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At least 523 records · Page 29

Preparation of 110K (Bi, Pb)-Sr-Ca-Cu-O superconductor from glass precursor

The Bi1.5Pb0.5Sr2Ca2Cu3O(x) glass, prepared by rapid quenching of the melt, showed T(sub g) of 383 C, crystallization temperature of approx. 446 C, melting temperature of approx. 855 C, and bulk density of 5.69 g/cu. cm. in air. The as-quenched glass was oxygen deficient. On heating in O2, it showed a slow, irreversible, and continuous weight gain starting at approx. 530 C. The influence of annealing conditions on the formation of various phases was investigated by XRD and electrical resistivity measurements. The 110K-T(sub c) phase did not form below 840 C. The amount of this phase increased with the sintering time at 840 C. A sample annealed at 840 C for 243 h in air and furnace cooled showed the highest T(sub c) (R=0) of 107.2 K and transition width delta T(sub c) (10 to 90 percent) of approx. 2 K.

Bansal, Narottam P.↗

Ice water path estimation and characterization using passive microwave radiometry

Model computations of top-of-atmospheric microwave brightness temperatures T(B) from layers of precipitation-sized ice of variable bulk density and ice water content (IWC) are presented. It is shown that the 85-GHz T(B) depends essentially on the ice optical thickness. The results demonstrate the potential usefulness of scattering-based channels for characterizing the ice phase and suggest a top-down methodology for retrieval of cloud vertical structure and precipitation estimation from multifrequency passive microwave measurements. Attention is also given to radiative transfer model results based on the multiparameter radar data initialization from the Cooperative Huntsville Meteorological Experiment (COHMEX) in northern Alabama. It is shown that brightness temperature warming effects due to the inclusion of a cloud liquid water profile are especially significant at 85 GHz during later stages of cloud evolution.

Vivekanandan, J.↗

Optical properties of grains in molecular clouds and accretion disks

A baseline model of the composition and abundances of grains and gases in molecular cloud cores and accretion disks around young stars is defined by employing: a wide range of astronomical data and theory; the composition of primitive bodies in the solar system; and solar elemental abundances. It is proposed that in the coldest portions of these objects the major grain species include amorphous olivine, amorphous orthopyroxene, volatile and refractory organics, water ice, troilite, and metallic iron. Using a combination of laboratory measurements of optical constants and asymptotic theory, values of the real and imaginary indices of refraction of these grain species over a wavelength range that runs from the vacuum UV to the radio domain are derived. Auxiliary information for these grain species, such as their vaporization temperatures bulk densities, and their fractional abundances by mass. The above information on grain properties in molecular cloud cores and accretion disks is used to estimate the Rosseland mean opacity of the grains in both environments and the IR and microwave opacity of grains in accretion disks.

Pollack, J. B.↗

Radar investigation of asteroids and planetary satellites

Radar reconnaissance of near-Earth asteroids, mainbelt asteroids, the Galilean satellites, the Martian satellites, and large Saturnian satellites, using the Arecibo 13-cm and the Goldstone 3.5-cm systems is discussed. Measurements of echo strength, polarization, delay/Doppler distribution of echo power provide information about dimensions, spin vector, large-scale topography, cm-to-m-scale morphology, and surface bulk density. The observations also yield refined estimates of target orbital elements.

Ostro, Steven J.↗

Imaging the earth's magnetosphere - Effects of plasma flow and temperature

The effects of Doppler shifting on the line centers of the magnetospheric O(+) cross section are investigated, and the resulting structure of the scattering rate as a function of bulk density is explained. Whereas the Doppler shifting frequently results in a decrease of the scattering rate, it is demonstrated that for certain drift speeds the overlap of the cross section and the solar intensity profile can lead to an increased rate, thus enhancing the relative brightness of the image above that obtained when v(p) is zero. Simulated images of the magnetosphere are obtained which are used to show quantitively how the magnetospheric image responds to variations in plasma drift speed and temperature. Changes in the brightness of the magnetospheric images also depend on the variability of the solar flux at 83.4 nm. In regions where there are plasma drifts, the brightness in the image is governed by the structure of the scattering rate, assuming a fixed temperature.

Garrido, D. E.↗

Surface reaction and pore diffusion in flow-tube reactors

The interaction of gas diffusion with surface reaction in porous solids is discussed and applied specifically to heterogeneous rate measurements in flow-tube reactors. External diffusion to the outer surface of a reactive solid, internal diffusion within the pores, surface reaction, and laminar flow are considered. A procedure is developed to correct observed surface rate constants for the interaction of these processes. Measured surface areas and bulk densities are used to construct a semiempirical model for porous diffusion in vapor-formed HNO3-H2O ices which are used to simulate polar stratospheric cloud surfaces. The model is tested experimentally by varying the thickness of these ices from about 15 to 120 microns. The results are consistent with the model predictions and show that the HNO3-H2O ices used are highly porous, and the internal surface must be considered in calculating kinetic parameters from observed loss rates. The best fit of the data yields a tortuosity factor of 3.3 +/-1.1 for the ice substrates.

Keyser, Leon F.↗

Application of Nuclear Well Logging Techniques to Lunar Resource Assessment

The use of neutron and gamma ray measurements for the analysis of material composition has become well established in the last 40 years. Schlumberger has pioneered the use of this technology for logging wells drilled to produce oil and gas, and for this purpose has developed neutron generators that allow measurements to be made in deep (5000 m) boreholes under adverse conditions. We also make ruggedized neutron and gamma ray detector packages that can be used to make reliable measurements on the drill collar of a rotating drill string while the well is being drilled, where the conditions are severe. Modern nuclear methods used in logging measure rock formation parameters like bulk density and porosity, fluid composition, and element abundances by weight including hydrogen concentration. The measurements are made with high precision and accuracy. These devices (well logging sondes) share many of the design criteria required for remote sensing in space; they must be small, light, rugged, and able to perform reliably under adverse conditions. We see a role for the adaptation of this technology to lunar or planetary resource assessment missions.

Albats, P.↗

Crystallization of amorphous ice as the cause of Comet P/Halley's outburst at 14 AU

An explanation is provided for the postperihelion eruption of Comet P/Halley, detected in February 1991 and believed to have started three months earlier, namely, the crystallization of amorphous ice taking place in the interior of the porous nucleus, at depths of a few tens of meters, accompanied by the release of trapped gases. Numerical calculations show that for a bulk density of 0.5 g/cu cm and a pore size of 1 micron crystallization occurs on the outbound leg of Comet P/Halley's orbit, at heliocentric distances between 5 AU and 17 AU. The trapped gas is released and flows to the surface through the porous medium. It may also open wider channels, as the internal pressures obtained surpass the tensile strength of cometary ice. The outflowing gas carries with it grains of ice and dust, and thus can explain the large amounts of dust observed in the coma at 14.3 AU and beyond.

Prialnik, D.↗

Rocket thrust variation with foamed liquid propellants

An analysis is presented on a method for varying rocket thrust by varying the bulk density of the propellants. This density variation was accomplished by uniformly dispersing an inert, insoluble gas in the liquid propellants. Only qualitative agreement with theory was obtained from preliminary experiments with a 1000-pound-thrust ammonia - nitric acid rocket engine; the required experimental gas-flow rates were two to six times greater than those predicted by theory. It was demonstrated, however, that this method of rocket-thrust variation is feasible.

Morrell, G↗

Explosive volcanism and the compositions of the cores of differentiated asteroids

Eleven iron meteorite groups showing correlations between Ni and siderophile trace elements that are predictable by distribution coefficients between liquid and solid metal of fractionally crystallizing metal magmas, are interpreted to be fragments of the fractionally crystallized cores of 11 differentiated asteroids. Many of these groups crystallized from S-depleted magmas which we propose resulted from removal of the first partial melt (a Fe,Ni-FeS cotectic) by explosive pyroclastic volcanism. It is shown that these dense, negatively buoyant melts can be driven to asteroidal surfaces by the combination of an excess pressure in the melt and the presence of buoyant bubbles of gas which decrease the bulk density of the melt. It is also shown that in typical asteroidal materials, veins will form which grow into dikes and serve as pathways for migration of melt and gas to asteroidal surfaces. Since cotectic Fe,Ni-FeS melt consists of about 85 wt. percent FeS and 15 wt. percent Fe,Ni, removal of small volumes of eutectic melts results in major loss of S but only minor loss of Fe,Ni, thus leaving sufficient Fe,Ni to form sizeable asteroidal cores.

Keil, Klaus↗

Planetary Radar Astronomy

Radar is a powerful technique that has furnished otherwise unavailable information about solar system bodies for three decades. The advantages of radar in planetary astronomy result from: (1) the observer's control of all the attributes of the coherent signal used to illuminate the target, especially the wave form's time/frequency modulation and polarization; (2) the ability of radar to resolve objects spatially via measurements of the distribution of echo power in time delay and Doppler frequency; (3) the pronounced degree to which delay-Doppler measurements constrain orbits and spin vectors; and (4) centimeter-to-meter wavelengths, which easily penetrate optically opaque planetary clouds and cometary comae, permit investigation of near-surface macrostructure and bulk density, and are sensitive to high concentrations of metal or, in certain situations, ice. Planetary radar astronomy has primarily involved observations with Earth-based radar telescopes, but also includes some experiments with a spaceborne transmitter or receiver. In addition to providing a wealth of information about the geological and dynamical properties of asteroids, comets, the inner planets, and natural satellites, radar experiments have established the scale of the solar system, have contributed significantly to the accuracy of planetary ephemerides, and have helped to constrain theories of gravitation. This review outlines radar astronomical techniques and describes principal observational results.

Ostro, Steven J.↗

Ices on the Satellites of Jupiter, Saturn, and Uranus

Three satellites of Jupiter, seven satellites of Saturn, and five satellites of Uranus show spectroscopic evidence of H2O ice on their surfaces, although other details of their surfaces are highly diverse. The icy surfaces contain contaminants of unknown composition in varying degrees of concentration, resulting in coloration and large differences in albedo. In addition to H2O, Europa has frozen SO2, and Ganymede has O2 in the surface; in both of these cases external causes are implicated in the deposition or formation of these trace components. Variations in ice exposure across the surfaces of the satellites are measured from the spectroscopic signatures. While H2O ice occurs on the surfaces of many satellites, the range of bulk densities of these bodies shows that its contribution to their overall compositions is highly variable from one object to another.

Cruikshank, Dale P.↗

Free Volume in Glassy Poly(arylene Ether Ketone)s

Amorphous polyarylene ether ketones were examined in the glassy state by positron annihilation lifetime spectroscopy ( PALS ) and in the melt by standard rheological techniques. Specimens were well-characterized fractions of two isomeric structures. PALS clearly shows that the polymer with meta linkages in its backbone contains larger voids (greater than 0.25 nm radius). Thus despite their similar bulk densities, the two materials must pack very differently on a local scale. On the other hand, the free volumes inferred from the WLF treatment of melt viscosity data are practically identical in both materials ca. 4% at T(sub g). The comparison between techniques sheds some light on the distribution of free volume.

Hinkley, J. A.↗

Planetary and Primitive Object Strength Measurements and Sampling Apparatus

We present experimental data and a model for the low-velocity (subsonic, 0 - 1000 m/s) penetration of brittle materials by both solid and hollow (i.e., coring) penetrators. The experiments show that penetration is proportional to momentum/frontal area of the penetrator. Because of the buildup of a cap in front of blunt penetrators, the presence or absence of a streamlined or sharp front end usually has a negligible effect for impact into targets with strength. The model accurately predicts the dependence of penetration depth on the various parameters of the target-penetrator system, as well as the qualitative condition of the target material ingested by a corer. In particular, penetration depth is approximately inversely proportional to the static bearing strength of the target. The bulk density of the target material has only a small effect on penetration, whereas friction can be significant, especially at higher impact velocities, for consolidated materials. This trend is reversed for impacts into unconsolidated materials. The present results suggest that the depth of penetration is a good measure of the strength, but not the density, of a consolidated target. Both experiments and model results show that, if passage through the mouth of a coring penetrator requires initially porous target material to be compressed to less than 26% porosity, the sample collected by the corer will be highly fragmented. If the final porosity remains above 26%, then most materials, except cohesionless materials, such as dry sand, will be collected as a compressed slug of material.

Ahrens, Thomas J.↗

Ambient Effects on Basalt and Rhyolite Lavas under Venusian, Subaerial, and Subaqueous Conditions

Both subaerial and subaqueous environments have been used as analog settings for Venus volcanism. To assess the merits of this, the effects of ambient conditions on the physical properties of lava on Venus, the seafloor, and land on Earth are evaluated. Rhyolites on Venus and on the surface of Earth solidify before basalts do because of their lower eruption temperatures. Rhyolite crust is thinner than basalt crust at times less than about an hour, especially on Venus. At later times, rhyolite crust is thicker because of its lower latent heat relative to basalt. The high pressure on the seafloor and Venus inhibits the exsolution of volatiles in lavas. Vesicularity and bulk density are proportional, so that lavas of the same composition should be more dense on the seafloor and less dense on land. Because viscosity depends partly upon the fraction of unvesiculated water in a melt, basalts with the same initial volatile abundance will be least viscous on the seafloor and most viscous on land. Assuming the same preeruptive H2O contents, molten rhyolites on Venus will have viscosities approx. 10% that of rhyolites on land. Despite lower expected viscosities, under-water flows are more buoyant and should have heights like subaerial and Venusian lavas of the same composition and extrusive history. In cases where the influence of crust is insignificant, a volume of rhyolite will have a higher aspect ratio than the same volume of basalt, no matter what the environment. If flow rheology is dominated by the presence of strong crust, aspect ratios differ little among environments or between compositions. These analyses support a rhyolitic interpretation for the composition of Venusian festooned flows and a basaltic interpretation for the composition of Venusian steep-sided domes. Although ambient effects are significant, extrusion rate and eruption history must also be considered to explain analogous volcanic landforms on Earth and Venus.

Bridges, Nathan T.↗

Mercury

Prior to the flight of the Mariner 10 spacecraft, Mercury was the least investigated and most poorly known terrestrial planet (Kuiper 1970, Devine 1972). Observational difficulties caused by its proximity to the Sun as viewed from Earth caused the planet to remain a small, vague disk exhibiting little surface contrast or details, an object for which only three major facts were known: 1. its bulk density is similar to that of Venus and Earth, much greater than that of Mars and the Moon; 2. its surface reflects electromagnetic radiation at all wavelengths in the same manner as the Moon (taking into account differences in their solar distances); and 3. its rotation period is in 2/3 resonance with its orbital period. Images obtained during the flyby by Mariner 10 on 29 March 1974 (and the two subsequent flybys on 21 September 1974 and 16 March 1975) revealed Mercury's surface in detail equivalent to that available for the Moon during the early 1960's from Earth-based telescopic views. Additionally, however, information was obtained on the planet's mass and size, atmospheric composition and density, charged-particle environment, and infrared thermal radiation from the surface, and most significantly of all, the existence of a planetary magnetic field that is probably intrinsic to Mercury was established. In the following, this new information is summarized together with results from theoretical studies and ground-based observations. In the quantum jumps of knowledge that have been characteristic of "space-age" exploration, the previously obscure body of Mercury has suddenly come into sharp focus. It is very likely a differentiated body, probably contains a large Earth-like iron-rich core, and displays a surface remarkably similar to that of the Moon, which suggests a similar evolutionary history.

Gault, D. E.↗

Radar Studies in the Solar System

We aid in study of the solar system by means of ground-based radar. We have concentrated on: (1) developing the ephemerides needed to acquire radar data at Arecibo Observatory and (2) analyzing the resultant data to: test fundamental laws of gravitation; determine the size , shape, topography, and spin vectors of the targets; and study the surface properties of these objects, through their scattering law and polarization characteristics. We are engaged in radar observations of asteroids and comets, both as systematically planned targets and as "targets of opportunity." In the course of the program, we have prepared ephemerides for about 80 asteroids and three comets, and the radar observations have been made or attempted at the Arecibo Observatory, in most cases successfully, and in some cases on more than one apparition. The results of these observations have included echo spectra for the targets and, in some cases, delay - Doppler images and measurements of the total round-trip delay to the targets. Perhaps the most dramatic of these results are the images obtained for asteroids (4179) Toutatis and 1989PB (Castalia), which were revealed to be double-lobed objects by the radar images. Besides these direct results, the radar observations have furnished information on the sizes and shapes of the targets through analysis of the Doppler width of the echoes as a function of time, and on the surface properties (such as composition, bulk density, and roughness) through analysis of the reflectivity and of the polarization state of the echoes. We have also refined the orbits of the observed asteroids as a result of the Doppler (and in some cases delay) measurements from the radar observations. Although the orbits of main-belt asteroids accessible to ground-based radar are quite well known from the available optical data, some near-Earth objects have been seen by radar very soon after their optical discovery (for example, 199OMF, just eight days after discovery). In such cases. the radar results ensure that the object in question can be anticipated and identified at the next apparition. We have also participated in radar studies of the terrestrial planets. The results of these studies have included both planetary topography profiles from the analysis of round-trip delays to points along the target Doppler equator and determinations of the target spin state. The latter is of special interest in the case of Venus, which is very close to, but not on, a multi-body spin-orbit resonance such that Venus rotates 12 times for every 8 Earth orbits and 13 Venus orbits. As a result, Venus presents nearly the same face toward Earth at each inferior conjunction. Our latest results confirm that the spin state of Venus is slightly off the resonance. The delay measurements from planetary 2 ranging have also been used in combination with other types of range data in testing general relativity with increasing accuracy. We have also been engaged in radar studies of planetary satellites. Using our ephemerides, Arecibo made radar observations of the Galilean satellites of Jupiter and of Mars' satellite Phobos during the favorable opposition seasons (1988-1992 for Jupiter and 1990 for Mars). An attempt was also made to observe Deimos, but without detecting an echo. In 1997, an attempt was made to observe Saturn's satellite Titan, using the newly upgraded Arecibo radar system for transmitting and the Goldstone radar for receiving, but no echo was detected. The study of satellites by radar is in many ways similar to that of asteroids. The results from these observations have included characterization of the surface properties from the reflectivity and polarization ratio, as well as (in the case of the large satellites of Jupiter) the variation of reflectivity with incidence angle.

Shaprio, Irwin I.↗

Measurements of solar system dust at R < 1 AU and R > 3 AU

In Situ experiments on space craft yield information about dust parameters such as velocity, flux and size, and mass of particles. In Situ experiments as well as brightness measurements in the inner solar system have been made with Helios from .3 to 1 AU in the ecliptic plane which reveal two different dust populations with different bulk densities and relative velocities to the spacecraft. Zodiacal light measurements from Helios 1 and 2 reveal a radial brightness gradient proportional to R(exp -2.3). Measurements of dust particles in the outer solar system have been made onboard the Pioneer 10 and 11 spacecraft and for the high latitude region with Ulysses. Pioneer 10 and 11 also carried a spin-scan photopolarimeter that was used to map the zodiacal light and background starlight during the cruise to Jupiter in two broad bandpasses centered at .44 and .64 micron. Details of these measurements are briefly discussed.

Mann, Ingrid↗