Low temperature battery First quarterly report, 14 Dec. 1965 - 13 Mar. 1966
Low temperature battery - development of pasted plate cathode construction to extend cell life
STRUCTURAL DESIGN↗
SEARCH · Engineering Papers
Results for “low temperatures”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Emissivity coatings for low-temperature space radiators Quarterly progress report, 1 Jul. - 30 Sep. 1966
Low solar absorption emissivity coatings for low temperature spacecraft radiators - ultraviolet radiation tests
ULTRAVIOLET RADIATION↗
Low temperature simulation of hypersonic melting ablation and the observed wave patterns.
Low temperature simulation of hypersonic melting ablation and wave patterns of gas-liquid interface
Chen, C.-J.↗
An experimental study of the cryoentrainment pump and the behavior of nude ionization gauges at low temperature
Cryoentrainment pump study and behavior of nude ionization gages at low temperature
Daggerhart, J. A., Jr.↗
The development of low temperature curing adhesives
An approach for the development of a practical low temperature (293 K-311 K/68 F-100 F) curing adhesive system based on a family of amide/ester resins was studied and demonstrated. The work was conducted on resin optimization and adhesive compounding studies. An improved preparative method was demonstrated which involved the reaction of an amine-alcohol precursor, in a DMF solution with acid chloride. Experimental studies indicated that an adhesive formulation containing aluminum powder provided the best performance when used in conjunction with a commercial primer.
Green, H. E.↗
Low temperature research facilities for shuttle and beyond
This paper describes the Low Temperature Research Facility program now under development at the Jet Propulsion Laboratory. This program will develop the experiments and cryogenic facility to fly experiments requiring temperatures in the liquid helium range, from the superfluid range (1.6 K) to the critical point (5.2 K). A shuttle facility is planned for 1998. It will be flown about every two years after that time. A free flyer is also being evaluated for the end of the decade or early in the next century. A brief discussion of the quality of micro-gravity available in various carriers is also given.
Mason, P.↗
Low Temperature Performance of a Boost Converter with MPP and HTS Inductors
Low temperature performance of a 150 W, 50 kHz, 24/48 V boost PWM dc-to-dc converter is reported. The efficiency of the converter using a molypermalloy powder (MPP) core based inductor went up from 94% at room temperature (23 C) to 95.9% at liquid nitrogen temperature (-196 C). A BSCCO based high temperature superconducting (HTS) inductor with a transition temperature of approximately -158 C was compared to a MPP core based inductor in terms of the power converter performance at liquid nitrogen temperature. The use of the HTS inductor in the converter tested yielded no significant performance improvement over the same converter with the MPP inductor. The experimental results are discussed along with the HTS inductor characteristics.
Ray, Biswajit↗
Low-temperature gas-phase formation of cyclopentadiene and its role in the formation of aromatics in the interstellar medium
The cyclopentadiene (C 5 H 6 ) molecule has emerged as a molecular building block of nonplanar polycyclic aromatic hydrocarbons (PAHs) and carbonaceous nanostructures such as corannulene (C 20 H 10 ), nanobowls (C 40 H 10 ), and fullerenes (C 60 ) in deep space. However, the underlying elementary gas-phase processes synthesizing cyclopentadiene from acyclic hydrocarbon precursors have remained elusive. Here, by merging crossed molecular beam experiments with rate coefficient calculations and comprehensive astrochemical modeling, we afford persuasive testimony on an unconventional low-temperature cyclization pathway to cyclopentadiene from acyclic precursors through the reaction of the simplest diatomic organic radical—methylidyne (CH)—with 1,3-butadiene (C 4 H 6 ) representing main route to cyclopentadiene observed in TaurusMolecular Cloud. This facile route provides potential solution for the incorporation of the cyclopentadiene moiety in complex aromatic systems via bottom–up molecular mass growth processes and offers an entry point to the low-temperature chemistry in deep space leading eventually to nonplanar PAHs in our carbonaceous Universe.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Low-temperature grapho-epitaxial La-substituted BiFeO 3 on metallic perovskite
Bismuth ferrite has garnered considerable attention as a promising candidate for magnetoelectric spin-orbit coupled logic-in-memory. As model systems, epitaxial BiFeO 3 thin films have typically been deposited at relatively high temperatures (650–800 °C), higher than allowed for direct integration with silicon-CMOS platforms. Here, we circumvent this problem by growing lanthanum-substituted BiFeO 3 at 450 °C (which is reasonably compatible with silicon-CMOS integration) on epitaxial BaPb 0.75 Bi 0.25 O 3 electrodes. Notwithstanding the large lattice mismatch between the La-BiFeO 3 , BaPb 0.75 Bi 0.25 O 3 , and SrTiO 3 (001) substrates, all the layers in the heterostructures are well ordered with a [001] texture. Polarization mapping using atomic resolution STEM imaging and vector mapping established the short-range polarization ordering in the low temperature grown La-BiFeO 3 . Current-voltage, pulsed-switching, fatigue, and retention measurements follow the characteristic behavior of high-temperature grown La-BiFeO 3 , where SrRuO 3 typically serves as the metallic electrode. These results provide a possible route for realizing epitaxial multiferroics on complex-oxide buffer layers at low temperatures and opens the door for potential silicon-CMOS integration.
36 MATERIALS SCIENCE↗
High-efficiency, low-temperature cesium diodes with lanthanum-hexaboride electrodes
Lanthanum hexaboride electrodes in 1700 K cesium diodes may triple power outputs compared with those demonstrated for nuclear thermionic space applications. Still greater relative gains seem possible for emitters below 1700 K. Further improvements in cesium diode performance should result from the lower collector temperatures allowed for earth and low power space duties. Decreased temperatures will lessen thermal transport losses that attend thermionic conversion mechanisms. Such advantages will add to those from collector Carnot and electrode effects. If plasma ignition difficulties impede diode temperature reductions, recycling small fractions of the output power could provide ionization. So high efficiency, low temperature cesium diodes with lanthanum hexaboride electrodes appear feasible.
Morris, J. F.↗
Numerical thermalization in 2D PIC simulations: Practical estimates for low-temperature plasma simulations
The process of numerical thermalization in particle-in-cell (PIC) simulations has been studied extensively. It is analogous to Coulomb collisions in real plasmas, causing particle velocity distributions (VDFs) to evolve toward a Maxwellian as macroparticles experience polarization drag and resonantly interact with the fluctuation spectrum. This paper presents a practical tutorial on the effects of numerical thermalization in 2D PIC applications. Scenarios of interest include simulations, which must be run for many thousands of plasma periods and contain a population of cold electrons that leave the simulation space very slowly. This is particularly relevant to many low-temperature plasma discharges and materials processing applications. We present numerical drag and diffusion coefficients and their associated timescales for a variety of grid resolutions, discussing the circumstances under which the electron VDF is modified by numerical thermalization. Though the effects described here have been known for many decades, direct comparison of analytically derived, velocity-dependent numerical relaxation timescales to those of other relevant processes has not often been applied in practice due to complications that arise in calculating thermalization rates in 1D simulations. Using these comparisons, we estimate the impact of numerical thermalization in several examples of low-temperature plasma applications including capacitively coupled plasma discharges, inductively coupled plasma discharges, beam plasmas, and hollow cathode discharges. Finally, we discuss possible strategies for mitigating numerical relaxation effects in 2D PIC simulations.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Characterization of PVT Grown ZnSe by Low Temperature Photoluminescence
ZnSe, a II-VI semiconductor with a large direct band gap of 2.7 eV at room temperature and 2.82 eV at 10 K, is considered a promising material for optoelectric applications in the blue-green region of the spectrum. Photoemitting devices and diode laser action has been demonstrated as a result of decades of research. A key issue in the development of II-VI semiconductors is the control of the concentration of the various impurities. The II-VI semiconductors seem to defy the effort of high level doping due to the well known self compensation of the donors and the acceptors. A good understanding of roles of the impurities and the behavior of the various intrinsic defects such as vacancies, interstitials and their complexes with impurities is necessary in the development and application of these materials. Persistent impurities such as Li and Cu have long played a central role in the photoelectronic properties of many II-VI compounds, particularly ZnSe. The shallow centers which may promote useful electrical conductivity are of particular interest. They contribute the richly structured near gap edge luminescence, containing weak to moderate phonon coupling and therefore very accessible information about the energy states of the different centers. Significance of those residual impurities which may contribute such centers in II-VI semiconductors must be fully appreciated before improved control of their electrical properties may be possible. Low temperature photoluminescence spectroscopy is an important source of information and a useful tool of characterization of II-VI semiconductors such as ZnSe. The low temperature photoluminescence spectrum of a ZnSe single crystal typically consists of a broad band emission peaking at 2.34 eV, known as the Cu-green band, and some very sharp lines near the band gap. These bands and lines are used to identify the impurity ingredients and the defects. The assessment of the quality of the crystal based on the photoluminescence analysis is then possible. In this report we present the characterization of a ZnSe single crystal as grown by the physical vapor transport method, with special intention paid to the possible effects of the gravitational field to the growth of the crystal.
Wang, Ling Jun↗
PV Technology for Low Intensity, Low Temperature (LILT) Applications
As a result of the recent NASA emphasis on smaller, lower cost space missions, PV is now being considered for a number of missions operating at solar distances of 3 AU or greater. In the past, many of these missions would utilize an RTG (radioisotope thermoelectric generator). Historically, silicon solar cell behavior at these distances has been compromised by a number of mechanisms including shunting, nonohmic back contacts, and the 'broken knee' curve shape. The former two can usually be neglected for modern silicon cells, but the latter has not been eliminated. This problem has been identified with localized diffusion at the top contact/silicon interface which leads to structural changes at the local junction. This is believed to create a resistive metal-semiconductor-like (MSL) interface in parallel with the junction which results in the characteristic forms of the LILT (low intensity, low temperature) 'broken knee'. This paper discusses a TaSiN contact barrier that will prevent the MSL structure in the junction.
spacecraft power LILT low temperature low intensit↗
(abstract) PV Technology for Low Intensity, Low Temperature (LILT) Applications
As a result of the recent NASA emphasis on smaller, lower cost space missions, PV is now being considered for a number of missions operating at solar distances of 3 AU or greater. In the past, many of these missions would utilize an RTG (radioisotope thermoelectric generator). Historically, silicon solar cell behavior at these distances has been compromised by a number of mechanisms including shunting, nonohmic back contacts, and the 'broken knee' curve shape. The former two can usually be neglected for modern silicon cells, but the latter has not been eliminated. This problem has been identified with localized diffusion at the top contact/silicon interface which leads to structural changes at the local junction. This is believed to create a resistive metal-semiconductor-like (MSL) interface in parallel with the junction which results in the characteristic forms of the LILT (low intensity, low temperature) 'broken knee'. This paper discusses a TaSiN contact barrier that will prevent the MSL structure in the junction.
spacecraft power LILT low temperature low intensit↗
Electrolytes for Li-Ion Cells in Low Temperature Applications
A number of upcoming NASA missions require energy storage devices which display high energy density and can effectively operate at low temperature. Lithium-ion batteries have been identified as the most promising technology which can meet these stringent requirements.
electrolytes↗
Isotopic equilibrium constants for very low-density and low-temperature nuclear matter
Yields of equatorially emitted light isotopes, 1 ≤ Z ≤ 14, observed in ternary fission in the reaction 241 Pu(n th, f) are employed to determine apparent chemical equilibrium constants for low-temperature and low-density nuclear matter. The degree of equilibration and role of medium modifications are probed through a comparison of experimentally derived reaction quotients with equilibrium constants calculated using a relativistic mean-field model employing a universal medium modification correction for the attractive σ meson coupling. The results of these comparisons indicate that equilibrium is achieved for the lighter ternary fission isotopes. For the heavier isotopes experimental reaction quotients are well below calculated equilibrium constants. This is attributed to a dynamical limitation reflecting insufficient time for full equilibrium to develop. The role of medium effects leading to yield reductions is discussed as is the apparent enhancement of yields for 8 He and other very neutron rich exotic nuclei.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Multiplicity of Th(IV) and U(VI) HEH[EHP] Chelates at Low Temperatures from Concentrated Nitric Acid Extractions
Organophosphorus extractants have been widely investigated for lanthanide recovery from ore and for application in the reprocessing of spent nuclear fuel, such as in Advanced TALSPEAK schemes. Determining the speciation of the extracted metal complex in the organic phase remains a significant challenge. A better understanding of the variability of HEH[EHP]–actinide complexes and the speciation of chelates for tetra- and hexavalent actinides can improve the predictability of actinide phase transfer in such biphasic systems. Here, the extraction of Th(IV) and U(VI) from nitric acid media using HEH[EHP] in heptane is examined. The distribution ratio as a function of nitric acid concentration was quantified using UV–vis spectroscopy, and then the speciation of HEH[EHP]–metal complexes in the organic phase was investigated using Fourier transform infrared (FTIR) spectroscopy and low-temperature 31 P nuclear magnetic resonance (NMR) spectroscopy. In addition to perturbation of the vibrational modes proximal to the phosphonic moiety in HEH[EHP] in the FTIR spectra, the appearance of a nitrate signal was found in the organic phase following extraction from the highest acidity conditions for U(VI). The 31 P NMR spectra of the organic phase at a low temperature (-70 °C) exhibited a surprising number (n) of resonances (n ≥ 7 for Th(IV) and n ≥ 11 for U(VI)), with the distribution between these resonances changing with the initial concentration of nitric acid in the aqueous phase. These results indicate that the compositions of the inner and outer spheres of the extracted actinides in the organic phase are more diverse than initially thought.
31P NMR↗
Low Temperature Combustion Exploration with Negative Valve Overlap
Progressively stringent emission regulations and increasing regulatory demands on fuel economy have led to advanced combustion development. Low temperature combustion (LTC), specifically homogenous charge compression ignition (HCCI), is a promising technology for reducing exhaust emissions and improving efficiency. However, its operating range is limited to low load without boosting and EGR, due to low volumetric efficiency and high pressure rise rates. In addition, effectively controlling the combustion phasing is another challenge in realizing the associated combustion gains. In this work, advanced valve control mechanisms known as continuously variable valve duration (CVVD) and continuously variable valve timing (CVVT) were used for both intake and exhaust valvetrains to enable negative valve overlap (NVO) for trapping hot exhaust residuals and to promote multipoint simultaneous ignition. Heat release phasing was controlled by varying the fueling scheme and by adjusting the amount of NVO. Parametric studies on valve timing and duration, fueling strategy, lambda, spark assist, etc., were carried out first. Afterwards the LTC strategy was proposed and then LTC operation was explored at different engine speeds. Various approaches for extending load limits were summarized and discussed. Finally, combustion performance was compared to that of spark ignition combustion, demonstrating the combustion gains of LTC.
02 PETROLEUM↗