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At least 523 records · Page 29

Analysis of Respirator Cartridge Performance Testing on a Hanford AW Tank Farm Exhauster Slipstream

Washington River Protection Solutions (WRPS) conducted tests on two types of chemical cartridges for use in air-purifying respirators (APR) to determine the period of time that the cartridges would provide adequate performance for APRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPCs) from vapors exiting the exhauster for the Hanford AW tank farm. The Occupational Safety and Health Administration (OSHA) identifies cartridge testing as a valid approach for establishing a cartridge change schedules. Testing is commonly applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate cartridge service-life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Testing was conducted from September 23-25, 2016, on a slipstream from the AW exhauster, under static conditions fed to a respirator cartridge test stand developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Multipurpose respirator cartridges, SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina), were assessed on separate days. Sample media (sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridge, and were subsequently analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life.

54 ENVIRONMENTAL SCIENCES↗

Multiscale Wildfire Simulation Framework and Remote Sensing

Wildfire as one type of climate extreme events causes huge socioeconomic losses and damages. Large wildfires (i.e., generated pyrocumulonimbus (PyroCb)) can inject tremendous amounts of smoke into the stratosphere, where black carbon and organic carbon aerosols can persist months to years and influence climate by imposing a significant reduction in the radiative forcing like that associated with large volcanic eruptions or proposed via climate interventions such as geoengineering. Both observations and numerical modeling results clearly indicate an increasing trend in wildfire frequency and intensity in many regions during the recent decades with climate change. However, current understanding of wildfire remains largely uncertain owing to limitations of modeling capabilities in representing the multiscale wildfire physics and dynamics and a scarcity of observations constraining important wildfire and environmental variables. This study primarily aims to improve the wildfire simulation capabilities in the state-of-the-art climate model by filling in two major gaps: (1) model resolution is typically too coarse to resolve fine scale processes associated with fires, and (2) chemistry and aerosol processes in fire smoke are poorly represented.

54 ENVIRONMENTAL SCIENCES↗

CPViz: Visualizing clinical pathways represented in higher-order networks

To improve clinical care practice, it is important to understand the variability of clinical pathways executed in different contexts (e.g., pathways in different geographical locations, demographics, and phenotypic groups). A common way of representing clinical pathways is through network-based representations that capture trajectories of treatment steps. However, first-order networks, which are based on the Markovian property and the de facto standard model to represent transitions between steps, often fail to capture real trajectories. This paper introduces a visual analytic tool to explore and compare pathways represented in higher-order networks. Because each higher node in the network is a subtrajectory (i.e., partial or full history of treatment steps), the tool can display true sequences of treatment steps and compute the similarity of the two networks in a space of higher-order nodes. The tool also highlights areas in which the two networks are similar and dissimilar and how a certain subtrajectory is realized differently in different pathways. The paper demonstrates the tool's usefulness by applying it to multiple antidepressant pharmacotherapy pathways for veterans diagnosed with major depressive disorder and by illustrating heterogeneity in prescription patterns across pathways.

Chae, Junghoon↗

Hybrid-Energy-Powered Electrochemical Ocean Alkalinity Enhancement Model: Plant Operation, Cost, and Profitability

Electrochemical ocean alkalinity enhancement is a form of marine carbon dioxide removal, a rapidly growing industry that is powered by efficient onshore or offshore energy sources. As more and larger deployments are being planned, it is important to consider how variable energy sources like tidal energy can impact plant performance and costs. An open-source Python-based generalizable model for electrodialysis-based ocean alkalinity enhancement has been developed that can capture key system-level insights of the electrochemistry, ocean chemistry, acid disposal, and co-product creation of these plants under various conditions. The model additionally accounts for hybrid energy system performance profiles and costs via the National Laboratory of the Rockies’ H2Integrate tool. The model was used to analyze an example theoretical plant deployment in North Admiralty Inlet, including how the plant is impacted by the available energy sources in the region and the scale at which plant costs are covered by the co-products it generates, such as recycled concrete aggregates, without requiring carbon credits. The results show that the example plant could be profitable without carbon credits at commercial scales of 100,000 to 1 million tons of carbon dioxide removal per year, so long as it uses low-cost electricity sources and either sells acid or recovers recycled concrete aggregates with about 1 molar acid concentrations, though more research is needed to confirm these results.

hybrid energy↗

The impact of stratospheric aerosol intervention on the North Atlantic and Quasi-Biennial Oscillations in the Geoengineering Model Intercomparison Project (GeoMIP) G6sulfur experiment

As part of the Geoengineering Model Intercomparison Project a numerical experiment known as G6sulfur has been designed in which temperatures under a high-forcing future scenario (SSP5-8.5) are reduced to those under a medium-forcing scenario (SSP2-4.5) using the proposed geoengineering technique of stratospheric aerosol intervention (SAI). G6sulfur involves introducing sulfuric acid aerosol into the tropical stratosphere where it reflects incoming sunlight back to space, thus cooling the planet. Here, we compare the results from six Earth-system models that have performed the G6sulfur experiment and examine how SAI affects two important modes of natural variability, the northern wintertime North Atlantic Oscillation (NAO) and the Quasi-Biennial Oscillation (QBO). Although all models show that SAI is successful in reducing global mean temperature as designed, they are also consistent in showing that it forces an increasingly positive phase of the NAO as the injection rate increases over the course of the 21st century, exacerbating precipitation reductions over parts of southern Europe compared with SSP5-8.5. In contrast to the robust result for the NAO, there is less consistency for the impact on the QBO, but the results nevertheless indicate a risk that equatorial SAI could cause the QBO to stall and become locked in a phase with permanent westerly winds in the lower stratosphere.

54 ENVIRONMENTAL SCIENCES↗

Suboptimal design of a class of nonlinear controllers.

A systematic design procedure is presented for suboptimal nonlinear controller synthesis. Such a control yields faster response characteristics than are normally possible with a linear controller. The technique is geared to single-input linear systems where excursions of one state variable are of more importance than others. Design steps are formulated in terms of readily applicable algebraic equations. The proposed method is applied to several design examples and the advantages are shown by comparison with the results obtained from existing techniques.

Rouse, W. B.↗

Properties of vacuum-evaporated boron films

The work on the properties of thin boron films made by vacuum evaporation of elemental boron using an electron beam as the energy source is reported. The program aimed at characterizing the properties of vacuum evaporated films. The work was directed toward those variables considered to be important in affecting the tensile strength of the boron films. In general, the thickness of the films was less than 0.002 in. The temperature of the substrate on which the boron was condensed was found to be most important. Three distinctly different forms of boron deposit were produced. Although the transition temperature was not sharply defined, at substrate temperatures of less than approximately 600 deg C the boron deposits were amorphous to X-ray. If the substrate were highly polished, the deposits were black and mirror-like. For substrates with coefficients of thermal expansion close to that of boron, the deposits were then continuous and uncracked. The studies suggest that the potential continues to exist for film-type composites to have both high strength and high modulus.

Feakes, F.↗

Comparison under a simulated sun of two black-nickel-coated flat-plate solar collectors with a nonselective black-paint-coated collector

A performance evaluation was made of two, black nickel coated, flat plate solar collectors. Collector performance was determined under a simulated sun for a wide range of inlet temperatures, including the temperature required for solar powered absorption air conditioning. For a basis of comparison a performance test was made on a traditional, two glass, nonselective, black paint coated, flat plate collector. Performance curves and performance parameters are presented to point out the importance of the design variables which determine an efficient collector. A black nickel coated collector was found to be a good performer at the conditions expected for solar powered absorption air conditioning. This collector attained a thermal efficiency of 50 percent at an inlet temperature of 366 K (200 F) and an incident flux of 946 watts/sq m (300 Btu/hr-sq ft).

Simon, F. F.↗

High purity silica reflective heat shield development

A high purity slip cast silica material has been developed for use as a reflective heat shield for entries into the atmospheres of the outer planets. The several stages leading to the development of this material are described and details of raw material selection, preparation of the slip material and casting techniques are discussed. Optical (reflectance and transmittance), physical and chemical properties measurements were performed as a function of the important material and processing variables. Performance analysis of a reflective heat shield fabricated from the high purity silica slip shows that approximately 90 percent of the radiant bow shock energy incident on the heat shield during entry into the atmosphere of Jupiter will be reflected.

Blome, J. C.↗

Special analysis of community annoyance with aircraft noise reported by residents in the vicinity of JFK Airport, 1972

During the summer of 1972, about 1500 residents were interviewed twice in 11 communities near JFK airport. Detailed aircraft operations reports were also collected for this period, and an effort has been made to analyze recorded human response data in relation to a number of physical exposure parameters. A series of exposure indexes, based on an arithmetic integration of aircraft operations, were correlated with summated aircraft noise annoyance responses. None of these correlations were as good as the CNR index which assumes a logrithmetic integration of numbers of aircraft exposures and includes a day-night differential weighting of 10:1. There were substantial variations in average annoyance responses among communities with similar CNR exposures, substantiating previous findings that attitudinal and other personal variables also play an important role in determining annoyance differences.

Borsky, P. N.↗

Driver steering dynamics measured in car simulator under a range of visibility and roadmaking conditions

A simulation experiment was conducted to determine the effect of reduced visibility on driver lateral (steering) control. The simulator included a real car cab and a single lane road image projected on a screen six feet in front of the driver. Simulated equations of motion controlled apparent car lane position in response to driver steering actions, wind gusts, and road curvature. Six drivers experienced a range of visibility conditions at various speeds with assorted roadmaking configurations (mark and gap lengths). Driver describing functions were measured and detailed parametric model fits were determined. A pursuit model employing a road curvature feedforward was very effective in explaining driver behavior in following randomly curving roads. Sampled-data concepts were also effective in explaining the combined effects of reduced visibility and intermittent road markings on the driver's dynamic time delay. The results indicate the relative importance of various perceptual variables as the visual input to the driver's steering control process is changed.

Allen, R. W.↗

The corona and heliosphere

The eleven-year solar cycle is an especially appropriate period over which to study the solar output and its variation, because during this cycle most of the important types of solar variability (many characterized by periods shorter than eleven years) are manifested. Studies of solar variability over a solar cycle will improve understanding of solar structure and of the generation of the solar wind, and this improved understanding can be useful in the related studies of stellar structure and stellar winds, since stellar observations are necessarily less detailed and sophisticated than are solar observations. A particularly significant benefit that will accrue from a thorough study of the solar atmosphere and its variability over the next solar cycle is a great enhancement in the usefulness of so-called 'proxy' data in studying longer term solar variations and their terrestrial implication.

Holzer, T.↗

Transionospheric propagation predictions

The current status and future prospects of the capability to make transionospheric propagation predictions are addressed, highlighting the effects of the ionized media, which dominate for frequencies below 1 to 3 GHz, depending upon the state of the ionosphere and the elevation angle through the Earth-space path. The primary concerns are the predictions of time delay of signal modulation (group path delay) and of radio wave scintillation. Progress in these areas is strongly tied to knowledge of variable structures in the ionosphere ranging from the large scale (thousands of kilometers in horizontal extent) to the fine scale (kilometer size). Ionospheric variability and the relative importance of various mechanisms responsible for the time histories observed in total electron content (TEC), proportional to signal group delay, and in irregularity formation are discussed in terms of capability to make both short and long term predictions. The data base upon which predictions are made is examined for its adequacy, and the prospects for prediction improvements by more theoretical studies as well as by increasing the available statistical data base are examined.

Klobucher, J. A.↗

Measurements of plasma wave spectra in Jupiter's magnetosphere

Compressed plots of E field averages for all of the 16-channel spectrum analyzer data from the Voyager 1 and 2 magnetosphere traversals are presented to provide an overall framework for the discussion. The importance of considering peaks as well as averages is illustrated by using 16-channel measurements from the first inbound and last outbound bow shock for Voyager 2. Selected wideband measurements from the waveform receivers are presented to demonstrate how many important wave bursts are variable in times less than or comparable to the 4-s scan period of the 16-channel analyzer.

Scarf, F. L.↗

Surface temperatures and glassy state investigations in tribology, part 5

Preliminary measurements of high shear rate viscosity at near atmospheric but variable pressure suggest the importance of low normal stress and cavitation or fluid fracture in the type of stress field existing in elastohydrodynam ic inlets and classical hydrodynamic configurations. An experimental basis is given for three regimes of traction in concentrated contacts: a thin film regime characterized by high traction and determined by lambda ratio, a thick film regime characterized by low traction and determined by the speed parameter, and the elastohydrodynamic regime for which traction is controlled by limiting shear stress. Traction measurements were performed with various liquids, two solid lubricants, and a grease. Film thickness and traction measurements of polymer blends and base oils are compared.

Bair, S.↗

Estimating regression coefficients from clustered samples: Sampling errors and optimum sample allocation

A number of surveys were conducted to study the relationship between the level of aircraft or traffic noise exposure experienced by people living in a particular area and their annoyance with it. These surveys generally employ a clustered sample design which affects the precision of the survey estimates. Regression analysis of annoyance on noise measures and other variables is often an important component of the survey analysis. Formulae are presented for estimating the standard errors of regression coefficients and ratio of regression coefficients that are applicable with a two- or three-stage clustered sample design. Using a simple cost function, they also determine the optimum allocation of the sample across the stages of the sample design for the estimation of a regression coefficient.

Kalton, G.↗

A stochastic atmospheric model for remote sensing applications

There are many factors which reduce the accuracy of classification of objects in the satellite remote sensing of Earth's surface. One important factor is the variability in the scattering and absorptive properties of the atmospheric components such as particulates and the variable gases. For multispectral remote sensing of the Earth's surface in the visible and infrared parts of the spectrum the atmospheric particulates are a major source of variability in the received signal. It is difficult to design a sensor which will determine the unknown atmospheric components by remote sensing methods, at least to the accuracy needed for multispectral classification. The problem of spatial and temporal variations in the atmospheric quantities which can affect the measured radiances are examined. A method based upon the stochastic nature of the atmospheric components was developed, and, using actual data the statistical parameters needed for inclusion into a radiometric model was generated. Methods are then described for an improved correction of radiances. These algorithms will then result in a more accurate and consistent classification procedure.

Turner, R. E.↗