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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29

HydroMINE: Simple, Modular and Scalable (Final Scientific/Technical Report)

Hydromine is a novel extremely versatile solution to hydrokinetics energy generation, where the external water flow facing energy sweeping area (&structure) is completely passive. One or multiple Hydromine units can easily deploy from a multitude of floating or stationary marine structures, opening a multitude of application and use cases. Proposing Hydromine, it was initially found that the concept could easily scale into all of the four areas of ARPA-E SHARKS cases, as well as other applications, this is illustrated in Figure 1. Also, the relatively aggressive cost of energy targets of the program could be met in the conceptual phase.

13 HYDRO ENERGY↗

Quantifying Energy Storage Density Utilization Trends in Redox Flow Battery Chemistries

The transition to new energy resources is driving the need for efficient energy storage. Redox flow batteries (RFBs) are a promising solution due to their flexible design and safer materials, particularly for long-duration storage applications. Despite these advantages, RFB technologies still have considerable room for growth in terms of utilizing all of their available energy storage density. Herein, we assess RFB energy storage density utilization trends for multiple chemistries by accounting for their unique thermodynamic limits, energy efficiencies, and charge capacity constraints. Of the RFBs chemistries analyzed, most still use less than 60% of their theoretical energy storage capacity. The conventional all-vanadium RFB was the closest to its thermodynamic limit available. Moreover, the volumetric footprint and electrolyte cost analyses demonstrate the real-world implications of these inefficiencies. This analysis further indicates that future studies would benefit from clearer reporting of two key quantities: discharge efficiency, which is more directly tied to practically recoverable energy density than round-trip energy efficiency, and state-of-charge or capacity-utilization limits, which govern access to theoretical storage capacity. More consistent reporting of these factors would improve the accuracy and comparability of energy storage utilization analyses across RFB chemistries.

battery energy storage↗

Multi-Energy Microgrid Planning Considering Heat Flow Dynamics

In this paper, we present a multi-energy microgrid optimal planning method, considering the intra-hour dynamics of the heating system as constraints of the energy dispatch, and consequently of the sizing of the Combined Heat and Power units. The fixed-mass flow rate method and finite difference technique are applied to linearize the dynamic constraints. Moreover, to determine the values of the mass flow rates, a critical scenario representing the slowest heat dynamic process is put forward. Finally, a realistic microgrid case study is presented to illustrate the effect of considering the heat flow dynamics in the overall solution.

24 POWER TRANSMISSION AND DISTRIBUTION↗

The total flow concept for geothermal energy conversion

A geothermal development project has been initiated at the Lawrence Livermore Laboratory (LLL) to emphasize development of methods for recovery and conversion of the energy in geothermal deposits of hot brines. Temperatures of these waters vary from 150 C to more than 300 C with dissolved solids content ranging from less than 0.1% to over 25% by weight. Of particular interest are the deposits of high-temperature/high-salinity brines, as well as less saline brines, known to occur in the Salton Trough of California. Development of this resource will depend on resolution of the technical problems of brine handling, scale and precipitation control, and corrosion/erosion resistant systems for efficient conversion of thermal to electrical energy. Research experience to date has shown these problems to be severe. Hence, the LLL program emphasizes development of an entirely different approach called the Total Flow concept.

Austin, A. L.↗

Graphical Gaussian Process Regression Model for Aqueous Solvation Free Energy Prediction of Organic Molecules in Redox Flow Battery

The solvation free energy of organic molecules is a critical parameter in determining emergent properties such as solubility, liquid-phase equilibrium constants, and pKa and redox potentials in an organic redox flow battery. In this work, we present a machine learning (ML) model that can learn and predict the aqueous solvation free energy of an organic molecule using Gaussian process regression method based on a new molecular graph kernel. To investigate the performance of the ML model on electrostatic interaction, the nonpolar interaction contribution of solvent and the conformational entropy of solute in solvation free energy, three data sets with implicit or explicit water solvent models, and contribution of conformational entropy of solute are tested. We demonstrate that our ML model can predict the solvation free energy of molecules at chemical accuracy with a mean absolute error of less than 1 kcal/mol for subsets of the QM9 dataset and the Freesolv database. To solve the general data scarcity problem for a graph-based ML model, we propose a dimension reduction algorithm based on the distance between molecular graphs, which can be used to examine the diversity of the molecular data set. It provides a promising way to build a minimum training set to improve prediction for certain test sets where the space of molecular structures is predetermined.

25 ENERGY STORAGE↗

Flow Cage Assemblies

Apparatus, systems and methods for implementing flow cages and flow cage assemblies in association with high pressure fluid flows and fluid valves are provided. Flow cages and flow assemblies are provided to dissipate the energy of a fluid flow, such as by reducing fluid flow pressure and/or fluid flow velocity. In some embodiments the dissipation of the fluid flow energy is adapted to reduce erosion, such as from high-pressure jet flows, to reduce cavitation, such as by controllably increasing the flow area, and/or to reduce valve noise associated with pressure surge.

Sherrit, Stewart↗

Generalization and extension of the law of acoustic energy conservation in a nonuniform flow

An exact conservation equation is derived which generalizes the familiar acoustic energy equations. The new relation is valid for arbitrary disturbances to a viscous, compressible flow. It is suggested by a development of the acoustic energy equation by means of a regular perturbation expansion of the general energy equation of fluid mechanics. A perturbation energy density and flux are defined and identified as the exact physical quantities whose leading order perturbation representations are the usual acoustic energy density and flux. The conservation equation governing the perturbation energy quantities is shown to yield previously known results for several special cases.

Myers, M. K.↗

Initial Flow Matching Results of MHD Energy Bypass on a Supersonic Turbojet Engine Using the Numerical Propulsion System Simulation (NPSS) Environment

Preliminary flow matching has been demonstrated for a MHD energy bypass system on a supersonic turbojet engine. The Numerical Propulsion System Simulation (NPSS) environment was used to perform a thermodynamic cycle analysis to properly match the flows from an inlet to a MHD generator and from the exit of a supersonic turbojet to a MHD accelerator. Working with various operating conditions such as the enthalpy extraction ratio and isentropic efficiency of the MHD generator and MHD accelerator, interfacing studies were conducted between the pre-ionizers, the MHD generator, the turbojet engine, and the MHD accelerator. This paper briefly describes the NPSS environment used in this analysis and describes the NPSS analysis of a supersonic turbojet engine with a MHD generator/accelerator energy bypass system. Results from this study have shown that using MHD energy bypass in the flow path of a supersonic turbojet engine increases the useful Mach number operating range from 0 to 3.0 Mach (not using MHD) to an explored and desired range of 0 to 7.0 Mach.

Benyo, Theresa L.↗

Rotational-translational energy transfer in rarefied nonequilibrium flows

A new model for simulating the transfer of energy between the translational and rotational modes is derived for a homogeneous gas of diatomic molecules. The model has been developed specifically for use in discrete particle simulation methods where molecular motion and intermolecular collisions are treated at the molecular level. A temperature dependence is introduced which has been predicted by theory and observed in experiment. The new model is applied to the relaxation of rotational temperature, and is found to produce significant differences in comparison with the model normally employed at both high and low temperatures. Calculations have also been performed for a Mach 7 normal shock wave.

Boyd, Iain D.↗

Effects of ion trapping and fluctuations of electron temperature and plasma flow on cross-beam energy transfer

The influences of ion trapping and fluctuations of electron temperature and plasma flow on cross-beam energy transfer (CBET) are examined using two- and three-dimensional particle-in-cell simulations in parameter regimes relevant to recent CBET experiments at the OMEGA laser facility. In mid-Z plasma irradiated by an intense pump beam and weaker probe beam, ion trapping, collisional de-trapping, and plasma flow induced by thermal effects are shown to affect the CBET gain. Ion trapping can enhance or detune the CBET resonance [Nguyen et al., Phys. Plasmas 28, 082705 (2021)]. Collisional de-trapping can affect the CBET gain at low seed beam intensity near the onset threshold for ion trapping. Thermal-effects-induced flow can also detune the CBET resonance at a level comparable to that from trapping at low seed beam intensity. As a consequence, the CBET gain is sensitive to collisions and dimensionality at low seed beam intensity where ion trapping is weak but is insensitive to collisions and dimensionality at high seed beam intensity where ion trapping is strong.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Imaging nuclear shape through anisotropic and radial flow in high-energy heavy-ion collisions

Most atomic nuclei exhibit ellipsoidal shapes characterized by quadrupole deformation β 2 and triaxiality γ, and sometimes even a pear-like octupole deformation β 3 . The STAR experiment introduced a new ‘imaging-by-smashing’ technique to image the nuclear global shape by colliding nuclei at ultra-relativistic speeds and analyzing outgoing debris. Features of nuclear shape manifest in collective observables like anisotropic flow vn and radial flow via mean transverse momentum [p T ]. We present new measurements of the variances of v n (n = 2, 3, and 4) and [p T ], and the covariance of $v$$^{2}_{n}$ with [p T ], in collisions of highly deformed 238 U and nearly spherical 197 Au. Ratios of these observables between the two systems effectively suppress common final-state effects, isolating the strong impact of uranium’s deformation. By comparing results with state-of-the-art hydrodynamic model calculations, we extract β 2U and γ U values consistent with those deduced from low-energy nuclear structure measurements. Measurements of v 3 and its correlation with [p T ] also provide the first experimental suggestion of a possible octupole deformation for 238 U. These findings provide significant support for using high-energy collisions to explore nuclear shapes on femtosecond timescales, with implications for both nuclear structure and quark-gluon plasma studies.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

A new energy transfer model for turbulent free shear flow

A new model for the energy transfer mechanism in the large-scale turbulent kinetic energy equation is proposed. An estimate of the characteristic length scale of the energy containing large structures is obtained from the wavelength associated with the structures predicted by a weakly nonlinear analysis for turbulent free shear flows. With the inclusion of the proposed energy transfer model, the weakly nonlinear wave models for the turbulent large-scale structures are self-contained and are likely to be independent flow geometries. The model is tested against a plane mixing layer. Reasonably good agreement is achieved. Finally, it is shown by using the Liapunov function method, the balance between the production and the drainage of the kinetic energy of the turbulent large-scale structures is asymptotically stable as their amplitude saturates. The saturation of the wave amplitude provides an alternative indicator for flow self-similarity.

Liou, William W.-W.↗

High-energy and low-cost membrane-free chlorine flow battery

Abstract Grid-scale energy storage is essential for reliable electricity transmission and renewable energy integration. Redox flow batteries (RFB) provide affordable and scalable solutions for stationary energy storage. However, most of the current RFB chemistries are based on expensive transition metal ions or synthetic organics. Here, we report a reversible chlorine redox flow battery starting from the electrolysis of aqueous NaCl electrolyte and the as-produced Cl 2 is extracted and stored in the carbon tetrachloride (CCl 4 ) or mineral spirit flow. The immiscibility between the CCl 4 or mineral spirit and NaCl electrolyte enables a membrane-free design with an energy efficiency of >91% at 10 mA/cm 2 and an energy density of 125.7 Wh/L. The chlorine flow battery can meet the stringent price and reliability target for stationary energy storage with the inherently low-cost active materials (~$5/kWh) and the highly reversible Cl 2 /Cl − redox reaction.

25 ENERGY STORAGE↗

Transport of energy by disturbances in arbitrary steady flows

An exact equation governing the transport of energy associated with disturbances in an arbitrary steady flow is derived. The result is a generalization of the familiar concept of acoustic energy and is suggested by a perturbation expansion of the general energy equation of fluid mechanics. A disturbance energy density and flux are defined and identified as exact fluid dynamic quantities whose leading-order regular perturbation representations reduce in various special cases to previously known results. The exact equation on disturbance energy is applied to a simple example of nonlinear wave propagation as an illustration of its general utility in situations where a linear description of the disturbance is inadequate.

Myers, M. K.↗

Precision Tests of the Nonlinear Mode Coupling of Anisotropic Flow via High-Energy Collisions of Isobars

Valuable information on dynamics of expanding fluids can be inferred from the response of such systems to perturbations in their initial geometry. We apply this technique in high-energy 96 Ru+ 96 Ru and 96 Zr+ 96 Zr collisions to scrutinize the expansion dynamics of the quark-gluon plasma, where the initial geometry perturbations are sourced by the differences in deformations and radial profiles between 96 Ru and 96 Zr, and the collective response is captured by the change in anisotropic flow V n between the two collision systems. Using a transport model, we analyze how the nonlinear coupling between lower-order flow harmonics V 2 and V 3 to the higher-order flow harmonics V 4 and V 5 , expected to scale as V 4 NL = χ 4 V 2 2 and V 5NL = χ 5 V 2 V 3 , gets modified as one moves from 96 Ru+ 96 Ru to 96 Zr+ 96 Zr systems. We find that these scaling relations are valid to high precision: variations of order 20% in V 4NL and V 5NL due to differences in quadrupole deformation, octupole deformation, and nuclear skin modify χ 4 and χ 5 by about 1–2%. Percent-level deviations are however larger than the expected experimental uncertainties and could be measured. Therefore, collisions of isobars with different nuclear structures are a unique tool to isolate subtle nonlinear effects in the expansion of the quark-gluon plasma that would be otherwise impossible to access in a single collision system.

Physics↗

A hybrid porous model for full reactor core scale CFD investigation of a prismatic HTGR

Three-dimensional (3-D) Computational Fluid Dynamics (CFD) analysis of a whole nuclear reactor core is a tremendous challenge due to the large geometric volume and complex structures. Here, this research presents a hybrid porous (HP) model to simplify a prismatic High Temperature Gas-cooled Reactor (HTGR) core, so 3-D CFD investigation can be performed on a full reactor core scale. In the HP model, the prototypic small coolant channels in the nuclear fuel blocks are lumped together to form multiple equivalent large coolant channels, and then the porous medium flow model is applied to each of them. Therefore, heat transfer in fuel blocks is computed by a hybrid combination of solid energy and porous flow energy equations. The similarity between the HP model and prototypic model is achieved by deriving the porous flow permeability, inertial resistance factor, and artificial thermophysical properties. Compared with the widely used whole porous (WP) flow model, the HP model preserves more realistic geometric structures, and therefore more accurate physical processes. The General Atomics' Modular High Temperature Gas-cooled Reactor (MHTGR) design was chosen as a prototype to demonstrate the methodology. Simulations were performed using the prototypic CFD model and HP model at steady-state forced circulation, steady-state natural circulation, and transient conditions that correspond to normal operation, extended period of pressurized cool down, and short-term transients after reactor shutdown, respectively. The comparison shows good agreement between the HP model and prototypic model in the maximum fuel temperature, average solid temperature, and helium flow rate, which demonstrates the potential applicability of the HP model for a full reactor core scale simulation in the future. As a benefit, the HP model reduces the mesh quantity by a factor of 50 from a prototypic model. Correspondingly, the computation time was reduced by a factor of at least 30.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Directing Energy Transfer in Halide Perovskite–Chromophore Hybrid Assemblies

Directing the flow of energy and the nature of the excited states that are produced in nanocrystal–chromophore hybrid assemblies is crucial for realizing their photocatalytic and optoelectronic applications. Using a combination of steady-state and time-resolved absorption and photoluminescence (PL) experiments, we have probed the excited-state interactions in the CsPbBr 3 –Rhodamine B (RhB) hybrid assembly. PL studies reveal quenching of the CsPbBr 3 emission with a concomitant enhancement of the fluorescence of RhB, indicating a singlet-energy-transfer mechanism. Transient absorption spectroscopy shows that this energy transfer occurs on the ~200 ps time scale. To understand whether the energy transfer occurs through a Förster or Dexter mechanism, we leveraged facile halide-exchange reactions to tune the optical properties of the donor CsPbBr 3 by alloying with chloride. This allowed us to tune the spectral overlap between the donor CsPb(Br 1–x Cl x ) 3 emission and acceptor RhB absorption. For CsPbBr 3 -RhB, the rate constant for energy transfer (k ET ) agrees well with Förster theory, whereas alloying with chloride to produce chloride-rich CsPb(Br 1–x Cl x ) 3 favors a Dexter mechanism. These results highlight the importance of optimizing both the donor and acceptor properties to design light-harvesting assemblies that employ energy transfer. Furthermore, the ease of tuning optical properties through halide exchange of the nanocrystal donor provides a unique platform for studying and tailoring excited-state interactions in perovskite–chromophore assemblies.

14 SOLAR ENERGY↗