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At least 523 records · Page 29

PAGEMS

Glenn Research Center has extensive instrumentation developed for measuring particulate and gaseous emissions. The Particulate and Gaseous Emissions Measurement System (PAGEMS) is a mobile facility housing advanced instrumentation used for measuring combustion particulates and gaseous species. Particulates sizes ranging from 10 nm to 10 mm can be measured along with SO2, NO, NO2, CO, CO2, THC and O2 . Measurements can be made from subatmospheric up to 60 atm. Representative data from two engine tests will be discussed. In one test, the fuel sulfur content was changed, while the other test (T-63 engine) used various fuel additives. Probe design is essential to acquiring accurate particulate data. I will discuss the AEDC designed particulate probe, and the results of a University of Minnesota calibration study using the probe. Another suite of instrumentation, a tunable diode laser (TDL), enables in-situ real time gaseous species measurements. Representative TDL data from a T-38 aircraft will be presented. In conclusion, near term measurement opportunities will be discussed.

Bulzan, Dan↗

Waste Water Treatment Apparatus and Methods

An improved draft tube spout fluid bed (DTSFB) mixing, handling, conveying, and treating apparatus and systems, and methods for operating are provided. The apparatus and systems can accept particulate material and pneumatically or hydraulically conveying the material to mix and/or treat the material. In addition to conveying apparatus, a collection and separation apparatus adapted to receive the conveyed particulate material is also provided. The collection apparatus may include an impaction plate against which the conveyed material is directed to improve mixing and/or treatment. The improved apparatus are characterized by means of controlling the operation of the pneumatic or hydraulic transfer to enhance the mixing and/or reacting by controlling the flow of fluids, for example, air, into and out of the apparatus. The disclosed apparatus may be used to mix particulate material, for example, mortar; react fluids with particulate material; coat particulate material, or simply convey particulate material.

Littman, Howard↗

Filter Efficiency and Leak Testing of Returned ISS Bacterial Filter Elements After 2.5 Years of Continuous Operation

The atmosphere revitalization equipment aboard the International Space Station (ISS) and future deep space exploration vehicles provides the vital functions of maintaining a habitable environment for the crew as well as protecting the hardware from fouling by suspended particulate matter. Providing these functions are challenging in pressurized spacecraft cabins because no outside air ventilation is possible and a larger particulate load is imposed on the filtration system due to lack of sedimentation in reduced gravity conditions. The ISS Environmental Control and Life Support (ECLS) system architecture in the U.S. Segment uses a distributed particulate filtration approach consisting of traditional High-Efficiency Particulate Adsorption (HEPA) filters deployed at multiple locations in each module. These filters are referred to as Bacteria Filter Elements (BFEs). As more experience has been gained with ISS operations, the BFE service life, which was initially one year, has been extended to two to five years, dependent on the location in the U.S. Segment. In previous work we developed a test facility and test protocol for leak testing the ISS BFEs. For this work, we present results of leak testing a sample set of returned BFEs with a service life of 2.5 years, along with particulate removal efficiency and pressure drop measurements. The results can potentially be utilized by the ISS Program to ascertain whether the present replacement interval can be maintained or extended to balance the on-ground filter inventory with extension of the lifetime of ISS to 2024. These results can also provide meaningful guidance for particulate filter designs under consideration for future deep space exploration missions.

ISS Air Quality↗

Life Support Filtration System Trade Study for Deep Space Missions

The National Aeronautics and Space Administrations (NASA) technical developments for highly reliable life support systems aim to maximize the viability of long duration deep space missions. Among the life support system functions, airborne particulate matter filtration is a significant driver of launch mass because of the large geometry required to provide adequate filtration performance and because of the number of replacement filters needed to a sustain a mission. A trade analysis incorporating various launch, operational and maintenance parameters was conducted to investigate the trade-offs between the various particulate matter filtration configurations. In addition to typical launch parameters such as mass, volume and power, the amount of crew time dedicated to system maintenance becomes an increasingly crucial factor for long duration missions. The trade analysis evaluated these parameters for conventional particulate matter filtration technologies and a new multi-stage particulate matter filtration system under development by NASAs Glenn Research Center. The multi-stage filtration system features modular components that allow for physical configuration flexibility. Specifically, the filtration system components can be configured in distributed, centralized, and hybrid physical layouts that can result in considerable mass savings compared to conventional particulate matter filtration technologies. The trade analysis results are presented and implications for future transit and surface missions are discussed.

particulate matter filtration↗

Our contaminated atmosphere: The danger of climate change, phases 1 and 2

The effects of increased concentrations of atmospheric particulate matter on average surface temperature and on the components of the earth's radiation budget are studied. An atmospheric model which couples particulate loading to surface temperature and to changes in the earth's radiation budget was used. A determination of the feasibility of using satellites to monitor the effect of increased atmospheric particulate concentrations is performed. It was found that: (1) a change in man-made particulate loading of a factor of 4 is sufficient to initiate an ice age; (2) variations in the global and hemispheric weighted averages of surface temperature, reflected radiant fluz and emitted radiant flux are nonlinear functions of particulate loading; and (3) a black satellite sphere meets the requirement of night time measurement sensitivity, but not the required day time sensitivity. A nonblack, spherical radiometer whose external optical properties are sensitive to either the reflected radiant fluz or the emitted radiant flux meets the observational sensitivity requirements.

Cimorelli, A. J.↗

Distributions of Trace Gases and Aerosols during the Dry Biomass Burning Season in Southern Africa

Vertical profiles in the lower troposphere of temperature, relative humidity, sulfur dioxide (SO2), ozone (O3), condensation nuclei (CN), and carbon monoxide (CO), and horizontal distributions of twenty gaseous and particulate species, are presented for five regions of southern Africa during the dry biomass burning season of 2000. The regions are the semiarid savannas of northeast South Africa and northern Botswana, the savanna-forest mosaic of coastal Mozambique, the humid savanna of southern Zambia, and the desert of western Namibia. The highest average concentrations of carbon dioxide (CO2), CO, methane (CH4), O3, black particulate carbon, and total particulate carbon were in the Botswana and Zambia sectors (388 and 392 ppmv, 369 and 453 ppbv, 1753 and 1758 ppbv, 79 and 88 ppbv, 2.6 and 5.5 micrograms /cubic meter and 13.2 and 14.3 micrograms/cubic meter). This was due to intense biomass burning in Zambia and surrounding regions. The South Africa sector had the highest average concentrations of SO2, sulfate particles, and CN (5.1 ppbv, 8.3 micrograms/cubic meter, and per 6400 cubic meter , respectively), which derived from biomass burning and electric generation plants and mining operations within this sector. Air quality in the Mozambique sector was similar to the neighboring South Africa sector. Over the arid Namibia sector there were polluted layers aloft, in which average SO2, O3, and CO mixing ratios (1.2 ppbv, 76 ppbv, and 3 10 ppbv, respectively) were similar to those measured over the other more polluted sectors. This was due to transport of biomass smoke from regions of widespread savanna burning in southern Angola. Average concentrations over all sectors of CO2 (386 +/- 8 ppmv), CO (261 +/- 81 ppbv), SO2 (2.5 +/- 1.6 ppbv), O3 (64 +/- 13 ppbv), black particulate carbon (2.3 +/- 1.9 microgram/cubic meter), organic particulate carbon (6.2 +/- 5.2 microgram/cubic meter), total particle mass (26.0 +/- 4.7 microgram/cubic meter), and potassium particles (0.4 +- 0.1 microgram/cubic meter) were comparable to those in polluted, urban air. Since the majority of the measurements in this study were obtained in locations well removed from industrial sources of pollution, the high average concentrations of pollutants reflect the effects of widespread biomass burning. On occasions, relatively thin (-0.5 km) layers of remarkably clean air were located at -3 km above mean sea level, sandwiched between heavily polluted air. The data presented here can be used for inputs to and validation of regional and global atmospheric chemical models.

Sinha, Parikhit↗

Remote Sensing Reflectance and Inherent Optical Properties in the Mid-mesohaline Chesapeake Bay

We used an extensive set of bio-optical data and radiative transfer (RT) model simulations of radiation fields to investigate relationships between inherent optical properties and remotely sensed quantities in the optically complex, mid-mesohaline Chesapeake Bay waters. Field observations showed that the chlorophyll algorithms used by the MODIS (MODerate resolution Imaging Spectroradiometer) ocean color sensor (i.e. Chlor_a, chlor_MODIS, chlor_a_3 products) do not perform accurately in these Case 2 waters. This is because, when applied to waters with high concentrations of chlorophyll, all MODIS algorithms are based on empirical relationships between chlorophyll concentration and blue-green wavelength remote sensing reflectance (Rrs) ratios that do not account for the typically strong blue-wavelength absorption by non-covarying, dissolved and non-algal particulate components. Stronger correlation was observed between chlorophyll concentration and Rrs ratios in the red (i.e. Rrs(677)/Rrs(554)) where dissolved and non-algal particulate absorption become exponentially smaller. Regionally-specific algorithms that are based on the phytoplankton optical properties in the red wavelength region provide a better basis for satellite monitoring of phytoplankton blooms in these Case 2 waters. Good optical closure was obtained between independently measured Rrs spectra and the optical properties of backscattering, b(sub b), and absorption, a, over the wide range of in-water conditions observed in the Chesapeake Bay. Observed variability in the quantity f/Q (proportionality factor in the relationship between Rrs and the water inherent optical properties ratio b(sub b)/(a+b(sub b)) was consistent with RT model calculations for the specific measurement geometry and water bio-optical characteristics. Data and model results showed that f/Q values in these Case 2 coastal waters are not considerably different from those estimated in previous studies for Case 1 waters. Variation in surface backscattering significantly affected Rrs magnitude across the visible spectrum and was most strongly correlated (R(sup 2)=0.88) with observed variability in Rrs at 670 nm. Surface values of particulate backscattering were strongly correlated with non-algal particulate absorption, a(sub nap), in the blue wavelengths (R(sup 2)=0.83). These results, along with the measured values of backscattering fraction magnitude and non-algal particulate absorption spectral slope, suggest that suspended non-algal particles with high inorganic content are the major water constituents regulating b(sub b) variability in the mid-mesohaline Chesapeake Bay. Remote retrieval of surface b(sub b) and (a(sub nap), from Rrs(670) can be used in regionally-specific satellite algorithms to separate contribution by non-algal particles and dissolved organic matter to total light absorption in the blue, and monitor non-algal suspended particle concentration and distribution in these Case 2 waters.

Tzortziou, Maria↗

Methods for providing ceramic matrix composite components with increased thermal capacity

A method for enhancing the cooling capability of a turbine component made from a ceramic matrix composite. The method improves the thermal performance of the component by producing a surface having increased cooling capacity, thereby allowing the component to operate at a higher temperature. The method tailors the available surface area on the cooling surface of the composite component by depositing a particulate layer of coarse grained ceramic powders of preselected size onto the surface of the ceramic matrix composite component. The size of the particulate is selectively tailored to match the desired surface finish or surface roughness of the article. The article may be designed to have different surface finishes for different locations, so that the application of different sized powders can provide different cooling capabilities at different locations, if desired. The compositions of the particulates are chemically compatible with the ceramic material comprising the outer surface or portion of the ceramic matrix composite. The particulates are applied using a slurry and incorporated into the article by heating to an elevated temperature without melting the matrix, the particulates or the fiber reinforcement.

Steibel, James Dale↗

International Space Station (ISS) Bacterial Filter Elements (BFEs): Filter Efficiency and Pressure Testing of Returned Units

The air revitalization system aboard the International Space Station (ISS) provides the vital function of maintaining a clean cabin environment for the crew and the hardware. This becomes a serious challenge in pressurized space compartments since no outside air ventilation is possible, and a larger particulate load is imposed on the filtration system due to lack of sedimentation due to the microgravity environment in Low Earth Orbit (LEO). The ISS Environmental Control and Life Support (ECLS) system architecture in the U.S. Segment uses a distributed particulate filtration approach consisting of traditional High-Efficiency Particulate Adsorption (HEPA) media filters deployed at multiple locations in each U.S. Segment module; these filters are referred to as Bacterial Filter Elements, or BFEs. These filters see a replacement interval, as part of maintenance, of 2-5 years dependent on location in the ISS. In this work, we present particulate removal efficiency, pressure drop, and leak test results for a sample set of 8 BFEs returned from the ISS after filter replacement. The results can potentially be utilized by the ISS Program to ascertain whether the present replacement interval can be maintained or extended to balance the on-ground filter inventory with extension of the lifetime of ISS beyond 2024. These results can also provide meaningful guidance for particulate filter designs under consideration for future deep space exploration missions.

Filtration↗

Studies of the inner shelf and coastal sedimentation environment of the Beaufort Sea from ERTS-1

The author has identified the following significant results. The particulate transport processes involved in the movement of surficial waters were examined using secchi disc readings, light attenuation coefficients, and particulate weights from filtration. Observations gathered during the summers of 1971 and 1972 indicate a remarkable difference in particulate matter and turbidity between the two years. ERTS-1 imagery during August 1972 showed turbid water along the northern Alaska coast. The uniformity of distribution of the turbid water and the fact that the river discharge is low at this period suggest that the turbidity is related to causes other than river effluent. Studies indicate that wave action is a more significant factor influencing particulate transport than believed heretofore. The boundary between the essentially immobile shorefast ice and the moving pack ice has been plotted from several ERTS-1 images and found to occur fairly consistently along the 20 meter contour. Considering the vast difference in the amount of ice movement shoreward and seaward of this boundary, ice-bottom action should also be different on either side of this boundary and for that matter at the shear zone that develops along the boundary.

Reimnitz, E.↗

CARETS: A prototype regional environmental information system. Volume 7: Land use information and air quality planning

The pilot national land use information system developed by the U.S. Geological Survey in the Central Atlantic Regional Ecological Test Site project has provided an improved technique for estimating emissions, diffusion, and impact patterns of sulfur dioxide (S0 2 ) and particulate matter. Implementation of plans to control air quality requires land use information, which, until this time, has been inadequate. The pilot system, however, provided data for updating information on the sources of point and area emissions of S0 2 and particulate matter affecting the Norfolk--Portsmouth area of Virginia for the 1971-72 winter (Dec.-Jan.-Feb.) and the annual 1972 period, and for a future annual period--1985. This emission information is used as input to the Air Quality Display Model of the Environmental Protection Agency to obtain diffusion and impact patterns for the three periods previously mentioned. The results are: (1) During the 1971-72 winter, estimated SO 2 amounts over an area with a SW-NE-axis in the central section of Norfolk exceeded both primary and secondary levels; (2) future annual levels of SO 2 , estimated by anticipated residential development and point-source changes, are not expected to cause serious deterioration of the region's present air quality; and (3) for the 1971-72 winter and annual 1972 period the diffusion results showed that both primary and secondary standards for particulate matter are regularly exceeded in central Norfolk and Portsmouth. In additions on the bas is of current control programs, the 1985 levels of particulate matter are expected to exceed the presently established secondary air quality standards throughout central Norfolk and Portsmouth and in certain areas of Virginia Beach. The land use information can be used to estimate emissions for inputs to diffusion models and to interpret the implications of diffusion patterns for: (1) Implementing various control strategies (2) selecting sites of air sampling stations, and (3) predicting the effects that proposed changes in land use might have on emission patterns and air quality.

Remote sensing↗

Analysis of suspended solids by single-particle scattering

Light scattering by individual particulates is used in a multiple-detector system to categorize the composition of suspended solids in terms of broad particulate categories. The scattering signatures of red clay and taconite tailings, the two primary particulate contaminants in western Lake Superior, along with two types of asbestiform fibers, amphibole and chrysolite, were studied in detail. A method was developed to predict the concentration of asbestiform fibers in filtration plant samples for which electron microscope analysis was done concurrently. Fiber levels as low as 50,000 fibers/liter were optically detectable. The method has application in optical categorization of samples for remote sensing purposes and offers a fast, inexpensive means for analyzing water samples from filtration plants for specific particulate contaminants.

Diehl, S. R.↗

Fuel economy and exhaust emissions characteristics of diesel vehicles: Test results of a prototype Fiat 131 NA 2.4 liter automobile

The vehicle was tested on a chassis dynamometer over selected drive cycles and steady-state conditions. Two fuels were used, a U.S. no. 2 diesel and a European diesel fuel. The vehicle was tested with retarded timing and with and without an oxidation catalyst. Particulate emission rates were calculated from dilution tunnel measurements and large volume particulate samples were collected for biological and chemical analysis. It was determined that while the catalyst was generally effective in reducing hydrocarbon and carbon monoxide levels, it was also a factor in increasing particulate emissions. Increased particulate emission rates were particularly evident when the vehicle was operated on the European fuel which has a high sulfur content.

Quayle, S. S.↗

Aspects of the mechanisms of smoke generation by burning materials

An investigation of smoke generation during the burning of natural and synthetic solid materials (relevant to fire safety problems), under simulated fire conditions, is presented. Smoke formation mechanisms, including flaming and nonflaming combustion, are reviewed, and the complex physical, chemical, and electrical processes, important in smoke particulate production, are identified. With reference to the smoke formation mechanisms, measured experimental data are discussed, and include effects of ventilation gas temperature, dependence on material composition, and chemical analysis of smoke particulates. Significant differences in smoke characteristics are observed between flaming and nonflaming conditions, which is attributed to specific differences in controlling mechanisms and resultant ways leading to particulate formation. The effects of polymer substrate properties and effects of additives for a given substrate on smoke properties are also discussed in terms of basic processes. It is shown that many of the measured trends can be interpreted by considering postulated mechanisms of particulate formation.

Bankston, C. P.↗

Concentration of hydrocarbons associated with particles in the shelf waters adjacent to the entrance of Chesapeake Bay

Particulate hydrocarbon concentrations were measured in 94 water samples. The concentrations ranged from below the detection limit ( 0.7 micro-G/L) to 32 micro-g/l. The mean for all samples was 5.6 micro-g/l. Particulate hydrocarbon concentrations are higher in the Bay mouth and lower in the shelf waters adjacent to the entrance of Chesapeake Bay. No coherent particulate hydrocarbon distribution is seen with depth in the water column. The Bay is postulated as one of the possible chronic sources of particulate hydrocarbons for the adjacent shelf waters.

Wade, T. L.↗

Fumigation of Alcohol in a Light Duty Automotive Diesel Engine

A light-duty automotive Diesel engine was fumigated with methanol in amounts up to 35% and 50% of the total fuel energy respectively in order to determine the effect of alcohol fumigation on engine performance at various operating conditons. Engine fuel efficiency, emissions, smoke, and the occurrence of severe knock were the parameters used to evaluate performance. Raw exhaust particulate and its soluble organic extract were screened for biological activity using the Ames Salmonella typhimurium assay. Results are given for a test matrix made up of twelve steady-state operating conditions. For all conditions except the 1/4 rack (light load) condition, modest thermal efficiency gains were noted upon ethanol fumigation. Methanol showed the same increase at 3/4 and full rack (high load) conditions. However, engine roughness or the occurrence of severe knock limited the maximum amount of alcohol that could be fumigated. Brake specific nitrogen oxide concentrations were found to decrease for all ethanol conditions tested. Oxides of nitrogen emissions, on a volume basis, decreased for all alcohol conditions tested. Based on the limited particulate data analyzed, it appears that ethanol fumigation, like methanol fumigation, while lowering the mass of particulated emitted, does enhance the biological activity of that particulate.

Broukhiyan, E. M. H.↗

Aluminum chloride formation on Space Shuttle aluminum oxide

Samples of particulates collected from the exhaust of Space Shuttle launches STS-1, -4, -5, -6, and -7 were analyzed. Scanning electron microscopy and X-ray diffractometry of these samples indicated that the particulates were spherical and predominantly composed of aluminum oxide. The water-soluble weight fraction, pH, acid-soluble weight fraction, and insoluble weight fraction were determined for each sample. Water-soluble weight fractions averaged about 7 percent of the total sample weight, were generally very acidic, and contained significantly elevated concentrations of chloride and aluminum (III) ion. The high concentrations of soluble aluminum (III) and chloride ions observed suggested that aluminum chlorides and/or oxychlorides had formed on the surface of the alumina particulates. More than 72 percent by weight of each sample was insoluble in either water or strong mineral acid, and was identified as alpha-Al2O3. The results from these analyses suggest that the surface of Space Shuttle exhaust alumina particulates will be highly acidic and heavily chlorided, and that a substantial amount of the surface chloride may be chemically associated with aluminum (III) ions rather than just physically adsorbed as HCl.

Cofer, W. R., III↗

Evaluation of several micromechanics models for discontinuously reinforced metal matrix composites

A systematic experimental evaluation of whisker and particulate reinforced aluminum matrix composites was conducted to assess the variation in tensile properties with reinforcement type, volume fraction, and specimen thickness. Each material was evaluated in three thicknesses, 1.8, 3.18, and 6.35 mm, to determine the size, distribution, and orientation of the reinforcements. This information was used to evaluate several micromechanical models that predict composite moduli. The longitudinal and transverse moduli were predicted for reinforced aluminum. The Paul model, the Cox model and the Halpin-Tsai model were evaluated. The Paul model gave a good upper bound prediction for the particulate reinforced composites but under predicted whisker reinforced composite moduli. The Cox model gave good moduli predictions for the whisker reinforcement, but was too low for the particulate. The Halpin-Tsai model gave good results for both whisker and particulate reinforced composites. An approach using a trigonometric projection of whisker length to predict the fiber contribution to the modulus in the longitudinal and transverse directions was compared to the more conventional lamination theory approach.

Johnson, W. Steven↗