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NASA NTRS1985

Bulk Formation of Metallic Glasses and Amorphous Silicon from the Melt

By using metallic glass compositions with a high relative glass transition temperature, such as Pd40Ni40P20, homogeneous nucleation also becomes negligible. Large (5g) masses of this alloys were obtained using a molten B2O3 flux. Presently, bulk glass formation in iron based glasses is being investigated. It is expected that if an undercooling of about 250K can be achieved in a Ge or Si melt, formation of the amorphous semiconductor phase (rather than the crystal) may be kinetically favored. The volumetric behavior of undercooled liquid Ga droplet dispersion is investigated by dilatometry. A theoretical model (both analytical and numerical) was developed for transient nucleation in glass forming melts. The model, originally designed for isothermal conditions, was extended to continuous quenching. It is being applied to glass formation in various metallic and oxide systems. A further refinement will be the inclusion of diffusion controlled interfacial rearrangements governing the growth of the crystal embryos.

Spaepen, F.↗
NASA NTRS1984

Crystal nucleation and glass formation in metallic alloy melts

Homogeneous nucleation, containerless solidification, and bulk formation of metallic glasses are discussed. Homogeneous nucleation is not a limiting factor for metallic glass formation at slow cooling rates if the reduced glass transition temperature is high enough. Such glasses can be made in bulk if heterogeneous nucleants are removed. Containerless processing eleminates potential sources of nucleants, but as drop tube experiments on the Pd-Si alloys show, the free surface may still be a very effective heterogeneous nucleant. Combination of etching and heating in vacuum or fluxing can be effective for cleaning fairly large ingots of nucleants. Reduced gravity processing has a potentially useful role in the fluxing technique, for example to keep large metallic ingots surrounded by a low density, low fluidity flux if this proved difficult under ground conditions. For systems where heterogeneous nucleants in the bulk of the ingot need gravity to segregate to the flux-metal interface, reduced gravity processing may not be appropriate for bulk glass formation.

Spaepen, F.↗
NASA NTRS1985

Development of a carbon formation reactor for carbon dioxide reduction

Applied research, engineering development, and performance evaluation were conducted on a process for formation of dense carbon by pyrolysis of methane. Experimental research showed that dense (0.7 to 1.6 g/cc bulk density and 1.6 to 2.2 g/cc solid density) carbon can be produced by methane pyrolysis in quartzwool-packed quartz tubes at temperatrues of 1100 to 1300 C. This result supports the condensation theory of pyrolytic carbon formation from gaseous hydrocarbons. A full-scale Breadboard Carbon Formation Reactor (CFR) was designed, fabricated, and tested at 1100 to 1200 C with 380 to 2280 sccm input flows of methane. Single-pass conversion of methane to carbon ranged from 60 to 100 percent, with 89 percent average conversion. Performance was projected for an Advanced Carbon Reactor Subsystem (ACRS) which indicated that the ACRS is a viable option for management of metabolic carbon on long-duration space missions.

Noyes, G.↗
NASA NTRS1986

Isotopic, petrologic and biogeochemical investigations of banded iron-formations

It is recognized that the first occurrence of banded iron-formations (BIFs) clearly predates biological oxygenation of the atmosphere-hydrosphere system and that their last occurrences extend beyond plausible dates of pervasive biological oxygenation. For this reason, and because enormous quantities of oxidizing power have been sequestered in them, it is widely thought that these massive, but enigmatic, sediments must encode information about the mechanism and timing of the rise of atmospheric O2. By coupling isotopic analyses of iron-formation carbonates with biogeochemical and petrologic investigations, we are studying (1) the mechanism of initial sedimentation of iron; (2) the role of iron in microbially mediated diagenetic processes in fresh iron-formation sediments; and (3) the logical integration of mechanisms of deposition with observed levels of banding. Thus far, it has been shown that (1) carbonates in BIFs of the Hamersley Group of Western Australia are isotopically inhomogenous; (2) the nature and pattern of isotopic ordering is not consistent with a metamorphic origin for the overall depletion of C-13 observed in the carbonates; (3) if biological, the origin of the C-13 depleted carbonate could be either respiratory or fermentative; (4) iron may have been precipitate d as Fe(3+), then reduced to Fe(2+) within the sediment; and (5) sedimentary biogeochemical systems may have been at least partially closed to mass transport of carbonate species.

Hayes, J. M.↗
NASA NTRS1985

Protostellar disks and star formation

The status of theoretical work on protostellar disks is reviewed. Accretion disk theory and its application to models of the solar nebula and protostellar disks are discussed. A unified view of the process of star formation is presented, starting from the evolution of molecular clouds, and leading naturally to the formation of protostellar disks. The models used to describe this process are idealized, but are believed to provide good prototypes that well represent the essential hydromagnetic phenomena involved in star and disk formation. Several possible evolutionary paths and final configurations are qualitatively discussed, showing how the outcomes depend on the relative efficiencies of various angular momentum transport processes.

Cassen, P.↗
NASA NTRS1986

The origin of dwarf galaxies, cold dark matter, and biased galaxy formation

A reexamination is conducted of the formation of dwarf, diffuse, metal-poor galaxies due to supernova-driven winds, in view of data on the systematic properties of dwarfs in the Local Group and Virgo Cluster. The critical condition for global gas loss as a result of the first burst of star formation is that the virial velocity lie below an approximately 100 km/sec critical value. This leads, as observed, to two distinct classes of galaxies, encompassing the diffuse dwarfs, which primarily originate from typical density perturbations, and the normal, brighter galaxies, including compact dwarfs, which can originate only from the highest density peaks. This furnishes a statistical biasing mechanism for the preferential formation of bright galaxies in denser regions, enhancing high surface brightness galaxies' clustering relative to the diffusive dwarfs.

Dekel, A.↗
NASA NTRS1986

Theoretical analysis of isotope effects on ozone formation in oxygen photochemistry

In situ measurements of stratospheric ozone and laboratory studies of ozone production in electric discharge through oxygen have shown previously that ozone containing heavy isotopes of oxygen (O-17, O-18) may be formed preferentially. In order to assess the relevance of thee latter experiment to the stratospheric measurements, detailed understanding of the effect of isotopic substitution on the O3 formation reaction O + O2 + M yields O3 + M and on the O atom exchange reaction O + O2 + O yields O2 + O is necessary. In this work, an estimate of the effect of isotopic substitution on the recombination rate is made by us of approximate dynamical theories and statistical mechanics. The results indicate the possibility of isotope effects on the O + O2 recombination rate of the order of several percent at stratospheric temperatures. In general, recombination reactions involving heavy (mass 49, 50) O3 formation are found to be slower than the reaction leading to normal (mass 48) O3 formation. The calculated isotope effects are sufficiently small that the uncertainties in the model input and the approximations in the dynamical theories will probably make the quantitative nature of these results subject to considerable uncertainty. This isotope effect should not be observable in the atmosphere given the precision of the current measurements but may be crucial in the understanding of the laboratory experiments, where observed enhancements are only of the order of several percent. Possible reasons for this discrepancy between the observed enhancement and predicted depletion are presented.

Kaye, J. A.↗
NASA NTRS1986

Generation of microwave background fluctuations from nonlinear perturbations at the era of galaxy formation

The production of temperature distortions of the microwave background by primordial galaxy formation is investigated theoretically. The temperature anisotropies induced by the presence of hot ionized gas during the formation of structure are roughly approximated and found to be greater than the initial anisotropies predicted by hierarchical models, and close to the present upper limit (delta (T/T = about 0.00001 at angular scale 1 arcmin) for standard cold-dark-matter models with Omega(0) = Omega(b) = H/(100 km/s) = 1. It is suggested that sensitive small-scale microwave-fluctuation measurements can impose significant constraints on models of primordial galaxy formation.

Ostriker, J. P.↗
NASA NTRS1986

Supershells and propagating star formation

Correlated supernovae from an OB association can carve large cavities (greater than 100 pc) in the interstellar medium (ISM), and can punch holes completely through the disk of a spiral galaxy. Supernova remnant energy within such a cavity is thermalized before the shock reaches the supershell. Thus stellar wind theory may be used to model these superbubbles. We describe how the evolution of the superbubble depends on the density distribution of the galactic disk gas and the rate of supernovae in the OB association. At a radius of 100 to 300 pc, the supershell becomes gravitationally unstable, forming giant molecular clouds which are the sites for new star formation. This gravitational instability of the supershells provides a physical mechanism for propagating star formation and may account for the observation of bursts of star formation in galaxies.

Maclow, M. M.↗
NASA NTRS1986

Formation of active region and quiescent prominence magnetic field configurations

To investigate the formation of prominences, researchers studied chromospheric mass injection into an overlying coronal dipole magnetic field using a 2-D ideal magnetohydrodynamic (MHD) numerical model. Researchers propose that active region prominences are formed by chromospheric plasmas injected directly into the overlying coronal magnetic field and that quiescent prominences are formed by plasmas evaporated at the interface between spicules and corona. Hence, for the simulation of an active region prominence magnetic field we inject the mass from one side, but use a symmetric mass injection to form a quiescent prominence field configuration. Researchers try to find optimum conditions for the formation of Kippenhahn-Schuluter(K-S)type field configuration for stable support of the injection plasmas. They find that the formation of K-S type field configuration by mass injection requires a delicate balance between injection velocity, density, and overlying magnetic fields. These results may explain why a prominence does not form on every neutral line.

An, C.-H.↗
NASA NTRS1987

Star formation in the large Magellanic cloud

What role the Large Magellanic Cloud (LMC), a dwarf irregular galaxy, plays in understanding infrared luminous galaxies is discussed. There are two main reasons the LMC may prove helpful. One, the LMC is only 55 kpc away, very nearby compared to much rarer high luminosity systems. Second, the environment in the LMC is distinctly different than in the Milky Way, at least those parts of the Milky Way interior to the sun, where most of the studies of massive star formation were concentrated. The LMC is an interacting system with a large amount of neutral hydrogen that is pushed around by the galaxy's encounter with the Milky Way. Perhaps a good understanding of star formation process in the LMC will provide guidance in the study of the infrared luminous galaxies. Two questions which will be addressed are: how is star formation in the LMC similar to the Milky Way Galaxy, and how is it different?

Jones, Terry Jay↗
NASA NTRS1987

Efficient star formation in the bright bar of M83

The bright molecular bar in M83 was detected standing out as a 100% enhancement of molecular emission with respect to the off-bar emission at the same radii. The spatial variations in the star formation efficiency, as traced by H alpha emission and the surface density of the interstellar gas, in M83 and M51 were compared. Both the central bar of M83 and the spiral arms of M51 are regions characterized by high massive star formation rates. For M83, it is ascribed that both the gas surface density and the star formation efficiency are high to the hydrodynamics of the central region.

Lord, S. D.↗
NASA NTRS1987

Nuclear star formation on 100 parsec scales: 10" resolution radio continuum, HI and CO observations

A program of radio line and continuum studies of star formation in nearby spiral galaxies is reported. The objective is a search for hot gas and peculiar dynamics in spiral nuclei with 10" to 30" angular resolution. Vigorous star formation is found to be a common phenomenon in the inner kpc of spirals. Arcsecond resolution observations of radio continuum emission at 6 and 2 cm were used to separate the thermal and nonthermal radio components. It was found that thermal and nonthermal emission are well mixed even on sizescales of 10 pc. To understand the reason for the increased level of star formation activity in spiral nuclei, HI and CO emission in these galaxies is studied. The CO transition was detected in M51, M82, NGC 253, NGC 6946 and IC 342 with T sub a approx. 0.5 to 2.0 K, at 20" angular resolution. The dynamics and spatial distribution of nuclear gas are being studied using VLA HI maps with 30" synthesized beams. Evidence for noncircular motions in HI was found in the nucleus of IC 342.

Turner, Jean L.↗
NASA NTRS1987

Induced star formation in interacting galaxies

Measurements of H alpha emission line fluxes and FIR fluxes in approx. 100 interacting spirals were used to investigate the effects of close tidal interactions on the disk and nuclear star formation rates in galaxies. Two samples of interacting spirals were studied, a complete sample of close pairs, and a set of strongly perturbed systems from the Arp atlas. Both the integrated H alpha luminosities and FIR luminosities are enhanced in the interacting galaxies, indicating that the encounters indeed trigger massive star formation in many cases. The response of individual galaxies is highly variable, however. A majority of the interacting spirals exhibit normal star formation rates, while a small fraction are undergoing bursts with luminosities which are rarely, if ever, observed in noninteracting systems. Virtually all of the latter are in the Arp sample, indicating that the Arp atlas is heavily biased to the most active star forming systems.

Kennicutt, R. C.↗
NASA NTRS1987

Cloud fluid models of gas dynamics and star formation in galaxies

The large dynamic range of star formation in galaxies, and the apparently complex environmental influences involved in triggering or suppressing star formation, challenges the understanding. The key to this understanding may be the detailed study of simple physical models for the dominant nonlinear interactions in interstellar cloud systems. One such model is described, a generalized Oort model cloud fluid, and two simple applications of it are explored. The first of these is the relaxation of an isolated volume of cloud fluid following a disturbance. Though very idealized, this closed box study suggests a physical mechanism for starbursts, which is based on the approximate commensurability of massive cloud lifetimes and cloud collisional growth times. The second application is to the modeling of colliding ring galaxies. In this case, the driving processes operating on a dynamical timescale interact with the local cloud processes operating on the above timescale. The results is a variety of interesting nonequilibrium behaviors, including spatial variations of star formation that do not depend monotonically on gas density.

Struck-Marcell, Curtis↗
NASA NTRS1987

Star formation around active galactic nuclei

Active galactic nuclei (Seyfert nuclei and their relatives) and intense star formation can both deliver substantial amounts of energy to the vicinity of a galactic nucleus. Many luminous nuclei have energetics dominated by one of these mechanisms, but detailed observations show that some have a mixture. Seeing both phenomena at once raises several interesting questions: (1) Is this a general property of some kinds of nuclei? How many AGNs have surround starbursts, and vice versa? (2) As in 1, how many undiscovered AGNs or starbursts are hidden by a more luminous instance of the other? (3) Does one cause the other, and by what means, or do both reflect common influences such as potential well shape or level of gas flow? (4) Can surrounding star formation tell us anything about the central active nuclei, such as lifetimes, kinetic energy output, or mechanical disturbance of the ISM? These are important points in the understanding of activity and star formation in galactic nuclei. Unfortunately, the observational ways of addressing them are as yet not well formulated. Some preliminary studies are reported, aimed at clarifying the issues involved in study of the relationships between stellar and nonstellar excitement in galactic nuclei.

Keel, William C.↗
NASA NTRS1987

Supershells and propagating star formation

Stellar winds and repeated supernovae from an OB association will create a cavity of coronal gas in the interstellar medium, with radius greater than 100 pc, surrounded by a dense, expanding shell of cool interstellar gas. If the association has a typical initial mass function, its supernovae explosions will inject energy into the supershell at a nearly constant rate for about 50 Myr. The supershell loses its interior pressure and enters the snowplow phase when radiative cooling becomes important or when the shell bursts through the gas disk of a galaxy, typically after a few times 10 Myr and with a radius of 100-300 pc. At approximately the same time, the supershell becomes gravitationally unstable, forming giant molecular clouds which are sites for new star formation. There is widespread evidence for supershells in the Galaxy and other spiral and irregular galaxies from 21-cm emission-line surveys, optical emission-line surveys, and studies of supernova remnants. The gravitational instability of the supershells provides a physical mechanism for induced star formation and may account for bursts of star formation, especially in irregular galaxies.

Mccray, Richard↗
NASA NTRS1988

Innovative design of composite structures: Further studies in the use of a curvilinear fiber format to improve structural efficiency

Further studies to determine the potential for using a curvilinear fiber format in the design of composite laminates are reported. The curvilinear format is in contrast to the current practice of having the fibers aligned parallel to each other and in a straight line. The problem of a plate with a central circular hole is used as a candidate problem for this study. The study concludes that for inplane tensile loading the curvilinear format is superior. The limited results to date on compression buckling loads indicate that the curvilinear designs are poorer in resistant buckling. However, for the curvilinear design of interest, the reduction in buckling load is minimal and so overall there is a gain in considering the curvilinear design.

Hyer, Michael W.↗