) have long been known to influence aerosol particle composition, cloud condensation nuclei (CCN) concentration, and Earth’s radiative budget. However, the impact of oceanic emissions of methanethiol (MeSH), a sulfur compound produced by the same oceanic precursor as DMS, has been relatively less explored. The gas-phase oxidation of MeSH has a higher effective yield of SO 2 and a shorter oxidative lifetime compared to DMS, highlighting the relevance of this pathway for the modeled representation of particle formation, growth, and CCN abundance in the marine atmosphere. Here, we use the global chemical transport model GEOS-Chem to explore possible scenarios representative of specific environmental conditions and MeSH emission schemes based on previous experimental studies. We further implement and test previously reported chemical mechanisms for MeSH oxidation, along with additional improvements, highlighting key uncertainties and sensitivities for regional and global sulfur budgets. We place our results in the context of recent modeling updates to DMS chemistry and cloud processing, which further impact SO 2 production in the marine atmosphere in parallel with MeSH oxidation. Within the overall marine sulfur budget, our findings highlight that MeSH plays a significant role in SO 2 production in the marine atmosphere, contributing to regional surface layer concentration increases of up to 40–60%. These results point to the importance of MeSH for efforts aimed at improving the modeled representation of sulfur spatiotemporal patterns relevant to air quality predictions and climate impact assessments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH