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At least 523 records · Page 29

Formation of ferrobasalt at east Pacific midocean spreading centers

A numerical modeling using a least squares petrologic mixing program demonstrates that ridge ferrobasalts from three east Pacific regions are generated from normal midocean ridge balsalt by crystal fractionation of plagioclase, clinopyroxene, and minor olivine at shallow mantle depths. Clinopyroxene is an important fractionating phase in this model in contrast to most previously proposed fractionation models. Calculations demonstrate that the ferrobasalts represent a much smaller percentage of residual liquid than has previously been proposed. Implications of extensive shallow crystal fractionation for the determination of depths of magma generation are discussed. The different fields on an anorthite-olivine-hypersthene ternary diagram for basalts from east Pacific fast and moderate spreading ridges can be explained by variable degrees of shallow crystal fractionation rather than by different depths of magma generation as suggested by Bass (1971) and Scheidegger (1973).

Clague, D. A.↗

A survey of lunar rock types and comparison of the crusts of earth and moon

The principal known types of lunar rocks are briefly reviewed, and their chemical relationships discussed. In the suite of low-KREEP highland rocks, Fe/(Fe + Mg) in the normative mafic minerals increases and the albite content of normative plagio-clase decreases as the total amount of normative plagioclase increases, the opposite of the trend predicted by the Bowen reaction principle. The distribution of compositions of rocks from terrestrial layered mafic intrusives is substantially different: here the analyses fall in several discrete clusters (anorthositic rocks, norites, granophyres and ferrogabbros, ultramafics), and the chemical trends noted above are not reproduced. It is suggested that the observed trends in lunar highland rocks could be produced by crystal fractionation in a deep global surface magma system if (1) plagiociase tended to float, upon crystallization, and (2) the magma was kept agitated and well mixed (probably by thermal convection) until crystallization was far advanced and relatively little residual liquid was left. After the crustal system solidified, but before extensive cooling had developed a thick, strong lithosphere, mantle convection was able to draw portions of the lunar anorthositic crust down into the mantle.

Wood, J. A.↗

Cooling histories of Apollo 15 quartz-normative basalts

Controlled cooling rate studies of vitrophyre 15597 are used to calculate the physical properties of a quartz-normative magma as well as cooling histories of Apollo 15 quartz-normative basalts (QNB). Pyroxene phenocrysts of a QNB magma do not settle appreciably during the cooling of the flow unit; this behavior is consistent with the small degree of chemical differentiation that occurred between members of the suite. Two types of cooling histories for QNB are discerned. The vitrophyres experienced initial slow cooling followed by rapid cooling, and the coarse-grained microgabbros underwent slow nearly linear cooling histories. Textural evidence suggests that lunar vitrophyres crystallized near the top of the flow. It is suggested that the pattern of cooling may have been caused by the chilling of liquids that inherited early crystals in the interior of the flow.

Grove, T. L.↗

KREEP petrogenesis revisited

An experimentally determined crystallization sequence for a composition similar to the LKFM breccias and experimentally determined crystal/liquid distribution coefficients are used to calculate the evolution of the abundances of several key elements during the crystallization of LKFM liquids. Results indicate that the LKFM breccias are not themselves precursors to Apollo 15 igneous KREEP, but that compositions slightly poorer in Ti and Fe might be. Consideration of the evolution of Ti and Sm abundances during the differentiation of proposed whole-moon compositions suggests that it may be necessary to appeal to 'unorthodox' mechanisms such as magma hybridization or interaction of magma with genetically unrelated minerals within the lunar crust to produce KREEP-rich liquids having the observed Ti/Sm. It is concluded that the compositions of samples with Sm contents greater than those in LKFM are dominated by igneous processes, while samples with lower Sm contents may be mixtures of an anorthositic component, a Mg-rich Sm-poor component, and a component similar in composition to LKFM.

Mckay, G. A.↗

Partitioning of Ni/2+/ between basaltic and synthetic melts and olivines An experimental study

Olivine/liquid distribution coefficients for Ni in basaltic and simple synthetic melts are found in the 1400-1070 C temperature range. The results suggest that: (1) the Ni distribution coefficients and NiO activity coefficients are strongly temperature dependent, (2) the Ni distribution coefficients are functions of melt composition and structure at a constant temperature although the dependence is small for most basaltic magmas, (3) differences in melt composition do not significantly influence generally 'basaltic' melts, (4) the Ni distribution coefficients may be used as geothermometers to predict the olivine crystallization temperatures of basaltic magmas to within plus or minus 50 C, (5) the Ni distribution coefficients are greater than one at all natural magmatic temperatures, and (6) the Ni distribution coefficients do not significantly vary as functions of the Ni content of the melt to at least one mole percent.

Leeman, W. P.↗

Zr and Nb partition coefficients - Implications for the genesis of mare basalts, KREEP, and sea floor basalts

The distribution coefficients of Zr and Nb have been found between armalcolite, ilmenite, clinopyroxene, rutile, plagioclase, and a coexisting high-Ti mare basalt melt in the 1105-1128 C temperature range. Henry's Law is not broken over the compositional range evaluated. The distribution coefficients of clinopyroxene are strongly dependent on melt and crystal compositions. The Al2O3 activity in the melt is a strong controlling parameter. It is concluded that: (1) Apollo 11 (low K) and Apollo 17 high-Ti mare basalts may have been generated by the partial melting of an ilmenite-rich cumulate, (2) Apollo 11 (high K) basalts may have been generated by a small amount of partial melting of a more fractionated ilmenite-rich cumulate, (3) KREEP magmas may have been formed as residual melts produced by fractional crystallization of the lunar magma ocean, and (4) anomalous (type II) MOR basalts may have been generated by small degrees of partial melting of a relatively undepleted mantle with clinopyroxene remaining in the residium.

Mccallum, I. S.↗

Dunite 72417 - A chemical study and interpretation

The rock selected for the study is one of the rare ultrabasic rocks, which seems to have survived early lunar differentiation. The Rb-Sr internal isochron for this dunite gave an age of about 4.55 AE. The dunite was sampled at Apollo 17, Station 2 from a single 10x20-cm clast incorporated into a KREEP-rich blue-gray breccia 72435, Boulder 3. Nine dunite samples were analyzed with the aid of instrumental and radiochemical neutron activation analysis procedures. Data for 27 elements are shown in a table. Attention is given to trapped liquid (magma), a garnet hypothesis, models for the dunite genesis, and magma compositions from which 15415 and 72417 crystallized.

Laul, J. C.↗

Glasses in the Luna 24 core and petrogenesis of ferrobasalts

Modal abundance and major- and minor-element chemical analysis of homogeneous, non-agglutinitic mare and non-mare glasses from the Luna 24 drill core show that most glasses can be related to known rock types. Mare glasses include: brown glass identical in composition to the fine-grained low-Mg VLT basalt; green glass which might be related to a coarser-grained ferrogabbro; a high-K green glass; and a high-Ti orange glass. Highland glass compositions include Highland basalt, gabbroic anorthosite, and pure anorthosite (i.e. plagioclase); minor Fra Mauro-type glass may also be present. It is apparent that fractional crystallization of some primitive basaltic magma occurred at Mare Crisium producing a chemically evolved ferrobasalt and related glasses. An early, high-Mg basin fill, as represented by the olivine vitrophyres, may be the parent magma. Subsequent near-surface fractionation produced a multiply-saturated liquid that finally erupted as the ferrobasalt flows sampled by Luna 24.

Norman, M.↗

On the origin of Luna 24 basalts and soils

Analyses of fine-grained very low titanium (VLT) basalt from the Luna 24 drill core suggest that a single homogeneous magma is represented by the sample. In particular, the small variation in MgO contents of the fine-grained basalt, together with the tight clustering of the compositions of brown glasses (which may be pyroclastic equivalents of the VLT basalt), provides evidence for the single-magma hypothesis. The high-Mg component in the soil samples, though not obviously explainable in petrographic terms, may be derived from material similar to olivine vitrophyre and its degraded products, or from some other high-Mg VLT basalt.

Ryder, G.↗

Chemistry and petrology of Luna 24 lithic fragments and less than 250-micron soils - Constraints on the origin of VLT mare basalts

Results are reported on a combined INAA-petrologic study of 17 small (0.2-1.5 mg) Luna 24 lithic and mineral fragments and INAA study of 5 bulk soils and mineral separates from gabbro 24170. Lithic and mineral fragments are classified into VLT mare basalts (ferrobasalt and metabasalts), low-Ti, variolitic mare basalt, gabbros, melt rock and soil breccia. Data indicate 5 possible magma types, represented by: (1) VLT ferrobasalt and gabbro fragments, with low-TiO2 (about 1%), slightly bow-shaped REE pattern, and low REE concentrations (5-10X chondritic); (2) a ferrobasalt (Laul et al., 1978) and metabasalt fragments with major and trace element contents similar to (1), but positive Eu anomalies; (3) one gabbro fragment with distinctive pyroxene compositional trend (increasing Ti with nearly constant Fe/Fe + Mg) and highest REE contents of any Luna 24 mare basaltic sample, (4) a gabbro fragment with considerably less V and Cr2O3 than ferrobasalt and metabasalt fragments; and (5) variolitic basalt fragment with higher Ti2(2.3%) than other Luna 24 basalts and pyroxene that has increasing then decreasing Ti with increasing Fe/Fe + Mg. Trace element data place constraints on the nature of the source region and possible parent magmas for the Luna 24 VLT ferrobasalt.

Ma, M.-S.↗

Modeling lunar volcanic eruptions

Simple physical arguments are used to show that basaltic volcanos on different planetary bodies would fountain to the same height if the mole fraction of gas in the magma scaled with the acceleration of gravity. It is suggested that the actual eruption velocities and fountain heights are controlled by the velocities of sound in the two phase gas/liquid flows. These velocities are in turn determined by the gas contents in the magma. Predicted characteristics of Hawaiian volcanos are in excellent accord with observations. Assuming that the only gas in lunar volcano is the CO which would be produced if the observed Fe metal in lunar basalts resulted from graphite reduction, lunar volcanos would fountain vigorously, but not as spectacularly as their terrestrial counterparts. The volatile trace metals, halogens, and sulfur released would be transported over the entire moon by the transient atmosphere. Orange and black glass type pyroclastic materials would be transported in sufficient amounts to produce the observed dark mantle deposits.

Housley, R. M.↗

The Sr and Nd isotopic record of Apollo 12 basalts - Implications for lunar geochemical evolution

Alkali, alkaline earth, and rare earth element data are reported for several Apollo 12 basalts which are representative of the four Apollo 12 magma types. Results confirm the heterogeneity of the lunar mantle and show that the Sm/Nd ratio of at least the Apollo 12 ilmenite basalts was decreased by 13-24% during magma genesis. In addition, whole mare basalt Sm-Nd data are not collinear on an isochron diagram; thus it is no longer possible to explain these data via mixing of 'primitive material' and 'early differentiates' as in the hybridization and assimilation models.

Nyquist, L. E.↗

Consortium breccia 73255 - Genesis and history of two coarse-grained 'norite' clasts

A study of two clasts of coarse-grained anorthositic-noritic-troctolitic-suite norites from the fragment-laden melt rock 73255 is presented. Both clasts are igneous rocks crystallized from melts that were probably internally generated; clast 27,80 is a cumulate, and the parent magmas of both rocks probably crystallized below the lunar surface. Despite similar history, the parent rocks of the two clasts appear to be derived from distinct magma types: the 27,80 is characterized by plagioclase and orthopyroxene as the major constituents and by a high K, Nb, and Zr content, while the 27,45 type also contains augite and has a low content of K, Nb, and Zr.

James, O. B.↗

Monogenetic volcanoes of the terrestrial planets

Monogenetic volcanic activity has produced cinder cones and small shield volcanoes on the earth, moon, and Mars. Extraterrestrial cinder cones have median volumes only 25% as large as average terrestrial cinder cones, implying that their magma chambers are smaller and shallower (1 km depth vs 3 km). Ejection velocities for lunar and Martian cinder cones range from 20 to 70 m/sec, only 1/3 to 1/10 as high as for equal volume terrestrial eruptions. These low velocities imply low volatile contents for both Martian and lunar magmas.

Wood, C. A.↗

Luna 24 ferrobasalt as a low-Mg primary melt

The fractional crystallization model for the petrogenesis of the Luna-24 very-low-titanium ferrobasalt is critically evaluated. Arguments are presented that show there is no real evidence favoring either surface of shallow subsurface differentiation of an Mg-rich primary magma; instead there is ample evidence suggesting such is not the case. It is therefore concluded that surface or near-surface fractionation of olivine from a primary vitrophyre/green glass magma did not produce the ferrobasalt composition. The ferrobasalt did not exist as a residual liquid within a differentiated flow, but rather was extruded as a melt in its own right.

Norman, M.↗

Eruption mechanics on the earth, moon and Mars

A survey is provided of recent comparative studies on the character of eruption mechanics on earth, the moon and Mars. Among the relevant determinations made are: (1) a source depth for lunar basaltic magmas deeper, at 100 km, than most terrestrial ones; (2) the rising of both lunar and terrestrial magmas to less than 2 km below the surface before gases begin to exsolve; (3) carbon monoxide concentrations in lunar basalts are an order of magnitude lower than the average volatile contents of terrestrial basalts; and (4) unequivocal proof is lacking for the existence of ignimbrites in Martian volcanic formations, which would be formed by the collapse of large eruption columns.

Wadge, G.↗

Occurrence and Mineral Chemistry of High Pressure Phases, Potrillo Basalt, Southcentral New Mexico

The presence of an older plagioclase-rich basalt and a younger olivine-rich basalt were confirmed by modal and chemical analysis. Chemical analysis also confirmed the presence of flows that are tholeiitic in composition and could be remnants of an original tholeittic parent magma. Eruptions from different levels of a differentiated magma chamber are proposed to account for the two members.

Sheffield, T. M.↗

Isotopic and REE studies of lunar basalt 12038 - Implications for petrogenesis of aluminous mare basalts

Sr, Nd, and Sm isotopic studies of lunar basalt 12038, one of the so-called aluminous mare basalts, are reported. The evolution of the Sr and Nd isotopic compositions and the rare earth element (REE) abundances is successfully modeled within the framework of the model developed by Nyquist et al. (1977, 1979) for Apollo 12 olivine-pigeonite and ilmenite basalts. It is pointed out that the isotopic and trace element features of 12038 can by modeled as produced by partial melting of a cumulate mantle source which crystallized from a lunar magma ocean with a chondrite-normalized REE pattern of constant negative slope. Chondrite-normalized La/Yb is equal to 2.2 for this hypothetical magma ocean pattern.

Nyquist, L. E.↗