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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Second Generation Novel High Temperature Commercial Receiver & Low Cost High Performance Mirror Collector for Parabolic Solar Trough

Norwich Technologies (NT) is developing a disruptively superior solar field for trough concentrating solar power (CSP). Troughs are the leading CSP technology (85% of installed capacity), being highly deployable and similar to photovoltaic (PV) systems for siting. NT has developed the SunTrap receiver, a disruptive alternative to vacuum-tube concentrating solar power (CSP) receivers, a market currently dominated by the Schott PTR-70. The SunTrap receiver will (1) operate at higher temperature (T) by using an insulated, recessed radiation-collection system to overcome the energy losses that plague vacuum-tube receivers at high T, (2) decrease acquisition costs via simpler structure, and (3) dramatically increase reliability by eliminating vacuum. It offers comparable optical efficiency with thermal loss reduction from ≥ 26% (at presently standard T) to ≥ 55% (at high T), lower acquisition costs, and near-zero O&M costs.

14 SOLAR ENERGY↗
DOE OSTI2016

Supercritical Carbon Dioxide Power Generation System Definition: Concept Definition and Capital Cost Estimate

The Department of Energy’s (DOE’s) Office of Renewable Power (ORP) has been tasked to provide effective program management and strategic direction for all of the DOE’s Energy Efficiency & Renewable Energy’s (EERE’s) renewable power programs. The ORP’s efforts to accomplish this mission are aligned with national energy policies, DOE strategic planning, EERE’s strategic planning, Congressional appropriation, and stakeholder advice. ORP is supported by three renewable energy offices, of which one is the Solar Energy Technology Office (SETO) whose SunShot Initiative has a mission to accelerate research, development and large scale deployment of solar technologies in the United States. SETO has a goal of reducing the cost of Concentrating Solar Power (CSP) by 75 percent of 2010 costs by 2020 to reach parity with base-load energy rates, and 30 percent further reductions by 2030. The SunShot Initiative is promoting the implementation of high temperature CSP with thermal energy storage allowing generation during high demand hours. The SunShot Initiative has funded significant research and development work on component testing, with attention to high temperature molten salts, heliostats, receiver designs, and high efficiency high temperature supercritical CO 2 (sCO2) cycles. DOE retained Black & Veatch to support SETO’s SunShot Initiative for CSP solar power tower technology in the following areas: 1. Concept definition, including costs and schedule, of a flexible test facility to be used to test and prove components in part to support financing. 2. Concept definition, including costs and schedule, of an integrated high temperature molten salt (MS) facility with thermal energy storage and with a supercritical CO 2 cycle generating approximately 10MWe. 3. Concept definition, including costs and schedule, of an integrated high temperature falling particle facility with thermal energy storage and with a supercritical CO 2 cycle generating approximately 10MWe. This report addresses the concept definition of the sCO2 power generation system, a sub-set of items 2 and 3 above. Other reports address the balance of items 1 to 3 above as well as the MS/sCO2 integrated 10MWe facility, Item 2.

14 SOLAR ENERGY↗
DOE OSTI2016

On the Path to SunShot - Emerging Opportunities and Challenges in U.S. Solar Manufacturing

Innovation-driven cost and performance improvements, along with strong projected solar demand in the United States and across the Americas, could increase the attractiveness of U.S.-based solar manufacturing (see Chung et al. 2016). Although improvements to standard PV modules have produced deep cost reductions over the past 5 years, the returns on such incremental improvements appear to be diminishing, and more dramatic innovations in module design and manufacturing are required to continue along the path of rapid progress. At the same time, major opportunities exist for innovation to unlock the potential of CSP technologies. This need for innovation could benefit U.S. PV and CSP manufacturers. The United States has been rated one of the world’s most competitive and innovative countries as well as one of the best locations for PV manufacturing. It is a global leader in PV and CSP R&D and patent production, and U.S. PV manufacturers are already pursuing highly differentiated innovations.

14 SOLAR ENERGY↗
DOE OSTI2018

A Systems Biology and Pond Culture-based Understanding and Improvement of Metabolic Processes Related to Productivity in Diverse Microalgal Classes for Viable Biofuel Production

The overarching goal of this project was to understand and manipulate fundamental molecular mechanisms involved in maximizing growth rate and lipid accumulation in diverse classes of microalgae under authentic diurnal conditions to enhance production capabilities for biofuels. The research was aimed at filling two critical knowledge gaps by addressing fundamental cellular issues that govern growth and fuel molecule accumulation in conjunction with realistic climate-simulated cultivation: 1) The insufficient understanding of the effect of metabolic topology on cellular carbon partitioning and its regulation with regards to productivity. 2) The understudied effect of the diurnal and cell cycles on cellular metabolism, resource allocation, and resource mobilization under simulated production conditions. To unravel broader as well as lineage-specific regulatory mechanisms that determine productivity, we compared green algae with diatoms. Complementing the systems approach with a pond-based cultivation method under authentic diurnal conditions, we anticipated an understanding of how the effect of diurnal and cell cycles affects growth and lipid productivity. Elucidation of the topology and regulation of relevant metabolic networks in proposed new model organisms was expected to enable improvements in functional capabilities and biosynthetic pathways. The major goals of the project were achieved by the following accomplishments. Genome assemblies and functional annotations for the green algae S. obliquus strain DOE0152Z and Coleastrella sp. strain DOE0202. Development of a metabolic map for the core carbon metabolism for S. obliquus. Analyzed the cellular topology for the core carbon network and proposed differences in core carbon metabolism for the Chlorophyceae versus the Trebouxiophyceae. Discovered the genes for enzymes involved in dicarboxylic acid metabolism and proposed the existence of C4-type metabolism for S. obliquus. Calculated the energy and reducing equivalencies for TAG and isoprenoid biosynthesis based on the core carbon network created in this project. Identified one newly created strain SOM-P004 (UV-Mutagenesis), which performed better at higher culture densities than wild type in LEAPS reactors under simulated environmental conditions. Results obtained within the course of this project were used in 2017 to apply for a Community Science Program (CSP) at the DOE Joint Genome Institute (JGI). The project (JGI Proposal Id: 503423) with the Title “Comparative genomics and germ plasm diversity in Acutodesmus, a green microalgal bioenergy feedstock candidate with potential for breeding and hybridization.” was selected for CSP 2018 for sequencing of up to 30 genomes of the alga A. obliquus (=S. obliquus). Our genome of the strain DOE0152Z serves as a reference for this new CSP project. Characterization of synchronized cultures of Cyclotella cryptica and the implications on productivity. Determination that some cellular pigments respond to light, but others to the cell cycle. Characterization of productivity of C. cryptica in PNNL ponds. Genome sequence and metabolic mapping of Marinichlorella kaistiae KAS603. Demonstration that some green algae store and utilize starch in the cytoplasm. Photorespiratory pathway clarified in T. pseudonana leading to a better understanding of carbon flux pathways in diatoms. Genome sequence determination, annotation, and comparison completed for C. cryptica, identifying potential metabolic differences that lead to high biomass and lipid accumulation ability for this species. Transcriptomic comparison of silicon (Si) and nitrogen (N) limited triacylglycerol accumulation in Cyclotella cryptica.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2018

Physics based Reliability Models for Supercritical CO 2 Turbomachinery Components

CSP plants using sCO 2 power cycle can potentially achieve high thermal conversion efficiency at low capital cost due to compact turbo-machinery and other components. An sCO 2 expander and improved heat exchanger is expected to provide a major stepping stone for achieving CSP power at $0.06/kW-hr LCOE, energy conversion efficiency > 50%, and total power block cost < $1,200/kW installed. Hybrid gas bearings (HGB) and Dry gas seals (DGS) are two key components that are critical for robust and efficient operation of future sCO 2 power cycles. From a system perspective, HGBs can provide substantial benefits (~3 to 5%) to the modular CSP operation, while use of DGSs limits the leakage losses as well as the windage losses in the generator and can increase overall generator efficiency by ~ 8%. The life limiting mechanisms of HGBs and DGSs in high pressure, high temperature sCO2 environment were not well understood and hence this program aims at developing physics-based performance prediction and life prediction models for these two components. The output of the performance models serves as input to the life models. The performance models were validated using experimental data and using data from literature. DGS and HGB models have shed light on some risks associated with its operation in sCO2 expander and will guide more robust designs tailored towards sCO 2 cycle applications. A DGS was tested in 1MWe sCO2 turbo expander to study its performance and validate the performance models. To understand the effect of high pressures, high temperatures and sCO 2 environment on crack initiation, crack propagation and LCF/HCF life of these components, a novel experimental setup was developed. The LCF test data was used to calibrate and validate the life prediction models. The effect of sCO 2 corrosion on the life of Ni-based super-alloys is quantified using long duration experiments. Advanced microstructure and spectroscopic analyses conducted shed light on some key differences between IN718 and IN617 in terms of oxidation morphology, chemical species diffusion and trapping, the formation of protective corrosion resistant layers and changes in surface properties. A novel crack initiation model was developed which takes into account strain distribution, temperature, hold times and activation energy at the gas-metal interface and predicts the number of cycles to initiate the crack in the Inconel alloy. An advanced 3D fracture mechanics-based crack propagation model was also developed which takes into account the transient loading mission of the component and predict how fast the crack will grow and what will be its final shape and size. High energy X-Ray tomography measurements were conducted to study and validate 3D morphology of crack growth inside the specimen. These two models along with chemical kinetics models obtained from corrosion tests can be combined to predict the total life of the component under given long term operating conditions. A Bayesian Hybrid Modeling (BHM) probabilistic framework was developed to quantify uncertainty in physics-based performance models and in crack initiation and crack propagation models, to calibrate the models and to validate the models with statistical confidence. Advanced coupled physics multi-phase flow models were developed to study condensation, boiling and phase change behavior of CO 2 under various sCO 2 turbomachinery and heat exchanger conditions. A novel experimental setup was also designed to observe phase change of CO 2 during its transition across liquid-gas-supercritical state lines.

14 SOLAR ENERGY↗
DOE OSTI2019

Physics based Reliability Models for Supercritical CO 2 Turbomachinery Components

CSP plants using sCO 2 power cycle can potentially achieve high thermal conversion efficiency at low capital cost due to compact turbo-machinery and other components. An sCO 2 expander and improved heat exchanger is expected to provide a major stepping stone for achieving CSP power at 0.06/kW-hr LCOE, energy conversion efficiency > 50 % ,and total power block cost< $1,200/kW installed. Hybrid gas bearings (HGB) and Dry gas seals (DGS) are two key components that are critical for robust and efficient operation of future sCO 2 power cycles. From a system perspective, HGBs can provide substantial benefits (~3 to 5%) to the modular CSP operation, while use of DGSs limits the leakage losses as well as the windage losses in the generator and can increase overall generator efficiency by ~ 8%. The life limiting mechanisms of HGBs and DGSs in high pressure, high temperature sCO 2 environment were not well understood and hence this program aims at developing physics-based performance prediction and life prediction models for these two components. The output of the performance models serves as input to the life models. The performance models were validated using experimental data and using data from literature. DGS and HGB models have shed light on some risks associated with its operation in sCO 2 expander and will guide more robust designs tailored towards sCO 2 cycle applications. A DGS was tested in 1MWe sCO 2 turbo expander to study its performance and validate the performance models. To understand the effect of high pressures, high temperatures and sCO 2 environment on crack initiation, crack propagation and LCF/HCF life of these components, a novel experimental setup was developed. The LCF test data was used to calibrate and validate the life prediction models. The effect of sCO 2 corrosion on the life of Ni-based super-alloys is quantified using long duration experiments. Advanced microstructure and spectroscopic analyses conducted shed light on some key differences between IN718 and IN617 in terms of oxidation morphology, chemical species diffusion and trapping, the formation of protective corrosion resistant layers and changes in surface properties. A novel crack initiation model was developed which takes into account strain distribution, temperature, hold times and activation energy at the gas-metal interface and predicts the number of cycles to initiate the crack in the Inconel alloy. An advanced 3D fracture mechanics-based crack propagation model was also developed which takes into account the transient loading mission of the component and predict how fast the crack will grow and what will be its final shape and size. High energy X-Ray tomography measurements were conducted to study and validate 3D morphology of crack growth inside the specimen. These two models along with chemical kinetics models obtained from corrosion tests can be combined to predict the total life of the component under given long term operating conditions. A Bayesian Hybrid Modeling (BHM) probabilistic framework was developed to quantify uncertainty in physics-based performance models and in crack initiation and crack propagation models, to calibrate the models and to validate the models with statistical confidence. Advanced coupled physics multi-phase flow models were developed to study condensation, boiling and phase change behavior of CO 2 under various sCO 2 turbomachinery and heat exchanger conditions. A novel experimental setup was also designed to observe phase change of CO 2 during its transition across liquid-gas-supercritical state lines.

14 SOLAR ENERGY↗
DOE OSTI2016

Degradation Mechanisms and Development of Protective Coatings for Thermal Energy Storage and High Temperature Fluid Containment Materials

This research addresses cost savings to achieve the SETO target of $15/kWh th for thermal energy storage and 6¢/kWh for levelized cost of energy. Next-generation solar power conversion systems require high-temperature, advanced fluids in the range of 600° to 900°C. The three major advanced fluid groups—supercritical CO 2 , liquid metal alloys, and molten salts—are very corrosive to common alloys used in vessels, heat exchangers, and piping at these temperatures. Understanding degradation mechanisms is essential for making recommendations on proper working conditions and suitable cost-effective coating materials for CSP applications at high temperatures. The implementation of the findings from this research will significantly reduce investment risk by increasing the lifetime of the CSP plant components. In the past, the majority of the hot corrosion evaluations have been performed for waste incinerators, gas turbine engines, and electric power generation (steam-generating equipment) applications for different materials, molten-salt systems, and coatings. Containment materials and resistant coatings for supercritical CO 2 , molten salts and liquid metal alloys have not being evaluated for CSP applications. We plan to understand the underlying degradation mechanisms to select protective approaches such as anodic passivation, cathodic protection, and coating designs.The novelty of the proposed research is the development of protective coatings and working conditions for materials in contact with high temperature TES and HTF. Current state-of-the-art materials and protection methods are non-existent. Novel approaches are: the use of graphite nanomaterials to enhance the non-wettability of the aggressive fluids with the coating; self-healing behavior of Si-coatings in liquid Al-Si alloys; anodic passivation in molten salts to protect metallic substrates and the modeling prediction of attack in liquid metal alloys.

14 SOLAR ENERGY↗
DOE OSTI2014

Low-cost self-cleaning reflector coatings for concentrating solar power collectors

One of the most significant maintenance problems and cost associated with CSP solar collectors is the soiling of the first surface of the solar radiation reflectors by the accumulation of sand, dust and other pollutants. According to Solar Power World, “a dust layer of one-seventh of an ounce per square yard decreases solar power conversion by 40 percent. In Arizona, dust is deposited each month at about 4 times that amount.” The optical performance of the CSP collectors is key to achieving low electricity costs, where a 1% increase in reflectance directly leads to a 1% reduction in LCOE. Self-cleaning (anti-soiling) and anti-reflection (AR) first surface reflector coatings are a viable solution to achieving high performance, low maintenance cost CSP electricity generation.

14 SOLAR ENERGY↗
DOE OSTI2020

High operating temperature heat transfer fluids for solar thermal power generation. Final report

This is the final technical report for the DOE MURI project on developing high-operating temperature heat transfer fluids for solar thermal power generation. This project aimed to evaluate liquid metals as a heat-transport fluid and potential energy storage medium for concentrated solar powered (CSP) systems. The project consisted of five phases, starting with fluid selection and screen and ending with potential CSP integration. The initial fluid selection arrived at heavy liquid metals as candidate fluids such as lead bismuth eutectic (LBE) as the prime liquid-alloy candidate to be studied, given the conditions above. Fifty-seven liquid compositions were initially identified with liquidus temperatures lower than 200°C, composed of elements that provide no driving force to the reduction of Cr 2 O 3 or Al 2 O 3 passivation layers in pipe material which is required for corrosion prevention. LBE was identified as the primary candidate fluid after these compositions were compared against computational thermodynamic modeling to screen all of the selected systems that would be compatible with our design objectives. Twenty-eight of these compositions were also investigated with the rapid characterization methods; the accuracies of the liquidus temperature and the specific heats predicted by the computations were better than 3 percent and 9 percent, respectively. We conducted numerus corrosion tests of various Fe-Cr-Al based steels in LBE and its variants at temperate as high as 800°C. It was found that minor additions to the liquid did not provide sufficient corrosion protection to warrant their use in real applications. Furthermore, we investigated the detailed mechanism of corrosion between heavy liquid metal and the pipe material at these very high temperatures. A liquid metal loop was constructed to operate at these high temperatures. The loop construction and operation lead to valuable lessons learned that will be needed for industrial scale loops. Furthermore, we learned that electromagnetic pumps at these extreme temperatures will have to be reengineered and redesigned to be used for CSP applications.

14 SOLAR ENERGY↗
DOE OSTI2020

Development of Tools Training and Outreach to Address Solar Glare and Flux-Related Avian Impacts

Millions of dollars and significant resources are being spent by developers of utility-scale solar photovoltaic (PV) and concentrating solar power (CSP) plants to address federal and local requirements regarding glare and avian hazards. Solar glare can occur from the glass surfaces of PV modules and from mirrors in CSP systems, which can produce safety and health risks for pilots, motorists, and residents located near these systems. In addition, concentrated solar flux at CSP plants has the potential to singe birds as they fly through regions of high solar flux. This work will develop tools to characterize and mitigate these potential hazards, which will address regulatory policies and reduce costs and efforts associated with the proposed deployment of gigawatts of solar energy systems throughout the nation. The development of standardized and publicly available tools to address these regulatory policies and ensure public and environmental safety is an appropriate role for the government.

14 SOLAR ENERGY↗
DOE OSTI2020

High-Temperature Particle Heat Exchanger for sCO2 Power Cycles

Particle receivers are being pursued to provide substantial performance improvements through higher temperatures (>700 °C) for more efficient and cost-effective concentrating solar power (CSP) systems with direct storage. However, the interface between the solar-collection and power-block subsystems - a high-temperature particle/supercritical CO 2 (sCO2) heat exchanger - has not been developed. The objective of this project is to design, construct, and test a first-of-a-kind particle-to-sCO2 heat exchanger. This work will enable emerging sCO2 power cycles that have the potential to meet SunShot targets of 50% thermal-to-electric efficiency, dry cooling with 40 °C ambient temperature, and $0.06/kWh for CSP systems. The development of next-generation particle-based systems and methods with potentially high consequences for improved performance and cost savings for CSP applications is an appropriate role for the government.

14 SOLAR ENERGY↗
DOE OSTI2021

Estimating the Value of Automation for Concentrating Solar Power Industry Operations (Final Report)

This report summarizes findings from a small, mixed-method research study examining industry perspectives on the potential for new forms of automation to invigorate the concentrating solar power (CSP) industry. In Fall 2021, the Solar Energy Technologies Office (SETO) of the United States Department of Energy (DOE) funded Sandia National Laboratories to elicit industry stakeholder perspectives on the potential role of automated systems in CSP operations. We interviewed eleven CSP professionals from five countries, using a combination of structured and open comment response modes. Respondents indicated a preference for automated systems that support heliostat manufacturing and installation, calibration, and responsiveness to shifting weather conditions. This pilot study demonstrates the importance of engaging industry stakeholders in discussions of technology research and development, to promote adoptable, useful innovation.

14 SOLAR ENERGY↗
DOE OSTI2021

Development of High Temperature (>700°C) molten Salt Pump Technology for Gen3 Solar Power Tower Systems

Generation 3 Concentrating Solar Power (CSP) Systems require thermal energy storage that can efficiently receive solar heat and deliver it to a working fluid at temperatures greater than 700°C. For liquid systems, the thermal transfer fluid must be phase stable over large temperature ranges. High temperature molten salts meet this criteria, but are difficult liquids to handle. The high heat and salt content can be very corrosive to several different materials that are wetted by the liquid salt. For power tower collectors, the molten salt must be pumped under high pressure to the top of the collector tower. These pumps have impellers and shafts as part of their rotating elements, and under load, require bearings to control shaft movement while rotating. These high temperature pumps require submerged bearings, and thus bearing materials that can withstand the temperature and molten salt contact over long periods of time. This is essential for keeping pump maintenance costs low, and downtime to a minimum. Long running bearing materials is an enabling technology for integrated liquid systems in Generation 3 CSP Systems. Keeping costs low and systems reliable are critical for the broad adoption of Gen 3 CSP Systems. Hayward Tyler, Inc (HTI) proposed development of journal bearing materials for use in vertical pumps designed for pumping high temperature molten salt on both the hot and cold sides of the solar power tower. To complete this objective, HTI utilized the testing capabilities of Oak Ridge National Laboratory (ORNL) and High Temperature System Design (HTSD). Materials would first be selected for static corrosion testing, then downselected for tribological testing. Successful tribologically tested materials would then be downselected for use in additional test regimes. Ten samples were selected for static corrosion testing. Three passed the static testing regime. Two of these materials were downselected for ball material in tribological testing against three metallic alloys: Sintered Y2O3 Partially Stabilized Zirconia YTZP and Silicon Nitride, Grade 147-31N. HTI also proposed collecting data from a thorough bearing test regime using a test rig designed and built as part of this project, and also a conceptual design for a high temperature molten salt vertical pump. HTI withdrew from the project prior to completion of this work and this report reflects only the work completed prior to withdrawal. The completed work produced two papers, one manuscript submitted for publication, and one paper published in the journal Solar Energy Materials and Solar Cells. The papers are: “Tribological behavior of ceramic-alloy bearing contacts in molten salt lubrication for concentrating solar power” and “Material Selection and Corrosion Studies Of Candidate Bearing Materials For Use In Molten Chloride Salt."

14 SOLAR ENERGY↗
DOE OSTI2022

Design Methods, Tools, and Data for Ceramic Solar Receivers Year 1 Continuation Report

This report describes the first year of work on a project to develop the methods, tools, and data required to analyze high temperature ceramic Concentrating Solar Power (CSP) components. This first year focused on developing the methods and data required for a time-independent assessment of potential components, focusing in particular on ceramic solar receivers. The report describes both model development and testing work focused on accomplishing this goal. Our overall conclusion is that high temperature ceramic CSP components are viable and could provide a means to overcome the expected low reliability and short service life for equivalent components constructed from Ni-based superalloys. Based on the results reported here, we recommend the project continue to Phase II which will develop more sophisticated, realistic models for time-dependent failure of ceramics operating in expected CSP component conditions and develop the time-dependent ceramic test data needed to parameterize these models, using commercial SiC as a reference material.

14 SOLAR ENERGY↗
DOE OSTI2022

Mechanically-, Thermally, and Chemically-Robust High-Temperature Ceramic Composites

In an effort to lower the levelized cost of electricity generated by Concentrated Solar Power (CSP) plants, the heat-to-electricity conversion efficiency may be increased by operating such plants with higher turbine inlet temperatures using closed Brayton cycles with high-pressure, supercritical carbon dioxide (sCO 2 ) as the working fluid. For example, if the turbine inlet temperature is raised to ≥750°C, in combination with sCO2 closed Brayton cycles, the relative heat-to-electricity efficiency may be raised by more than 20% (compared to subcritical steam Rankine cycles operating with turbine inlet temperatures ≤550°C). The associated reduction in the cost of dispatchable electricity from such CSP plants (utilizing high-temperature thermal energy storage) would be an important breakthrough on the path towards direct competition with fossil-fuel-based plants. A key barrier to achieve such high-temperature efficient operation has been the limited thermomechanical performance of metal alloys used in compact, primary printed circuit- type heat exchangers (PCHEXs) for heat transfer to high-pressure sCO 2 . The maximum allowed stresses for the use of conventional stainless steels and nickel-based superalloys at high sCO 2 pressures (≥20 MPa) decline rapidly at temperatures ≥550°C. This project has been focused on demonstrating the desired high-temperature properties and attractive manufacturing characteristics of mechanically-, thermally-, and chemically-robust ceramic/metal composites (cermets), in order to allow for the use of such composites in primary PCHEXs for heat transfer to sCO 2 at ≥750°C and ≥20 MPa in CSP plants. Prior work with high-temperature, co-continuous carbide/refractory metal cermets, such as ZrC/W composites, has already demonstrated: i) the attractive combination of high-temperature properties exhibited by such materials (e.g., high values of stiffness, failure strength, and thermal conductivity at 800°C), and ii) cost-effective processes for manufacturing PCHEX plates comprised of such cermets with tailorable channel patterns. However, ZrC/W cermets were not found to be inherently corrosion resistant in sCO 2 at 750°C and 20 MPa. While the application of a Cu coating to ZrC/W surfaces, along with a modest addition (50 ppm) of CO to CO 2 , rendered such composites resistant to corrosion for 1000 h in such sCO 2 -based fluids at 750°C, such additional steps would increase the design complexity of such cermet-based components. An alternative approach (the focus of this project) is to develop mechanically-robust, cost- effective cermets that are inherently resistant to high-temperature oxidation in air and CO 2 . The overall goals of this project have been to demonstrate: i) the oxidation resistance of at least one cermet at 750°C in air and in CO 2 (i.e., with a projected annual corrosion ≤30 μm), ii) the mechanically robust nature of at least one cermet at 750°C (i.e., with an average failure strength ≥200 MPa), and iii) that the selected cermet can be manufactured via low-cost forming techniques.

14 SOLAR ENERGY↗
DOE OSTI2022

MIRACL Co-Simulation Platform Lab assets and tools integration

Pacific Northwest National Laboratory's (PNNL) co-simulation platform (CSP) for the Microgrids, Infrastructure Resilience, and Advanced Controls Launchpad (MIRACL) project, also known as MIRACL-CSP, is a functional layer designed and developed to oversee the operational exchanges of data at the application level to and from different resources residing on the MIRACL Data Hub shared platform. MIRACL-CSP allows virtual interactions between various data hub resources during co-simulation runtime.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2023

Technology Strategy Assessment: Findings from Storage Innovations 2030 Thermal Energy Storage

The concept of thermal energy storage (TES) can be traced back to early 19th century, with the invention of the ice box to prevent butter from melting. Modern TES development began with building heating and cooling and concentrated solar thermal technologies for power generation in the early 1900s and late 1970s, respectively. TES systems provide many advantages compared with other long-duration energy storage (LDES) technologies, which include low costs, long operational lives, high energy density, synchronous power generation capability with inertia that inherently stabilizes the grid, and the ability to output both heat and electricity. TES Use Cases TES technologies can couple with most renewable energy systems, including wind, photovoltaic, and concentrated solar thermal energy, and can be used for heat-to-heat, heat-to-electricity, electricity-to-heat, and electricity-to-electricity (bidirectional electricity) applications. The three types of TES that have heat as an input or output are grouped together for the purposes of this report. Retrofitting retired thermal power plants can be a potential cost-effective option for TES with electricity output because they both use a similar thermal-to-electricity type of conversion. Additionally, TES can directly serve heat demand for buildings and industrial processes, displacing fossil fuels to achieve broad decarbonization. Bidirectional Electricity Figure 1 shows a bidirectional electricity TES (ETES) architecture that is emerging as a prime technology for LDES at a grid scale. The ETES technology can utilize existing TES technology infrastructures, has no geological limitations (such as mountains and water for pumped storage hydro, underground natural caverns for compressed-air energy storage, etc.), and is capable of deployment anywhere in the United States and the world for broad uses. Particularly, ETES technology can be placed at retired fossil-fueled thermal power plants to reuse decommissioned assets, protect job security in associated communities, and provide resilient and high-inertia (i.e., spinning) power to the grid. Heat Input and Output There also are many ways to integrate TES within heat-to-electricity, heat-to-heat, and electricity-to-heat applications, such as those used in concentrating solar power (CSP), buildings, district heating, and industry process heat applications. These categories can be further classified for low- and high-temperature applications. High-temperature thermal energy storage (HTTES) heat-to-electricity TES applications are currently associated with CSP deployments for power generation. TES with CSP has been deployed in the Southwestern United States with rich solar resources and has proved its value to the electric grid. Electricity-to-heat and heat-to-heat HTTES applications present great potential for decarbonizing energy-intensive industrial process heat applications [8, 9], such as iron ore processing, iron smelting, cement production, glass manufacturing, mineral processing, and chemical production. Some industrial processes require process heat at temperatures > 1,400°C, so HTTES can be utilized to reduce fuel consumption in those processes through fuel, oxidizer, and process material pre-heating. Thermal energy storage for augmenting existing industrial process heat applications makes a much more attractive economic case because the energy penalty due to thermal-to-electric conversion is eliminated. Co-located applications of power production and heat also can add to the value stacking of integrating utility-scale TES; however, these scenarios are very case specific and not practically possible in many cases. These constraints are primarily attributed to the existing infrastructure being designed, developed, and constructed for many decades around the most economically feasible technologies, such as electricity and a selection of fossil fuels for heat input. Low-temperature TES can be utilized for building and district heating and cooling, as well as some process heat applications in electricity-to-heat and heat-to-heat configurations. Lower temperature TES (LTTES) can be added to heat pump equipment (electric input), either directly interacting with the refrigerant in the condenser or evaporator, or through a secondary heat transfer fluid. It also can be integrated in the building envelope or within the ducts of the heating, ventilation, and air conditioning (HVAC) system. Cost-effective integration of TES into buildings adds significant cost, and it is one of the key barriers preventing the commercialization and deployment of TES. The optimal strategy for integrating TES with buildings has yet to be determined for various applications of TES. Nevertheless, thermal storage materials are far less costly per unit of energy stored than electricity storage materials. This means that thermal storage has the potential to reduce the cost to society of energy storage.

25 ENERGY STORAGE↗
DOE OSTI2023

High Temperature Ceramic Heat Exchangers for the Gen3 Concentrated Solar Power Systems

As part of the Department of Energy’s Solar Energy Technology Office (SETO), the Concentrated Solar Power (CSP) Gen3 Demonstration Roadmap outlined the various technology pathways, goals, and technology needs/gaps to integrate CSP to a supercritical CO 2 (sCO 2 ) power cycle that operates at temperatures >700 °C. It is envisioned that the higher temperature power cycle will enhance the overall system efficiencies and reduce the levelized cost of electricity (LCOE) to meet a 2030 cost target of $0.05/kWhe for baseload CSP plants with ≥12 hours of storage. In this regard, there is a need for heat exchangers (HXs) that can operate at high sCO 2 pressures and temperatures >700 °C. Since current high-temperature alloys degrade at high temperatures, as part of this project, advanced ceramic materials, HX designs, and low-cost additive manufacturing approaches were developed to fabricate and evaluate the performance of the lab-scale ceramic HX prototypes.

14 SOLAR ENERGY↗