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At least 523 records · Page 29

Bellerophon Environment for Analysis of Materials (BEAM)

Improvements in scientific instrumentation allow imaging at mesoscopic to atomic length scales, many spectroscopic modes, and now--with the rise of multimodal acquisition systems and the associated processing capability--the era of multidimensional, informationally dense data sets has arrived. Technical issues in these combinatorial scientific fields are exacerbated by computational challenges best summarized as a necessity for drastic improvement in the capability to transfer, store, and analyze large volumes of data. The Bellerophon Environment for Analysis of Materials (BEAM) platform provides material scientists the capability to directly leverage the integrated computational and analytical power of High Performance Computing (HPC) to perform scalable data analysis and simulation and manage uploaded data files via an intuitive, cross-platform client user interface. This framework delivers authenticated, "push-button" execution of complex user workflows that deploy data analysis algorithms and computational simulations utilizing compute-and-data cloud infrastructures and HPC environments like Titan at the Oak Ridge Leadershp Computing Facility (OLCF).

Lingerfelt, Eric J↗

The R&D PERFROI Project on Thermal Mechanical and Thermal Hydraulics Behaviors of a Fuel Rod Assembly during a Loss of Coolant Accident

The safety principle in case of a LOCA is to preserve the short and long term coolability of the core. The associated safety requirements are to ensure the resistance of the fuel rods upon quench and post-quench loads and to maintain a coolable geometry in the core. An R&D program has been launched by IRSN with the support of EDF, to perform both experimental and modeling activities in the frame of the LOCA transient, on technical issues such as: - flow blockage within a fuel rods bundle and its potential impact on coolability, - fuel fragment relocation in the ballooned areas: its potential impact on cladding PCT (Peak Cladding Temperature) and on the maximum oxidation rate, - potential loss of cladding integrity upon quench and post-quench loads. The PERFROI project (2014-2019) focusing on the first above issue, is structured in two axes: 1. axis 1: thermal mechanical behavior of deformation and rupture of cladding taking into account the contact between fuel rods; specific research at LaMCoS laboratory focus on the hydrogen behavior in cladding alloys and its impact on the mechanical behavior of the rod; and, 2. axis 2: thermal hydraulics study of a partially blocked region of the core (ballooned area taking into account the fuel relocation with local over power), during cooling phase by water injection; More detailed activities foreseen in collaboration with LEMTA laboratory will focus on the characterization of two phase flows with heat transfer in deformed structures.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Microalgae Commodities from Coal-Fired Power Plant Flue Gas CO 2 (Draft Final Report, October 1, 2015 to June 30, 2018)

The Orlando Utilities Commission (OUC) operates an approximately 900-MWe coal fired-power plant at Stanton Energy Center (SEC), which was the site for this project to develop an integrated process for microalgae utilization of flue gas CO 2 for the production of biofuels and animal feeds. Microalgae have both potentially high yields (tons biomass/acre-year) and can be used for biofuels or high value animal feeds. The high biomass yields of microalgae cultures allows efficient use of land and water resources. They can also use wastewaters, recycle fertilizers, and have lower overall greenhouse gas emissions than conventional biofuels or animal feeds. However, many technical issues and technology gaps related to large-scale algae biomass production still must be resolved before such a process can be scaled-up. In this project, techno-economic analyses (TEAs) and life cycle assessments (LCAs) were carried out, projecting the costs and impacts of large-scale algae biomass cultivation for production of biofuels and animal feeds using OUC-SEC flue gas CO 2 . In addition, 3.5-m 2 (~ 40-ft 2 ) experimental raceway ponds were used for the cultivation of microalgae at OUC-SEC and also at the University of Florida. A large-scale algae farm was designed for a 1,300-acre site (~500-ha) located near the OUC-SEC plant, consisting of 400 hectares (1,000 acres) of paddle wheel mixed raceway ponds (each 4 ha), receiving flue gas piped approximately 3 km (2 miles) from the SEC plant. In the first year of this project (Budget Period 1, BP1), the TEA and LCA studies focused on the production of biogas produced from algae biomass and its use to replace coal at the power plant. However, due to the resulting very high cost of CO 2 mitigation, the process was modified to produce compressed natural gas (‘renewable natural gas’, RNG) for transportation fuel from the biogas, in conjunction with wastewater treatment by the algae cultures. During Budget Period 2 (BP2), the TEA and LCA studies focused on the production of animal feeds by the algae farm, using fresh water and agricultural fertilizers. In this case, CO 2 mitigation costs would be entirely covered if the algal biomass could be sold at between a two to three-fold premium above soybean feed, based on a higher nutritional value for the algal biomass. In support of the above analyses, microalgae cultivation experiments were carried out for over two years during this project in small 3.5-m 2 ponds at both SEC and the University of Florida. The most important results were the demonstration at SEC of the cultivation, on flue gas CO 2 , of filamentous algae biomass, which can be harvested at much lower cost than processes required for the colloidal algae species, as currently used by almost all algal mass culture biofuels and animal feeds projects. The yield of biogas production from the algal biomass was investigated by the University of Florida, and the value of the algal biomass as animal feed was projected based on biochemical analysis of the SEC ad UF biomasses. The conclusion from TEA/LCA carried out for the biogas case in BP1 was that a 400-ha algae system producing biomethane for co-firing at OUC-SEC could generate 27,500 MWh/yr of renewable power, offsetting 28,400 Mg CO 2eq /yr, which amounted to less than 1% of the CO 2 emitted by the SEC plant. (Mg = metric ton = 1.10 short tons). The overall cost was projected at $820/Mg of CO 2eq reduction, making this process unfeasible under any possible scenario. More favorable economics were projected when the biogas was converted to higher value transportation fuel, RNG, which also would benefit from renewable fuel (RINs) and possibly other credits. However, only by combining RNG production with municipal wastewater treatment in the algal ponds would CO 2 utilization result in no net cost or even be economically beneficial (i.e., generate income to the power plant). However, in that case the amount of CO 2 utilization would be even lower than that in the biogas case, because a large fraction of the carbon required would be supplied from the wastewater and CO 2 recovered during biogas upgrading to RNG. In brief, use of power plant CO 2 emissions for algal biofuels production was not favorable, even with optimistic assumptions about biomass productivity and biogas yields. For the animal feed case, developed during BP2, algal biomass would replace soybean feeds. The same scale 400-ha algal production plant was projected to produce 26,280 Mg per year of animal feed with a utilization of 45,300 Mg flue gas CO 2 taken up by the algal biomass. However, the process would result in a projected reduction of 112,500 Mg CO 2eq emissions per year, or roughly 1.9% of OUC-SEC emissions, mainly due to the large CO 2eq emissions from conventional soybean production. A major factor in this analysis were greenhouse gas emissions from land use changes. The cost of CO 2 utilization was projected at $116/Mg if the biomass sold for the same price as soybean meal, but if sold as a premium feed (e.g., based on high omega-3 fatty acid and carotenoid content), the power plant could actually charge for the CO 2 utilized. These economic projections are sensitive to assumptions underlying the TEA and LCA models, including biomass composition and the financial models used to project CAPEX and OPEX. Further development of an algal animal feed production using coal-fired power plant flue gas CO 2 is recommended based on the TEA and LCA, as well as experimental results. The required research and development is detailed in a technology gap analysis (Section 11), which focuses on the demonstrations of the cultivation of higher value filamentous algal biomass at OUC-SEC.

01 COAL, LIGNITE, AND PEAT↗

Durability, Reliability and Safety of Energy Storage Systems

For grid modernization, energy storage systems play a critical role in reliability. There are many technical issues and barriers that need to be addressed to redefine the reliability issues in modern grid system integration with renewable and distributed energy resources. This presentation is to disseminate some existing reliability issues in the energy storage systems to paint a bigger picture of what needs to be addressed. This presentation is intended to define these issues before we strive for a solution.

25 ENERGY STORAGE↗

Exploiting Knowledge of Technetium in the Subsurface to Develop Remediation Strategies – 18223

Technetium-99 (Tc) contamination remains a major environmental problem at legacy nuclear reprocessing sites, such as the Hanford Site in south-central Washington state, where the total inventory of released Tc is estimated at 700 Ci. The environmental risk associated with Tc is due to its long half-life (213,000 years) and the high mobility of the oxidized anionic pertechnetate species (Tc(VII)O4-). Thus, there is a critical need to resolve scientific and technical issues underpinning the ability to safely, cost-effectively, and efficiently remediate Tc-contaminated vadose zone sediments and groundwater. Developing enhanced attenuation strategies for released Tc that reduce contaminant migration, while mitigating risk to human health and the environment, requires characterization of any retardation processes and mass flux. The current conceptual model for Tc transport in the vadose zone assumes that Tc is predominantly present in its oxidized form as TcO4-, which is highly soluble and mobile. However, under certain conditions, Tc can become entrained in solid phases. Characterization of Tc-containing mineral phases from sediment cores extracted from various Hanford waste disposal sites were analyzed to determine Tc present in vadose zone sediments as (i) TcO4- that remains in water films associated with fine-grained sediments; (ii) Tc co-precipitated with other lanthanides in phosphate mineral phases; and (iii) Tc present as TcO2•nH2O in localized reducing zones. These results will be used to develop improved long-term Tc remediation strategies that are most likely to succeed during field application, through stimulation of conditions that enhance Tc attenuation.

Pearce, Carolyn I.↗

Introduction to Life Cycle Analysis

Presented by NETL at Indiana Utility Regulatory Commission - 2019 Integrated Resource Planning Contemporary Issues Technical Conference, 04/19

Jamieson, Matthew↗

Industrial Cavity Production: Lessons Learned to Push the Boundaries of Nitrogen-Doping

Nitrogen doping has been proven now in several labs to enhance Q0 values of 1.3 GHz cavities in the gradient domain favored by CW operation. The choice of doping for the LCLS-II project has given the community a wealth of statistics and experience on the challenge of transferring the doping technology to industry. Overall, industry-produced nitrogen-doped cavities have shown excellent performance, however some technical issues have arisen. This talk focuses on lessons learned from the production of over 300 nitrogen-doped cavities for LCLS-II and how issues were mitigated to further improve performance. Finally, I will discuss pushing the boundaries of nitrogen-doping further by exploring different doping regimes in order to maintain excellent Q0 performance, while reaching higher quench fields.

Gonnella, D.↗

International Developments on Uncertainties in NPP Decommissioning costs and planned work on Benchmarking at the OECD-NEA - 17074

The ability to decommission NPPs shut down after normal operation has been proven technically. Issues of current concern include the ability to accurately calculate and demonstrate the validity of decommissioning cost estimates, and to control costs during decommissioning. This paper describes recent international developments concerning addressing uncertainties in NPP decommissioning cost estimation, and work currently being planned relating to decommissioning cost benchmarking at the OECD Nuclear Energy Agency. The process of decommissioning cost estimation is evolving, with a general trend towards showing greater levels of detail in the estimate. The International Structure for Decommissioning Costing was published in 2012 and presents a common reporting format for decommissioning costing undertaken on a deterministic basis. However, this does not address probabilistic methods or associated presentation formats for the inclusion of uncertainties in decommissioning estimates. A consistent and comparable treatment of uncertainties in decommissioning cost estimation would further facilitate comparison between different cost estimates and enhance understanding of and confidence in the estimates themselves. There is growing interest in benchmarking decommissioning costs, reflecting a need to better understand the relationships between estimates and actual costs, to give greater confidence that funding will be sufficient, and as a useful tool in project management and enhancing project delivery. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Development and Testing of a High Level Waste Slurry Sampling Technique to Support Hanford Waste Processing - 17164

The Hanford Tank Operations Contractor must demonstrate the capability to adequately sample staged high-level waste feed. The sampler employed must have accuracy and precision performance that allow the Tank Operations Contractor (TOC) to meet the Waste Treatment and Immobilization Plant (WTP) Waste Acceptance Criteria Data Quality Objectives (DQO). A full-scale sampling loop was used at a test facility to develop and demonstrate sampler capability. This paper will discuss the modifications to a sampler configuration previously tested - modifications focused on the improvement of the accuracy of test results. This work targets one of the remaining technical issues with the high-level waste treatment mission at Hanford. The sampling method employed must support both Tank Operations and Waste Treatment and Immobilization Plant requirements. To facilitate information transfer between the two facilities the mixing and sampling demonstrations are led by the TOC's Chief Technology Office in conjunction with the One System Integrated Project Team. Results of the testing showed that performance of the Isolok{sup R} sampler, chosen for implementation, can be greatly improved by modifying the systems configuration to provide accurate, repeatable results for Hanford's simulated high level waste. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Application of Robotics Technology to D and D - 17249

The Knowledge Management Information Tool (KM-IT) is a web-based system developed to maintain and preserve the deactivation and decommissioning (D and D) knowledge base across the Department of Energy (DOE) complex. The system was developed by the Applied Research Center (ARC) at Florida International University (FIU) with the support of the D and D community, including the DOE Office of Environmental Management (DOE EM), and with the active collaboration and support of the DOE's Energy Facility Contractors Group (EFCOG). The KM-IT system is a D and D community driven system tailored to serve the technical issues faced by the D and D workforce across the DOE Complex. As part of the D and D KM-IT, FIU has developed a robotics database in collaboration with DOE EM and Nuvision/Cogentus which currently contains over 500 robotics technologies along with information about the robotics technology vendors. This information is aggregated in real time and presented as a robotics technology fact sheet to the end user based on the selected technology. FIU is researching these technologies and studying their capabilities and application to D and D. As part of the research, FIU is categorizing each technology into specific application areas: characterization, decontamination, inspection, and demolition. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Full-Scale Vessel Testing of the Standard High-Solids Vessel for the Hanford Waste Treatment Plant Pretreatment Facility - 17282

Concerns over the mixing performance of the planned pulse-jet mixed (PJM) vessels for high solids applications in the Hanford Waste Treatment and Immobilization Plant (WTP) Pretreatment (PT) Facility, led to the development of a standard high-solids vessel (SHSV) design and full-scale vessel testing. The SHSV is intended as a potential replacement for several high-level waste feed receipt and lag storage vessels, ultrafiltration feed preparation vessels, and plant wash vessels. The SHSV design concept uses multiple smaller vessels (60 500 to 79 500 liters nominal batch size) to replace larger vessels, providing redundancy, improved mixing (PJM design and spargers), monitoring (multi-level bubblers), reduced material at risk, and improved structural features. The SHSV also requires qualification of a single vessel design for high solids Newtonian and non-Newtonian slurry processing, rather than earlier multiple vessel designs. Qualification of the SHSV design for mixing will be achieved through full-scale vessel testing (FSVT) with a prototypic SHSV under a set of most adverse design conditions in conjunction with additional engineering analyses. An Integrated Technical Team consisting of the U.S. Department of Energy (DOE), Bechtel National, Inc. (BNI), and independent experts was established to accelerate and provide oversight and direction to the test program and SHSV qualification. This paper will present an overview of the SHSV, full-scale vessel test and qualification program, and the management program to achieve closure of technical issues associated with PJM vessel mixing and control systems. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Searching for science in the past and present discussion on commingling policy in the US - 15083

Since 1985, the policy in the United States for disposing of nuclear waste has included commingling defense and civilian spent nuclear fuel (SNF) and high-level radioactive waste (HLW) in a mined geologic repository. Commingling policy is under discussion again because of developments over the last several years in the nuclear waste management and disposal program. The authors reviewed the extent to which scientific and technical information was involved in considerations of commingling from the 1950's to the present. Evaluations undertaken by the US Department of Energy (US DOE) in 1985 and April 2014 are compared and the technical issues of health and safety, transportation, and national security are addressed in both evaluations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Knowledge management information tool Web analytics - 15182

The Knowledge Management Information Tool (KM-IT) is a web-based [01] system developed to maintain and preserve the Department of Energy's (DOE's) D and D knowledge base. The system was developed by Florida International University's Applied Research Center (FIU-ARC) with the support of the D and D community including the DOE Office of Environmental Management, and with the active collaboration and support of the DOE's Energy Facility Contractors Group (EFCOG). The KM-IT system is a D and D community driven system tailored to serve the technical issues faced by the D and D workforce across the DOE Complex. The D and D KM-IT is an interactive web-based system operational and available for free access at www.dndkm.org. [02] The D and D KM-IT is currently composed of the following tailored D and D modules: Web Crawler, Hotline, Technology, Document Library (including Hanford's and Savannah River Sites' ALARA Center Reports), Specialist Directory, Lessons Learned, Best Practices, Video/Picture Library, Vendors, Collaboration Tools, Training, and Mobile Systems. The Web Crawler dynamically searches through the D and D KM-IT repository as well as the web and displays search results based on the search criteria. The Hotline allows registered users to post questions/problems related to D and D and to receive solutions from a subject-matter specialist. The Technology module serves as repository of D and D technologies and contains technology/ demonstration fact sheets and vendor information. D and D community members can add Lessons Learned, Best Practices, Documents, and Pictures/Videos to the D and D KM-IT repository, after a formal approval process. The Vendor module provides a directory of commercial vendors who provide D and D related technologies, supplies, and services. D and D KM-IT makes excellent use of the knowledge that exists within the D and D community by allowing D and D project managers around the DOE complex to collaborate by sharing innovative ideas, past experiences, and practices and by maintaining a directory of subject matter specialists. The mobile version of the KM-IT can be accessed from m.dndkm.org [03] and currently has six active modules: Vendor, Technology, Picture/Video Library, Hotline, Lessons Learned and Specialist Directory. Web analytics is a key tool being implemented by the D and D KM-IT project team in an effort to enhance the system to better meet users' needs. The D and D KM-IT project team incorporates web analytics as part of its operational elements to analyze information and key data points on how the system is being used. Web analytics is the measurement, collection, analysis and reporting of internet data for the purposes of understanding and optimizing web usage. The use of web analytics retains or attracts D and D community members to access and share knowledge through virtual collaboration on the KM-IT platform. D and D KM-IT web analytics measures details on the overall usage of the system without tracking personal information or specific user behavior: how many users visited the application, how many of those users were unique visitors, how visitors come to the system (i.e., by following a link to the system or by using the web site URL via bookmark or directly typing the address), what keywords were used to perform searches with the search engine, how long the average user stayed on a given screen or on the entire system and what links were clicked on. This information is used to identify which areas of the system are more popular than the others and provides information that can be used to streamline the application for a better user experience. (authors)

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

The underground research facilities (URF) network - illustrating the IAEA's concept and use of professional networks - 15382

Since 2001, the IAEA has championed the concept and use of professional networks (Communities of Practice) to advance best practices and to provide a platform for cooperation in radioactive waste management, decommissioning and environmental remediation across the globe. The Underground Research Facilities (URF) Network was the first in a series of networks implemented under the auspices of the IAEA to share experiences, elicit best practices, and transfer knowledge on topics relevant to the development and implementation of geological disposal of long lived and high level radioactive waste - i.e. intermediate level waste (ILW), high-level waste (HLW) and/or spent nuclear fuel (SNF). Special emphasis is placed on the role and use of URFs to support such geological disposal developments. In addition to the direct benefits provided to Member States through its programme of work, the URF Network also delivers less tangible, yet equally valuable benefits through the informal exchange of information, the development of peer-to-peer professional networks, and seeding of multi-lateral cooperation between Member States. Network members represent a range of nuclear programme sizes and advancements in their respective repository programmes. After a decade of fruitful cooperation, delivering more than 30 training courses on topics relevant to geological disposal, the URF Network is gradually reassessing its mode of operation and focus of work. Emphasizing selected strategic goals - focused in part on more systematic training of URF Network members human resources and in part on select key technical issues - would benefit all network members, while remaining cautious in the commitment of scarce resources. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Life Cycle Costing in Radioactive Waste Packaging: Reducing Costs Whilst Accelerating Clean-Up - 16131

In recognition of the high up-front costs and potentially long timescales to implement the more traditional methods of encapsulating wastes, in the UK alternative approaches to help accelerate hazard reduction and reduce such costs are being deployed. When considering such the cost of alternative approaches to waste packaging strategies, it is important that the complete waste life cycle is taken into account. This paper will demonstrate that when evaluating waste packaging options, whilst individual elements (e.g. container costs) within an overall waste management programme may appear to offer a cost benefit by comparison with alternatives, the programme as a whole may not necessarily be the most cost effective solution when life cycle costs are taken into account, or when other technical issues are considered. To illustrate this point this paper will present a view of the application of LCC, utilising a number of waste packaging scenarios, to promote discussion and consideration of the benefits of undertaking a holistic assessment of the investment decision as part of an overall waste management strategy. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Public Outreach in FUSRAP - 16201

The U. S. Army Corps of Engineers (USACE) is the lead federal agency for the Formerly Utilized Sites Remedial Action Program (FUSRAP) which was initiated in 1974 to address contamination remaining from Manhattan Engineer District and early U.S. Atomic Energy Commission activities. As the lead agency, USACE follows the protocols set forth in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) to address FUSRAP sites. During certain project milestones of the CERCLA process, community outreach initiatives occur to communicate the status and/or findings from site investigations and project decision documents. The style of public interaction is tailored to match the project milestone, technical complexity of a project, the stakeholder involvement level, or type of decision being made on a particular project. Community involvement is one of the most important aspects of environmental work, and proactive and transparent communication can build meaningful relationships with the community and between project stakeholders. The USACE Buffalo District has experience using different stakeholder interaction techniques and providing information on projects through a variety of media. Rather than simply distributing information, the goal of community outreach is to encourage participation in the process and to provide opportunities for the public to fully understand, ask questions about, and provide feedback on the complex technical issues involved in decision-making for each FUSRAP site. The frequency and method of interaction depends on the project, and the USACE Buffalo District has worked to promote openness and transparency and to ensure the community is provided with many opportunities for public participation. Project information has been provided to stakeholders using multiple techniques, such as formal project workshops, poster sessions, site tours, news releases, storybooks, and videos. Aside from project-specific community relations plans, the USACE Buffalo District has participated in Science, Technology, Engineering and Math (STEM) programs established to inspire current and future generations of young people to pursue careers in STEM fields. Each year, the USACE Buffalo District performs outreach in the community to share information on our projects as well as to introduce students to various disciplines associated with environmental careers. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Robotics Technologies on Knowledge Management Information Tool (KM-IT) Platform - 16465

The Knowledge Management Information Tool (KM-IT) is a web-based system developed to maintain and preserve the deactivation and decommissioning (D and D) knowledge base across the Department of Energy (DOE) complex. The system was developed by the Applied Research Center (ARC) at Florida International University (FIU) with the support of the D and D community, including the DOE Office of Environmental Management (DOE EM), and with the active collaboration and support of the DOE's Energy Facility Contractors Group (EFCOG). The KM-IT system is a D and D community driven system tailored to serve the technical issues faced by the D and D workforce across the DOE Complex. New information, including vendors and technologies related to D and D, are researched and added to KM-IT on an ongoing basis. In late 2014, DOE EM provided a database of 471 robotic technologies, originally developed by NuVision Engineering and Cogentus Consulting, with a request to evaluate the potential for integrating the data into the KM-IT framework for ongoing hosting/maintenance of the information. All of the data from the original database as well as photographs, documents, and videos are now available on KM-IT. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Exploiting Knowledge of Technetium in the Subsurface to Develop Remediation Strategies - 18223

Technetium-99 (Tc) contamination remains a major environmental problem at legacy nuclear reprocessing sites, such as the Hanford Site in south-central Washington State, where the total inventory of released Tc is estimated at 700 curies (Ci). The environmental risk associated with Tc is due to its long half-life (213,000 years) and the high mobility of the oxidized anionic pertechnetate species (Tc(VII)O{sub 4}{sup -}). Thus, there is a critical need to resolve scientific and technical issues underpinning the ability to safely, cost-effectively, and efficiently remediate Tc-contaminated vadose zone sediments and groundwater. Developing enhanced attenuation strategies for released Tc that reduce contaminant migration, while mitigating risk to human health and the environment, requires characterization of any retardation processes and Tc mass flux. The current conceptual model for Tc transport in the vadose zone assumes that Tc is predominantly present in its oxidized form as TcO{sub 4}{sup -}, which is highly soluble and mobile. However, under certain conditions, Tc can become entrained in solid phases. Tc-containing mineral phases from sediment cores extracted from various Hanford waste disposal sites were characterized to determine Tc present in vadose zone sediments as (i) TcO{sub 4} - that remains in water films associated with fine-grained sediments; (ii) Tc co-precipitated with other lanthanides in phosphate mineral phases; and (iii) Tc present as TcO{sub 2}.nH{sub 2}O in localized reducing zones. These results will be used to develop improved long-term Tc remediation strategies that are most likely to succeed during field application, through stimulation of conditions that enhance Tc attenuation. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗