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At least 523 records · Page 29

Photosynthesis-dependent Isoprene Emission from Leaf to Planet in a Global Carbon-chemistry-climate Model

We describe the implementation of a biochemical model of isoprene emission that depends on the electron requirement for isoprene synthesis into the FarquharBallBerry leaf model of photosynthesis and stomatal conductance that is embedded within a global chemistry-climate simulation framework. The isoprene production is calculated as a function of electron transport-limited photosynthesis, intercellular and atmospheric carbon dioxide concentration, and canopy temperature. The vegetation biophysics module computes the photosynthetic uptake of carbon dioxide coupled with the transpiration of water vapor and the isoprene emission rate at the 30 min physical integration time step of the global chemistry-climate model. In the model, the rate of carbon assimilation provides the dominant control on isoprene emission variability over canopy temperature. A control simulation representative of the present-day climatic state that uses 8 plant functional types (PFTs), prescribed phenology and generic PFT-specific isoprene emission potentials (fraction of electrons available for isoprene synthesis) reproduces 50 of the variability across different ecosystems and seasons in a global database of 28 measured campaign-average fluxes. Compared to time-varying isoprene flux measurements at 9 select sites, the model authentically captures the observed variability in the 30 min average diurnal cycle (R2 6496) and simulates the flux magnitude to within a factor of 2. The control run yields a global isoprene source strength of 451 TgC yr1 that increases by 30 in the artificial absence of plant water stress and by 55 for potential natural vegetation.

photosynthesis↗

Launch Vehicle Production and Operations Cost Metrics

Traditionally, launch vehicle cost has been evaluated based on $/Kg to orbit. This metric is calculated based on assumptions not typically met by a specific mission. These assumptions include the specified orbit whether Low Earth Orbit (LEO), Geostationary Earth Orbit (GEO), or both. The metric also assumes the payload utilizes the full lift mass of the launch vehicle, which is rarely true even with secondary payloads.1,2,3 Other approaches for cost metrics have been evaluated including unit cost of the launch vehicle and an approach to consider the full program production and operations costs.4 Unit cost considers the variable cost of the vehicle and the definition of variable costs are discussed. The full program production and operation costs include both the variable costs and the manufacturing base. This metric also distinguishes operations costs from production costs, including pre-flight operational testing. Operations costs also consider the costs of flight operations, including control center operation and maintenance. Each of these 3 cost metrics show different sensitivities to various aspects of launch vehicle cost drivers. The comparison of these metrics provides the strengths and weaknesses of each yielding an assessment useful for cost metric selection for launch vehicle programs.

Watson, Michael D.↗

Anisotropic Solar Wind Sputtering of the Lunar Surface Induced by Crustal Magnetic Anomalies

The lunar exosphere is generated by several processes each of which generates neutral distributions with different spatial and temporal variability. Solar wind sputtering of the lunar surface is a major process for many regolith-derived species and typically generates neutral distributions with a cosine dependence on solar zenith angle. Complicating this picture are remanent crustal magnetic anomalies on the lunar surface, which decelerate and partially reflect the solar wind before it strikes the surface. We use Kaguya maps of solar wind reflection efficiencies, Lunar Prospector maps of crustal field strengths, and published neutral sputtering yields to calculate anisotropic solar wind sputtering maps. We feed these maps to a Monte Carlo neutral exospheric model to explore three-dimensional exospheric anisotropies and find that significant anisotropies should be present in the neutral exosphere depending on selenographic location and solar wind conditions. Better understanding of solar wind/crustal anomaly interactions could potentially improve our results.

exosphere↗

The Influence of Heat Treatments on the Microstructure and Tensile Properties of Additively Manufactured Inconel 939

This study investigated the effect of heat treatment variations on the microstructure and tensile properties of laser powder bed fused Inconel 939 manufactured via laser powder bed fusion. Three different heat treatment schedules, all of which comprise stress relief, hot isostatic pressing, solution annealing, and aging, were followed, and resulting changes in microstructure were analyzed using scanning electron microscopy. Tensile tests were conducted on specimens subjected to different heat treatments to evaluate the mechanical properties at room temperature. Microstructural results showed that solution treatment at 1190 °C for 4 h led to better removal of dendritic microstructure, while second-step aging at 850 °C resulted in monomodal distribution of precipitates. However, the second-step aging temperatures from 750 to 800 °C resulted in bi-modal distribution. The optimal heat treatment schedule, which yielded a superior combination of strength and ductility, involved solution treatment at 1190 °C for 4 h and two-step aging at 1000 °C for 6 h and 800 °C for 4 h.

Laser powder bed fusion (L-PBF)↗

Impact cratering - The effect of crustal strength and planetary gravity

The effect of varying planetary crustal strength and surface gravity on the depth of impact craters is investigated, by coupling the results of compressible flow, finite difference calculations carried out to stress levels below the compressional dynamic yield point, in keeping with the incompressible fluid flow model of Maxwell (1973). The fundamental assumption in this description is that the amplitude of the particle velocity field decreases with time as kinetic energy is converted into heat and gravitational potential energy. By using a Mohr-Coulomb yield criterion, the effect of varying strength on transient crater depth and on crater formation time in the gravity field of the moon is investigated for the case of 5 km/sec impactors having radii in the 10 to 10 to the 7th cm range.

Okeefe, J. D.↗

Absolute oscillator strengths for the iron group - A correction to the data of Warner for the second spectra and a comment on some of the semiempirical results of Kurucz and Peytremann

It has already been shown that the Fe II absolute oscillator strengths (f-values) measured by Warner (1967) contain a systematic error, the magnitude of which depends on the energy of the transition's upper level. The present paper demonstrates that this error affects all of Warner's oscillator strengths for the second spectra of the iron group and develops a correction formula for Warner's results. A comparison of the corrected f-values with other measured f-values for Ti II, V II, and Fe II indicates that the correction improves the usefulness of Warner's data and that the corrected f-values have no large systematic dependence on wavelength, level energy, or line strength. Solar abundances for iron-group elements computed using the original and corrected f-values are compared with recently suggested abundances, and it is found that the corrected f-values yield more consistent results. Semiempirical oscillator strengths calculated by Kurucz and Peytremann (1975) for Fe I, Ti II, and V II are also compared with measured data to evaluate the accuracy of the calculations. It is found that the absolute scales of these results are roughly correct, but some of them are subject to very large errors.

Smith, P. L.↗

Affordable, Robust Ceramic Joining Technology (ARCJoinT) for High Temperature Applications

Ceramic joining is recognized as one of the enabling technologies for the successful utilization of silicon carbide-based monolithic ceramic and fiber reinforced composite components in a number of demanding and high temperature applications in aerospace and ground-based systems. An affordable, robust ceramic joining technology (ARCJoinT) for joining of silicon carbide-based ceramics and fiber reinforced composites has been developed. This technique is capable of producing joints with tailorable thickness and composition. A wide variety of silicon carbide-based ceramics and composites, in different shapes and sizes, have been joined using this technique. The room and high temperature mechanical properties and fractography of ceramic joints have been reported. In monolithic silicon carbide ceramics, these joints maintain their mechanical strength up to 1350 C in air. There is no change in the mechanical strength of joints in silicon carbide matrix composites up to 1200 C in air. In composites, simple butt joints yield only about 20% of the ultimate strength of the parent materials. This technology is suitable for the joining of large and complex shaped ceramic and composite components, and with certain modifications, can be applied to repair of ceramic components damaged in service.

Singh, M.↗

Early thermal profiles and lithospheric strength of Ganymede from extensional tectonic features

The early thermal profiles and the lithospheric stability and strength of Ganymede are quantitatively determined on the basis of brittle lithosphere thickness estimates derived from the width and spacing of extensional tectonic features, together with lithospheric strength envelopes for ice. Plots of the brittle and ductile yield stress vs. depth for the icy lithosphere of Ganymede exhibit a linear increase in brittle strength with depth to a maximum at the brittle-ductile transition that is followed by an exponential decrease in ductile yield stress with depth. The results obtained imply that the thermal gradient and lithospheric strength have varied laterally by factor as great as 5, and that Ganymede underwent cooling in a highly inhomogeneous fashion with lateral thermal anomalies. The present analysis furnishes reasons for the stability of large cratered terrain remnants.

Golombek, Matthew P.↗

Spatial derivatives of flow quantities behind curved shocks of all strengths

Explicit formulas in terms of shock curvature are developed for spatial derivatives of flow quantities behind a curved shock for two-dimensional inviscid steady flow. Factors which yield the equations indeterminate as the shock strength approaches 0 have been cancelled analytically so that formulas are valid for shocks of any strength. An application for the method is shown in the solution of shock coalescence when nonaxisymmetric effects are felt through derivatives in the circumferential direction. The solution of this problem requires flow derivatives behind the shock in both the axial and radial direction.

Darden, C. M.↗

Theoretical Model of the Effect of Crack Tip Blunting on the Ultimate Tensile Strength of Welds in 2219-T87 Aluminum

A theoretical model representing blunting of a crack tip radius through diffusion of vacancies is presented. The model serves as the basis for a computer program which calculates changes, due to successive weld heat passes, in the ultimate tensile strength of 2219-T81 aluminum. In order for the model to yield changes of the same order in the ultimate tensile strength as that observed experimentally, a crack tip radius of the order of .001 microns is required. Such sharp cracks could arise in the fusion zone of a weld from shrinkage cavities or decohered phase boundaries between dendrites and the eutectic phase, or, possibly, from plastic deformation due to thermal stresses encountered during the welding process. Microstructural observations up to X2000 (resolution of about .1 micron) did not, in the fusion zone, show structural details which changed significantly under the influence of a heat pass, with the exception of possible small changes in the configuration of the interdendritic eutectic and in porosity build-up in the remelt zone.

Beil, R. J.↗

Deformational models of rifting and folding on Venus

Features of presumed tectonic origin on Venus are reviewed, and lithospheric strength envelopes are derived based on laboratory measurements of the deformational properties of crustal and subcrustal rocks, extrapolated to conditions appropriate to Venus. Models for rifting and folding are developed that use this lithospheric structure and take into account both brittle and ductile yielding as well as finite elastic strength. For both rifting and folding, structures with characteristic widths and spacings are predicted whose size depends on the thickness of the lithosphere, density contrast, and elastic properties of the layer. Finally, the model predictions are compared with the widths and spacings of observed tectonic features, and it is concluded that they are consistent with a relatively strong mantle layer separated from a thin brittle surface layer by a ductile lower crust. These results allow constraints to be placed on the crustal thickness and thermal gradient on Venus.

Banerdt, W. Bruce↗

V-378A: A modified bismaleimide for advanced composites

Addition polyimides cure with no evolution of gaseous by-products at relatively low temperatures and may be cured at low pressures to yield composites with excellent hot-wet strength retention. These properaties have made them excellent candidates as matrix resins for advanced composites. However, commercially available bismaleimides are solids and difficult to handle in preimpregnated form. V-378A is an addition polyimide composed of a mixture of bismaleimides and other reactive ingredients formulated to provide good prepreg properties and handling, facile cure and excellent composite mechanical properties. Several curing mechanisms are utilized to provide the characteristics exhibited by V-378A. Part of the mechanism is free radial and takes place at ambient temperature and above. Other mechanisms are principally Diels-Alder in nature. V-378A prepregs are tacky at ambient temperature, but do not have long tacky outlife similar to some epoxies. V-378A yields composites which exhibit hot-wet strength retention which is superior to that provided by epoxy resin systems.

Street, S. W.↗

A Study of the Non-Thermal X-Ray Emission of Shell-Type Supernova Remnants

We present an analysis of the X-ray spectrum of the Galactic shell-type SNR G347.3-0.5 (RX 51713.7-3946). This SNR is a member of a growing class of SNRs which are dynamically young, shell-type sources that emit non-thermal X-rays from specific regions on their outer shells. By performing a joint spectral analysis of data from observations made of G347.3-0.5 using the ROSAT PSPC, the ASCA GIS and the RXTE PCA, we have fit the spectra of particular regions of this SNR (including the bright northwestern and southwestern rims, the northeast rim and the interior diffuse emission) over the approximate energy range of 0.5 through 30 keV. We find that fits to the spectra of this SNR over this energy range using the SRCUT model were superior to a simple power law model or the SRESC model. We find that the inclusion of a thermal model with the SRCUT model helps to improve the fit to the observed X-ray spectrum: this represents the first detection of thermal X-ray emission from G347.3-0.5. Thermal emission appears to be more clearly associated with the diffuse emission in the interior of the SNR than with the bright X-ray emitting rims. A weak emission feature seen near 6.4 keV in the RXTE PCA spectrum most likely originates from diffuse X-ray emission from the surrounding Galactic Ridge rather than from G347.3-0.5 itself. We have analyzed our RXTE PCA data to search for pulsations from a recently discovered radio pulsar (PSR 51713-3949) which may be associated with G347.3-0.5, and we do not detect any X-ray pulsations at the measured radio period of 392 ms. Using the best-fit parameters obtained from the SRCUT model, we estimate the maximum energy of cosmic-ray electrons accelerated by the rims of G347.3-0.5 to be 19-25 TeV (assuming a magnetic field strength of B = 10muG), consistent with the results of Ellison et al. We present a broadband (radio to gamma ray) photon energy-flux spectrum for the northwestern rim of G347.3-0.5, where we have fit the spectrum using a more sophisticated synchrotron-inverse Compton model with a variable magnetic field strength. Our fit derived from this model yields a maximum energy of only 8.8 (+4.1) (-3.4) TeV for the accelerated cosmic-ray electrons and a much greater magnetic field strength of 150 (+250) (-80). Finally, we compare the gross properties of G347.3-0.5 with other SNRs known to possess X-ray spectra dominated by non-thermal emission.

Allen, Glenn E.↗

A Study of the Non-Thermal X-Ray Emission of Shell-Type Supernova Remnants

The term of the second year of the award is the period from March 15, 2001 to March 14, 2002. As was the specified goal of the second year, we analyzed the spatial and spectral X-ray data for several young supernova remnants. I published a paper about an analysis of the ROSAT, ASCA, and RXTE data for the supernova remnant SN 1006. A copy of this paper is enclosed. As described in the paper, we believe that we accurately modeled the nonthermal X-ray emission from the remnant. The results of this analysis are used to infer properties about the cosmic rays accelerated in the remnant and to argue that the strength of the magnetic field in the remnant is considerably larger than the value of about 10 micro G reported elsewhere. The results were presented at the August 2001 International Cosmic Ray Conference in Hamburg, German),. I began analyzing new Chandra X-ray data for SN 1006. This analysis will yield the first measure of the strength of the magnetic field in the remnant for the first time. Preliminary results support our previous conclusion that the magnetic field strength in the remnant is much larger than 10 micro G. The field strength seems to be about the strength expected based on an equipartition calculation. The result supports recent models that describe the how the shock structure is influenced by the efficient acceleration of cosmic rays. This work will be presented at the April 2002 High Energy Astrophysics Division meeting in Albuquerque and published this summer. A copy of the abstract for the talk is enclosed. I began studying new Chandra X-ray data for the supernova remnant Cas A. The results of this work show that the forward shock is a region where cosmic-ray electrons are accelerated, which is consistent with theoretical expectations. The work was presented at the September 2001 Two Years of Science with Chandra symposium in Washington, DC. A copy of the poster paper is enclosed. Dr. Thomas Pannuti, whose research work is supported by the award, analyzed ROSAT, ASCA, and RXTE data for the supernova remnant G347.3-0.5. The results show for the first time that thermal X-ray emission is produced in the remnant. As expected, the thermal emission is consistent with a model in which the remnant is expanding into a very low density environment. The results also provide an accurate description of the nonthermal emission from the remnant. Dr. Pannuti presented this work at several conferences. A copy of the paper for the proceedings of the August 2001 Neutron Stars in Supernova Remnants symposium in enclosed. The work will be submitted to the Astrophysical Journal in the next few months.

Allen, Glenn E.↗

Determination of Yield in Inconel 718 for Axial-Torsional Loading at Temperatures up to 649 C

An experimental program has been implemented to determine small offset yield loci under axial-torsional loading at elevated temperatures. The nickel-base superalloy Inconel 718 (IN718) was chosen for study due to its common use in aeropropulsion applications. Initial and subsequent yield loci were determined for solutioned IN718 at 23, 371, and 454 C and for aged (precipitation hardened) IN718 at 23 and 649 C. The shape of the initial yield loci for solutioned and aged IN718 agreed well with the von Mises prediction. However, in general, the centers of initial yield loci were eccentric to the origin due to a strength-differential (S-D) effect that increased with temperature. Subsequent yield loci exhibited anisotropic hardening in the form of translation and distortion of the locus. This work shows that it is possible to determine yield surfaces for metallic materials at temperatures up to at least 649 C using multiple probes of a single specimen. The experimental data is first-of-its-kind for a superalloy at these very high temperatures and will facilitate a better understanding of multiaxial material response, eventually leading to improved design tools for engine designers.

Gil, Christopher M.↗

Determination of Yield in Inconel 718 for Axial-Torsional Loading at Temperatures up to 649 C

An experimental program has been implemented to determine small offset yield loci under axial-torsional loading at elevated temperatures. The nickel-base superalloy Inconel 718 (IN718) was chosen for study due to its common use in aeropropulsion applications. Initial and subsequent yield loci were determined for solutioned IN718 at 23, 371, and 454 C and for aged (precipitation hardened) IN718 at 23 and 649 C. The shape of the initial yield loci for solutioned and aged IN718 agreed well with the von Mises prediction. However, in general, the centers of initial yield loci were eccentric to the origin due to a strength-differential (S-D) effect that increased with temperature. Subsequent yield loci exhibited anisotropic hardening in the form of translation and distortion of the locus. This work shows that it is possible to determine yield surfaces for metallic materials at temperatures up to at least 649 C using multiple probes of a single specimen. The experimental data is first-of-its-kind for a superalloy at these very high temperatures and will facilitate a better understanding of multiaxial material response, eventually leading to improved design tools for engine designers.

Gil, Christopher M.↗

Directionally Solidified NiAl-Based Alloys Studied for Improved Elevated-Temperature Strength and Room-Temperature Fracture Toughness

Efforts are underway to replace superalloys used in the hot sections of gas turbine engines with materials possessing better mechanical and physical properties. Alloys based on the intermetallic NiAl have demonstrated potential; however, they generally suffer from low fracture resistance (toughness) at room temperature and from poor strength at elevated temperatures. Directional solidification of NiAl alloyed with both Cr and Mo has yielded materials with useful toughness and elevated-temperature strength values. The intermetallic alloy NiAl has been proposed as an advanced material to extend the maximum operational temperature of gas turbine engines by several hundred degrees centigrade. This intermetallic alloy displays a lower density (approximately 30-percent less) and a higher thermal conductivity (4 to 8 times greater) than conventional superalloys as well as good high-temperature oxidation resistance. Unfortunately, unalloyed NiAl has poor elevated temperature strength (approximately 50 MPa at 1027 C) and low room-temperature fracture toughness (about 5 MPa). Directionally solidified NiAl eutectic alloys are known to possess a combination of high elevated-temperature strength and good room-temperature fracture toughness. Research has demonstrated that a NiAl matrix containing a uniform distribution of very thin Cr plates alloyed with Mo possessed both increased fracture toughness and elevated-temperature creep strength. Although attractive properties were obtained, these alloys were formed at low growth rates (greater than 19 mm/hr), which are considered to be economically unviable. Hence, an investigation was warranted of the strength and toughness behavior of NiAl-(Cr,Mo) directionally solidified at faster growth rates. If the mechanical properties did not deteriorate with increased growth rates, directional solidification could offer an economical means to produce NiAl-based alloys commercially for gas turbine engines. An investigation at the NASA Glenn Research Center at Lewis Field was undertaken to study the effect of the directional solidification growth rate on the microstructure, room temperature fracture toughness, and strength at 1027 C of a Ni-33Al-31Cr-3Mo eutectic alloy. The directionally solidified rates varied between 7.6 and 508 millimeters per hour Essentially fault-free, alternating (Cr, Mo)/NiAl lamellar plate microstructures (left photograph) were formed during growth at and below 12.7 mm/hr, whereas cellular microstructures (right photograph) with the (Cr, Mo) phase in a radial spokelike pattern were developed at faster growth rates. The compressive strength at 1027 C continuously increased with increasing growth rate and did not indicate a maxima as was reported for directionally solidified Ni-33Al-34Cr. Surprisingly, samples with the lamellar plate microstructure (left photograph) possessed a room-temperature fracture toughness of approximately 12 MPa(sup square root of m), whereas all the alloys with a cellular microstructure had a toughness of about 17 MPa(sup square root of m). These results are significant since they clearly demonstrate that Ni-33Al-31Cr-3Mo can be directionally solidified at much faster growth rates without any observable deterioration in its mechanical properties. Thus, the potential to produce strong, tough NiAl-based eutectics at commercially acceptable growth rates exists. Additional testing and alloy optimization studies are underway.

Whittenberger, J. Daniel↗