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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

A global-scale model of aerosol backscatter at CO2 wavelengths for satellite-based lidar sensors

The status of a global-scale model of background aerosol backscatter cross-sections at CO2 wavelengths is described. The model needs, strategy, concept, parameters, and capabilities are addressed, and the data base is discussed, concluding data selection, CO2 backscatter measurements, aerosol optical measurements, aerosol microphysical measurements, water vapor measurements, and data analysis. Strong evidence is reported for a 'universal' background tropospheric aerosol population. Typical background backscatter values at CO2 wavelengths appear to be about 3 x 10 to the -11th to 8 x 10 to the -11th/m/sr. Background signatures are evident in most aerosol data sets which have global-scale coverage in space or time.

Bowdle, David A.↗
NASA NTRS1987

Application of Advanced Very High Resolution Radiometer vegetation index to study atmosphere-biosphere exchange of CO2

Normalized difference vegetation indices derived from radiances measured by the Advanced Very High Resolution Radiometer were used to prescribe the phasing of terrestrial photosynthesis. The satellite data were combined with field data on soil respiration and a global map of net primary productivity to obtain the seasonal exchange of CO2 between the atmosphere and the terrestrial biosphere. The monthly fluxes of CO2 thus obtained were employed as source/sink functions in a global three-dimensional atmospheric tracer transport model to simulate the annual oscillations of CO2 in the atmosphere. The results demonstrate that satellite data of high spatial and temporal resolution can be used to provide quantitative information about seasonal and longer-term variations of photosynthetic activity on a global scale.

Fung, I. Y.↗
NASA NTRS1987

Climate warming due to increasing atmospheric CO2 - Simulations with a multilayer coupled atmosphere-ocean seasonal energy balance model

The transient response of the climate to increasing CO2 is studied using a modified version of the multilayer energy balance model of Peng et al. (1982). The main characteristics of the model are described. Latitudinal and seasonal distributions of planetary albedo, latitude-time distributions of zonal mean temperatures, and latitudinal distributions of evaporation, water vapor transport, and snow cover generated from the model and derived from actual observations are analyzed and compared. It is observed that in response to an atmospheric doubling of CO2, the model reaches within 1/e of the equilibrium response of global mean surface temperature in 9-35 years for the probable range of vertical heat diffusivity in the ocean. For CO2 increases projected by the National Research Council (1983), the model's transient response in annually and globally averaged surface temperatures is 60-75 percent of the corresponding equilibrium response, and the disequilibrium increases with increasing heat diffusivity of the ocean.

Li, Peng↗
NASA NTRS1987

The loss and depth of CO2 ice in comet nuclei

The chemical differentiation of a homogeneous, initially unmantled cometary nucleus whose composition encompasses water ice, unclathrated CO2 ice, and silicate dust, is presently simulated by an analytical model to test whether the selective sublimation of any free CO2 ice in the new comet will produce a surface layer of water ice and dust covering the undifferentiated core. The model encompasses the effects of nucleus rotation, arbitrary rotatiuon axis orientation, latitude, nucleus heat conduction, and CO2 gas outflow restriction by the water ice and dust layer.

Fanale, Fraser P.↗
NASA NTRS1988

CO2-rich fluid inclusions in greenschists, migmatites, granulites, and hydrated granulites

Data was discussed from several different terrains in which CO2-rich fluid inclusions occur despite parageneses that predict the presence of H2O-rich fluids. CO2-rich fluid inclusions, some having densities appropriate for peak-metamorphic conditions, were found in greenschists, amphibolites, migmatites, and hydrated granulites. The author suggested that there may be a common process that leads to CO2-rich secondary inclusions in metamorphic rocks.

Hollister, L. S.↗
NASA NTRS1988

Maturity of the Bosch CO2 reduction technology for Space Station application

The Bosch process, which catalytically reduces CO2 with H2 to solid carbon and water, is a promising technique for the reduction of the CO2 removed from the Space Station atmosphere and the subsequent water formation for O2 recovery. A Bosch engineering subsystem prototype CO2 reduction unit was developed to demonstrate the feasibility of the Bosch process as a viable technology for Space Station application. A man-rated prototype unit is then described as part of the ECLSS Technology Demonstrator Program. The goal was to develop a Bosch subsystem that not only meets the performance requirements of two 60 person-day carbon cartridge capacities, but also satisfies inherent man-rated requirements such as offgassing characteristics, fail-safe operation, and ease of maintainability. It is concluded that the technology is at a state of maturity directly applicable to flight status for the NASA Space Station program.

Wagner, Robert C.↗
NASA NTRS1988

Electrochemically regenerable metabolic CO2 and moisture control system for an advanced EMU application

Regenerable CO2 and moisture removal techniques that reduce expendables and logistics requirements are needed to sustain people undertaking extravehicular activities for the Space Station. NASA has been investigating ways to advance the Electrochemically Regenerable CO2 and Moisture Absorption (ERCA) technology to replace the nonregenerable solid lithium hydroxide absorber for the advanced Portable Life Support System (PLSS). The ERCA technology, due to its use of liquid absorbent, has the ability to effectively satisfy the high metabolic CO2 and moisture removal requirements of PLSS applications. This paper defines the ERCA technology concept and its advantages for the PLSS application, reviews breadboard and subscale testdata and presents the results of design concepts for a prototype Absorber Module of improved performance and the physical characteristics of the projected flight hardware.

Lee, M. C.↗
NASA NTRS1989

Recharge of the early atmosphere of Mars by impact-induced release of CO2

The question as to whether high impact rates early in the history of Mars could have aided in maintaining a relatively thick CO2 atmosphere is discussed. Such impacts could have released CO2 into the atmosphere by burial, by shock-induced release during impact events, and by the addition of carbon to Mars from the impacting bolides. On the assumption that cratering rates on Mars were comparable to those of the moon's Nectarial period, burial rates are a result of 'impact gardening' at the end of heavy bombardment are estimated to have ranged from 20 to 45 m/million years; at these rates, 0.1-0.2 bar of CO2 would have been released every 10 million years as a result of burial to depths at which carbonate dissociation temperatures are encountered.

Carr, Michael H.↗
NASA NTRS1990

A computer program for the design of optimum catalytic monoliths for CO2 lasers

Pulsed CO2 lasers have many applications in aeronautics, space research, weather monitoring and other areas. Full exploitation of the potential of these lasers is hampered by the dissociation of CO2 that occurs during laser operation. The development of closed-cycle CO2 lasers requires active CO-O2 recombination (CO oxidation) catalysts and design methods for implementation of catalysts inside lasers. The performance criteria and constraints involved in the design of catalyst configurations for use in a closed-cycle laser are discussed, and several design studies performed with a computerized design program that was written are presented. Trade-offs between catalyst activity and dimensions, flow channel dimensions, pressure drop, O2 conversion and other variables are discussed.

Guinn, K.↗
NASA NTRS1989

'Design of CO-O2 recombination catalysts for closed-cycle CO2 lasers'

Pulsed CO2 lasers have many applications in aeronautics, space research, weather monitoring and other areas. Full exploitation of the potential of these lasers is hampered by the dissociation of CO2 that occurs during laser operation. The development of closed-cycle CO2 lasers requires active CO-O2 recombination (CO oxidation) catalysts and design methods for implementation of catalysts inside lasers. This paper will discuss the performance criteria and constraints involved in the design of monolith catalyst configurations for use in a closed-cycle laser and will present a design study performed with a computerized design program that had been written. Trade-offs between catalyst activity and dimensions, flow channel dimensions, pressure drop, O2 conversion and other variables will be discussed.

Guinn, K.↗
NASA NTRS1990

O2 and CO2 glow-discharge-assisted oxygen transport through Ag

Experiments were conducted to determine whether dissociative adsorption is a possible limitation of the oxygen permeability through Ag, using the upstream glow-discharge dissociation of O2 and CO2 to provide a gas phase source of atomic oxygen. Results suggest that the dissociative adsorption step limits the supply of oxygen atoms to the upstream side of the membrane. When the upstream O2 was replaced by an equal pressure of CO2 in absence of glow discharge, only a small permeation signal was observed; the application of the glow discharge increasded the oxygen transport flux from 3.25 x 10 to the 12th/sq cm per sec to 1.74 x 10 to the 14th/sq cm per sec. It is suggested that this method of separating O2 from a CO2-rich atmosphere may be considered for providing oxygen for the astronauts in a manned expedition to Mars.

Outlaw, R. A.↗
NASA NTRS1990

Reaction and electronic excitation in crossed-beams collisions of low-energy O(3P) atoms with H2O and CO2

Collisions of low-energy (5-20 eV), ground-state oxygen atoms with H2O and CO2 in a crossed-beams geometry lead to chemical reaction in the case of H2O to produce OH (A2Sigma+ - X2Pi) emissions; and to inelastic electronic excitation in the case of CO2 to produce CO2 flame bands. Species identifications are made through known wavelengths and emission intensities in the range 300-400 nm. The measured difference in threshold energies for the two processes confirm the channels involved. These are the first measurements in this energy range of optical emissions through collisions of fast neutral species.

Orient, O. J.↗
NASA NTRS1991

Aerosol size distribution, composition, and CO2 backscatter

The aerosol size distribution, composition, and CO2 backscatter at 10.6 microns (beta-CO2) were measured continuosly at the Mauna Loa Observatory (Hawaii) during January-March and November-December, 1988 periods to compare the characteristics of periods associated with appreciable Asian dust transport to that site (January-March) with those of periods characterized by low-dust condition. The aerosol size distribution in the range 0.15 micron to 7.6 microns was measured at temperatures of 40, 150, and 340 C to differentiate between volatile and nonvolatile aerosols. Large ranges of variability was found in measurements of aerosol size distribution during both periods, but the average distributions were similar for both the high-dust and the low-dust periods. However, values for beta-CO2 were more elevated (by about six times) during periods associated with active Asian dust transport to the observatory site than during the low-dust periods.

Clarke, Antony D.↗
NASA NTRS1991

Oxygen isotope fractionation in stratospheric CO2

A new cryogenic collection system has been flown on board a balloon gondola to obtain separate samples of ozone and carbon dioxide without entrapping major atmospheric gases. Precision laboratory isotopic analysis of CO2 samples collected between 26 and 35.5 km show a mass-independent enrichment in both O-17 and O-18 of about 11 per mil above tropospheric values. Ozone enrichment in its heavy isotopes was 9 to 16 percent in O3-50 and 8 to 11 percent in O3-49, respectively (Schueler et al., 1990). A mechanism to explain the isotope enrichment in CO2 has been recently proposed by Yung et al. (1991). The model is based on the isotope exchange between CO2 and O3 via O(1D), resulting in a transfer of the ozone isotope enrichment to carbon dioxide. Predicted enrichment and measured values agree well.

Thiemens, M. H.↗
NASA NTRS1990

CO2 laser oscillators for laser radar applications

This paper reviews the spectral purity, frequency stability, and long-term stabilization of newly developed CO2 isotope lasers. Extremely high spectral purity, and short-term stability of less than 1.5 x 10 to the -13th have been achieved. A brief description on using CO2 isotope lasers as secondary frequency standards and in optical radar is given. The design and output characteristics of a single frequency, TEM00q mode, variable pulse width, hybrid TE CO2 laser system is also described. The frequency chirp in the output has been measured and almost completely eliminated by means of a novel technique.

Freed, C.↗
NASA NTRS1990

The Extended Duration Orbiter Regenerable CO2 Removal System

A new carbon dioxide scrubber system is undergoing development for extended duration orbiter (EDO) missions. The EDO requirements of missions up to 18 days and the capability for future missions up to 30 days necessitated the development and implementation of a regenerative CO2 removal process. This new system will reduce the launch weight and stowage volume as compared to the present method of CO2 removal, lithium hydroxide, which is stowed in canisters. The selected design, called the Regenerable CO2 Removal System (RCRS), uses a solid amine material to adsorb carbon dioxide and water vapor and periodically desorb these to space vacuum. The RCRS, which is located below the middeck floor, interfaces with the orbiter's cabin Atmospheric Revitalization System and is adjustable from four to seven crewmembers. The RCRS is designed to automatically cycle the beds from absorb to vacuum-desorb every 30 minutes. Also incorporated into the design are features such consumable recovery, external leak protection, trace contaminant control and automatic control logic operation.

Ouellette, Fred A.↗
NASA NTRS1990

Preliminary evaluation of a membrane-based system for removing CO2 from air

Processes to remove and/or recover CO2 from air are essential to the long-term success of the U.S. space program. The results of a preliminary investigation of the use of a novel membrane-based system for removal of CO2 from air are presented. Features of this technology that make it attractive include the following: (1) it is lightweight; (2) it requires no consumables or expendables; (3) it is relatively simple; and (4) it does not rely directly on other subsystems. Preliminary designs of systems for removing CO2 from spacecraft cabin atmospheres and from the extravehicular mobility unit are presented.

Mccray, Scott B.↗
NASA NTRS1991

Studies of proton irradiated H2O + CO2 and H2O + CO ices and analysis of synthesized molecules

Infrared spectra of H2O + CO2 and H2O + CO ices before and after proton irradiation showed that a major reaction in both mixtures was the interconversion of CO2 yields CO. Radiation synthesized organic compounds such as carbonic acid were identified in the H2O + CO2 ice. Different chemical pathways dominate in the H2O + CO ice in which formaldehyde, methanol, ethanol, and methane were identified. Sublimed material was also analyzed using a mass spectrometer. Implications of these results are discussed in reference to comets.

Moore, M. H.↗