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All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

Mineralogy, Petrology, and Oxygen-isotope Compositions of Magnetite ± Fayalite Assemblages in CO3, CV3, and LL3 Chondrites

We report on the mineralogy, petrology, and O-isotope compositions of magnetite and fayalite (Fa90−100) from several metasomatically altered and weakly metamorphosed carbonaceous (Y-81020 [CO3.05], EET 90043 [CO3.1], MAC 88107 [CO3.1-like], and Kaba [oxidized Bali-like CV3.1]) and unequilibrated ordinary chondrites (UOCs; Semarkona [LL3.00], MET 00452 [LL3.05], MET 96503 [LL3.05], EET 910161 [LL3.05], Ngawi [LL3.0−3.6 breccia], and Vicencia [LL3.2]). In MAC 88107, EET 90043, and Kaba, nearly pure fayalite (Fa98−100) associates with phyllosilicates, magnetite, Fe, Ni-sulfides, and hedenbergite (Fs~50Wo~50), and occurs in all chondritic components—chondrules, matrices,and refractory inclusions. In UOCs, nearly pure fayalite (Fa95−98) associates withphyllosilicates and magnetite, and occurs mainly in matrices and fine-grained chondrulerims. Oxygen-isotope compositions of fayalite and magnetite in UOCs, COs, CVs, and MAC 88107 are in disequilibrium with those of chondrule olivine and low-Ca pyroxene phenocrysts, and plot along mass-dependent fractionation lines with slope of~0.5, butdifferent 17O (~+4.3 1.4‰,−0.2 0.6‰,−1.5 1‰, and−1.8 0.8‰, respectively). Based on the mineralogical observations, thermodynamic analysis, O-isotope compositions, and recently reported experimental data, we infer that (1) fayalite and magnetite in COs,CVs, MAC 88107, and UOCs resulted from aqueous fluid–rock interaction on the chondrite parent asteroids that occurred at low local water-to-rock mass ratios (0.1−0.4) and elevated temperatures (~100−300°C), and (2) 17O of fayalite and magnetite reflects O-isotope compositions of aqueous fluids on the host meteorite parent bodies. The observed differences in 17O of fayalite–magnetite assemblages in UOCs, CVs, COs, and MAC 88107suggest that water ices that accreted into the ordinary chondrite and carbonaceous chondrite parent asteroids had different 17O, implying spatial and/or temporal variations in O-isotope compositions of water in the protoplanetary disk.

Alexander N Krot↗
NASA NTRS2017

Pulsed-Laser Irradiation Space Weathering Of A Carbonaceous Chondrite

Grains on the surfaces of airless bodies experience irradiation from solar energetic particles and melting, vaporization and recondensation processes associated with micrometeorite impacts. Collectively, these processes are known as space weathering and they affect the spectral properties, composition, and microstructure of material on the surfaces of airless bodies, e.g. Recent efforts have focused on space weathering of carbonaceous materials which will be critical for interpreting results from the OSIRIS-REx and Hayabusa2 missions targeting primitive, organic-rich asteroids. In addition to returned sample analyses, space weathering processes are quantified through laboratory experiments. For example, the short-duration thermal pulse from hypervelocity micrometeorite impacts have been simulated using pulsed-laser irradiation of target material e.g. Recent work however, has shown that pulsed-laser irradiation has variable effects on the spectral properties and microstructure of carbonaceous chondrite samples. Here we investigate the spectral characteristics of pulsed-laser irradiated CM2 carbonaceous chondrite, Murchison, including the vaporized component. We also report the chemical and structural characteristics of specific mineral phases within the meteorite as a result of pulsed-laser irradiation.

Thompson, M. S.↗
NASA NTRS2012

Comparing the Atmospheres of Mercury and the Earth's Moon

The exospheres of Mercury and the Earth's Moon are fundamentally similar, but the differences that do exist between them can help us to develop a better understanding of the processes at work on the two bodies that produce and remove volatiles. The major differences are derived from (1) the different compositions of the two surfaces, (2) the different particle and field em'ironments above the surface of each body (particularly the presence of intrinsic magnetic field of Mercury), and (3) the larger flux of interplanetary dust incident at the orbit of Mercury. The first difference, surface composition, is the most intractable problem, but the most challenging part of that problem, the composition of the Hermean regolith, may be at least partially addressed as the MESSENGER mission completes work over the next year. Much progress has been made with respect to exploring the second difference above--spacecraft such as Helios, Ulysses, WIND, and ACE have measured the solar wind and its composition both in Earth orbit and at distances encompassing the orbit of Mercury. While our knowledge of the solar wind is incomplete, again it is far more detailed than a simple 1/R(sup 2) law would predict. Another problem is that of the flux of charged particles to the surfaces. While Mercury's magnetosphere is the subject of current study with MESSENGER, the influx of charged particles on the Moon has gone beyond a cos (psi) picture, where psi is the solar zenith angle. We know that the influx of ions at the Moon is affected by magnetic anomalies, by craters, and by surface charging. The third external difference is the differing flux of interplanetary dust incident on the two surfaces. In this talk we will consider: (1) the species that one can compare now for these two exospheres (Na, K, and He); (2) the species that you might be able to compare with future measurements (Ca and Mg); arid (3) how intensive ground-based observations of the easiest lunar species to observe from the ground, Na and K, might help us address source processes at work on both surfaces. We will discuss current and planned modeling efforts for both the lunar and Hermean exospheres, and some current and planned observations, both ground-based and space-based.

Morgan, Thomas H.↗
NASA NTRS2015

The Mineralogy and Petrology of Anomalous Eucrite Emmaville

It has long been known that certain basaltic achondrites share similarities with eucrites. These eucrite-like achondrites have distinct isotopic compositions and petrologic characteristics indicative of formation on a separate parent body from the howardite-eucrite-diogenite (HED) clan (e.g., Ibitira, Northwest Africa (NWA) 011). Others show smaller isotopic variations but are otherwise petrologically and compositionally indistinguishable from basaltic eucrites (e.g., Pasamonte, Pecora Escarpment (PCA) 91007). The Emmaville eucrite has a delta O-17 value of -0.137 plus or minus 0.024 per mille (1 sigma), which is substantially different from the eucrite mean of -0.246 plus or minus 0.014 per mille (2 sigma), but similar to those of A-881394 and Bunburra Rockhole (BR). Currently little data exist for Emmaville in terms of petrology or bulk composition. Studying anomalous eucrites allows us to more completely understand the numbers of asteroids represented by eucrite- like basalts and thus constrain the heterogeneity of the HED suite. In this study, we present our preliminary petrological and mineral composition results for Emmaville.

Barrett, T. J.↗
DOE OSTI2023

Effect of recycled fibers and shredded intermediates variation on the mechanical properties and energy absorption of fiber‐reinforced composite panels

Abstract The global composite industry generates large quantities of waste which mostly ends up in landfills due to a lack of established end‐use applications for multiple waste streams. The scrap from end‐of‐life (EoL) includes manufacturing waste such as dry chopped fiber tows, loose fibers, shredded fibers from fabric textile operations, cured/semi‐cured prepregs, and fully cured composite structure waste from aircraft, automobiles, wind blades, boats, and pressure vessels. In this work, different composite waste streams were reduced to shredded intermediates, followed by simple blending, and subjected to wet compression molding to produce composite panels. The panels/plaques were tested for mechanical properties (flexure and impact), fiber‐matrix wet‐out, and property bounds. It was found that wet‐compression molding was a viable and scale‐able approach to produce recycled panels from EoL composites shredded scrap. Furthermore, full‐scale size panels for use in truck bodies and intermodal shipping container flooring were manufactured and their impact resistance was tested using a drop weight impact test. They were tested both for high‐ and low‐velocity load. In the case of high‐velocity load, the average impact load was 14,673 N; the average absorbed energy was 101.6 J; the average elastic energy was 11.7 J and the impact resistance was 1065 J/m. In the case of the low‐velocity drop weight impact test, it was found that the average impact load was 7877.358 N; the average absorbed energy was 9.718 J; the average elastic energy was 9.14 J, and the impact resistance was 184.1 J/m. The shredded composite was shown to be a candidate material for the manufacture of truck bodies and intermodal containers’ flooring panels. Highlights By using shredded intermediates from different composite waste streams, it is possible to manufacture composite panels. Wet–compression process is an appropriate technique for manufacturing recycled fiber composite panels. Regardless of the source of scrap, the mechanical properties of the produced composite panels were improved. The recycling process technology can be transformed to commercial scale to produce full‐size transportation flooring panels. A product pathway is established in consideration of lower cost and improved recyclability.

Vaidya, Uday↗
DOE OSTI2022

Systematic electronic structure in the cuprate parent state from quantum many-body simulations

The quantitative description of correlated electron materials remains a modern computational challenge. We demonstrate a numerical strategy to simulate correlated materials at the fully ab initio level beyond the solution of effective low-energy models and apply it to gain a detailed microscopic understanding across a family of cuprate superconducting materials in their parent undoped states. We uncover microscopic trends in the electron correlations and reveal the link between the material composition and magnetic energy scales through a many-body picture of excitation processes involving the buffer layers. Our work illustrates a path toward a quantitative and reliable understanding of more complex states of correlated materials at the ab initio many-body level.

Science & Technology - Other Topics↗
NASA NTRS1993

A Team Approach to the Development of Gamma Ray and x Ray Remote Sensing and in Situ Spectroscopy for Planetary Exploration Missions

An important part of the investigation of planetary origin and evolution is the determination of the surface composition of planets, comets, and asteroids. Measurements of discrete line X-ray and gamma ray emissions from condensed bodies in space can be used to obtain both qualitative and quantitative elemental composition information. The Planetary Instrumentation Definition and Development Program (PIDDP) X-Ray/Gamma Ray Team has been established to develop remote sensing and in situ technologies for future planetary exploration missions.

Trombka, J. I.↗
NASA NTRS1993

The asteroid-meteorite connection: Forging a new link to Vesta as the parent body of basaltic achondrite (HED) meteorites

Asteroid 4 Vesta has been at the center of the debate over the identity of the howardite eucrite diogenite (HED) parent body since the early 1970s. Despite its unique (among the 500 largest asteroids) compositional match to HED meteorites, substantial dynamical difficulties in delivering fragments from Vesta to the Earth have precluded any conclusive HED parent body link. These dynamical difficulties arise because Vesta's orbital location is far from known resonances. Consequently, it has been argued as dynamically improbable that meteoroid-sized (1 km) fragments could be excavated from Vesta with sufficient velocities to reach the resonances. Through new astronomical observations, numerous small (4-7 km) asteroids between Vesta and the 3:1 resonance have been discovered to have eucrite and diogenite compositions. Based on similar orbital elements to Vesta, all of these new asteroids are likely large impact fragments excavated from Vesta. Their current orbits imply ejection velocities in excess of 700 m/sec. Smaller (1 km) fragments can therefore be expected to have been ejected with velocities greater than 1 km/sec, sufficient to reach the 3:1 and v6 resonances. Thus it now appears to be dynamically viable for Vesta to be linked as the HED parent body.

Binzel, R. P.↗
NASA NTRS2017

Plausible Compositions of the Seven TRAPPIST-1 Planets Using Long-Term Dynamical Simulations

TRAPPIST-1 is a nearby ultra-cool dwarf that is host to a remarkable planetary system consisting of seven transiting planets. The orbital properties and radii of the planets have been well constrained, and recently, the masses of the inner six planets have been measured with additional ground- and space-based photometric observations. Large uncertainties in these mass measurements have prevented a robust analysis of the planetary compositions. Here, we perform many thousands of N-body dynamical simulations with planet properties perturbed from the observed values and identify those that are stable for millions of years. This allows us to identify self-consistent orbital solutions that can be used in future studies. From our range of dynamical masses, we find that most of the planets are consistent with an Earth-like composition, where TRAPPIST-1f is likely to have a volatile-rich envelope.

Quarles, B.↗
NASA NTRS2017

Plausible Compositions of the Seven TRAPPIST-1 Planets Using Long-Term Dynamical Simulations

TRAPPIST-1 is a nearby ultra-cool dwarf that is host to a remarkable planetary system consisting of seven transiting planets. The orbital properties and radii of the planets have been well constrained, and recently, the masses of the inner six planets have been measured with additional ground- and space-based photometric observations. Large uncertainties in these mass measurements have prevented a robust analysis of the planetary compositions. Here, we perform many thousands of N-body dynamical simulations with planet properties perturbed from the observed values and identify those that are stable for millions of years. This allows us to identify self-consistent orbital solutions that can be used in future studies. From our range of dynamical masses, we find that most of the planets are consistent with an Earth-like composition, where TRAPPIST-1f is likely to have a volatile-rich envelope.

B. Quarles↗
NASA NTRS2017

Plausible Compositions of the Seven TRAPPIST-1 Planets Using Long-Term Dynamical Simulations

TRAPPIST-1 is a nearby ultra-cool dwarf that is host to a remarkable planetary system consisting of seven transiting planets. The orbital properties and radii of the planets have been well constrained, and recently, the masses of the inner six planets have been measured with additional ground- and space-based photometric observations. Large uncertainties in these mass measurements have prevented a robust analysis of the planetary compositions. Here, we perform many thousands of N-body dynamical simulations with planet properties perturbed from the observed values and identify those that are stable for millions of years. This allows us to identify self-consistent orbital solutions that can be used in future studies. From our range of dynamical masses, we find that most of the planets are consistent with an Earth-like composition, where TRAPPIST-1f is likely to have a volatile-rich envelope.

B. Quarles↗
NASA NTRS2010

The Effects of Parent Body Processes on Amino Acids in Carbonaceous Chondrites

To investigate the effect of parent body processes on the abundance, distribution, and enantiomeric composition of amino acids in carbonaceous chondrites, the water extracts from nine different powdered Cl, CM, and CR carbonaceous chondrites were analyzed for amino acids by ultrahigh performance liquid chromatography-fluorescence detection and time-of-flight mass spectrometry (UPLC-FD/ToF-MS). Four aqueously altered type 1 carbonaceous chondrites including Orgueil (C11), Meteorite Hills (MET) 01070 (CM1), Scott Glacier (SCO) 06043 (CM1), and Grosvenor Mountains (GRO) 95577 (CR1) were analyzed using this technique for the first time. Analyses of these meteorites revealed low levels of two- to five-carbon acyclic amino alkanoic acids with concentrations ranging from -1 to 2,700 parts-per-billion (ppb). The type 1 carbonaceous chondrites have a distinct distribution of the five-carbon (C5) amino acids with much higher relative abundances of the gamma- and delta-amino acids compared to the type 2 and type 3 carbonaceous chondrites, which are dominated by a-amino acids. Much higher amino acid abundances were found in the CM2 chondrites Murchison, Lonewolf Nunataks (LON) 94102, and Lewis Cliffs (LEW) 90500, the CR2 Elephant Moraine (EET) 92042, and the CR3 Queen Alexandra Range (QUE) 99177. For example, a-aminoisobutyric acid ((alpha-AIB) and isovaline were approximately 100 to 1000 times more abundant in the type 2 and 3 chondrites compared to the more aqueously altered type 1 chondrites. Most of the chiral amino acids identified in these meteorites were racemic, indicating an extraterrestrial abiotic origin. However, non-racemic isovaline was observed in the aqueously altered carbonaceous chondrites Murchison, Orgueil, SCO 06043, and GRO 95577 with L-isovaline excesses ranging from approximately 11 to 19%, whereas the most pristine, unaltered carbonaceous chondrites analyzed in this study had no detectable L-isovaline excesses. These results are consistent with the theory that aqueous alteration played an important role in amplification of small initial left handed isovaline excesses on the parent bodies.

Glavin, Daniel P.↗
NASA NTRS1975

Summary of recent design studies of advanced acoustic-composite nacelles

The results are summarized of recent NASA-sponsored studies of advanced acoustic-composite nacelles. Conceptual nacelle designs for current wide-bodied transports and for advanced technology transports, intended for operational use in the mid-1980's, were studied by Lockheed-California Company and the Douglas Aircraft Company. These studies were conducted with the objective of achieving significant reductions in community noise and/or fuel consumption with minimum penalties in airplane weights, cost, and operating expense. The results indicate that the use of advanced composite materials offer significant potential weight and cost savings and result in reduced fuel consumption and noise when applied to nacelles. The most promising concept for realizing all of these benefits was a long duct, mixed flow acoustic composite nacelle with advanced acoustic liners.

Norton, H. T., Jr.↗
NASA NTRS1986

Properties of the Guin ungrouped iron meteorite - The origin of Guin and of group-IIE irons

The composition and structure of the Guin ungrouped iron meteorite inclusions have been investigated experimentally. The structural characteristics of polished and etched slabs of the meteorite were studied microscopically in reflected light. Modal abundances of troilite nodules and silicate inclusions were determined by weighing paper traces. The bulk composition of the silicate inclusions was calculated by combining modal phase abundances and mineral compositions. It is found that the largest silicate inclusion (2 x 4 cm) consists mostly of a shock-melted plagioclase-rich matrix surrounding large, partly melted augite grains. The oxygen isotopic composition of the inclusion is near that of LL chondrites. The inclusion is found to be similar in composition to selected melt pocket glasses in ordinary chondrites produced in situ by preferential melting of plagioclase rock due to shock compression. It is suggested that the Guin assemblage was formed by impact melting on a chondritic parent body. Silicate inclusions in IIE irons share many of the compositional and petrological characteristics of the Guin inclusions, indicating that IIE irons also formed by impact-melting of chondritic materials. Black and white photomicrographs of the silicate inclusions are provided.

Rubin, A. E.↗
NASA NTRS2017

Pathways to Meteoritic Glycine and Methylamine

Glycine and methylamine are meteoritic water-soluble organic compounds that provide insights into the processes that occurred before, during, and after the formation of the Solar System. Both glycine and methylamine and many of their potential synthetic precursors have been studied in astrophysical environments via observations, laboratory experiments, and modeling. Despite these studies, the synthetic mechanisms for their formation leading to their occurrence in meteorites remain poorly understood. Typical 13C-isotopic values ((delta)13C) of meteoritic glycine and methylamine are 13C-enriched relative to their terrestrial counterparts; thus, analyses of their stable carbon isotopic compositions (13C/12C) may be used not only to assess terrestrial contamination in meteorites but also to provide information about their synthetic routes inside the parent body. Here, we examine potential synthetic routes of glycine and methylamine from a common set of precursors present in carbonaceous chondrite meteorites, using data from laboratory analyses of the well-studied CM2 Murchison meteorite. Several synthetic mechanisms for the origins of glycine and methylamine found in carbonaceous chondrites may be possible, and the prevalence of these mechanisms will largely depend on (a) the molecular abundance of the precursor molecules and (b) the levels of processing (aqueous and thermal) that occurred inside the parent body. In this work, we also aim to contextualize the current knowledge about gas-phase reactions and irradiated ice grain chemistry for the synthesis of these species through parent body processes. Our evaluation of various mechanisms for the origins of meteoritic glycine and methylamine from simple species shows what work is still needed to evaluate both the abundances and isotopic compositions of simpler precursor molecules from carbonaceous chondrites as well as the effects of parent body processes on those abundances and isotopic compositions. The analyses presented here combined with the indicated measurements will aid a better interpretation of quantitative analysis of reaction rates, molecular stability, and distribution of organic products from laboratory simulations of interstellar ices, astronomical observations, and theoretical modeling.

interstellar ice↗
DOE OSTI2021

Thermal expansion of liquid Fe-S alloy at high pressure

The local structure and density of liquid Fe-S alloys at high pressure have been determined in situ by combined angle and energy dispersive X-ray diffraction experiments in a multi-anvil apparatus, covering a large temperature and compositional range. Precise density measurements collected for increasing temperature allowed us to directly derive the thermal expansion coefficients for liquid Fe-S alloys as a function of composition. In turn, thermal expansion has been used to refine thermodynamic models and to address the crystallization regime of telluric planetary cores by comparing the adiabatic temperature gradient and the slope of the liquidus in the Fe-FeS system. For Fe-S cores of asteroids and small planetesimals, top-down solidification is the dominant scenario as the compositional domain for which the slope of the liquidus is greater than the adiabatic gradient is limited to a narrow portion on the Fe-rich side. However, bottom-up growth of the inner core is expected for S-poor cases, with this compositional domain expanding to more S-rich compositions with increasing pressure (size of the planetary body). In particular, bottom-up crystallization cannot be excluded for the Moon and Ganymede.

36 MATERIALS SCIENCE↗
NASA NTRS1975

Structure and evolutionary history of the solar system

General principles and observational facts concerning the solar system are examined, taking into account the orbits of planets and satellites, the small bodies, the resonance structure, spin and tides, and postaccretional changes in the solar system. A description is given of the accretion of celestial bodies and the plasma phase is considered. Aspects of chemical differentiation and the matrix of the groups of bodies are also discussed, giving attention to chemical compositions in the solar system, meteorites and their precursor states, mass distribution and the critical velocity, and the structure of the groups.

Alfven, H.↗
NASA NTRS1983

Origin of the atmospheres of the terrestrial planets

The monotonic decrease in the atmospheric abundance of per gram of planet in the sequence, Venus, earth, and Mars has been assumed to reflect some conditions in the primitive solar nebula at the time of formation of the planetary atmospheres, having to do either with the composition of the nebula itself or the composition of the trapped gases in small solid bodies in the nebula. Behind such hypotheses lies the assumption that planetary atmospheres steadily gain components. However, not only can gases enter atmospheres; they may also be lost from atmospheres both by adsorption into the planetary interior and by loss into space as a result of collisions with minor and major planetesimals. In this paper a necessarily qualitative discussion is given of the problem of collisions with minor planetesimals, a process called atmospheric cratering or atmospheric erosion, and a discussion is given of atmospheric loss accompanying collision of a planet with a major planetesimal, such as may have produced the earth's moon.

Cameron, A. G. W.↗