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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Coupling of 3,8-Dibromo-1,10-Phenanthroline With 3,5-Diethynylheptyloxybenzene: A Suzuki/Miyaura Versus a Sonogashira Perspective

We report a new application of the Suzuki-Miyaura reaction whereas two bifunctional reactants, 3,8-dibromo-1,10-phenanthroline and 3,5-diethynylheptyloxylbenzene (9), yield 3,8-bis (3-ethynyl-5-heptyloxyphenylethynyl)-1,10-phenanthroline (2) efficiently (74% yield) without polymerization. This was achieved by reacting a stoichiometric amount of 9 and (Me3Si)2NLi to obtain quantitatively the monoacetylide anion of 9 (10). The latter was activated with B-methoxy-9-BBN and reacted in analogy to the alkynyl copper complex of a Sonogashira route. However, in the Sonogashira reaction, the alkynyl copper complex is present in small equilibrium concentrations and polymerization takes place even when reagents are mixed slowly. Actually the Sonogashira route gave no desired product 2, as the latter polymerizes easily via homo-coupling in the presence of air and Cu(I). Sonogashira coupling involves the palladium(0) catalyzed reaction of terminal alkynes.

Yang, Jinhua↗
NASA NTRS2005

Protection of 2-(3-Thienyl)ethanol with 3-Thienylacetic Acid and Hard Cross- Linked Conducting Films by Electropolymerization of the Ester

The ester (compound 1) of 2-(3-thienyl)ethanol (T-etOH) with 3-thienylacetic acid was synthesized as a monomer whose two thiophene groups could be electropolymerized independently, becoming members of different polymer chains in a highly-crosslinked highly-insoluble polymer. Indeed, 1 was electropolymerized successfully alone and together with 3-methylthiophene (3MeT). Films of poly(1) are hard (3H, as opposed to less than 6B for poly(3MeT)), and the close proximity of the polymeric strands creates pi-stacking interactions. The behavior of 1 suggests that by: (a) limiting the potential used for the oxidation of monomeric esters of T-etOH at the foot of their oxidation waves (less than 1.8 V vs. Ag/AgCl); and, (b) compensating for the decrease in the electrogenerated radical concentration by increasing the monomer concentration, practically all esters of T-etOH should be electropolymerizable. This was confirmed by durable film formation from the archetypical ester of T-etOH, the 2-(3-thienyl)ethyl acetate (T-etOAc), whose homo-electropolymerization is reported for the first time.

Leventis, Nicholas↗
NASA NTRS1994

CoSb(sub 3)-IrSb(sub 3)Solid Solutions: Preparations and Characterization

The binary antimonide compounds of the skutterudite family have a good potential for thermoelectric applications as recent results at JPL have shown. However, the room temperature thermal conductivity of these materials is about 10 Wm(sup -1)K(sup -1) with an 80 % contribution from the lattice. To achieve maximum ZT values, the lattice thermal conductivity needs to be lowered. Because the lattice thermal conductivity of solid solutions can substantially decrease due to the addition of point defect phonon scattering (all state-of-the-art thermoelectric materials are solid solutions), a study of the formation of solid solutions between the antimonide skutterudite compounds is of interest. The preparation and characterization of both p-type and n-type CoSb(sub 3)-IrSb(sub 3) solid solutions by several techniques is reviewed in this paper. Experimental results showed that solid solutions were successfully formed in a wide range of compositions. The changes in the thermoelectric properties indicated the influence of a strong point defect scattering, resulting in large decreases in Hall mobility and thermal conductivity. The potential for high ZT values in CoSb(sub 3)-IrSb(sub 3) solid solutions is discussed.

mobility↗
NASA NTRS2005

Synthesis and Near IR Photoluminescence of Os(II) Bis(2,2'-bipyridine) (3,8-Diarylethynyl-1,10-phemanthroline) Complexes: Anomalous Behavior of the 3,8-Dinitrophenylethynyl-substituted Homologue

A large bathochromic shift (50 nm) and emission in the near infrared is observed by attaching arylethynyl groups at the 3,8-positions of the 1,10-phenanthroline ligand (phen) of [Os(bipy)2(phen)]2+ (where bipy = 2,2'-bipyridine). Thus [Os(bipy)2(3,8-di-4-methoxyphenylethynyl-1,10-phenathroline)]2+ emits at 795 nm, while [Os(bipy)2(3,8-diphenylethynyl-1,10-phenanthroline)]2+ emits at 815 nm. According to this trend it would have been expected that [Os(bipy)2(3,8-di-4-nitrophenylethynyl-1,10-phenathroline)]2+ emits farther in the near infrared. Nevertheless, this complex is not photoluminescent because of intramolecular electron transfer quenching of the MLCT excited state by the nitroaromatic group. These results set structural and redox potential standards in the design of near infrared emitters based on [Os(bipy)2(phen)]2+ type complexes.

Yang, Jinhua↗
NASA NTRS1963

Space Flight Handbooks. Volume 3- Planetary Flight Handbook: Supplementary Trajectory Data: Venus to Earth and Mars to Earth - Part 3

Parts 2 and 3 present tabulations of trajectory data for scheduling flights to and from Venus and Mars during the period 1960-2000. Part 2 contains information for outbound flights to these planets; Part 3 contains information for trajectories returning from the planets to Earth. Each Part contains data for single-plane transfers, as well as for broken-plane transfers which employ a midcourse plane-change to eliminate the high speed "ridges." The mathematical analyses employed for all calculations are described in Part 1 of this handbook. To facilitate the construction of round-trip trajectories, the date at the target planet is held fixed while the trip duration is varied in 10-day increments from zero days to the length of that planet's synodic period with Earth. Dates of arrival at the target planet are presented in the extreme right-hand column of Part 2, and dates of departure from the target planet are presented in the extreme left-hand column of Part 3. Thus, by holding Part 2 directly to the left of Part 3, the analyst may easily and rapidly scan all trip possibilities which involve any desired stopover time at the target planet. Within approximately 200 days of each conjunction or opposition, data are presented in 10-day increments at the target planet. Only those trips are listed for which the hyperbolic excess speeds at either or both ends of the trajectory do not exceed 0.6 EMOS (Earth Mean Orbital Speed). For the remaining mission regions, the requirements are so smoothly varying that a 50-day interval in dates at the target planet may be employed; the 10-day interval in trip times is, however, preserved here. In these regions, only those trips are listed for which either or both speeds do not exceed 0.3 EMOS.

Source record↗
NASA NTRS1982

The CARE 3 Phase 3 Report: Test and Evaluation

CARE 3 (Computer-Aided Reliability Estimation, version three) is a computer program designed to help estimate the reliability of complex, redundant systems; although the program can model a wide variety of redundant structures, it was developed specifically for fault-tolerant avionics systems, systems distinguished by the need for extremely reliable performance since a system failure could well result in the loss of human life. CARE 3 further generalizes the class of system structures that can be modeled and greatly expands the coverage model to take into account such effects as intermittent and transient faults, latent faults, error propagation, etc. The initial test and evaluation of CARE 3 are reported.

Stiffler, J. J.↗
NASA NTRS1987

Simultaneous measurements of energetic ion (50 keV and above) and electron (220 keV and above) activity upstream of earth's bow shock and inside the plasma sheet - Magnetospheric source for the November 3 and December 3, 1977 upstream events

Simultaneous observations of energetic ions and electrons by the IMP 7 and 8 spacecraft are used here to separate temporal variations from spatial variations during the upstream ion events observed on December 3, 1977 and November 2-3, 1977, in order to determine the source of these particles. Analysis of the observations and comparison with theory shows that: (1) for each of the observed upstream enhancements, energetic ions and electrons were simultaneously present inside the plasma sheet; (2) the low-energy ion intensity profile inside the plasma sheet was relatively flat, while at higher energies there was considrable variability; (3) relativistic electron bursts were seen inside the plasma sheet and also upstream of the shock but at substantially reduced intensities; (4) the ion energy spectrum for the December 3 event, extended to energies of about 2 MeV, was identical in form with the plasma sheet and upstream of the shock; (5) ion anisotropies exhibited typically large dawn-dusk or dusk-dawn gradients and large field-aligned streaming away from the bow shock.

Sarris, E. T.↗
NASA NTRS1990

Oligomerizations of deoxyadenosine bis-phosphates and of their 3-prime-5-prime, 3-prime-3-prime, and 5-prime-5-prime dimers - Effects of a pyrophosphate-linked, poly(T) analog

The effect of a 3-prime-5-prime pyrophosphate-linked oligomer of pTp on oligomerizations of pdAp and of its 3-prime-5-prime, 3-prime-3-prime, and 5-prime-5-prime dimers was investigated, using HPLC to separate the reaction mixtures; peak detection was by absorbance monitoring at 254 nm. It was expected that the dimers would form stable complexes with the template, with the degree of stability depending upon the internal linkage of each dimer. It was found that, although the isomers differ substantially in their oligomerization behavior in the absence of template, the analog-template catalyzes the oligomerization to about the same extent in all three cases.

Visscher, J.↗
NASA NTRS1953

Aerodynamic Characteristics of a Two-blade NACA 10-(3)(062)-045 Propeller and of a Two-blade NACA 10-(3)(08)-045 Propeller

Characteristics are given for the two-blade NACA 10-(3)(062)-045 propeller and for the two-blade NACA 10-(3)(08)-045 propeller over a range of advance ratio from 0.5 to 3.8, through a blade-angle range from 20 degrees to 55 degrees measured at the 0.75 radius. Maximum efficiencies of the order of 91.5 to 92 percent were obtained for the propellers. The propeller with the thinner airfoil sections over the outboard portion of the blades, the NACA 10-(3)(062)-045 propeller, had lower losses at high tip speeds, the difference amounting to about 5 percent at a helical tip Mach number of 1.10.

BLADE SECTIONS-PROPELLERS↗
NASA NTRS2003

STS-112 Mission Highlights Resource, Part 3 of 3

The STS-112 Mission begins with a view of the center radiator on the S(1) Truss. A good view of the International Space Station's (ISS) Destiny Laboratory, Soyuz Crew Return Vehicle and Quest Airlock are shown from a video camera located at the end of the S(1) Truss Segment. The ISS Canadarm 2 is shown getting in position for spacewalk three. Highlights of flight day eight begin with Pilot Pam Melroy and Mission Specialist Fyodur Yurchikhin shown inside of the Quest Airlock closing the hatch as spacewalkers David Wolf and Piers Sellers move in the outer compartment of the Airlock to begin Extravehicular Activity 3 (EVA 3). During EVA 3, Dave Wolf and Piers Sellers are installing spool positioning devices on ammonia lines located on the ISS. Robot Arm Operators Peggy Whitson and Sandy Magnus are shown reviewing procedures for operating the robot arm. A view of Piers Seller climbing back into the Quest Airlock is presented. During flight day nine, robot arm operators Pam Melroy, Jeff Ashby and Peggy Whitson are in the process of removing spacesuits worn by David Wolf and Piers Sellers. A final farewell of the nine crewmembers shown inside of the Destiny Laboratory is presented during flight day ten. The undocking of Space Shuttle Atlantis from the International Space Station is shown on flight day eleven. This presentation ends on flight day 12 with a view of head up displays and the actual landing of the Space Shuttle Atlantis.

Source record↗
NASA NTRS2001

Pentopyranosyl Oligonucleotide Systems. Part 11: Systems with Shortened Backbones: D)-beta-Ribopyranosyl-(4 yields 3 )- and (L)-alpha - Lyxopyranosyl-(4 yields 3 )-oligonucleotides

The (L)-a-lyxopyranosyl-(4'yields 3')-oligonucleotide system-a member of a pentopyranosyl oligonucleotide family containing a shortened backbone-is capable of cooperative base-pairing and of cross-pairing with DNA and RNA. In contrast, corresponding (D)-beta-ribopyransoyl-(4' yields 3')-oligonucleotides do not show base-pairing under similar conditions. We conclude that oligonucleotide systems can violate the six-bonds-per-backbone-unit rule by having five bonds instead, if their vicinally bound phosphodiester bridges can assume an antiperiplanar conformation. An additional structural feature that seems relevant to the cross-pairing capability of the (L)-a-lyxopyranosyl-(4' yields 3')-oligonucleotide system is its (small) backbone/basepair axes inclination. An inclination which is similar to that in B-DNA seems to be a prerequisite for an oligonucleotide system s capability to cross-pair with DNA.

Wippo, Harald↗
NASA NTRS1972

Apollo guidance, navigation and control: Guidance system operations plan for manned CM earth orbital and lunar missions using Program COLOSSUS 3. Section 3: Digital autopilots (revision 14)

Digital autopilots for the manned command module earth orbital and lunar missions using program COLOSSUS 3 are discussed. Subjects presented are: (1) reaction control system digital autopilot, (2) thrust vector control autopilot, (3) entry autopilot and mission control programs, (4) takeover of Saturn steering, and (5) coasting flight attitude maneuver routine.

Source record↗
NASA NTRS1971

Vibrational population of the A super 3 sigma sub u/+/ and B super 3 pi sub g states of N2 in normal auroras.

Use of new electron impact excitation cross sections for the six lowest triplet states (A, B, W, C, E, D) of N2, and solution of the coupled equations of statistical equilibrium to obtain the vibrational population of each electronic state. The results show that cascade from high levels of the A super 3 sigma sub u(+) state and from the W super 3 delta sub u state is significant in populating the lower vibrational levels of the B state and hence the character of its ?apparent' excitation cross sections. For the B state excited under auroral conditions, the fraction of the total population due to cascade processes exceeds 25% for all levels lower than 7 and is greater than 80% for B(v' = 0). For the A state under similar conditions, cascade from the B state contributes 50% or more of the total vibrational population for levels lower than 7, and 80% or more for levels below 4. For levels of the A state greater than 7, the A yields B transitions depopulate the levels rapidly and indicate that the Vegard-Kaplan emissions from these higher levels will be weak or totally absent in normal auroras.

Cartwright, D. C.↗