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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Improving Tropical Cyclogenesis Forecasts of Hurricane Irma (2017) through the Assimilation of All-Sky Infrared Brightness Temperatures

The assimilation of satellite all-sky infrared (IR) brightness temperatures (BTs) has been shown in previous studies to improve intensity forecasts of tropical cyclones. Here, in this study, we examine whether assimilating all-sky IR BTs can also potentially improve tropical cyclogenesis forecasts by improving the pregenesis cloud and moisture fields. By using an ensemble-based data assimilation system, we show that the assimilation of upper-tropospheric water vapor channel BTs observed by the Meteosat-10 SEVIRI instrument two days before the formation of a tropical depression improves the genesis forecast of Hurricane Irma (2017), a classic Cape Verde storm, by up to 24 h while also capturing its later rapid intensification in deterministic forecasts. In an experiment that withholds the assimilation of all-sky IR BTs, the assimilation of conventional observations from the Global Telecommunications System (GTS) leads to the premature genesis of Hurricane Irma by at least 24 h. This premature genesis is shown to result from an overestimation of the spatial coverage of deep convection within the African easterly wave (AEW) from which Irma eventually forms. The gross overestimation of deep convection without all-sky IR BTs is accompanied by higher column saturation fraction, stronger low-level convergence, and the earlier spinup of a low-level meso- β -scale vortex within the AEW that ultimately becomes Hurricane Irma. Through its adjustment to the initial moisture and cloud conditions, the assimilation of all-sky IR BTs leads to a more realistic convective evolution in forecasts and ultimately a more realistic timing of genesis.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Swab Tensile Testing and Procedures

This tensile test is to mimic the worst-case scenario of the swab being caught on an obstruction when being pulled out of the nasopharyngeal space. It is to determine how much tensile force the swab can withstand without breaking. A variety of different swabs (different materials and different geometries) were tested using the protocol outlined in Section 2 (Tensile Testing Procedure). Not all of the swabs were pre-treated using the Autoclave. For those swabs that were pre-treated using the Autoclave, the tensile tests were performed within 6 hours of completion of the Autoclave pre-treatment, unless otherwise noted. The FormLabs-USF and FormLabs-Northwell were printed at LLNL using FormLabs Surgical Grade V1 Resin on a Form 3B Printer. Results Summary: All FormLabs design and treatment variations (e.g. autoclaving and “aging”) had higher tensile strength compared commercial swabs. Autoclaving degraded the tensile strength. “Aging” after autoclaving improved the tensile strength. “Aging” without autoclaving degraded the tensile strength. No differences were observed in tensile strength with different autoclaving protocols. No significant differences were observed in tensile strength for different batches.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

Hydrophobic, Thermal Shock-and-Corrosion-Resistant XSBR Latex-Modified Lightweight Class G Cement Composites in Geothermal Well Energy Storage Systems

Energy losses can be significantly reduced if thermally insulating cement is used for energy storage and recovery. The thermal conductivity (TC) of the currently used cement is between 1 and 1.2 W/mK. In this study we assessed the ability of polystyrene (PS)–polybutadiene (PB)–polyacrylic acid (PAA) terpolymer (cross-linked styrene–butadiene rubber, XSBR) latex to improve thermal insulating properties and thermal shock (TS) resistance of class G ordinary Portland cement (OPC) and fly ash cenosphere (FCSs) composites in the temperature range of 100–175 °C. The composites autoclaved at 100 °C were subjected to three cycles, one cycle: 175 °C heat → 25 °C water quenching). In hydrothermal and thermal (TS) environments at elevated temperatures in cement slurries the XSBR latex formed acrylic calcium complexes through acid–base reactions, and the number of such complexes increased at higher temperatures due to the XSBR degradation with formation of additional acrylic groups. As a result, these complexes offered the following five advanced properties to the OPC-based composites: (1) enhanced hydrophobicity; (2) decreased water-fillable porosity; (3) reduced TC for water-saturated composites; (4) minimized loss of compressive strength, Young’s modulus, and compressive fracture toughness after TS; and (5) abated pozzolanic activity of FCSs, which allowed FCSs to persist as thermal insulators under strongly alkaline conditions of cement slurries. Additionally, XSBR-modified slurries possessed improved workability and decreased slurry density due to the air-entraining effect of latex, which resulted in further improvement of thermal insulation performance of the modified composites.

15 GEOTHERMAL ENERGY↗
DOE OSTI2024

High-Temperature Oxidation Behavior of Wrought and Additive Manufactured Alloys in Direct-Fired Supercritical CO2 Power Cycle Environments

Materials selection is a key concern for corrosion resistance in elevated temperature and pressure direct-fired supercritical CO2 (sCO2) power cycles. The effect of elevated pressure on corrosion resistance can be critical, as impurities within the supercritical fluid such as H2O and O2 can have additional corrosion effects than found at ambient pressure conditions. Several wrought nickel-based commercial alloys (230, 263, 282, 617, 625, 740H) were exposed to direct-fired conditions (95CO2 – 4H2O – 1 O2) at 750 °C at both atmospheric pressure (0.1 MPa) and supercritical conditions (20 MPa) for over 2,000 h. Additionally, additive manufactured (AM) 282 produced by laser powder bed fusion (LPBF) were also included in the exposures. Supercritical conditions affected the oxidation behavior of several alloys. Most notably, water-vapor assisted Cr-oxide volatilization was observed at 750 °C supercritical conditions. Many alloys did not form sufficient protective Cr-oxide scales at supercritical conditions, leading to increased oxidation at elevated pressure. Differences in oxidation behavior were also observed for 282 AM samples compared to their wrought counterparts, with the differences also dependent on the LPBF build parameters and post-production treatments (heat treatment and surface finishing procedures). The AM samples formed Mo-rich carbides in the alloy beneath the oxide following sCO2 exposure, implying potentially higher levels of carbon uptake relative to the wrought

Carney, Casey↗
DOE OSTI2023

Probing supermassive black hole growth and its dependence on stellar mass and star formation rate in low-redshift galaxies

ABSTRACT We present an improved study of the relation between supermassive black hole growth and their host galaxy properties in the local Universe (z < 0.33). To this end, we build an extensive sample combining spectroscopic measurements of star formation rate (SFR) and stellar mass from Sloan Digital Sky Survey, with specific Black Hole accretion rate (sBHAR, $\lambda _{\mathrm{sBHAR}} \propto L_{\rm X}/\mathcal {M}_{\ast }$) derived from the XMM–Newton Serendipitous Source Catalogue (3XMM–DR8) and the Chandra Source Catalogue (CSC2.0). We find that the sBHAR probability distribution for both star-forming and quiescent galaxies has a power-law shape peaking at log λsBHAR ∼ −3.5 and declining towards lower sBHAR in all stellar mass ranges. This finding confirms the decrease of active galactic nucleus (AGN) activity in the local Universe compared to higher redshifts. We observe a significant correlation between $\log \, \lambda _{\rm sBHAR}$ and $\log \, {\rm SFR}$ in almost all stellar mass ranges, but the relation is shallower compared to higher redshifts, indicating a reduced availability of accreting material in the local Universe. At the same time, the BHAR-to-SFR ratio for star-forming galaxies strongly correlates with stellar mass, supporting the scenario where both AGN activity and stellar formation primarily depend on the stellar mass via fuelling by a common gas reservoir. Conversely, this ratio remains constant for quiescent galaxies, possibly indicating the existence of the different physical mechanisms responsible for AGN fuelling or different accretion mode in quiescent galaxies.

Torbaniuk, O. (ORCID:0000000344652564)↗
DOE OSTI2021

Effects of Fe(III) Oxide Mineralogy and Phosphate on Fe(II) Secondary Mineral Formation during Microbial Iron Reduction

The bioreduction of Fe(III) oxides by dissimilatory iron-reducing bacteria may result in the formation of a suite of Fe(II)-bearing secondary minerals, including magnetite (a mixed Fe(II)/Fe(III) oxide), siderite (Fe(II) carbonate), vivianite (Fe(II) phosphate), chukanovite (ferrous hydroxy carbonate), and green rusts (mixed Fe(II)/Fe(III) hydroxides). In an effort to better understand the factors controlling the formation of specific Fe(II)-bearing secondary minerals, we examined the effects of Fe(III) oxide mineralogy, phosphate concentration, and the availability of an electron shuttle (9,10-anthraquinone-2,6-disulfonate, AQDS) on the bioreduction of a series of Fe(III) oxides (akaganeite, feroxyhyte, ferric green rust, ferrihydrite, goethite, hematite, and lepidocrocite) by Shewanella putrefaciens CN32, and the resulting formation of secondary minerals, as determined by X-ray diffraction, Mössbauer spectroscopy, and scanning electron microscopy. The overall extent of Fe(II) production was highly dependent on the type of Fe(III) oxide provided. With the exception of hematite, AQDS enhanced the rate of Fe(II) production; however, the presence of AQDS did not always lead to an increase in the overall extent of Fe(II) production and did not affect the types of Fe(II)-bearing secondary minerals that formed. The effects of the presence of phosphate on the rate and extent of Fe(II) production were variable among the Fe(III) oxides, but in general, the highest loadings of phosphate resulted in decreased rates of Fe(II) production, but ultimately higher levels of Fe(II) than in the absence of phosphate. In addition, phosphate concentration had a pronounced effect on the types of secondary minerals that formed; magnetite and chukanovite formed at phosphate concentrations of ≤1 mM (ferrihydrite), <~100 µM (lepidocrocite), 500 µM (feroxyhyte and ferric green rust), while green rust, or green rust and vivianite, formed at phosphate concentrations of 10 mM (ferrihydrite), ≥100 µM (lepidocrocite), and 5 mM (feroxyhyte and ferric green rust). These results further demonstrate that the bioreduction of Fe(III) oxides, and accompanying Fe(II)-bearing secondary mineral formation, is controlled by a complex interplay of mineralogical, geochemical, and microbiological factors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Sustained Oxygen Spectral Gaps and Their Dynamic Evolution in the Inner Magnetosphere

Van Allen Probes observations of ion spectra often show a sustained gap within a very narrow energy range throughout the full orbit. To understand their formation mechanism, we statistically investigate the characteristics of the narrow gaps for oxygen ions and find that they are most frequently observed near the noon sector with a peak occurrence rate of over 30%. The magnetic moment (μ) of the oxygen ions in the gap shows a strong dependence on magnetic local time (MLT), with higher and lower μ values in the morning and afternoon sectors, respectively. Moreover, we find through superposed epoch analysis that the gap formation also depends on geomagnetic conditions. Those gaps formed at lower magnetic moments (μ < 3,000 keV/G) are associated with stable convection electric fields, which enable magnetospheric ions to follow a steady drift pattern that facilitates the gap formation by corotational drift resonance. On the other hand, gaps with higher μ values are statistically preceded by a gradual increase of geomagnetic activity. Here, we suggest that ions within the gap were originally located inside the Alfven layer following closed drift paths, before they were transitioned into open drift paths as the convection electric field was enhanced. The sunward drift of these ions, with very low fluxes, forms a drainage void in the dayside magnetosphere manifested as the sustained gap in the oxygen spectrum. This scenario is supported by particle-tracing simulations, which reproduce most of the observed characteristics and therefore provide new insights into inner magnetospheric dynamics.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Physical Properties of the Star-forming Regions in the Interacting Galaxies NGC 3395/NGC 3396

We report long-slit spectroscopy of the early major merger galaxies NGC 3395/NGC 3396. The spectra are consistent with those for star-forming galaxies, but there is some indication of LINER-like active galactic nucleus activity in the center of NGC 3396. The total star formation rate in the regions observed is 2.83 M {sub ⊙} yr{sup −1}, consistent with estimates for the entire galaxies. The highest abundances are in the centers of the galaxies, with the abundances decreasing with distance. There is a correlation between high abundance and high ionization parameter, both of which can be attributed to the presence of massive stars. Modeling with SB 99 indicates the star-forming regions are younger than 10 Myr. There are 1000–2000 WNL stars in the system, along with several thousand O stars, consistent with the ages of the star-forming regions. The highest electron densities are found in young regions with high star formation rates. The electron temperatures are higher than results for non-interacting galaxies, which is probably due to shock waves produced by the galaxy–galaxy interaction, the outflow of gas from massive stars, and/or collisions between gas clouds in the galaxies. There is star formation in the bridge of material between the galaxies. These regions are among the youngest in the system and have low abundances, suggesting the gas was pulled from the outer parts of the galaxies. X-ray point sources, probably high-mass X-ray binaries, are associated with several star-forming regions.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Tetragonal Kondo Insulator EuCd 2 Sb 2 Discovered via High Pressure High Temperature Synthesis

Abstract Magnetic and electronic properties of quantum materials heavily rely on the crystal structure even in the same chemical compositions. In this study, it is demonstrated that a layered tetragonal EuCd 2 Sb 2 structure can be obtained by treating bulk trigonal EuCd 2 Sb 2 under high pressure (6 GPa) and high temperature (600 °C). Magnetization measurements of the newly formed layered tetragonal EuCd 2 Sb 2 confirm an antiferromagnetic ordering with Neel temperature ( T N ) around 16 K, which is significantly higher than that ( T N ≈ 7 K) of trigonal EuCd 2 Sb 2 , consistent with heat capacity measurements. Moreover, bad metal behavior is observed in the temperature dependence of the electrical resistivity and the resistivity shows a dramatic increase around the Neel temperature. Electronic structure calculations with local density approximation dynamic mean–field theory (LDA+DMFT) show that this material is strongly correlated with well‐formed large magnetic moments, due to Hund's coupling, which is known to dramatically suppress the Kondo scale.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Preparation of Ultrathin Gold Films with Subatomic Surface Roughness

Nanoscale device fabrication requires control over film growth at the atomic scale. Growth conditions must be tuned in consideration of interface parameters like chemical bonding, surface free energy, and lattice matching. In metals, electronic properties may also be utilized for control of physical parameters. Quantum size effects can induce metals to spontaneously form specific shapes and sizes according to their electronic structure. Unfortunately, such electronic growth is generally known only for a few systems and is typically only stable under cryogenic conditions. In this work, we explore a recently discovered class of electronic growth systems in which metal films are grown upon the relatively inert surfaces of van der Waals crystals. In this class of materials, the electronic growth is highly stable at room temperature and actually requires higher temperature annealing to achieve proper equilibrium. We work with the Au/MoS 2 system, which shows excellent stability and can readily form discrete and atomically flat nanostructures. Here, we show how the electronic growth modes facilitate the formation of atomically flat films with nanometer scale thickness. Here, the surface roughness of these films was found to be less than a single atom over several square microns, creating nearly perfect surfaces for studies of self-assembled monolayers or other applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Thermophysical Properties of Mixtures of Thorium and Uranium Nitride

Abstract The miscibility, lattice parameter, and thermophysical properties of (Th 0.2 U 0.8 )N and (Th 0.5 U 0.5 )N have been investigated. It is shown that additions of thorium nitride (ThN) to uranium nitride (UN) increases the thermophysical performance of the mixed nitride fuel form in comparison to reference UN. In the more dilute limit, additions of ThN serve as a burnable neutronic poison and reduces the change in k eff over the lifecycle of the fuel. At higher concentrations, additions of ThN serve as a significant fertile source of 233 U. Where appropriate, comparisons to previous work on UN + PuN mixtures are made, as this is a comparable fuel form for potential fast reactor concepts, and a suitable point of contrast in the possible design space afforded by mixed (Th x U 1 − x )N fuel forms. The data from this work are the input parameters for finite element modeling of the temperature distribution in a compact reactor. The results of modeling and simulation of this core design are shown for the case of steady-state operation and during double, adjacent heat pipe failure.

Parker, S. S. (ORCID:000000018597440X)↗
DOE OSTI2024

Environmental Dependence of Type Ia Supernovae in Low-redshift Galaxy Clusters

Abstract We present an analysis of 102 Type Ia supernovae (SNe Ia) in nearby ( z < 0.1), x-ray-selected galaxy clusters. This is the largest such sample to date and is based on archival data primarily from ZTF and ATLAS. We divide our SNe Ia into an inner cluster sample projected within r 500 of the cluster center and an outer cluster sample projected between r 500 and 2 r 500 . We compare these to field samples of SNe Ia at similar redshifts in both quiescent and star-forming host galaxies. Based on SALT3 fits to the light curves, we find that the inner cluster SNe Ia have a higher fraction of fast-evolving objects (SALT3 x 1 < −1) than the outer cluster or field quiescent samples. This implies an intrinsically different population of SNe Ia occurs in inner cluster environments, beyond known correlations based on host galaxy alone. Our cluster samples show a strongly bimodal x 1 distribution with a fast-evolving component that dominates the inner cluster objects (≳75%) but is just a small fraction of SNe Ia in field star-forming galaxies (≲10%). We do not see strong evidence for variations in the color (SALT3 c ) distributions among the samples and find only minor differences in SN Ia standardization parameters and Hubble residuals. We suggest that the age of the stellar population drives the observed distributions, with the oldest populations nearly exclusively producing fast-evolving SNe Ia.

Larison, Conor (ORCID:0000000320374619)↗
DOE OSTI2023

Time, momentum, and energy resolved pump-probe tunneling spectroscopy of two-dimensional electron systems

Abstract Real-time probing of electrons can uncover intricate relaxation mechanisms and many-body interactions in strongly correlated materials. Here, we introduce time, momentum, and energy resolved pump-probe tunneling spectroscopy (Tr-MERTS). The method allows the injection of electrons at a particular energy and observation of their subsequent decay in energy-momentum space. Using Tr-MERTS, we visualize electronic decay processes, with lifetimes from tens of nanoseconds to tens of microseconds, in Landau levels formed in a GaAs quantum well. Although most observed features agree with simple energy-relaxation, we discovered a splitting in the nonequilibrium energy spectrum in the vicinity of a ferromagnetic state. An exact diagonalization study suggests that the splitting arises from a maximally spin-polarized state with higher energy than a conventional equilibrium skyrmion. Furthermore, we observe time-dependent relaxation of the splitting, which we attribute to single-flipped spins forming skyrmions. These results establish Tr-MERTS as a powerful tool for studying the properties of a 2DES beyond equilibrium.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Study of interface reaction in a B 4 C/Cr mirror at elevated temperature using soft X-ray reflectivity

Boron carbide is a prominent material for high-brilliance synchrotron optics as it remains stable up to very high temperatures. The present study shows a significant change taking place at 550°C in the buried interface region formed between the Cr adhesive layer and the native oxide layer present on the silicon substrate. An in situ annealing study is carried out at the Indus-1 Reflectivity beamline from room temperature to 550°C (100°C steps). The studied sample is a mirror-like boron carbide thin film of 400 Å thickness deposited with an adhesive layer of 20 Å Cr on a silicon substrate. The corresponding changes in the film structure are recorded using angle-dependent soft X-ray reflectivity measurements carried out in the region of the boron K-edge after each annealing temperature. Analyses performed using the Parratt recursive formalism reveal that the top boron carbide layer remains intact but interface reactions take place in the buried Cr–SiO2 region. After 300°C the Cr layer diffuses towards the substrate. At higher temperatures of 500°C and 550°C the Cr reacts with the native oxide layer and tends to form a low-density compound of chromium oxysilicide (CrSiOx). Depth profiling of Si and Cr distributions obtained from secondary ion mass spectroscopy measurements corroborate the layer model obtained from the soft X-ray reflectivity analyses. Details of the interface reaction taking place near the substrate region of boron carbide/Cr sample are discussed.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

Assembly of Disordered Cocontinuous Morphologies by Multiblock Copolymers with Random Block Sequence and Length Dispersity

Among the wide variety of nanostructures accessible by self-assembly of block copolymers, cocontinuous morphologies are of great interest for separations, catalysis, sensing, and energy storage due to their ability to integrate distinct properties of the constituent polymers. Furthermore, we investigate the tendency to form disordered cocontinuous phases of multiblock copolymers (MBCs) with random block sequence and length dispersity prepared by step-growth polymerization of pre-made telechelic polymers, specifically using thiol-Michael addition between diacrylate functionalized polystyrene (PS) and poly (D,L - lactide) (PLA) chains and a small molecule dithiol. In the phase diagram so established, disordered cocontinuous nanostructures occupy a wide window (≈ 25 % vol) at a modest segregation strength of χN = 15, close to the critical value for microphase separation. At a higher segregation strength of χN = 30, only a moderately wide (≈ 10 vol %) cocontinuous window is found, with MBCs instead tending to form ordered nanostructures. Although the breadth of the cocontinuous widow is less than that found in prior work on analogous randomly end-linked copolymer networks (RECNs), the MBC architecture offers offsetting advantages in terms of solution and melt processability.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Anomalous Redox Features Induced by Strong Covalency in Layered NaTi 1-y V y S 2 Cathodes for Na-Ion Batteries

The rising demand for energy density of cathodes means the need to raise the voltage or capacity of cathodes. Transition metal (TM) doping has been employed to enhance the electrochemical properties in multiple aspects. The redox voltage of doped cathodes usually falls in between the voltage of undoped layered cathodes. However, in this study, we found anomalous redox features in NaTi 1-y V y S 2 . The first discharge platform potential (2.4 V) is significantly higher than that of undoped NaTiS 2 and NaVS 2 (both around 2.2 V), and the energy density is raised by 15%. We speculate that the anomalous voltage is mainly attributed to the strong hybridization in the Ti-V-S system. Ti 3+ and V 3+ undergo charge transfer and form a more stable Ti (t 2g 0 e g 0 ) and V (t 2g 3 e g 0 ) electronic configuration. Our results indicate that higher voltage of cathode materials could be achieved by strong TM-ligand covalency, and this conclusion provides possible opportunities to explore high voltage materials for future layered cathodes.

36 MATERIALS SCIENCE↗