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At least 523 records · Page 29

The Beginning and End of the Universe

Cosmology is the scientific study of how the Universe began more than 13 billion years ago, how its properties have changed, and what its future might be. The balance of forces and energy cause the Universe to expand, first accelerating, then decelerating and then accelerating again. Within this overall structure, the interplay of atoms and light with the mysterious dark matter and dark energy causes stars and galaxies to form and evolve, leading to galaxies like our own home, the Milky Way. Observational cosmology uses telescopes on Earth and in space to reach back in time to find the faint remaining echoes of the Big Bang and to trace the formation and evolution of the galaxies and structures that fill the Universe. In this lecture, Dr. Gardner will give an overview of cosmology, outlining the 13-billion year history of the Universe, and highlighting the very rapid progress this field has made in the last decade. He will discuss the role that NASA space telescopes have played in this progress and will continue to play in the years to come. He will give a time-based history of the Universe, discussing the successive processes that formed matter, particles, atoms, stars and galaxies. In particular, he will focus on cosmological inflation, the rapid accelerated expansion that marks the beginning of the Universe, and dark energy, a tenuous substance that overcomes gravity and whose properties will determine its final fate.

Gardner, Jonathan P.↗

The Beginning and End of the Universe

Cosmology is the scientific study of how the Universe began more than 13 billion years ago, how its properties have changed, and what its future might be. The balance of forces and energy cause the Universe to expand, first accelerating, then decelerating and then accelerating again. Within this overall structure, the interplay of atoms and light with the mysterious dark matter and dark energy causes stars and galaxies to form and evolve, leading to galaxies like our own home, the Milky Way. Observational cosmology uses telescopes on Earth and in space to reach back in time to find the faint remaining echoes of the Big Bang and to trace the formation and evolution of the galaxies and structures that fill the Universe. In this lecture, Dr. Gradner will give an overview of cosmology, outlining the 13-billion year history of the Universe, and highlighting the very rapid progress this field has made i the last decade. He will discuss the role that NASA space telescopes have played in this progress and wil continue to play in the years to come. He will give a time-based history of the Universe, discussing the successive processes that formed matter, particles, atoms, stars and galaxies. In particular, he will focus on cosmological inflation, the rapid accelerated expansion that marks the beginning of the Universe, and dark energy, a tenuous substance that overcomes gravity and whose properties will determine its final fate.

Gardner, Jonathan↗

Comparison of Non-Combusting Spray Fields in a Model Combustor using Shadowgraphy

Droplet sizes were measured using shadowgraphy in the spray issuing from the center element of the baseline configuration of the NASA 7-element lean direct injector (LDI) array. Each LDI element consisted of a 60 degree clockwise axial air swirler, converging-diverging venturi, and a pressure-swirl atomizer positioned with its tip at the venturi throat. The non-combusting measurements were conducted using water spray in a 3-inch diameter research combustor operating at pressure of 5 bar and air inlet temperature of 700 K. At these inlet conditions, three air flow rates were used, producing reference velocities of 7.6, 15.2, and 22.9 m/s. Only the center nozzle was used. At each reference velocity, water flow rates were adjusted to simulate a common equivalence. Data were collected at a frame rate of 15 Hz over a range of positions near the LDI dump plane, and downstream, along the combustor centerline. Velocity measurements were achieved by use of a dual head Nd:YAG laser and frame transfer PIV camera. Droplet size and velocity, mass and number density, and volume fraction are compared at these inlet conditions to determine the effect of nozzle pressure drop on the measured properties.

lean direct injection↗

Comparison of Non-Combusting Spray Fields in a Model Combustor using Shadowgraphy

Droplet sizes were measured using shadowgraphy in the spray issuing from the center element of the baseline configuration of the NASA 7-element lean direct injector (LDI) array. Each LDI element consisted of a 60 degree clockwise axial air swirler, converging-diverging venturi, and a pressure-swirl atomizer positioned with its tip at the venturi throat. The non-combusting measurements were conducted using water spray in a 3-inch diameter research combustor operating at pressure of 5 bar and air inlet temperature of 700 K. At these inlet conditions, three air flow rates were used, producing reference velocities of 7.6, 15.2, and 22.9 m/s. Only the center nozzle was used. At each reference velocity, water flow rates were adjusted to simulate a common equivalence. Data were collected at a frame rate of 15 Hz over a range of positions near the LDI dump plane, and downstream, along the combustor centerline. Velocity measurements were achieved by use of a dual head Nd:YAG laser and frame transfer PIV camera. Droplet size and velocity, mass and number density, and volume fraction are compared at these inlet conditions to determine the effect of nozzle pressure drop on the measured properties.

lean direct injection↗

Sensitive Technique Developed Using Atomic Force Microscopy to Measure the Low-Earth-Orbit Atomic Oxygen Erosion of Polymers

A recession measurement technique has been developed at the NASA Glenn Research Center to determine the atomic oxygen durability of polymers exposed to the space environment for short durations. Polymers such as polyimide Kapton and Teflon FEP (fluorinated ethylene propylene, DuPont) are commonly used in spacecraft because of their desirable properties, such as flexibility, low density, and in the case of FEP, low solar absorptance and high thermal emittance. Polymers on the exterior of spacecraft in the low- Earth-orbit environment are exposed to energetic atomic oxygen, resulting in erosion and potential structural loss. It is, therefore, important to understand the atomic oxygen erosion yield (E, the volume loss per incident oxygen atom) of polymers being considered in spacecraft design. Because long-term space exposure data are rare and very costly, short-term exposures, such as on the space shuttles, are often relied on for atomic oxygen erosion determination. The most common technique for determining E is through mass-loss measurements. For limited-duration exposure experiments, such as shuttle flight experiments, the atomic oxygen fluence is often so small that mass-loss measurements are not sensitive enough. Therefore, a recession measurement technique has been developed at Glenn to obtain accurate erosion yields of polymers exposed to low atomic oxygen fluences.

deGroh, Kim D.↗

Surface Diagnostics in Tribology Technology and Advanced Coatings Development

This paper discusses the methodologies used for surface property measurement of thin films and coatings, lubricants, and materials in the field of tribology. Surface diagnostic techniques include scanning electron microscopy, transmission electron microscopy, atomic force microscopy, stylus profilometry, x-ray diffraction, electron diffraction, Raman spectroscopy, Rutherford backscattering, elastic recoil spectroscopy, and tribology examination. Each diagnostic technique provides specific measurement results in its own unique way. In due course it should be possible to coordinate the different pieces of information provided by these diagnostic techniques into a coherent self-consistent description of the surface properties. Examples are given on the nature and character of thin diamond films.

Miyoshi, Kazuhisa↗

Thermal Materials and Coatings for Near Rectilinear Halo Orbit (NRHO)

Passive thermal control of a spacecraft is reliant on external surface optical properties (solar absorptivity and IR emissivity), which degrade over time depending on length of mission, material or coating, and natural and induced environments. Understanding the degradation and resulting End of Life (EOL) optical properties enables optimization of the thermal performance and reduces risk. The environmental factors that affect degradation of materials and coatings include UV, solar wind, vacuum, contamination, lunar dust, atomic oxygen, and more. Future spacecraft such as Gateway will be flying in the Near Rectilinear Halo Orbit (NRHO), an environment that has not been flown before and environmental factors are different from Low Earth Orbit. There is no on orbit data for materials in this environment, and optical property data from on-orbit and ground experiments for other environments is of limited use. This 1.5 hour short course will explore optical properties and degradation by introducing the expected environment of NRHO, types of materials and coatings that could be used, how to estimate their EOL properties, and future work. This course will focus on the NRHO environment, but it will be beneficial for anyone interested in optical property degradation in the space environment.

Optics↗

Transport coefficients of partially ionized argon.

Properties of partially ionized Ar computed via Chapman-Enskog-Burnett expressions noting ambipolar diffusion coefficient, electron-atom momentum, electrical and thermal conductivity, etc

TRANSPORT COEFFICIENT↗

On the nature of S II emission from Jupiter's hot plasma torus

An effective electron temperature T(e) of 80,000 K is indicated by the Voyager 1 encounter Jupiter hot torus emission rates in the 6731, 1256, 911 and reclassified 765 A transitions of S II. A set of 53 measurements of the S II red line doublet obtained at 5.9 Jupiter radii shows strong, irregular fluctuations in intensity, but no variation in the line ratio. At this distance from Jupiter, the torus is found to be longitudinally uniform in density; this is consonant with Voyager UVS findings, but contrary to magnetic anomaly model predictions. It is suggested that presently unidentified ion-ion and/or iron-atom reactions are responsible for the S II component irregular variations, in view of the fact that electron properties are regular and variable only over a small range in the hot torus at 5.9 Jupiter radii.

Brown, R. A.↗

Anti-Stokes scattering as an XUV radiation source

Harris (1977) has shown that laser induced scattering from atoms stored in a metastable level may be used to produce an XUV radiation source with several unique properties, including narrow linewidth, tunability, linear polarization, picosecond pulsewidth, and relatively high peak spectral brightness. The present investigation provides a summary concerning the progress made on the use of this radiation source as a unique instrument for XUV spectroscopy, and as a possible flashlamp for a 200 A laser. Zych et al. (1978) demonstrated that the maximum spectral brightness of the source is that of a blackbody with a temperature of the metastable storage level. The peak count rate and peak spectral brightness of the anti-Stokes emission at 569 A are 17 times and 139 times greater than those of the 584 A resonance line. The anti-Stokes process was employed as an external source of radiation for high resolution spectroscopy of the 3p6 shell of potassium. Attention is also given to emission spectroscopy of lithium, metastable levels which are appropriate for storage, and a hollow cathode discharge.

Harris, S. E.↗

The cosmic ray composition as viewed from the chemical abundances of the solar system

It is shown that the chemical composition of cosmic rays at their sources for the elements up to the atomic number as 80 is quite similar to that of the carbonaceous chondrites, which have been keeping the properties of the protosolar nebula. In particular, the similarity between these two compositions is significant to the elements classified as refractory and siderphile, in addition to the elements, Ca and Al. These results as cited above suggest that cosmic rays, being currently observed near the Earth, may have been accelerated from the matter with the composition similar to that which is found of these chondrites as Allende.

Sakurai, K.↗

Nuclear techniques in studies of condensed matter

Nuclear techniques have played an important role in the studies of materials over the past several decades. For example, X-ray diffraction, neutron diffraction, neutron activation, and particle- or photon-induced X-ray emission techniques have been used extensively for the elucidation of structural and compositional details of materials. Several new techniques have been developed recently. Four such techniques are briefly reviewed which have great potential in the study and development of new materials. Of these four, Mossbauer spectroscopy, muon spin rotation, and positron annihilation spectroscopy techniques exploit their great sensitivity to the local atomic environments in the test materials. Interest in synchrotron radiation, on the other hand, stems from its special properties, such as high intensity, high degree of polarization, and high monochromaticity. It is hoped that this brief review will stimulate interest in the exploitation of these newer techniques for the development of improved materials.

Singh, Jag J.↗

Coatings could protect composites from hostile space environment

An experiment has been conducted on about 100 different material/process combinations, most of which were candidates for use in solar arrays having high power-to-weight ratios. These substances were exposed to the LEO environment during Long-Duration Exposure Facility Experiment A0171 in order to evaluate the synergistic effects of the LEO environment on the materials' mechanical, electrical, and optical properties. Materials evaluated include solar cells, cover slips having antireflectance coatings, adhesives, encapsulants, reflective materials, mast and harness materials, structural composites, and thermal control thin films. About one-sixth of the experiment tray was devoted to composite-material tensile specimens, which were specifically to be studied for changes in their mechanical properties. Preliminary results of the surface-damage evaluation are presented. These surface effects are dominated by atomic-oxygen erosion and micrometeoroid/space debris impacts.

Whitaker, Ann F.↗

Thermophysical properties of simple liquid metals: A brief review of theory

In this paper, we review the current theory of the thermophysical properties of simple liquid metals. The emphasis is on thermodynamic properties, but we also briefly discuss the nonequilibrium properties of liquid metals. We begin by defining a 'simple liquid metal' as one in which the valence electrons interact only weakly with the ionic cores, so that the interaction can be treated by perturbation theory. We then write down the equilibrium Hamiltonian of a liquid metal as a sum of five terms: the bare ion-ion interaction, the electron-electron interaction, the bare electron-ion interaction, and the kinetic energies of electrons and ions. Since the electron-ion interaction can be treated by perturbation, the electronic part contributes in two ways to the Helmholtz free energy: it gives a density-dependent term which is independent of the arrangement of ions, and it acts to screen the ion-ion interaction, giving rise to effective ion-ion pair potentials which are density-dependent, in general. After sketching the form of a typical pair potential, we briefly enumerate some methods for calculating the ionic distribution function and hence the Helmholtz free energy of the liquid: monte Carlo simulations, molecular dynamics simulations, and thermodynamic perturbation theory. The final result is a general expression for the Helmholtz free energy of the liquid metal. It can be used to calculate a wide range of thermodynamic properties of simple metal liquids, which we enumerate. They include not only a range of thermodynamic coefficients of both metals and alloys, but also many aspects of the phase diagram, including freezing curves of pure elements and phase diagrams of liquid alloys (including liquidus and solidus curves). We briefly mention some key discoveries resulting from previous applications of this method, and point out that the same methods work for other materials not normally considered to be liquid metals (such as colloidal suspensions, in which the suspended microspheres behave like ions screened by the salt solution in which they are suspended). We conclude with a brief discussion of some non-equilibrium (i.e., transport) properties which can be treated by an extension of these methods. These include electrical resistivity, thermal conductivity, viscosity, atomic self-diffusion coefficients, concentration diffusion coefficients in alloys, surface tension and thermal emissivity. Finally, we briefly mention two methods by which the theory might be extended to non-simple liquid metals: these are empirical techniques (i.e., empirical two- and three-body potentials), and numerical many-body approaches. Both may be potentially applicable to extremely complex systems, such as nonstoichiometric liquid semiconductor alloys.

Stroud, David↗

Substrate Preparations in Epitaxial ZnO Film Growth

Epitaxial ZnO films were grown on the two polar surfaces (O-face and Zn-face) of (0001) ZnO single crystal substrates using off-axis magnetron sputtering deposition. Annealing-temperature dependence of ZnO substrates was studied. ZnO films grown on sapphire substrates have also been investigated for comparison purposes and the annealing temperature of A1203 substrates is 1000 C. Substrates and films were characterized using photoluminescence (PL) spectrum, x-ray diffraction, atomic force microscope, energy dispersive spectrum, and electric transport measurements. It has been found that the ZnO film properties were different when films were grown on the two polarity surfaces of ZnO substrates and the A1203 substrates. An interesting result shows that high temperature annealing of ZnO single crystals will improve the surface structure on the O-face surface rather than the opposite surface. The measurements of homoepitaxial ZnO films indicate that the O-terminated surface is better for ZnO epitaxial film growth.

Zhu, Shen↗

Applications of Quantum Chemistry to the Study of Carbon Nanotubes

For several years, scientists at NASA Ames have been studying the properties of carbon nanotubes using various experimental and computational methods. In this talk, I will compare different strategies for using quantum chemistry calculations to describe the electronic structure, deformation and chemical functionalization of single wall carbon nanotubes (SWNT) and the physisorption of small molecules on nanotube surfaces. The SWNT can be treated as an infinite (periodic) or finite length carbon cylinder or as a polycyclic aromatic hydrocarbon (PAH) molecule with an imposed curvature maintained by external constraints (as if it were cut out of the SWNT surface). Calculations are carried out using DFT and MP2 methods and a variety of atomic orbital basis sets from minimal (STO-3G) to valence triple zeta. The optimal approach is based on the particular SWNT property of interest. Examples to be discussed include: nanotube fluorination and other functionalization reactions; coating of nanotubes by water vapor and low-molecular weight organic molecules; and the nature of the interface between SWNT and liquids such as water and amines. In many cases, the quantum chemistry calculations are used to parameterize or validate force fields for molecular dynamics simulations. The results of these calculations have helped explain experimental data and contributed to the design of novel materials and sensors based on carbon nanotubes. Some of this research is described in the following papers:

Jaffe, Richard L.↗

Carbon Nanotubes: Properties and Functionalization

A viewgraph presentation (including an explanation for each slide) gives an overview of nanoscale hybrid materials, chemistry in confined environments, and single molecule/single atom detection. The allotropes of carbon are described and illustrated, and the production of nanotubes is outlined. Single-wall nanotube interaction and irradiation are discussed. The formation of peapods in PLV material is shown.

David E. Luzzi↗