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At least 523 records · Page 29

Analysis of Respirator Cartridge Performance Testing on a Hanford AW Tank Farm Exhauster Slipstream

Washington River Protection Solutions (WRPS) conducted tests on two types of chemical cartridges for use in air-purifying respirators (APR) to determine the period of time that the cartridges would provide adequate performance for APRs used to protect workers when exposed to a mixture of Chemicals of Potential Concern (COPCs) from vapors exiting the exhauster for the Hanford AW tank farm. The Occupational Safety and Health Administration (OSHA) identifies cartridge testing as a valid approach for establishing a cartridge change schedules. Testing is commonly applied in situations where mixtures of COPCs exist, and where other approaches, such as manufacturer recommendations and modeling, are less reliable. The tests were designed and conducted to assure measurement and/or control of the key variables OSHA identified as important to estimate cartridge service-life, including temperature, humidity, COPC concentration, breathing rate, and cartridge adsorption capacity. Testing was conducted from September 23-25, 2016, on a slipstream from the AW exhauster, under static conditions fed to a respirator cartridge test stand developed by WRPS in collaboration with HiLine Engineering (Richland, Washington). Multipurpose respirator cartridges, SCOTT 7422-SD1 and SCOTT 7422-SC1 (SCOTT Safety, Monroe, North Carolina), were assessed on separate days. Sample media (sorbent tubes) were used to collect samples of the vapor stream entering and exiting the respirator cartridge, and were subsequently analyzed for COPC concentrations. Pacific Northwest National Laboratory was tasked with conducting an independent analysis of the analytical results and making recommendations based on the results for respiratory cartridge performance and service life.

54 ENVIRONMENTAL SCIENCES↗

Fabrication, test and demonstration of critical environment monitoring system

Design and performance of an analytical system for the evaluation of certain environmental constituents in critical environmental areas of the Quality Reliability and Assurance Laboratory are reported. Developed was a self-contained, integrated, minimum sized unit that detects, interrogates, and records those parameters of the environment dictated for control in large storage facilities, clean rooms, temporarily curtained enclosures, and special working benches. The system analyzes humidity, temperature, hydrocarbons particle size, and particle count within prescribed clean areas.

Heimendinger, K. W.↗

Optical Breath Gas Sensor for Extravehicular Activity Application

The function of the infrared gas transducer used during extravehicular activity in the current space suit is to measure and report the concentration of carbon dioxide (CO2) in the ventilation loop. The next generation portable life support system (PLSS) requires next generation CO2 sensing technology with performance beyond that presently in use on the Space Shuttle/International Space Station extravehicular mobility unit (EMU). Accommodation within space suits demands that optical sensors meet stringent size, weight, and power requirements. A laser diode spectrometer based on wavelength modulation spectroscopy is being developed for this purpose by Vista Photonics, Inc. Two prototype devices were delivered to NASA Johnson Space Center (JSC) in September 2011. The sensors incorporate a laser diode-based CO2 channel that also includes an incidental water vapor (humidity) measurement and a separate oxygen channel using a vertical cavity surface emitting laser. Both prototypes are controlled digitally with a field-programmable gate array/microcontroller architecture. The present development extends and upgrades the earlier hardware to the Advanced PLSS 2.0 test article being constructed and tested at JSC. Various improvements to the electronics and gas sampling are being advanced by this project. The combination of low power electronics with the performance of a long wavelength laser spectrometer enables multi-gas sensors with significantly increased performance over that presently offered in the EMU.

Wood, William R.↗

The Spacelab-Mir-1 "Greenhouse-2" experiment

The Spacelab-Mir-1 (SLM-1) mission is the first docking of the Space Shuttle Atlantis (STS-71) with the Orbital Station Mir in June 1995. The SLM-1 "Greenhouse-2" experiment will utilize the Russian-Bulgarian-developed plant growth unit (Svet). "Greenhouse-2" will include two plantings (1) designed to test the capability of Svet to grow a crop of Superdwarf wheat from seed to seed, and (2) to provide green plant material for post-flight analysis. Protocols, procedures, and equipment for the experiment have been developed by the US-Russian science team. "Greenhouse-2" will also provide the first orbital test of a new Svet Instrumentation System (SIS) developed by Utah State University to provide near real time data on plant environmental parameters and gas-exchange rates. SIS supplements the Svet control and monitoring system with additional sensors for substrate moisture, air temperature, IR leaf temperature, light, oxygen, pressure, humidity, and carbon-dioxide. SIS provides the capability to monitor canopy transpiration and net assimilation of the plants growing in each vegetation unit (root zone) by enclosing the canopy in separate, retractable, ventilated leaf chambers. Six times during the seed-to-seed experiment, plant samples will be collected, leaf area measured, and plant parts fixed and/or dried for ground analysis. A second planting initiated 30 days before the arrival of a U.S. Shuttle [originally planned to be STS-71] is designed to provide green material at the vegetative development stage for ground analysis. [As this paper is being edited, the experiment has been delayed until after the arrival of STS-71.].

Non-NASA Center↗

The physics of desiccation cracks 1: Ductile fracturing and dependence on relative humidity

Ductile deformation is ubiquitously found in the shrinkage of geomaterials. The existence of ductility requires elastoplastic mechanics when analyzing the structure deformation under external stress. Here, in this work, we explore the physics of ductile fracturing based on the results from desiccation experiments and triaxial tests. By using the digital image correlation (DIC) method to generate the strain maps of samples undergoing desiccation cracking under different relative humidities, we obtain results showing the previously postulated Cnoidal Wave ductile failure patterns propagating under atmospheric condition-controlled crack velocities. We then correlate these observations with rate-dependent plasticity models calibrated through triaxial tests undergoing several unloading–reloading cycles and velocity stepping. This work demonstrates the necessity to consider ductility in soil cracking, indicating that the formation of crack patterns in soil desiccation is a slow and predictable process.

58 GEOSCIENCES↗

Embryogenesis in 100% O2 at reduced pressure.

Fertile chicken eggs were incubated in an altitude chamber in a near 100% O2 atmosphere at 225 torr. Both N2 and CO2 were kept under 0.5%. Temperature was a standard 37.5 C but a high relative humidity of 90% was required to prevent dehydration. In ten trials involving 382 eggs, hatchability averaged 21% of controls and weight of chicks was 11% less than controls, but embryo mortality was distributed similarly. Low pressure per se and small differences in O2 tension may have affected the results, but similarities to incubation in 21% O2-79% He call attention to absence of nitrogen as a possible explanation.

Weiss, H. S.↗

Advanced air revitalization for optimized crew and plant environments

The Hybrid Air Revitalization System (HARS) closed ecosystem concept presented encompasses electrochemical CO2 and O2 separators, in conjunction with a mechanical condenser/separator for maintaining CO2, O2, and humidity levels in crew and plant habitats at optimal conditions. HARS requires no expendables, and allows flexible process control on the bases of electrochemical cell current, temperature, and airflow rate variations. HARS capacity can be easily increased through the incorporation of additional chemical cells. Detailed system flowcharts are provided.

Lee, M. G.↗

The use of membranes in life support systems for long-duration space missions

The use of membrane processes in a long-duration manned mission's regenerative environmental control and life-support system is presently discussed, in the cases of treatment for hygiene water, urine, humidity condensate, and phase-change distillate, as well as of water-vapor and CO2 removal from spacecraft air. Attention is given to the design of a tube-side-feed hollow-fiber module for membrane support and fluids-feed, as well as to the schematics for a membrane-based urine processor, an air recirculator, a potable-water producer, and a two-stage urine treater.

Mccray, S. B.↗

Results from the Space Shuttle STS-95 Electronic Nose Experiment

A miniature electronic nose in which the sensing media are insulating polymers loaded with carbon black as a conductive medium has been designed and built at the Jet Propulsion Laboratory. The ENose has a volume of 1700 cc, weighs 1.4 kg including the operating computer, and uses 1.5 W average power (3 W peak power). This ENose was used in a demonstration experiment aboard STS-95 (October, 1998), in which the ENose was operated continuously for six days and recorded the sensors' response to the air in the middeck. The ENose was designed to detect ten common contaminants in space shuttle crew quarters air. The experiment was controlled by collecting air samples daily and analyzing them using standard analytical techniques after the flight. Changes in humidity were detected and quantified, neither the ENose nor the air samples detected any of the contaminants on the target list. The device is microgravity insensitive.

Ryan, M. A.↗

Satellite Validation: A Project to Create a Data-Logging System to Monitor Lake Tahoe

Flying aboard the satellite Terra, the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) is an imaging instrument used to acquire detailed maps of Earth's surface temperature, elevation, emissivity, and reflectance. An automated site consisting of four buoys was established 6 years ago at Lake Tahoe for the validation of ASTERS thermal infrared data. Using Campbell CR23X Dataloggers, a replacement system to be deployed on a buoy was designed and constructed for the measurement of the lake's temperature profile, surrounding air temperature, humidity, wind direction and speed, net radiation, and surface skin temperature. Each Campbell Datalogger has been programmed to control, power, and monitor 14 different temperature sensors, a JPL-built radiometer, and an RM Young 32500 meteorological station. The logger communicates with the radiometer and meteorological station through a Campbell SDM-SIO4 RS232 serial interface, sending polling commands, and receiving filtered data back from the sensors. This data is then cataloged and sent back across a cellular modem network every hour to JPL. Each instrument is wired via a panel constructed with 18 individual plugs that allow for simple installation and expansion. Data sent back from the system are analyzed at JPL, where they are used to calibrate ASTER data.

Roy, Rudy A.↗

Glycoalkaloids in potato tubers grown under controlled environments

Tuber content of alpha-solanine, alpha-chaconine, and total glycoalkaloids (TGA) was determined for the potato cultivars, Norland, Russet Burbank, and Denali grown under different environmental conditions in growth chambers. The lowest TGA concentrations (0.30 to 0.35 mg g-1 dry tissue) were found in the cv. Norland with 400 micromoles m-2 s-1 photosynthetic photon flux (PPF), 12 h day length, 16 C temperature, and 350 micromoles mol-1 carbon dioxide. The ratio of alpha-chaconine to alpha-solanine was close to 60:40 under all growing conditions, except that it was 50:50 under the low temperature of 12 C. Cultivars responded similarly to environmental conditions although TGA was about 20% greater in cv. Russet Burbank and about 30% greater in Denali compared to Norland. The largest changes in TGA occurred with changes in temperature. In comparison to 16 C, TGA were 40% greater at 12 C, 80% greater at 20 C, and 125% greater at 24 C (0.70 mg g-1 dry weight). The TGA concentration increased from 10 to 25% with an increase in light from 400 to 800 micromoles m-2 s-1 PPF for all three cultivars. TGA increased 20% with extension of the day length from 12 to 24 hr and also increased 20% when carbon dioxide was increased from 350 to 1000 micromoles mol-1. TGA concentrations were not influenced by changes in relative humidity from 50 to 80%. TGA concentrations decreased only slightly in harvests made from 9 to 21 weeks after planting. Variations in TGA among the different growing conditions and cultivars were below 20 mg/100 g fresh weight (approximately 1.0 mg g-1 dry weight) recognized as the upper concentration for food safety. However the results suggest that TGA should be considered when potatoes are grown at temperatures above 20 C.

NASA Discipline Life Support Systems↗

Stereo Camera Deployment in Support of TRACER (Field Campaign Report)

An improved understanding of the salient environmental controls on cloud formation, evolution, and eventual dissipation is critical to address ongoing challenges with cloud process and parameterization representations in global climate and Earth system models. One goal for the recent U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s Tracking Aerosol Convection Interactions Experiment (TRACER) campaign was to collect a comprehensive data set that enabled such convective cloud process studies and key demonstrations for those controls that influenced cloud life cycle (i.e., aerosols, thermodynamics) in the Houston, Texas region. To help accomplish this, ARM instrumentation during TRACER was tasked with tracking a large number of individual, isolated convective cells – and to follow the evolution of these cells at high spatiotemporal resolution to characterize changes in cloud dynamic and microphysical properties. Since Houston experiences a range of convective clouds, it was known that the standard ARM Mobile Facility (AMF) instruments may not be sufficient to completely document initiating, transient, or dissipating low- or shallow-cloud behaviors that were also expected during this campaign (in terms of sensitivity, resolution, and/or operational availability). As one partial solution, a supplemental stereo camera deployment (this sub-campaign) was requested to augment the ARM AMF instrumentation to better address shallow and shallow-to-deep transitional types of cloud process drivers during TRACER (ARM stereo cameras for clouds [STEREOCAM]; Romps and Öktem 2018). The primary scientific focus was the relationships between cloud properties and the ambient conditions, which points to several key TRACER science questions including: ‘What is the relationship between cloud size or updraft intensity to the environmental wind shear and/or humidity?’ Overall, the ARM TRACER stereo camera deployment demonstrated unique effectiveness in observing a wide range of critical shallow, congestus, and transitioning or time-evolving cloud characteristics. The data sets from these cameras include information on the clouds' horizontal dimensions, elevations, and depths, while also enabling potential products for cloud initiation and dissipation rates, and vertical velocities. Stereo cameras simultaneously inform on cloud life cycle stage and spatial properties such as cloud fractional coverage, which should provide complementary information for ARM users when combined with TRACER cloud radars, lidar, and/or other profiling sensors. Moreover, camera products offer large-eddy simulation (LES),-scale-appropriate cloud coverage, depth, and spatial variability estimates, while opening additional avenues to challenge difficult process questions on cloud updrafts/entrainment and their covariability with environmental controls such as wind shear and humidity.

47 OTHER INSTRUMENTATION↗

Packing the PLSS

NASA Engineers design spacesuits for ultimate protection and functionality in the extreme environment of space. The spacesuit is often referred to as a "personal spacecraft" because it provides the astronaut with everything he or she needs to survive and work in space outside of the vehicle or habitat. The systems within the spacesuit include the pressure garment system (PGS), the Portable Life Support System (PLSS), and the power, avionics, and software (PAS) system. These elements are necessary to protect crewmembers and allow them to work effectively in the pressure and temperature extremes of space environments. Development of the spacesuit system is necessary to support future human extravehicular exploration activities to Lunar, Martian, microgravity, and possibly other space destinations. Although all the systems that makeup the space suit are important, the PLSS is one of the most complex. The PLSS provides the life support needed by the astronaut and consists of the oxygen (O2) subsystem, ventilation subsystem, and thermal control subsystem. Within each subsystem, there are many different components, a few of which are explained as follows. The oxygen tanks hold the oxygen that the crewmember uses to breath and pressurizes the suit. The primary oxygen tank is responsible during normal operations and the secondary oxygen tank kicks on in the case of an emergency. The Rapid Cycle Amine (RCA) canister is used to remove the carbon dioxide (CO2) and extra humidity in the crewmember's ventilation/breathing gas. The fan moves the oxygen around the suit. Suit Water Membrane Evaporator (SWME) is used within the thermal control loop to cool the water that is used to maintain a comfortable temperature for both the crew member and the other equipment inside the suit. Another component is the battery, which supplies the power needed to operate all these and the many other pieces. The battery is one of the biggest and heavies components within the PLSS. These are just a few of the components that encompass the PLSS. Each component has a weight and a certain volume that the NASA Engineers must take into account when building the PLSS, because the weight and volumes affect the crewmembers center of gravity (CG). [See the Notes Section for the link to an Apollo video that demonstrates the issues some of the crewmembers had picking up tools and dealing with center of gravity/tools on the surface of the Moon.] In this activity, students will simulate engineering design techniques that NASA Engineers and Designers are currently implementing to configuring the components within the PLSS. Through testing, students will consider the comfort, mobility, and center of gravity for their test subjects and how that changes after adjusting the placement of their simulated PLSS components.

Jennings, Mallory↗

Evaluating the Adsorptive Capabilites of Chemsorb 1000 and Chemsorb 1425

The removal of trace contaminants from spacecraft cabin air is necessary for crew health and comfort during long duration space exploration missions. The air revitalization technologies used in these future exploration missions will evolve from current ISS ISS State-of-Art (SOA) and is being designed and tested by the Advanced Exploration Systems (AES) Program's Atmosphere Resource Recovery and Environmental Monitoring (ARREM) project. The ARREM project is working to mature optimum atmosphere revitalization and environmental monitoring system architectures to enable exploration beyond Lower Earth Orbit (LEO). The Air Revitalization Lab at KSC is one of six NASA field centers participating in the ARREM that specializes in adsorbent and catalyst characterization with simulated spacecraft gas streams using combinations of pressure, O2 partial pressure, CO2 partial pressure, and humidity that are representative of a range of anticipated cabin atmospheric conditions and loads. On board ISS, the Trace Contaminant Control Subassembly (TCCS) provides active control of trace contaminants from the cabin atmosphere utilizing physical adsorption, thermal catalytic oxidation, and chemical adsorption processes. High molecular weight contaminants and ammonia (NH3) are removed a granular activated carbon treated with approx. 10% by weight phosphoric acid (H3PO4) (B-S Type 3032 4×6 mesh), which is expendable and is periodically refurbished. The Type 3032 granular activated carbon bed is no longer commercially available and therefore it is important to characterize the efficiency and capacity of commercially available NH3 sorbents. This paper describes the characterization of two Molecular Products LTD activated carbons: Chemsorb 1000 and Chemsorb 1425. Untreated activated carbons (e.g. Chemsorb 1000) remove contaminants by physisorption, which concentrates the contaminant within the pores of the carbon while letting air to pass through the sorbent4. Low molecular weight or polar gases (e.g. HCl, SO2, formaldehyde, and NH3) are not removed by physisorption and typically require chemisorption for removal. Treated activated carbons (e.g. Chemsorb 1425) are impregnated with a a chemical agent (e.g. phosphoric acid) that reacts with those gases, converting them to solids or salts within the carbon and removes them from the air stream. This process occurs via neutralization or catalysis reactions and adsorption capacity is exhaustedwhen the available impregnated chemicals are consumed. Moisture affects removal performance since adsorption sites within the pores are filled with water. The performance of impregnated carbons may be enhanced by moisture content because the mechanisms of contaminant removal are chemical reactions that occur in reagents contained within the pores. The adsorptive capacity data (mol/kg) of Chemsorb 1000 and 1425 for gas mixtures (ethanol, acetone, toluene, acetaldehyde, dichloromethane, and xylene) was measured with 40% relative humidity at 23 deg C air temperature. The adsorptive capacity data (mol/kg) of Chemsorb 1425 was measured using NH3 gas streams.

adsorptive capacities↗

A chemo-mechanical model for describing sorption hysteresis in a glassy polyurethane

Abstract Hysteretic sorption and desorption of water is observed from 0 to 95% relative humidity and 298–333 K on a glassy polyurethane foam. It is postulated that sorption-induced swelling of the glassy polyurethane increases the concentration of accessible hydrogen-bonding adsorption sites for water. The accessibility of sites is kinetically controlled due to the restricted thermal motions of chains in the glassy polymer, causing a difference in accessible site concentrations during sorption and desorption. This discrepancy leads to hysteresis in the sorbed concentrations of water. A coupled chemo-mechanical model relating volumetric strain, adsorption site concentration, and sorbed water concentration is employed to describe water sorption hysteresis in the glassy polyurethane. This model not only describes the final mass uptake for each relative humidity step, but also captures the dynamics of water uptake, which exhibit diffusion and relaxation rate-controlled regimes.

36 MATERIALS SCIENCE↗

Long-term ultrasonic monitoring of concrete affected by alkali-silica reaction

This article presents continuous monitoring results of alkali-silica reaction (ASR) development in concrete specimens for over 400 days using ultrasonic testing and expansion measurements. Eight concrete specimens with nonreactive aggregate (Control), reactive coarse aggregate, and reactive fine aggregates were cast with two reinforced confinement conditions. The specimens were conditioned in an environmental chamber with high temperature and humidity (38°C and 90% relative humidity) to accelerate the ASR development. A multichannel ultrasonic monitoring system was developed to collect ultrasonic signals automatically, and the expansions in three directions were measured periodically. Results showed that the relative velocity change could detect the ASR initiation in all reactive specimens and show a correlation with expansion in the early stage. However, these correlations are inconsistent for different ASR specimens, and the velocity change becomes less sensitive to ASR damage in the late stage (after 300 days). Irrecoverable velocity drop was observed during every chamber shutdown period, especially in specimens with higher levels of ASR damage. This phenomenon suggests that the nonlinear ultrasonic response caused by the ambient temperature variation may indicate the ASR damage.

Engineering↗

Laboratory Heat Flux Estimates of Seawater Foam for Low Wind Speeds

Laboratory experiments were conducted to measure the heat flux from seafoam continuously generated in natural seawater. Using a control volume technique, heat flux was calculated from foam and foam-free surfaces as a function of ambient humidity (ranged from 40% to 78%), air–water temperature difference (ranged from -9 °C to 0 °C), and wind speed (variable up to 3 m s-1). Water-surface skin temperature was imaged with a calibrated thermal infrared camera, and near-surface temperature profiles in the air, water, and foam were recorded. Net heat flux from foam surfaces increased with increasing wind speed and was shown to be up to four times greater than a foam-free surface. The fraction of the total heat flux due to the latent heat flux was observed for foam to be 0.75, with this value being relatively constant with wind speed. In contrast, for a foam-free surface the fraction of the total heat flux due to the latent heat flux decreased at higher wind speeds. Temperature profiles through foam are linear and have larger gradients, which increased with wind speed, while foam free surfaces show the expected logarithmic profile and show no variation with temperature. The radiometric surface temperatures show that foam is cooler and more variable than a foam-free surface, and bubble-resolving thermal images show that radiometrically transparent bubble caps and burst bubbles reveal warm foam below the cool surface layer, contributing to the enhanced variability.

54 ENVIRONMENTAL SCIENCES↗

The effect of molecular relaxation processes in air on the rise time of sonic booms

A theory is developed to explain the effect of molecular relaxation processes on the rise time of sonic booms. To determine the rise time of sonic booms, both O2 and N2 relaxation processes must be included. The N2 relaxation process delays the shock pressure reaching the maximum pressure, and the O2 relaxation process causes a shock profile to have a gentle slope. The N2 relaxation controls the lower part of overpressure; the O2 relaxation controls the higher part. The constant rise time curves show that the rise times increase as the overpressures and humidity decrease. The present approach gives longer rise times than those acquired by Bass et al. for given shock overpressures.

Kang, Jongmin↗