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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Ultrafast transient absorption measurements of photocarrier dynamics in PdSe 2

We investigate the photocarrier dynamics in bulk PdSe 2 , a layered transition metal dichalcogenide with a novel pentagonal structure and unique electronic and optical properties. Using femtosecond transient absorption microscopy, we study the behavior of photocarriers in mechanically exfoliated bulk PdSe 2 flakes at room temperature. By employing a 400 nm ultrafast laser pulse, electron–hole pairs are generated, and their dynamics are probed using an 800 nm detection pulse. Our findings reveal that the lifetime of photocarriers in bulk PdSe 2 is approximately 210 ps. Furthermore, by spatially resolving the differential reflection signal, we determine a photocarrier diffusion coefficient of about 7.3 cm 2 s –1 . Based on these results, we estimate a diffusion length of around 400 nm and a photocarrier mobility of approximately 300 cm 2 V –1 s –1 . Furthermore, these results shed light on the ultrafast optoelectronic properties of PdSe 2 , offer valuable insights into photocarriers in this emerging material, and enable design of high-performance optoelectronic devices based on PdSe 2 .

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Evolution of structure and spectroscopic properties of a new 1,3-diacetylpyrene polymorph with temperature and pressure

A new polymorph of 1,3-diacetylpyrene has been obtained from its melt and thoroughly characterized using single-crystal X-ray diffraction, steady-state UV–Vis spectroscopy and periodic density functional theory calculations. Experimental studies covered the temperature range from 90 to 390 K and the pressure range from atmospheric to 4.08 GPa. Optimal sample placement in a diamond anvil cell according to our previously presented methodology ensured over 80% data coverage up to 0.8 Å for a monoclinic sample. Unrestrained Hirshfeld atom refinement of the high-pressure crystal structures was successful and anharmonic behavior of carbonyl oxygen atoms was observed. Unlike the previously characterized polymorph, the structure of 2°AP-β is based on infinite π-stacks of antiparallel 2°AP molecules. 2°AP-β displays piezochromism and piezofluorochromism which are directly related to the variation in interplanar distances within the π-stacking. The importance of weak intermolecular interactions is reflected in the substantial negative thermal expansion coefficient of -55.8 (57) MK -1 in the direction of C—H∙∙∙O interactions.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Collective Energy Transport of Excitons in Two-dimensional Materials

Electronic thermal transport and thermoelectric measurements are pursued in this project to obtain unique insights into the unusual collective energy transport behaviors in two-dimensional (2D) heterostructures. Electronic thermal transport and thermoelectric measurements are essential techniques for characterizing bulk superconductors by probing the heat-carrying quasi-particles. Thermoelectric and electronic thermal transport measurements are expanded in this work beyond bulk systems to probe interactions among electrons, holes, and phonons in 2D heterostructures. In one experiment, a microbridge platform is advanced to demonstrate field-effect resistive-thermometry measurements of the electronic thermal conductivity of graphene heterostructures. Together with first principles theoretical calculations and analytical models, the experimental results suggest that tunable electron coupling with flexural phonons provides a knob to control quantum matters in graphene heterostructures with broken reflection symmetry. In another experiment, the Seebeck coefficient (S) is measured to probe interlayer interactions in electron-hole bilayers that are predicted to give rise to the emergence of a variety of correlated states. As a measure of the entropy, the measured S reveals the signature of electric injection of interlayer excitons in transition metal dichalcogenide (TMD) structures.

36 MATERIALS SCIENCE↗
NASA NTRS1972

Some new results on electron transport in the atmosphere

The penetration, diffusion and slowing down of electrons in a semi-infinite air medium has been studied by the Monte Carlo method. The results are applicable to the atmosphere at altitudes up to 300 km. Most of the results pertain to monoenergetic electron beams injected into the atmosphere at a height of 300 km, either vertically downwards or with a pitch-angle distribution isotropic over the downward hemisphere. Some results were also obtained for various initial pitch angles between 0 deg and 90 deg. Information has been generated concerning the following topics: (1) the backscattering of electrons from the atmosphere, expressed in terms of backscattering coefficients, angular distributions and energy spectra of reflected electrons, for incident energies T(o) between 2 keV and 2 MeV; (2) energy deposition by electrons as a function of the altitude, down to 80 km, for T(o) between 2 keV and 2 MeV; (3) the corresponding energy depostion by electron-produced bremsstrahlung, down to 30 km; (4) the evolution of the electron flux spectrum as function of the atmospheric depth, for T(o) between 2 keV and 20 keV. Energy deposition results are given for incident electron beams with exponential and power-exponential spectra.

Berger, M. J.↗
NASA NTRS1978

Stratospheric-related research using the shock tube

The capabilities of shock tubes used in stratospheric-related research are considered, and the results of three independent shock tube research projects are reported. The studies are concerned with the evaluation of stratospheric ozone depletion. In the first experiment, photoabsorption cross sections of Freon 11 and 12 at stratospheric temperatures were measured using rarefaction waves. In the second experiment, reaction-rate coefficients were determined from measurements made behind reflected shock waves. In the third experiment, electronic-transition moments of the O2 Schumann-Runge system and the A2Pi-X2Pi system of ClO were deduced from intensity measurements made behind the incident shock.

Cooper, D. M.↗
NASA NTRS1980

Radar estimation of slant path rain attenuation at frequencies above 10 GHz and comparisons with measured multi-season results

Techniques and results pertaining to estimating Earth satellite path rain attenuation events and statistics using radar at nonattenuating wavelengths are presented. The radar formulation and beam scanning methods are described and the procedure for relating the radar measured Rayleigh reflectivity to the high frequency Mie attenuation coefficient are given. Examples of radar derived single terminal statistics and estimation criteria as they relate to path angle and frequency are reviewed. Radar derived space diversity statistics and their dependence on terminal spacing and frequency are described. Site diversity performance curves obtained by radar and radiometry are compared with each other demonstrating the utility of radar methods. Results of a multi-year experiment to test, refine, and establish accuracies of radar methods for arriving at estimates of rain attenuation along an Earth-satellite path are discussed. Comparisons of measured and radar estimated fade events are presented and found to be good. Comparisons of cumulative fade distributions show agreement to be excellent giving an rms deviation of 1 dB.

Goldhirsh, J.↗
NASA NTRS1988

New acousto-ultrasonic techniques applied to aerospace materials

The use of an NdYAG pulsed laser for generating ultrasonic waves for NDE in resin matrix composites was investigated. A study was conducted of the use of the 1.064 micron wavelength NdYAG pulsed laser with the neat, unreinforced resin as well as graphite fiber/polymer composite specimens. In the case of the neat resins it was found that, at normal incidence, about 25 percent of the laser pulse energy was reflected at the incident surface. An attenuation coefficient for the polyimide resin, PMR-15 was determined to be approximately 5.8 np/cm. It was found in energy balance studies that graphite fiber/polymer specimens attenuate the laser beam more than do neat resins. The increase absorption is in the graphite fibers. The occurrence of laser induced surface damage was also studied. For the polymer neat resin, damage appears as pit formation over a small fraction of the pulse impact area and discoloration over a larger part of the area. A damage threshold was inferred from observed damage as a function of pulse energy. The 600 F cured PMR-15 and PMR-11 exhibit about the same amount of damage for a given laser pulse energy. The damage threshold is between 0.06 and 0.07 J/sq cm.

Kautz, Harold E.↗
NASA NTRS1993

An extended UTD analysis for the scattering and diffraction from cubic polynomial strips

Spline and polynomial type surfaces are commonly used in high frequency modeling of complex structures such as aircraft, ships, reflectors, etc. It is therefore of interest to develop an efficient and accurate solution to describe the scattered fields from such surfaces. An extended Uniform Geometrical Theory of Diffraction (UTD) solution for the scattering and diffraction from perfectly conducting cubic polynomial strips is derived and involves the incomplete Airy integrals as canonical functions. This new solution is universal in nature and can be used to effectively describe the scattered fields from flat, strictly concave or convex, and concave convex boundaries containing edges. The classic UTD solution fails to describe the more complicated field behavior associated with higher order phase catastrophes and therefore a new set of uniform reflection and first-order edge diffraction coefficients is derived. Also, an additional diffraction coefficient associated with a zero-curvature (inflection) point is presented. Higher order effects such as double edge diffraction, creeping waves, and whispering gallery modes are not examined. The extended UTD solution is independent of the scatterer size and also provides useful physical insight into the various scattering and diffraction processes. Its accuracy is confirmed via comparison with some reference moment method results.

Constantinides, E. D.↗
NASA NTRS2012

Extensive MRO CRISM Observations of 1.27 micron O2 Airglow in Mars Polar Night and Their Comparison to MRO MCS Temperature Profiles and LMD GCM Simulations

The Martian polar night distribution of 1.27 micron (0-0) band emission from O2 singlet delta [O2(1Delta(sub g))] is determined from an extensive set of Mars Reconnaissance Orbiter (MRO) Compact Reconnaissance Imaging Spectral Mapping (CRISM) limb scans observed over a wide range of Mars seasons, high latitudes, local times, and longitudes between 2009 and 2011. This polar nightglow reflects meridional transport and winter polar descent of atomic oxygen produced from CO2 photodissociation. A distinct peak in 1.27 micron nightglow appears prominently over 70-90NS latitudes at 40-60 km altitudes, as retrieved for over 100 vertical profiles of O2(1Delta(sub g)) 1.27 micron volume emission rates (VER). We also present the first detection of much (x80+/-20) weaker 1.58 micron (0-1) band emission from Mars O2(1Delta(sub g)). Co-located polar night CRISM O2(1Delta(sub g)) and Mars Climate Sounder (MCS) (McCleese et al., 2008) temperature profiles are compared to the same profiles as simulated by the Laboratoire de Météorologie Dynamique (LMD) general circulation/photochemical model (e.g., Lefèvre et al., 2004). Both standard and interactive aerosol LMD simulations (Madeleine et al., 2011a) underproduce CRISM O2(1Delta(sub g)) total emission rates by 40%, due to inadequate transport of atomic oxygen to the winter polar emission regions. Incorporation of interactive cloud radiative forcing on the global circulation leads to distinct but insufficient improvements in modeled polar O2(1Delta(sub g)) and temperatures. The observed and modeled anti-correlations between temperatures and 1.27 mm band VER reflect the temperature dependence of the rate coefficient for O2(1Delta(sub g)) formation, as provided in Roble (1995).

Atmosphere↗
NASA NTRS2016

Retrieval of Aerosol Optical Properties Using MERIS Observations: Algorithm and Some First Results

The MEdium Resolution Imaging Spectrometer (MERIS) instrument on board ESA Envisat made measurements from 2002 to 2012. Although MERIS was limited in spectral coverage, accurate Aerosol Optical Thickness (AOT) from MERIS data are retrieved by using appropriate additional information. We introduce a new AOT retrieval algorithm for MERIS over land surfaces, referred to as eXtensible Bremen AErosol Retrieval (XBAER). XBAER is similar to the dark-target (DT) retrieval algorithm used for Moderate-resolution Imaging Spectroradiometer (MODIS), in that it uses a lookup table (LUT) to match to satellite-observed reflectance and derive the AOT. Instead of a global parameterization of surface spectral reflectance, XBAER uses a set of spectral coefficients to prescribe surface properties. In this manner, XBAER is not limited to dark surfaces (vegetation) and retrieves AOT over bright surface (desert, semiarid, and urban areas). Preliminary validation of the MERIS-derived AOT and the ground-based Aerosol Robotic Network (AERONET) measurements yield good agreement, the resulting regression equation is y (0.92 x +/- 0.07) + (0.05 +/- 0.01) and Pearson correlation coefficient of R 0.78. Global monthly means of AOT have been compared from XBAER, MODIS and other satellite-derived datasets.

satellite retrievals↗
NASA NTRS2019

Spatiotemporal Monitoring of Hydrilla [Hydrilla verticillata (L. f.) Royle] to Aid Management Actions

Hydrilla is an invasive aquatic plant that has rapidly spread through many inland water bodies across the globe by outcompeting native aquatic plants. Drinking water supply, power generation, and recreational use of lakes are threatened by the spread of this invasive species. Moreover, hydrilla serves as a host for an epiphytic, toxic cyanobacteria known to be the causative agent of the neurodegenerative disease called avian vacuolar myelinopathy, which affects waterfowl, raptors, and amphibians. The early detection of hydrilla infestation is very important to reduce the costs associated with control and removal efforts of this invasive species. Therefore, this study was aimed at developing a rapid, frequent, and large-scale tool for monitoring and predicting spatial extent of hydrilla habitat. This was achieved by integrating in situ and Landsat 8 OLI satellite data for Lake J. Strom Thurmond, the largest US Army Corps of Engineers Lake east of the Mississippi River located on the Georgia/South Caroline border. The predictive model incorporated remote sensing reflectance, Secchi disk depth (SDD), light attenuation coefficient (Kd), maximum depth of colonization (Zc), and percentage of light available through water column (PLW). The model predicted ideal habitat for hydrilla featuring high SDD, low values of Kd, high Zc and PLW. Final analysis showed that hydrilla starts growing in April, reaches peak around October, begins retreating in the following months, and disappears in February. Additionally, physical meteorological factors were analyzed and were found to be closely associated with hydrilla extent. Management agencies can use these results to not only to plan future removal efforts, but also evaluate and adapt their current mitigation efforts.

Percentage of light available through the water co↗
NASA NTRS2022

Spectrally Simplified Approach for Leveraging Legacy Geostationary Oceanic Observations

The use of multispectral geostationary satellites to study aquatic ecosystems improves the temporal frequency of observations and mitigates cloud obstruction, but no operational capability presently exists for the coastal and inland waters of the United States. The Advanced Baseline Imager (ABI) on the current iteration of the Geostationary Operational Environmental Satellites, termed the R Series (GOES-R), however, provides sub-hourly imagery and the opportunity to overcome this deficit and to leverage a large repository of existing GOES-R aquatic observations. The fulfillment of this opportunity is assessed herein using a spectrally simplified, two-channel aquatic algorithm consistent with ABI wave bands to estimate the diffuse attenuation coefficient for photosynthetically available radiation, K(d)(PAR). First, an in situ ABI dataset was synthesized using a globally representative dataset of above- and in-water radiometric data products. Values of K(d)(PAR) were estimated by fitting the ratio of the shortest and longest visible wave bands from the in situ ABI dataset to coincident, in situ K(d)(PAR) data products. The algorithm was evaluated based on an iterative cross-validation analysis in which 80% of the dataset was randomly partitioned for fitting and the remaining 20% was used for validation. The iteration producing the median coefficient of determination (R2) value (0.88) resulted in a root mean square difference of 0.319 m−1, or 8.5% of the range in the validation dataset. Second, coincident mid-day images of central and southern California from ABI and from the Moderate Resolution Imaging Spectroradiometer (MODIS) were compared using Google Earth Engine (GEE). GEE default ABI reflectance values were adjusted based on a near infrared signal. Matchups between the ABI and MODIS imagery indicated similar spatial variability (R2 = 0.60) between ABI adjusted blue-to-red reflectance ratio values and MODIS default diffuse attenuation coefficient for spectral downward irradiance at 490 nm, K(d)(490), values. This work demonstrates that if an operational capability to provide- ABI aquatic data products was realized, the spectral configuration of ABI would potentially support a sub-hourly, visible aquatic data product that is applicable to water-mass tracing and physical oceanography research.

Advanced Baseline Imager↗
NASA NTRS1987

Crack diffusion coefficient - A candidate fracture toughness parameter for short fiber composites

In brittle matrix composites, crack propagation occurs along random trajectories reflecting the heterogeneous nature of the strength field. Considering the crack trajectory as a diffusive process, the 'crack diffusion coefficient' is introduced. From fatigue crack propagation experiments on a set of identical SEN polyester composite specimens, the variance of the crack tip position along the loading axis is found to be a linear function of the effective 'time'. The latter is taken as the effective crack length. The coefficient of proportionality between variance of the crack trajectory and the effective crack length defines the crack diffusion coefficient D which is found in the present study to be 0.165 mm. This parameter reflects the ability of the composite to deviate the crack from the energetically most efficient path and thus links fracture toughness to the microstructure.

Mull, M. A.↗
NASA NTRS1980

Visual evaluation of nystagmus intensity in points to diagnose vestibular dysfunction

The amplitude of nystagmus multiplied by its frequency gives a value commensurate to the velocity of slow phase. If the amplitude and the frequency during the visual observation are expressed in relative units (e.g., in points ranging from 1 to 3) the results of multiplication are used for a relative evaluation of nystagmus intensity. The relative evaluation of nystagmus intensity is used to compare the responses and, in particular, to calculate the coefficients of labyrinth asymmetry and of directional preponderance. A suggestion is made to analyze the formal results of caloric tests using a simple graphic model reflecting the left-right interactions by which the obtained coefficients are conditioned.

Levashov, M. M.↗
NASA NTRS1975

Effects of high energy simulated space radiation on polymeric second-surface mirrors

A radiation effects experimental program was performed, in which second surface mirror type thermal control coatings were exposed to ultraviolet radiation, electrons, and protons simultaneously. Stability was assessed by making periodic spectral reflectance measurements in situ (and in air after testing for comparison). Solar absorption coefficients were derived by computer. Many of the exposed materials showed large amounts of degradation in reflectance absorptance, principally due to the electron exposure. A series of tests was conducted, leading to the identification of a modified second surface mirror that shows considerable improvement and promise for stability during thermal control applications in a charged particle space radiation environment.

Eogdall, L. B.↗
NASA NTRS1999

Rate Coefficient Measurements of the Reaction CH3 + O2 = CH3O + O

Rate coefficients for the reaction CH3 + O2 = CH3O + O were measured behind reflected shock waves in a series of lean CH4-O2-Ar mixtures using hydroxyl and methyl radical diagnostics. The rate coefficients are well represented by an Arrhenius expression given as k = (1.60(sup +0.67, sub -0.47 ) x 10(exp 13) e(-15813 +/- 587 K/T)/cubic cm.mol.s. This expression, which is valid in the temperature range 1575-1822 K, supports the downward trend in the rate coefficients that has been reported in recent determinations. All measurements to date, including the present study, have been to some extent affected by secondary reactions. The complications due to secondary reactions, choice of thermochemical data, and shock-boundary layer interactions that affect the determination of the rate coefficients are examined.

Hwang, S. M.↗
NASA NTRS1999

Rate Coefficient Measurements of the Reaction CH3+O2+CH3O+O

Rate coefficients for the reaction CH3 + O2 = CH3O + O were measured behind reflected shock waves in a series of lean CH4-O2-Ar mixtures using hydroxyl and methyl radical diagnostics. The rate coefficients are well represented by an Arrhenius expression given as k = (1.60(sup +0.67, -0.47)) X 10(exp 13) exp(- 15813 +/- 587 K/T)cc/mol s. This expression, which is valid in the temperature range 1575-1822 K, supports the downward trend in the rate coefficients that has been reported in recent determinations. All measurements to date, including the present study, have been to some extent affected by secondary reactions. The complications due to secondary reactions, choice of thermochemical data, and shock-boundary layer interactions that affect the determination of the rate coefficients are examined.

Hwang, S. M.↗
NASA NTRS2021

Development and Validation of an Empirical Ocean Color Algorithm with Uncertainties: A Case Study with the Particulate Backscattering Coefficient

We explored how algorithm (model) and in situ measurement (observation) uncertainties can effectively be incorporated into empirical ocean color model development and assessment. In this study we focused on methods for deriving the particulate backscattering coefficient at 555 nm, b(bp)(555)/(m). We developed a simple empirical algorithm for deriving b(bp)(555) as a function of a remote sensing reflectance line height (LH) metric. Model training was performed using a high-quality bio-optical dataset that contains coincident in situ measurements of the spectral remote sensing reflectances, R(rs)(λ)/(sr), and the spectral particulate backscattering coefficients, b(bp)(λ). The LH metric used is defined as the magnitude of Rrs(555) relative to a linear baseline drawn between R(rs)(490) and R(rs)(670). Using an independent validation dataset, we compared the skill of the LH-based model with two other models. We used contemporary validation metrics, including bias and mean absolute error (MAE), that were corrected for model and observation uncertainties. The results demonstrated that measurement uncertainties do indeed impact contemporary validation metrics such as mean bias and MAE. Zeta-scores and z-tests for overlapping confidence intervals were also explored as potential methods for assessing model skill.

ocean color↗