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At least 55 records · Page 3

Determining the r p -Process Flow through Ni 56 : Resonances in Cu 57 ( p , γ ) Zn 58 Identified with GRETINA

An approach is presented in this paper to experimentally constrain previously unreachable (p,γ) reaction rates on nuclei far from stability in the astrophysical rp process. Energies of all critical resonances in the 57 Cu(p,γ) 58 Zn reaction are deduced by populating states in 58 Zn with a (d,n) reaction in inverse kinematics at 75 MeV/u, and detecting γ-ray-recoil coincidences with the state-of-the-art γ-ray tracking array GRETINA and the S800 spectrograph at the National Superconducting Cyclotron Laboratory. The results reduce the uncertainty in the 57 Cu(p,γ) reaction rate by several orders of magnitude. Finally, the effective lifetime of 56 Ni, an important waiting point in the rp process in x-ray bursts, can now be determined entirely from experimentally constrained reaction rates.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Project 57 Air Monitoring Annual Report - Fiscal Year 2013 (October 1, 2012 to September 30, 2013)

The U.S. Department of Energy (DOE), National Nuclear Security Administration, Nevada Field Office (NNSA/NFO) is currently working to achieve regulatory closure of radionuclide-contaminated Soils sites under its auspices. Corrective Action Unit (CAU) 415, Project 57 No. 1 Plutonium Dispersion Site is located in Emigrant Valley, Nevada, on Range 4808A of the Nevada Test and Training Range (NTTR), and consists of one Corrective Action Site (CAS): NAFR-23-02, Pu Contaminated Soil. Closure plans being developed for the CAUs both on and off of the Nevada National Security Site (NNSS) may include postclosure monitoring for the possible release of radioactive contaminants. Determining the potential for transport of radionuclide-contaminated soils under ambient climatic conditions will facilitate an appropriate closure design and postclosure monitoring program. The DOE has authorized the Desert Research Institute (DRI) to conduct field assessments of potential transport of radionuclide-contaminated soil from the Project 57 site during ambient wind events. The assessment is intended to provide site-specific information on meteorological conditions that result in airborne soil particle redistribution, as well as determine which, if any, radiological contaminants may be entrained with the soil particles and estimate their concentrations.

54 ENVIRONMENTAL SCIENCES↗

Coexisting Multiple Martensites in Ni 57-x Mn 21+x Ga 22 Ferromagnetic Shape Memory Alloys: Crystal Structure and Phase Transition

A comprehensive study of the crystal structure and phase transition as a function of temperature and composition in Ni 57–x Mn 21+x Ga 22 (x = 0, 2, 4, 5.5, 7, 8) (at. %) magnetic shape memory alloys was performed by a temperature-dependent synchrotron X-ray diffraction technique and transmission electron microscopy. A phase diagram of this Ni 57–x Mn 21+x Ga 22 alloy system was constructed. The transition between coexisting multiple martensites with monoclinic and tetragonal structures during cooling was observed in the Ni 51.5 Mn 26.5 Ga 22 (x = 5.5) alloy, and it was found that 5M + 7M multiple martensites coexist from 300 K to 160 K and that 5M + 7M + NM multiple martensites coexist between 150 K and 100 K. The magnetic-field-induced transformation from 7M martensite to NM martensite at 140 K where 5M + 7M + NM multiple martensites coexist before applying the magnetic field was observed by in situ neutron diffraction experiments. The present study is instructive for understanding the phase transition between coexisting multiple martensites under external fields and may shed light on the design of novel functional properties based on such phase transitions.

36 MATERIALS SCIENCE↗

The exciting star of HH 57

The first spectral classification for the exciting star of HH 57 is provided. The star is an F8 III and suffers about 5 mag of visual extinction, far greater than that toward the HH 57A knot, only a few arcseconds away. This difference supports the previous identification of a flattened geometry for the circumstellar dust around this star. Using IRAS photometry, a distance of 940 pc to HH 57 is determined by bolometrically matching the observed luminosity of the star to those of FU Ori and V1057 Cyg.

Cohen, M.↗

Simulating the Benesov Bolide Flowfield and Spectrum at Altitudes of 47 and 57 km

This paper develops a computational fluid dynamics capability for simulating the radiative emission from a meteor shock-layer and wake to an external observer. The developed capability includes the impact of radiation and ablation on the meteor flowfield, where coupled radiation accounts for the impact of radiation on the flowfield energy equations and coupled ablation accounts for the injection of ablation species from the meteoroid surface into the ow. This capability includes updated flowfield chemistry and nonequilibrium radiation models, which are compiled from the literature. To provide a level of validation for this capability, the Benesov spectral measurements are considered. Although the meteoroid was likely fragmented at the 47 and 57 km altitudes considered, and the measurement uncertainty is roughly ±50%, these measurements represent the best available spectral measurements for a relatively large (meter-class) bolide. To determine the equivalent meteoroid diameter to simulate, the continuum component of the spectrum in the 570 to 610 nm range is considered. This range is dominated by air emission from the high pressure and temperature shock-layer in front of the meteoroid, which is simulated with a relatively small uncertainty (because of the abundance of relevant shock tube measurements) and sensitive to the equivalent meteoroid diameter. This allows an equivalent diameter between 0.62 to 0.9 m to be determined, based on comparisons between measurements and simulations in the 570 to 610 nm range. The range of equivalent diameters is due to the various meteoroid geometries considered, where increasing the bluntness decreases the required diameter. Applying these diameters to simulations at 47 and 57 km results in simulated spectra that compare within 30% of the measured values, considering the wavelength integrated values between 400 and 650 nm. This agreement is well within the estimated measurement uncertainty of ±50%. All major spectral features are captured by the simulations. This agreement provides a level of validation for the developed model that has not been previously available.

Luminous efficiency↗

Nuclear resonant scattering measurements on {sup 57}Fe by multichannel scaling with a 64-pixel silicon avalanche photodiode linear-array detector

We developed a silicon avalanche photodiode (Si-APD) linear-array detector for use in nuclear resonant scattering experiments using synchrotron X-rays. The Si-APD linear array consists of 64 pixels (pixel size: 100 × 200 μm{sup 2}) with a pixel pitch of 150 μm and depletion depth of 10 μm. An ultrafast frontend circuit allows the X-ray detector to obtain a high output rate of >10{sup 7} cps per pixel. High-performance integrated circuits achieve multichannel scaling over 1024 continuous time bins with a 1 ns resolution for each pixel without dead time. The multichannel scaling method enabled us to record a time spectrum of the 14.4 keV nuclear radiation at each pixel with a time resolution of 1.4 ns (FWHM). This method was successfully applied to nuclear forward scattering and nuclear small-angle scattering on {sup 57}Fe.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Fe-implanted 6H-SiC: Direct evidence of Fe{sub 3}Si nanoparticles observed by atom probe tomography and {sup 57}Fe Mössbauer spectroscopy

In order to understand ferromagnetic ordering in SiC-based diluted magnetic semiconductors, Fe-implanted 6H-SiC subsequently annealed was studied by Atom Probe Tomography, {sup 57}Fe Mössbauer spectroscopy and SQUID magnetometry. Thanks to its 3D imaging capabilities at the atomic scale, Atom Probe Tomography appears as the most suitable technique to investigate the Fe distribution in the 6H-SiC host semiconductor and to evidence secondary phases. This study definitely evidences the formation of Fe{sub 3}Si nano-sized clusters after annealing. These clusters are unambiguously responsible for the main part of the magnetic properties observed in the annealed samples.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Study of yrast structures in {sup 55,57}Cr

The characteristic nuclear structure properties of yrast bands of {sup 55,57}Cr have been investigated by using two body effective interactions incorporated in phenomenological axial framework. In order to check the validity of the chosen framework as well as chosen valence space, the calculated results are compared with the available experimental data and a good agreement has been found from the comparison. The back-bending in moment of inertia has also been studied and attributed to the alignment of odd g{sub 9/2} neutron along the rotation axis.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Internal electron conversion of the isomeric {sup 57}Fe nucleus state with an energy of 14.4 keV excited by the radiation of the plasma of a high-power femtosecond laser pulse

We recorded the spectrum of delayed secondary electrons ejected from the target, which was coated with a layer of iron enriched with the {sup 57}Fe isotope to 98%, under its irradiation by fluxes of broadband X-ray radiation and fast electrons from the plasma produced by a femtosecond laser pulse at an intensity of 10{sup 17} W cm{sup -2}. Maxima were identified at energies of 5.6, 7.2, and 13.6 keV in the spectrum obtained for a delay of 90 - 120 ns. The two last-listed maxima owe their origin to the internal electron conversion of the isomeric level with an energy of 14.4 keV and a lifetime of 98 ns to the K and L shells of atomic iron, respectively; the first-named level arises from a cascade K - L{sub 2}L{sub 3} Auger process. Photoexcitaion by the X-ray plasma radiation is shown to be the principal channel of the isomeric level excitation. (interaction of laser radiation with matter)

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Search for 14.4 keV solar axions from M1 transition of {sup 57}Fe with CUORE crystals

We report the results of a search for axions from the 14.4 keV M1 transition from {sup 57}Fe in the core of the sun using the axio-electric effect in TeO{sub 2} bolometers. The detectors are 5 × 5 × 5 cm{sup 3} crystals operated at about 10 mK in a facility used to test bolometers for the CUORE experiment at the Laboratori Nazionali del Gran Sasso in Italy. An analysis of 43.65 kg⋅d of data was made using a newly developed low energy trigger which was optimized to reduce the energy threshold of the detector. An upper limit of 0.58 c⋅kg{sup −1}⋅d{sup −1} is established at 95% C.L., which translates into lower bounds f{sub A} ≥ 3.12 × 10{sup 5} GeV 95% C.L. (DFSZ model) and f{sub A} ≥ 2.41 × 10{sup 4} GeV 95% C.L. (KSVZ model) on the Peccei-Quinn symmetry-breaking scale, for a value of S = 0.5 of the flavor-singlet axial vector matrix element. These bounds can be expressed in terms of axion masses as m{sub A} ≤ 19.2 eV and m{sub A} ≤ 250 eV at 95% C.L. in the DFSZ and KSVZ models respectively. Bounds are given also for the interval 0.35 ≤ S ≤ 0.55.

79 ASTRONOMY AND ASTROPHYSICS↗

Sensitivity of the CUORE detector to 14.4 keV solar axions emitted by the M1 nuclear transition of {sup 57}Fe

In this paper we present a calculation of the sensitivity of the CUORE detector to the monoenergetic 14.4 keV solar axions emitted by the M1 nuclear transition of {sup 57}Fe in the Sun and detected by inverse coherent Bragg-Primakoff conversion in single-crystal TeO{sub 2} bolometers. The expected counting rate is calculated using density functional theory for the electron charge density of TeO{sub 2} and realistic background and energy resolution of CUORE. Monte Carlo simulations for 5y × 741 kg=3705 kg y of exposure are analyzed using time correlation of individual events with the theoretical time-dependent counting rate. We find an expected model-independent limit on the product of the axion-photon coupling and the axion-nucleon coupling g{sub aγγ}g{sub aN}{sup eff} < 1.105 × 10{sup −16} /GeV for axion masses less than 500 eV with 95% confidence level.

79 ASTRONOMY AND ASTROPHYSICS↗

Project 57 Air Monitoring Report: January 1 through December 31, 2015

On April 24, 1957, the Atomic Energy Commission (AEC, now the Department of Energy [DOE]) conducted the Project 57 safety experiment in western Emigrant Valley north east of the Nevada National Security Site (NNSS, formerly the Nevada Test Site) on lands withdrawn by the Department of Defense (DOD) for the Nevada Test and Training Range (NTTR). The test was undertaken to develop (1) a means of estimating plutonium distribution resulting from a non-nuclear detonation; (2) biomedical evaluation techniques for use in plutonium-laden environments; (3) methods of surface decontamination; and (4) instruments and field procedures for prompt estimation of alpha contamination (Shreve, 1958). Although the test did not result in the fission of nuclear materials, it did disseminate plutonium across the land surface. Following the experiment, the AEC fenced the contaminated area and returned control of the surrounding land to the DOD. Various radiological surveys were performed in the area and in 2007, the DOE expanded the demarked Contamination Area by posting signs 200 to 400 feet (60 to 120 meters) outside of the original fence.

(1)↗

The Electrochemical Sodiation of FeSb 2 : New Insights from Operando 57 Fe Synchrotron Mössbauer and X-Ray Absorption Spectroscopy

Operando Sb K–edge X–ray absorption spectroscopy and 57 Fe Synchrotron Mössbauer Spectroscopy, used for the first time in the field of operando energy storage materials, assisted by operando magnetic measurements, were combined to clarify the role of iron and antimony in the electrochemical reaction mechanism of FeSb 2 as negative electrode material for sodium–ion batteries (SIB). Both datasets were analyzed using an innovative chemometric approach involving principal component analysis (PCA) and multivariate curve resolution – alternating least square analysis (MCR–ALS) yielding new insights on the sodiation reaction. Our findings show that the reaction of Na with FeSb 2 during discharge leads to the formation of Na 3 Sb along with superparamagnetic Fe amorphous nanoparticles which contain small amounts of Sb dissolved in their lattice. During the following desodiation, the pristine material FeSb 2 is not recovered while iron nanoparticles grow in size, and continue growing also along the following discharge. Here, even though such iron nanoparticles remain electrochemically inactive, they play a key role in the reduction and stabilization of the polarization as well as in the reversibility of the electrochemical sodiation of antimony.

25 ENERGY STORAGE↗

On magnetic structure of CuFe 2 Ge 2 : Constrains from the 57 Fe Mössbauer spectroscopy

57 Fe Mössbauer spectroscopy measurements were performed on a powdered CuFe 2 Ge 2 sample that orders antiferromagnetically at ~175 K. Whereas a paramagnetic doublet was observed above the Néel temperature, a superposition of paramagnetic doublet and magnetic sextet (in approximately 0.5:0.5 ratio) was observed in the magnetically ordered state, suggesting a magnetic structure similar to a double-Q spin density wave with half of the Fe paramagnetic and another half bearing static moment of ~0.5–1μ B . Lastly, these results call for a re-evaluation of the recent neutron scattering data and band structure calculations, as well as for deeper examination of details of sample preparation techniques.

36 MATERIALS SCIENCE↗

Identification of In Situ Generated High-Spin Fe(II)-N 4 Active Sites for Acidic Oxygen Reduction Reaction via Operando 57 Fe Mössbauer Spectroscopy

Iron-nitrogen-carbon (FeNC) catalysts are considered among the most promising alternative to Pt catalysts in acidic oxygen reduction reaction (ORR), yet the geometric and electronic structures of the true active site under reaction conditions have not been clearly elucidated. Herein, we synthesized a representative FeNC catalyst by pyrolyzing Fe 3+ absorbed on ZIF-8-derived N-doped carbon at a mild temperature under the H 2 /Ar atmosphere, where a formation mechanism of FeN 4 sites through a Zn-mediated Fe nanoparticle atomization process was proposed. The resulting FeNC-750 catalyst shows high acidic ORR activity with a half-wave potential of 0.838 V and a peak power density of 1 W cm -2 in proton-exchange membrane fuel cell (PEMFC). By using operando 57 Fe Mössbauer spectroscopy on FeNC-750, it was revealed that the pyrrolic N-coordinated high-spin Fe 2+ N 4 sites, which are in situ generated from high-spin Fe 3+ N 4 during ORR, are identified as catalytic active states. Density functional theory calculations further verified that, compared to the pyridinic N-coordinated low-spin Fe 2+ N 4 , the pyrrolic N-coordinated high-spin Fe 2+ exhibits optimized adsorption energy for reaction intermediates, thereby lowering the energy barrier of the rate-determining step (RDS) and facilitating OH* desorption. In conclusion, this work provides both experimental and theoretical evidence of the true active site in the FeNC during acidic ORR, offering significant insights for the rational design of high-performance materials for acidic fuel cells.

FeNC catalyst↗

57 Fe nuclear resonance vibrational spectroscopic studies of tetranuclear iron clusters bearing terminal iron( III )–oxido/hydroxido moieties

57 Fe nuclear resonance vibrational spectroscopy (NRVS) has been applied to study a series of tetranuclear iron ([Fe 4 ]) clusters based on a multidentate ligand platform (L 3− ) anchored by a 1,3,5-triarylbenzene linker and pyrazolate or (tertbutylamino)pyrazolate ligand (PzNH t Bu − ). These clusters bear a terminal Fe(III)–O/OH moiety at the apical position and three additional iron centers forming the basal positions. The three basal irons are connected with the apical iron center via a μ 4 -oxido ligand. Detailed vibrational analysis via density functional theory calculations revealed that strong NRVS spectral features below 400 cm −1 can be used as an oxidation state marker for the overall [Fe 4 ] cluster core. The terminal Fe(III)–O/OH stretching frequencies, which were observed in the range of 500–700 cm −1 , can be strongly modulated (energy shifts of 20–40 cm −1 were observed) upon redox events at the three remote basal iron centers of the [Fe 4 ] cluster without the change of the terminal Fe(III) oxidation state and its coordination environment. Therefore, the current study provides a quantitative vibrational analysis of how the remote iron centers within the same iron cluster exert exquisite control of the chemical reactivities and thermodynamic properties of the specific iron site that is responsible for small molecule activation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Synergy between Ni and Fe in NiFe aerogel oxygen evolution reaction catalyst: in situ 57 Fe Mössbauer and X-ray absorption spectroscopy studies

Anion-exchange-membrane water electrolyzers (AEMWE) for hydrogen production have attracted interest because cost-effective Ni- and Fe-based catalysts can be used for the oxygen evolution reaction (OER). Although NiFe oxide/hydroxide-based catalysts have been extensively studied, the role of Fe and its chemical state during OER are not well understood, with inconsistent findings across different studies. In this work, we combined in situ 57 Fe Mössbauer (MS) and X-ray absorption spectroscopy (XAS) to investigate the chemical states of Fe and Ni and elucidate their synergy during the OER. A NiFe (8 : 1 molar ratio) aerogel catalyst with high surface area, nano crystallinity, and high performance in AEMWE was used. We show that both Fe and Ni are oxidized during anodic polarization, and the potential for the change of oxidation states correlates well with the onset of the OER. In situ MS shows that 80–90% of Fe 3+ becomes tetravalent at OER potentials and remains so even after the potential is lowered below OER onset. Analysis of in situ XAS results suggests full Fe incorporation into Ni hydroxide. At OER potentials, lattice contraction indicates high oxidation states for both Ni and Fe. Upon returning to lower potentials, a portion of the Fe remains in its more oxidized form which corroborates the in situ MS findings. Results from this work affirm the importance of high-valent Ni and Fe in promoting the OER. Ni and Fe exhibit synergy during OER and the aerogel's unique nanomorphology leads to high OER activity.

36 MATERIALS SCIENCE↗