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At least 523 records · Page 29

Formulation/cure technology for ultrahigh molecular weight silphenylene-siloxane polymers

Molecular weights above one million were achieved for methylvinylsilphenylene-siloxane terpolymers using a two-stage polymerization technique which was successfully scaled up to 200 grams. The resulting polymer was vulcanized by two different formulations and compared to an identically formulated commercial methylvinyl silicone on the basis of ultimate strength, Young's modulus, percent elongation at failure, and tear strength. Relative thermal/oxidative stabilities of the elastomers were assessed by gradient and isothermal thermogravimetric analyses performed in both air and nitrogen. The experimental elastomer exhibited enhanced thermal/oxidative stability and possed equivalent or superior mechanical properties. The effect of variations in prepolymer molecular weight on mechanical properties was also investigated.

Hundley, N. H.↗

Oscillation Damper With Two Spring Rates

Hydraulic damping used in device developed to stabilize vibrating structure in space. Damping mechanism stops oscillation of attached boom. Two bellows provide fluid damping. Springs are engaged when extra spring force required. Otherwise they retract. Mechanism especially useful for arresting oscillatory motion of slender boom with large mass. On Earth, such configurations arise in design of masts and cranes.

Sevilla, D. R.↗

Properties and potential applications of brominated P-100 carbon fibers

A review of the properties and potential applications of bromine-intercalated pitch-based carbon fibers is presented. The dynamics of the intercalation reaction are summarized, and characteristics, such as resistivity, density, and stability, are discussed. In addition, the mechanical and electrical properties of bromine-intercalated fiber-epoxy conposites will be addressed. With conductivities comparable to stainless steel, these brominated carbon fibers may be used in a number of composite applications, such as electromagnetic interference shielding containers, large conductive space structures, lightning strike-tolerant aircraft surfaces, and aircraft deicing applications.

Jaworske, D. A.↗

An innovative exercise method to simulate orbital EVA work - Applications to PLSS automatic controls

An exercise method has been proposed which may satisfy the current need for a laboratory simulation representative of muscular, cardiovascular, respiratory, and thermoregulatory responses to work during orbital extravehicular activity (EVA). The simulation incorporates arm crank ergometry with a unique body support mechanism that allows all body position stabilization forces to be reacted at the feet. By instituting this exercise method in laboratory experimentation, an advanced portable life support system (PLSS) thermoregulatory control system can be designed to more accurately reflect the specific work requirements of orbital EVA.

Lantz, Renee↗

Gravitational contributions to microstructural coarsening in liquid phase sintering

Preliminary experiments for determining the role of gravity in liquid phase sintering have been carried out. Tungsten heavy alloys were selected for this investigation because of the large density difference between solid and liquid, extensive interest in the alloys and considerable data on these alloys. By identifying and isolating the role that gravity plays in shape distortion and microstructural coarsening, further insight into the mechanisms of coarsening kinetics may be realized. Improvements in mechanical properties, shape complexity, and dimensional stability may be realized in the future from low gravity sintering.

Kipphut, C. M.↗

Gravity and configurational energy induced microstructural changes in liquid phase sintering

Experiments were performed with W-Ni-Fe heavy alloys in order to measure the microstructural changes vs. position that occur in liquid-phase sintering under normal gravity. The experimentally observed segregation is less than the calculated equilibrium segregation due to the retarding effect from the rigid solid skeleton formed during sintering. These results improve understanding of microstructure, mechanical properties, component shape, and dimensional stability benefits that may be realized from low-gravity sintering.

Kipphut, C. M.↗

Chemistry of the CO dimer at low temperatures

Researchers conducted a series of experiments on the chlorine-catalyzed photodecomposition of O sub 3 both in the gas and in inert solvents such as CF sub 4 and CO sub 2 in the temperature range about 190 to 225 K. The liquid medium was chosen in order to minimize possible surface loss of long-lived ClO dimer, and to aid in the stabilization of transient excited intermediates. The mechanism of dimer formation was as follows: (1) Cl sub 2 + hv yields Cl + Cl; (2) Cl + O sub 3 yields ClO + O sub 2; (3) ClO + ClO yields Cl sub 2 O sub 2. The experiments were done in cooled low temperature cells, with irradiation from an Osram high pressure mercury arc, filtered to remove radiation below 325 nm. Spectral analysis was by means of a Cary Model 2200 UV spectrometer. The principal objectives were: (1) to determine the lifetime of the dimer as a function of temperature; (2) to observe spectral changes in the mixtures which could be attributed to dimer or related products; and (3) to observe chemical or photochemical reactions of the dimer.

Demore, W. B.↗

Oscillating aerodynamics and flutter of an aerodynamically detuned cascade in an incompressible flow

A mathematical model is developed and utilized to demonstrate the enhanced torsion mode stability associated with alternate blade circumferential aerodynamic detuning of a rotor operating in an incompressible flow field. The oscillating cascade aerodynamics, including steady loading effects, are determined by developing a complete first order unsteady aerodynamic analysis. An unsteady aerodynamic influence coefficient technique is then utilized, thereby enabling the stability of both conventional uniformly spaced rotors and detuned nonuniform circumferentially spaced rotors to be determined. To demonstrate the enhanced flutter aeroelastic stability associated with this aerodynamic detuning mechanism, this model is applied to a baseline unstable rotor with a Gostelow flow geometry.

Chiang, Hsiao-Wei D.↗

Emerging polyheterocyclic films, coatings and resins - Thermoplastic polyquinolines

The processing and performance characteristics of a soluble, thermoplastic polyquinoline suggest its utility in a variety of high performance applications. The polymer is characterized by excellent thermal and oxidative stability, very low moisture absorption, good mechanical properties, very low dielectric constant, and an unusually low thermal expansion coefficient. This polymer, designated PQ-100 (TM), can be cast into strong, transparent, free standing films from common solvents. Coatings of variable thickness can be spin-coated on to silicon and other surfaces. After processing into films, PQ-100 (TM) can be rendered insoluble in a wide range of solvents using a proprietary process. The low CTE contributes to very low residual stress when the polymer is spin-coated onto silicon wafers. PQ-100 (TM) is currently under evaluation for use as an interlayer dielectric substrate in high-density interconnect applications, including multichip modules. Many of the characteristics of the polymer also suggest its utility as a high-performance film and as a matrix resin for specialty composite applications.

Hendricks, Neil H.↗

Use of rotation to suppress thermosolutal convection in directionally solidified binary alloys

Effects of rotation on onset of convection during plane-front directional solidification of Pb-Sn and the pseudobinary system mercury cadmium telluride (Hg(1-x)Cd(x)Te), and on dendritic solidification of Pb-Sn have been studied by means of linear stability analysis. Incorporating Coriolis and centrifugal accelerations into the momentum equation of Coriell et al., we find that under realistic processing conditions, a large degree of stabilization can be achieved using modest rotation rates for both Pb-Sn and mercury cadmium telluride. At a growth velocity of 5 micron/sec and nominal liquid-side temperature gradient of 200 K/cm in Pb-Sn, rotation at 500 rpm results in a hundredfold increase in the critical Sn concentration. Large increases in the maximum allowable growth velocity at fixed melt composition are also attainable with modest rotation rates. The effect is amplified under conditions of reduced gravitational acceleration. For Hg(1-x)Cd(x)Te, we have also studied the nonrotating case. The key differences are due to the existence of a composition range for Hg(1-x)Cd(x)Te in which the melt density has a local maximum as a function of temperature. When the melt solidifies by cooling from below, the liquid density may initially increase with distance above the interface, before ultimately decreasing as the melt temperature increases above the value at which the local density maximum occurs. In contrast to the Pb-Sn case where density depends monotonically on temperature and composition, for Hg(1-x)Cd(x)Te there exists a critical value of the growth velocity above which plane-front solidification is unstable for all bulk CdTe mole fractions. Again, rotation leads to significant inhibition of onset. We identify the predicted stabilization with the Taylor-Proudman mechanism by which rotation inhibits thermal convection in a single-component fluid heated from below. In a binary liquid undergoing solidification, rotation inhibits the onset of buoyancy-driven convection, and has no effect on the short-wavelength morphological instability. At large growth velocities, the plane-front interface between liquid and solid becomes unstable with respect to a morphological instability and solidification occurs dendritically, with a mushy zone of dendrites and interdendritic fluid separating the solid from the melt. For the Pb-Sn system, rotation substantially suppresses the onset of convection in the mushy zone and in the overlying liquid, holding open the promise that rotation can suppress freckling and other macrosegregation defects.

Pearlstein, Arne J.↗

Raman and Photoluminescence Spectroscopy of Er(3+) Doped Heavy Metal Oxide Glasses

The potential applications of rare-earth ion doped materials include fiber lasers which can be pumped conveniently by infrared semiconductor laser diodes. The host material systems most widely studied are fluoride crystals and glasses because fluorides have low nonradiative relaxation rates due to their lower phonon energies. However, the mechanical strength, chemical durability and temperature stability of the oxide glasses are generally much better than fluoride glasses. The objective of this research was to investigate the optical and spectroscopic properties of Er(3+)-doped lead-germanate and lead-tellurium-germanate glasses. The maximum vibrational energy of lead-tellurium-germanate glasses are in the range of 740-820/cm, intermediate between those of silicate (1150/cm) and fluoride (530/cm) glasses.

Dyer, Keith↗

A Review of Scientific and Technological Results from the TSS-1R Mission

The Tethered Satellite System (TSS) program was designed to provide a unique opportunity to explore certain space plasma-electrodynamic processes and the orbital mechanics of a gravity-gradient stabilized system of two satellites linked by a long conducting tether. A unique data set was obtained during deployment which has allowed significant science to be accomplished. This paper focuses on results from the TSS-1R mission that are most important to the future technological applications of electrodynamic tethers in space, in particular, the current collection process. Of particular significance is an apparent transition of the physics of current collection when the potential of the collecting body becomes greater than the ram energy of the ionospheric atomic oxygen ions. Previous theoretical models of current collection were electrostatic, assuming that the orbital motion of the system, which is highly subsonic with respect to electron thermal motion, was unimportant. This may still be acceptable for the case of relatively slow-moving sounding rockets. However, the TSS-1R results show that motion relative to the plasma must be accounted for in orbiting systems.

Stone, N. H.↗

The Tethered Satellite System: Scientific and Technological Results

The bi-national, US-Italian, Tethered Satellite System (TSS) program was designed to provide a unique opportunity to explore certain space plasma- electrodynamic processes and the orbital mechanics of a gravity-gradient stabilized system of two satellites linked by a long conducting tether. The second flight, TSS-LR, was launched February 22, 1996 on STS-75 and satellite deployment began at MET 3/00:27. A unique data set was obtained over the next five hours as the tether was deployed to a length of 19695 meters, which has allowed significant science to be accomplished. This presentation will focus on results from the TSS-LR mission that are most important to the future technological applications of electrodynamic tethers in space - in particular, the current collection process. Of particular significance is an apparent transition of the physics of current collection when the potential of the collecting body becomes greater than the ram energy of the ionospheric atomic oxygen ions. Previous theoretical models of current collection were electro- static - assuming that the orbital motion of the system, which is highly sub-sonic with respect to electron thermal motion, was unimportant. This may still be acceptable for the case of relatively slow-moving sounding rockets. However, the TSS-LR results show that motion relative to the plasma must be accounted for in orbiting systems.

Stone, Nobie H.↗

The TSS-1R Electrodynamic Tether Experiment: Scientific and Technological Results

The Tethered Satellite System (TSS) program was designed to provide the opportunity to explore certain space plasma-electrodynamic processes (associated with high-voltage bodies and electrical currents in space) and the orbital mechanics of a gravity-gradient stabilized system of two satellites linked by a long conducting tether. A unique data set was obtained during the TSS-1 R mission in which the tether emf and current reached values in excess of 3500 volts and 1 amp, respectively. The insight this has allowed into the current collection process and the physics of high-voltage plasma sheaths is significant. Previous theoretical models of current collection were electro-static assuming that the orbital motion of the system, which is highly sub-sonic with respect to electron thermal motion, was unimportant. This may still be acceptable for the case of relatively slow-moving sounding rockets. However, the TSS-1 R results show that motion relative to the plasma does affect current collection and must be accounted for in orbiting systems.

Stone, Nobie H.↗

The TSS-1R Electrodynamic Tether Experiment: Scientific and Technological Results

The bi-national, US-Italian, Tethered Satellite System (TSS) program was designed to provide a unique opportunity to explore certain space plasma- electrodynamic processes and the orbital mechanics of a gravity-gradient stabilized system of two satellites linked by a long conducting tether. The second flight, TSS-LR, was launched February 22, 1996 on STS-75 and satellite deployment began at MET 3/00:27. A unique data set was obtained over the next five hours, as the tether was deployed to a length of 19695 meters, which has allowed significant science to be accomplished. This presentation will focus on electrodynamic processes generated by the tether--in particular, the collection of electrical current from the ionospheric plasma. Of particular significance is an apparent transition of the physics of current collection when the potential of the collecting body becomes greater than the ram energy of the ionospheric atomic oxygen ions. Previous theoretical models of current collection were electrostatic--assuming that the orbital motion of the system, which is highly subsonic with respect to electron thermal motion, was un- important. This may still be acceptable for the case of relatively slow-moving sounding rockets. However, the TSS-LR results show that motion relative to the plasma must be accounted for in orbiting systems.

Stone, Nobie H.↗

Magnetic Liquids

Ferrofluidics Corporation's recent innovation is a spindle for rotating computer discs that supports the disc's rotating shaft on a film of magnetic fluid instead of conventional ball bearings. According to its developers, the spindle offers greatly increased rotational stability, meaning substantially reduced vibration and mechanical noise, and non- repeatable runout. This allows disc drives to store two to 10 times more information.

Source record↗

Dispersion of Single Wall Carbon Nanotubes by in situ Polymerization Under Sonication

Single wall nanotube reinforced polyimide nanocomposites were synthesized by in situ polymerization of monomers of interest in the presence of sonication. This process enabled uniform dispersion of single wall carbon nanotube (SWNT) bundles in the polymer matrix. The resultant SWNT-polyimide nanocomposite films were electrically conductive (antistatic) and optically transparent with significant conductivity enhancement (10 orders of magnitude) at a very low loading (0.1 vol%). Mechanical properties as well as thermal stability were also improved with the incorporation of the SWNT.

Park, Cheol↗

Effects of silver ions (Ag+) on contractile ring function and microtubule dynamics during first cleavage in Ilyanassa obsoleta

The terminal phase of cell division involves tight constriction of the cleavage furrow contractile ring, stabilization/elongation of the intercellular bridge, and final separation of the daughter cells. At first cleavage, the fertilized eggs of the mollusk, Ilyanassa obsoleta, form two contractile rings at right angles to each other in the same cytoplasm that constrict to tight necks and partition the egg into a trefoil shape. The cleavage furrow contractile ring (CF) normally constricts around many midbody microtubules (MTs) and results in cleavage; the polar lobe constriction contractile ring (PLC) normally constricts around very few MTs and subsequently relaxes without cleavage. In the presence of Ag+ ions, the PLC 1) begins MT-dependent rapid constriction sooner than controls, 2) encircles more MTs than control egg PLCs, 3) elongates much more than control PLCs, and 4) remains tightly constricted and effectively cleaves the polar lobe from the egg. If Ag(+)-incubated eggs are returned to normal seawater at trefoil, tubulin fluorescence disappears from the PLC neck and the neck relaxes. If nocodazole, a drug that depolymerizes MTs, is added to Ag(+)-incubated eggs during early PLC constriction, the PLC is not stabilized and eventually relaxes. However, if nocodazole is added to Ag(+)-incubated eggs at trefoil, tubulin fluorescence disappears from the PLC neck but the neck remains constricted. These results suggest that Ag+ accelerates and gradually stabilizes the PLC constriction by a mechanism that is initially MT-dependent, but that progressively becomes MT-independent.

Non-NASA Center↗