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At least 523 records · Page 29

Wetting transition and fluid trapping in a microfluidic fracture

Immiscible fluid–fluid displacement in confined geometries is a fundamental process occurring in many natural phenomena and technological applications, from geological CO 2 sequestration to microfluidics. Due to the interactions between the fluids and the solid walls, fluid invasion undergoes a wetting transition from complete displacement at low displacement rates to leaving a film of the defending fluid on the confining surfaces at high displacement rates. While most real surfaces are rough, fundamental questions remain about the type of fluid–fluid displacement that can emerge in a confined, rough geometry. Here, we study immiscible displacement in a microfluidic device with a precisely controlled structured surface as an analogue for a rough fracture. We analyze the influence of the degree of surface roughness on the wetting transition and the formation of thin films of the defending liquid. We show experimentally, and rationalize theoretically, that roughness affects both the stability and dewetting dynamics of thin films, leading to distinct late-time morphologies of the undisplaced (trapped) fluid. Finally, we discuss the implications of our observations for geologic and technological applications.

42 ENGINEERING↗

Biomass Resources and Emission Reduction Potential of Agricultural and Livestock Residues in Mainland China from 2013 to 2022

Controlling carbon emissions is a global goal, and China is actively implementing carbon reduction measures. As a major agricultural nation, China has considerable potential for developing agricultural residues as renewable and environmentally friendly biomass energy. In this study, we obtained data on crop yields, crop-to-grain ratios, and livestock excretion coefficients to calculate the biomass resources of agricultural and livestock residues in Chinese provinces from 2013 to 2022. Crop residue biomass resources showed a distribution pattern with higher levels in the north than in the south and the east than in the west. Henan and Heilongjiang provinces consistently had the highest resource levels, exceeding 35 million tons annually for 10 years. The biomass resources from livestock residues were relatively abundant in Sichuan, Henan, Yunnan, Shandong, Hunan, and Inner Mongolia. Inner Mongolia, Sichuan, Shandong, and Henan had the greatest potential for CO2 emission reductions, primarily located in regions abundant in biomass resources and with high traditional energy consumption levels. ArcGIS was used to apply natural break classification to categorize the potential for emission reductions from agricultural and livestock residues across China from 2013 to 2022 into five classes. Based on factors such as crop planting area and livestock numbers, the spatiotemporal distribution of factors influencing the quantity of biomass resources was examined using Geographically and Temporally Weighted Regression. A tailored and integrated approach should be used for biomass, and the development of biomass energy should be promoted through policy support and technological innovation.

Environmental Sciences & Ecology↗

Design of a finline antenna for current drive in TST-2

A novel “finline” antenna was designed to excite lower-hybrid waves (LHWs) for plasma current drive at 2.45 GHz in the TST-2 spherical tokamak. A periodic fin array acts as a transmission line for electromagnetic surface waves. Cold tests confirmed propagation of the electromagnetic surface wave on the fin array which was dominantly Transverse Magnetic (TM). Unlike the conventional waveguide array “grill” antenna, the finline antenna requires only two ports to feed all the elements, and calculations show that there is little reflection regardless of the plasma conditions in front of the antenna. Characteristics of the microwave transmission on the fin array were investigated using a three-dimensional full-wave simulation and the fin geometry was tuned to achieve the desired refractive index. Coupling to LHWs under typical TST-2 scrape-off layer conditions was confirmed by the simulation. Finally, to demonstrate LHW excitation, the finline antenna was energized in the presence of a plasma generated by another 200 MHz LH antenna. The x-ray radiation showed strong enhancement during the finline antenna pulse which indicated successful generation of fast electrons by LHWs.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Electron heating in kinetic-Alfvén-wave turbulence

We report analytical and numerical investigations of subion-scale turbulence in low-beta plasmas using a rigorous reduced kinetic model. We show that efficient electron heating occurs and is primarily due to Landau damping of kinetic Alfvén waves, as opposed to Ohmic dissipation. This collisionless damping is facilitated by the local weakening of advective nonlinearities and the ensuing unimpeded phase mixing near intermittent current sheets, where free energy concentrates. The linearly damped energy of electromagnetic fluctuations at each scale explains the steepening of their energy spectrum with respect to a fluid model where such damping is excluded (i.e., a model that imposes an isothermal electron closure). In conclusion, the use of a Hermite polynomial representation to express the velocity-space dependence of the electron distribution function enables us to obtain an analytical, lowest-order solution for the Hermite moments of the distribution, which is borne out by numerical simulations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Local magnetic moments due to loop currents in metals

We present Hartree-Fock calculations on a simple model to obtain the conditions of formation of local magnetic moments due to loop currents $L$ $o$ and spin-loop currents $L$ $s$ and compare them to the conditions of formation of local spin moments $M$ which were given long ago in a similar approximation by Anderson. A model with three degenerate orbitals sitting on an equilateral triangle, with on-site and nearest-neighbor repulsions $U$ and $V$, respectively, and intersite kinetic energy, hybridizing with conduction electrons with a parameter $Δ$ is investigated. $L$ $o$ and $L$ $s$ are promoted by large $V$/$Δ$ and their magnitude is relatively unaffected by $U$/$Δ$. Spin-magnetic moments $M$ promoted by large $U$/$Δ$ on the other hand are adversely affected by $V$/$Δ$. In this model, $L$ $o$ for $V$ multiplied by the number of neighbors is approximately the same as the $M$ promoted by $U$ in Anderson’s local model for $M$. $L$ $o$ and $L$ $s$ are degenerate if exchange interactions and Hund’s rule are neglected but $L$ $o$ is favored when they are included. Many of the qualitative results are visible in an expression for the Hartree-Fock ground state energy derived as a function of small $L$ $o$ , $L$ $s$ , and $M$. Numerical minimization of the Hartree-Fock energy is presented for larger values. Additionally, we also briefly discuss the connection and differences of the interaction-generated orbital currents and spin currents discussed here and generalized to a lattice with the topological states in metals and semiconductors.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Looking back at 50 years of cutting-edge capabilities: LANSCE ‘underpins Los Alamos as a world-class scientific institution’

What started with an idea and a memo has since grown into a one-of-a-kind, world-renowned facility that contributes to the nation’s advancement of science and technology. First known as LAMPF (Los Alamos Meson Physics Facility) until the 1990s when it became LANSCE (Los Alamos Neutron Science Center), the facility is celebrating the 50th anniversary of its first full-capacity proton beam on June 9, 1972. Since then, LANSCE has contributed to a range of national security goals, such as supporting the Lab’s stockpile stewardship program, helping to advance the science of medical radioisotopes, improving the understanding of hydrodynamics, and more. “LANSCE has served the nation through its near-unique capabilities,” said Alan Carr, Senior Historian at the National Security Research Center, which houses the facility’s evolution through decades of documents, photos and other materials. “Since 1972, LANSCE has been the Lab’s major experimental science facility and underpins Los Alamos as a world-class scientific institution. This was true 50 years ago and is still true today.” In commemoration of this anniversary, we’re taking a look back at LANSCE’s historic five decades, including its first director, earliest milestones and important contributions to national security.

43 PARTICLE ACCELERATORS↗

Investigation of Main Bearing Fatigue Estimate Sensitivity to Synthetic Turbulence Models Using a Novel Drivetrain Model Implemented in OpenFAST

ABSTRACT A coupled medium‐fidelity drivetrain model is developed and implemented in OpenFAST for a 10‐MW land‐based reference turbine. The implementation is verified against a fully coupled multibody wind turbine model, including a detailed drivetrain. The new model can simultaneously and accurately estimate main bearing loads and represent elastic bending of the drivetrain. It has low computational cost and is useful for early design phases, sensitivity analyses and complex systems like wind farms (where computational expense must be expended elsewhere). Here, the model is implemented for a monopile offshore wind turbine and used to investigate the sensitivity of main bearing basic rating life to different synthetic turbulence models. Large‐eddy simulations (LES) targeting stable, neutral, and unstable atmospheric conditions at below‐, near‐ and above‐rated wind speeds are used as a reference. The turbulence models recommended by the International Electrotechnical Commission, the Mann spectral tensor model, and the Kaimal spectral model with exponential coherence are fitted to the LES data. Additionally, a constrained turbulence generator, PyConTurb (short for Python Constrained Turbulence ), based on LES data, is applied in the aero‐hydro‐servo‐elastic simulations. Taking PyConTurb as the baseline, the Kaimal model significantly underestimates fatigue of the downwind main bearing, with between 10% and 40% less damage. The Mann model also underestimates the downwind main bearing fatigue by up to 30%. The upwind main bearing damage is driven by mean loads, and differences between models are less significant, although the trends are similar. Reasons for these discrepancies are investigated and attributed to differences in spatial and temporal variations among the turbulence models.

17 WIND ENERGY↗

Exceptional points in a passive strip waveguide

Abstract Exceptional points (EPs) in non‐Hermitian systems have attracted significant interest due to their unique behaviors, including novel wave propagation and radiation. While EPs have been explored in various photonic systems, their integration into standard photonic platforms can expand their applicability to broader technological domains. In this work, we propose and experimentally demonstrate EPs in an integrated photonic strip waveguide configuration, exhibiting unique deep wave penetration and uniform‐intensity radiation profiles. By introducing the second‐order grating on one side of the waveguide, forward and backward propagating modes are coupled both directly through second‐order coupling and indirectly through first‐order coupling via a radiative intermediate mode. To describe the EP behavior in a strip configuration, we introduce modified coupled‐mode equations that account for both transverse and longitudinal components. These coupled‐mode formulas reveal the formation of EPs in bandgap closure, achieved by numerically optimizing the grating’s duty cycle to manipulate the first‐ and second‐order couplings simultaneously. Experimental observations, consistent with simulations, confirm the EP behavior, with symmetric transmission spectra and constant radiation profiles at the EP wavelength, in contrast to conventional exponential decay observed at detuned wavelengths. These results demonstrate the realization of EPs in a widely applicable strip waveguide configuration, paving the way for advanced EP applications in nonlinear and ultrafast photonics, as well as advanced sensing technologies.

Materials Science↗

Regulatory Research Planning for Micro-Reactor Development

A limited-scope Regulatory Research Development Plan (RRDP) is being developed to link important advanced non light water nuclear microreactor technology research and development (R&D) activities sponsored by the U.S. Department of Energy’s Office of Nuclear Energy (DOE NE), Science, and Technology to regulatory requirements and critical licensing needs likely to impact the deployment of a domestic commercial microreactor fleet. This document is a precursor to that forthcoming limited scope microreactor RRDP. This report is being published to aid in the identification of key fiscal year (FY) 2022 topical research opportunities (as conveyed to the RRDP development team) by respondent microreactor developers and suppliers in consideration of micro-reactor regulatory needs and challenges noted by industry, DOE, and Nuclear Regulatory Commission (NRC) stakeholders. Although this document does not contain the regulatory effects analysis and R&D recommendations that is expected in the final RRDP, this document is being released now to assist DOE researchers and investigators in FY22 research planning activities.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

First-Principles Investigation of Electrides Derived from Sodalites

Recently, electride materials, with excess anionic electrons confined in their empty space, have received growing attention due to their promising applications in catalysis, nonlinear optics, and spin electronics. However, the utilization of electride materials is limited by their thermal instability. Here, we introduce an alternative way to achieve the localized anionic electron states via the removal of highly symmetric Wyckoff sites of anions from the existing sodalite compounds. Using four halide sodalites as the parental structures, our simulation reveals that the materials after the removal of anionic halide sites exhibit typical electride behaviors that are characterized by the existence of localized electronic states near the Fermi level. Compared to most previously studied electrides, these materials are expected to be more thermally stable due to the complex structural framework and thus promising for practical applications. Among them, Na 4 (AlSiO 4 ) 3 manifests magnetic electronic structure. We demonstrate that this magnetism originates from a highly localized excess electron state surrounded by electropositive alkaline cations. Here, our results suggest Na 4 (AlSiO 4 ) 3 could be a promising spintronics component, thus encouraging further experimental study.

36 MATERIALS SCIENCE↗

An overview of bipolar plates in proton exchange membrane fuel cells

Bipolar plates are a crucial component of proton exchange membrane fuel cells. They are responsible for transporting reactant gases, carrying the current from the membrane electrode assembly to the end plates, providing heat and water management, and separating the individual cells. However, these plates also contribute to 80% of the fuel cell’s weight, 50% of its volume, and 40% of its cost, posing a barrier to the commercialization of fuel cells. This paper provides a comprehensive review of the materials and manufacturing processes used in the fabrication of bipolar plates as well as recent research conducted on the improvement of bipolar plate weight, volume, and cost through material selection and manufacturing methods. Additive manufacturing is highlighted in this work as an innovative manufacturing method to produce bipolar plates. Novel contributions in this paper include a detailed explanation of traditional manufacturing processes for metallic and graphitic-polymer bipolar plates as well as a cost comparison between additive and traditional manufacturing processes.

08 HYDROGEN↗

Reversible Ferroelectric Polarization Modulation of Chiral Molecular Ferroelectrics by Circularly Polarized Light

Abstract The optical modulation of ferroelectric polarization constitutes a transformative, non‐contact strategy for the precise manipulation of ferroelectric properties, heralding advancements in optically stimulated ferroelectric devices. Despite its potential, progress in this domain is constrained by material limitations and the intricate nature of the underlying mechanisms. Recent studies have achieved efficient regulation of ferroelectric polarization and thermal conductivity in chiral ferroelectric thin films through the application of left‐ and right‐handed circularly polarized light (LCP and RCP). Differential absorption of circularly polarized light (CPL) induces nonequilibrium carrier dynamics, generating distinctive interfacial electrostatic fields that enable precise control of ultrathin ferroelectric films. For (R)‐BINOL−DIPASi and (S)‐BINOL−DIPASi (C 26 H 26 O 2 Si), polarization changes surpass 23%, exhibiting opposite response under LCP and RCP excitation. In R chiral films, remnant polarization decreases from 1.05 µC cm − 2 under LCP to 0.85 µC cm − 2 under RCP, whereas in S chiral films, polarization increases from 0.85 µC cm − 2 under LCP to 0.98 µC cm − 2 under RCP. This reversible modulation facilitates reliable switching between ON and OFF states, presenting the potential of chiral ferroelectric materials for flexible, high‐speed integrated photonic sensor technologies.

Chemistry↗

Moiré photonics and optoelectronics

Moiré superlattices, the artificial quantum materials, have provided a wide range of possibilities for the exploration of completely new physics and device architectures. In this Review, we focus on the recent progress on emerging moiré photonics and optoelectronics, including but not limited to moiré excitons, trions, and polaritons; resonantly hybridized excitons; reconstructed collective excitations; strong mid- and far-infrared photoresponses; terahertz single-photon detection; and symmetry-breaking optoelectronics. We also discuss the future opportunities and research directions in this field, such as developing advanced techniques to probe the emergent photonics and optoelectronics in an individual moiré supercell; exploring new ferroelectric, magnetic, and multiferroic moiré systems; and using external degrees of freedom to engineer moiré properties for exciting physics and potential technological innovations.

Science & Technology - Other Topics↗

Glancing Angle Deposition in Gas Sensing: Bridging Morphological Innovations and Sensor Performances

Glancing Angle Deposition (GLAD) has emerged as a versatile and powerful nanofabrication technique for developing next-generation gas sensors by enabling precise control over nanostructure geometry, porosity, and material composition. Through dynamic substrate tilting and rotation, GLAD facilitates the fabrication of highly porous, anisotropic nanostructures, such as aligned, tilted, zigzag, helical, and multilayered nanorods, with tunable surface area and diffusion pathways optimized for gas detection. This review provides a comprehensive synthesis of recent advances in GLAD-based gas sensor design, focusing on how structural engineering and material integration converge to enhance sensor performance. Key materials strategies include the construction of heterojunctions and core–shell architectures, controlled doping, and nanoparticle decoration using noble metals or metal oxides to amplify charge transfer, catalytic activity, and redox responsiveness. GLAD-fabricated nanostructures have been effectively deployed across multiple gas sensing modalities, including resistive, capacitive, piezoelectric, and optical platforms, where their high aspect ratios, tailored porosity, and defect-rich surfaces facilitate enhanced gas adsorption kinetics and efficient signal transduction. These devices exhibit high sensitivity and selectivity toward a range of analytes, including NO2, CO, H2S, and volatile organic compounds (VOCs), with detection limits often reaching the parts-per-billion level. Emerging innovations, such as photo-assisted sensing and integration with artificial intelligence for data analysis and pattern recognition, further extend the capabilities of GLAD-based systems for multifunctional, real-time, and adaptive sensing. Finally, current challenges and future research directions are discussed, emphasizing the promise of GLAD as a scalable platform for next-generation gas sensing technologies.

Chemistry↗

NNSS Plumbs the Bright Side of Dark-Field X-ray Microscopy

Article to be included in the second quarter, FY 2021, issue of the LDRD Quarterly Highlights. website: https://www.lanl.gov/projects/ldrd-tri-lab/quarterly-highlights.php. The article may also be used internally on the MSTS Science and Technology website and on the NNSS.gov SDRD news highlights page.

36 MATERIALS SCIENCE↗