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At least 523 records · Page 29

Modeling High Current Pulsed Discharge in AA Battery Cathodes: The Effect of Localized Charging during Rest

During high current operation, substantial heterogeneity develops within battery cathodes, particularly when their thickness is large. Heterogeneity relaxation during subsequent rest is important for understanding battery performance under pulsed conditions. Localized charge balancing phenomena within batteries at zero net current are not well understood and merit investigation. In this work, the heterogeneity within cathodes of commercial alkaline Zn–MnO 2 batteries is measured during discharge and monitored during rest using energy dispersive X-ray diffraction (EDXRD). Significant gradients in protonation form during discharge and partially relax under rest. It is demonstrated that the proton gradient relaxation is through local redox activity at zero net current, where local (de)protonation works to redistribute charge across the cathode thickness. To support this redox-based relaxation, a fundamental kinetic study on prismatic MnO 2 cathodes is conducted to determine an appropriate model to describe both discharge and charge kinetics of MnO 2 . These kinetics are incorporated into a computational model to simulate the proton gradient formation and partial relaxation under identical discharge conditions as the operando EDXRD experiments. Model and experimental data are found to be in excellent agreement, correctly predicting localized charge balancing at rest.

Batteries↗

Modeling of a 43 GHz microplasma within a photonic crystal

The electron density (n e ) and argon metastable density (1 s 5 ) of a 43GHz microplasma are obtained using the zero-dimensional plasma kinetics solver (ZDPlasKin®) for an incident power of 160 and 1000mW and argon pressures of 10–600Torr (1.3 ×10 3 to 8.0 × 10 4 Pa). These simulations are compared with previously published experimental data. To determine the self-consistent electric field in the modeled plasma, the three-dimensional millimeter wave fields are computed as a function of electron density using ANSYS EM19.2, HFSS®. This electromagnetic field model is coupled to ZDPlasKin such that any increase in the simulated plasma density correctly attenuates the simulated electric field within the microplasma. The electron density is found to be sensitive to argon gas temperature, so a two-zone temperature model was needed to obtain agreement with experimental measurements. The temperature in the central core of the microplasma was determined by a previous experimental study. That temperature was used as an input to the model for the simulation of volume recombination losses. The outer regions of the microplasma are assumed to be in equilibrium with the walls (300K). This second temperature was used in the model to determine diffusion losses. The modeled electron and metastable densities are of the order 10 20 and 10 18 m –3 , respectively. This is in good agreement with those measured experimentally as long as the two-zone temperature model is used. In the absence of a hot gas core, the modeled three-body recombination rates are excessive and the simulation severely under-predicts the electron density and over-estimates the metastable density. We conclude that the millimeter wave microplasma has a hot core (2500K at 600 Torr) that rarifies the argon gas and effectively reduces three-body recombination. Furthermore, this allows one to achieve high electron density on the order of 10 20 m –3 with only 100mW of wave power.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

CCD photometry of Abell clusters. I - Magnitudes and redshifts for 84 brightest cluster galaxies

The way in which the luminosity of brightest cluster galaxy varies with cluster parameters is investigated in a sample of 84 Abell clusters of moderate redshift and of richness classes in the zero-to-5 range. A photometric system is used which is well matched with the low noise CCD detector employed, as well as to the arrangement of galaxies with different redshifts on a standard system. The data, together with measurements from earlier work which forms a low redshift sample of the 199 brightest cluster galaxies, confirm that the luminosity dispersion in first-rank cluster galaxies is about 0.34 mag. The colors of giant ellipticals have not changed since redshifts of 0.25, and the richness correction is well established at 0.10 mag/Abell richness class. Application of these corrections reduces the luminosity dispersion to 0.29 mag.

Schneider, D. P.↗

Free-vibration characteristics and correlation of a space station split-blanket solar array

Two methods for studying the free-vibration characteristics of a large split-blanket solar array in a zero-g cantilevered configuration are presented. The zero-g configuration corrresponds to an on-orbit configuration of the Space Station solar array. The first method applies the equations of continuum mechanics to determine the natural frequencies of the array; the second uses the finite element method program, MSC/NASTRAN. The stiffness matrix from the NASTRAN solution was found to be erroneously grounded. The results from the two methods are compared. It is concluded that the grounding does not seriously compromise the solution to the elastic modes of the solar array. However, the correct rigid body modes need to be included to obtain the correct dynamic model.

Carney, Kelly S.↗

Free-vibration characteristics and correlation of a Space Station split-blanket solar array

Two methods for studying the free-vibration characteristics of a large split-blanket solar array in a zero-g cantilevered configuration are presented. The zero-g configuration corresponds to an on-orbit configuration of the Space Station solar array. The first method applies the equations of continuum mechanics to determine the natural frequencies of the array; the second uses the finite element method program, MSC/NASTRAN. The stiffness matrix from the NASTRAN solution was found to be erroneously grounded. The results from the two methods are compared. It is concluded that the grounding does not seriously compromise the solution to the elastic modes of the solar array. However, the correct rigid body modes need to be icluded to obtain the correct dynamic model.

Carney, Kelly S.↗

Chiral limit and origin of topological flat bands in twisted transition metal dichalcogenide homobilayers

Abstract The observation of zero field fractional quantum Hall analogs in twisted transition metal dichalcogenides (TMDs) asks for a deeper understanding of what mechanisms lead to topological flat bands in two-dimensional heterostructures, and what makes TMDs an excellent platform for topologically ordered phases, surpassing twisted bilayer graphene. To this aim, we explore the chiral limits of massive Dirac theories applicable toC 3 -symmetric moiré materials, and show their relevance for both bilayer graphene and TMD homobilayers. In the latter, the Berry curvature of valence bands leads to relativistic corrections of the moiré potential that promote band flattening, and permit a limit with exactly flat bands with nonzero Chern number. The relativistic corrections enter as alayer-orbit coupling, analogous to spin-orbit coupling for relativistic Dirac fermions, which we show is non-negligible on the moiré scale. The Berry curvature of the TMD monolayers therefore plays an essential role in the flattening of moiré Chern bands in these heterostructures.

Physics↗

Study of and proposals for the correction of errors in a radar ranging device designed to facilitate docking of a teleoperator maneuvering system

A frequency modulated continuous wave radar system was developed. The system operates in the 35 gigahertz frequency range and provides millimeter accuracy range and range rate measurements. This level of range resolution allows soft docking for the proposed teleoperator maneuvering system (TMS) or other autonomous or robotic space vehicles. Sources of error in the operation of the system which tend to limit its range resolution capabilities are identified. Alternative signal processing techniques are explored with emphasis on determination of the effects of inserting various signal filtering circuits in the system. The identification and elimination of an extraneous low frequency signal component created as a result of zero range immediate reflection of radar energy from the surface of the antenna dish back into the mixer of the system is described.

Mcdonald, M. W.↗

Lower-hybrid drift waves and their interaction with plasmas in a 3D symmetric reconnection simulation with zero guide field

We investigate lower-hybrid drift waves (LHDW) in symmetric magnetic reconnection with zero guide field using three-dimensional particle-in-cell simulations. The long-wavelength mode with kρiρe∼1 develops in the bifurcated electron current layer around the X-line within the width of the electron meandering motion from the mid-plane, where ρi(e) is the ion (electron) gyroradius. The short-wavelength mode with kρe∼1 develops in the separatrix region downstream of the electron outflow jet, producing electron vortices in the background flow frame. Electrons follow the E × B drift with corrections from the diamagnetic drift and are heated inside the vortices with diverging electric fields. In the vortices, ions have comparable E × B and inertia drifts, which together mostly cancel the diamagnetic drift. Toward the center of diverging field vortices, ions are decelerated, leading to a decrease in the perpendicular temperature, while the loss of low-energy ions results in an increase in the parallel temperature. Parallel electric fields exist as a combination of the LHDW wave field projected to the magnetic field direction and the penetration of whistler waves that are mainly outside of the LHDW layer. The magnetic flux tube is twisted in the vortices. The twist may potentially lead to slippage reconnection, as indicated by the non-uniform parallel potential variation across field lines, while the periodic variations of the twisting directions are a limiting factor.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Measurement of the parity-violating asymmetry in the 𝑁 → Δ transition at low 𝑄 2

Here, we report the measurement of the parity-violating asymmetry in the 𝑁 → Δ transition via the 𝑒 − + 𝑝 → 𝑒 − + Δ + reaction at two different kinematic points with low four-momentum transfer 𝑄 2 . Measurements were made with incident electron beam energies of 0.877 and 1.16 GeV, corresponding to 𝑄 2 values of 0.0111 and 0.0208 (GeV/c) 2 , respectively. These measurements put constraints on a low-energy constant in the weak Lagrangian, 𝑑 Δ , corresponding to a parity-violating electric-dipole transition matrix element. This matrix element has been shown to be large in the strangeness-changing channel, via weak hyperon decays such as Σ + → 𝑝⁢𝛾. The measurements reported here constrain 𝑑 Δ in the strangeness-conserving channel. The final asymmetries were −0.65±1.00⁢(stat.)±1.02⁢(syst.) ppm (parts per million) for 0.877 GeV and −3.59±0.82⁢(stat.)±1.33⁢(syst.) ppm for 1.16 GeV. With these results we deduce a small value for 𝑑 Δ , consistent with zero, in the strangeness-conserving channel, in contrast to the large value for 𝑑 Δ previously reported in the strangeness-changing channel.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

A Comprehensive Reliability Methodology for Assessing Risk of Reusing Failed Hardware Without Corrective Actions with and Without Redundancy

This paper deals with the development of a reliability methodology to assess the consequences of using hardware, without failure analysis or corrective action, that has previously demonstrated that it did not perform per specification. The subject of this paper arose from the need to provide a detailed probabilistic analysis to calculate the change in probability of failures with respect to the base or non-failed hardware. The methodology used for the analysis is primarily based on principles of Monte Carlo simulation. The random variables in the analysis are: Maximum Time of Operation (MTO) and operation Time of each Unit (OTU) The failure of a unit is considered to happen if (OTU) is less than MTO for the Normal Operational Period (NOP) in which this unit is used. NOP as a whole uses a total of 4 units. Two cases are considered. in the first specialized scenario, the failure of any operation or system failure is considered to happen if any of the units used during the NOP fail. in the second specialized scenario, the failure of any operation or system failure is considered to happen only if any two of the units used during the MOP fail together. The probability of failure of the units and the system as a whole is determined for 3 kinds of systems - Perfect System, Imperfect System 1 and Imperfect System 2. in a Perfect System, the operation time of the failed unit is the same as that of the MTO. In an Imperfect System 1, the operation time of the failed unit is assumed as 1 percent of the MTO. In an Imperfect System 2, the operation time of the failed unit is assumed as zero. in addition, simulated operation time of failed units is assumed as 10 percent of the corresponding units before zero value. Monte Carlo simulation analysis is used for this study. Necessary software has been developed as part of this study to perform the reliability calculations. The results of the analysis showed that the predicted change in failure probability (P(sub F)) for the previously failed units is as high as 49 percent above the baseline (perfect system) for the worst case. The predicted change in system P(sub F) for the previously failed units is as high as 36% for single unit failure without any redundancy. For redundant systems, with dual unit failure, the predicted change in P(sub F) for the previously failed units is as high as 16%. These results will help management to make decisions regarding the consequences of using previously failed units without adequate failure analysis or corrective action.

Putcha, Chandra S.↗

EI_MS_ML

The unambiguous identification of compounds from their electron ionization mass (EI-MS) spectra remains a significant unsolved problem in the field of metabolomics and analytical chemistry as a whole. Typically EI-MS spectra are compared using various mathematical operations that convert the spectral similarity or differences into a distance-like metric that roughly approximates the similarity of any two spectra. A commonly used metric for this is the cosine similarity metric which has values close to one for very similar spectra and a value of zero for very dissimilar spectra; however, no metric is perfect. Due to the prevalence of structurally-similar compounds such as isomers and the prevalence of certain fragmentation patterns across structurally-dissimilar compounds, the unambiguous assignment of EI-MS spectra compounds remains difficult. Frequently, querying an observed EI-MS spectrum against a large database such as the NIST17 library yields multiple possible assignments requiring the end user to distinguish between multiple high scoring hits, or multiple low scoring hits while keeping in mind that the correct hit may not be in the database at all. Although techniques such as orthogonal information from techniques such as chromatography can greatly aid in unambiguous assignment, this also requires more complicated experimental designs and access to more complicated analytical instrumentation. Substructures can be trivially detected and represented as strings using a previously published technique called node coloring from a known chemical structure. However, for experimentally-derived EI-MS spectra this information must be derived from the spectra itself (i.e., because we do not know what compound it represents). To achieve this, the software uses techniques from the field of machine learning and a large training dataset of EI-MS spectra corresponding to known structures annotated with substructure strings, to build models that can predict the presence of a given chemical substructure from an EI-MS spectrum directly.If these predictions are of high-quality (i.e., are unlikely to be false positives), the presence of one or more predicted substructures can be used to constrain the number of possible hits for a query spectrum. Mathematically, this restriction could be expressed in many forms, but the most straight-forward implementation is to weight the cosine similarity of a query spectrum and a plausible database match with a Tanimoto-like coefficient based on the ratio of the number of substructures predicted to the number of substructures present in the potential database hit. Determining which combination of models best reduces assignment ambiguity will be achieved using a combination of manual curation and optimization techniques such as genetic algorithms. This software will perform all the steps necessary to construct said models from a training dataset and evaluate them using a holdout dataset. Various statistical analyses can be performed to determine if this approach does decrease assignment ambiguity. For example, if this approach works, on average, the rank-order of the correct assignment for the holdout set of EI-MS spectra should decrease and the weighted cosine similarities for most of the possible matches in the database should be better than the unweighted cosine similarities. Furthermore, this same pipeline can be used on real experimental data to generate less ambiguous assignments.

Mitchell, Joshua↗

Improved Convergence and Robustness of USM3D Solutions on Mixed-Element Grids

Several improvements to the mixed-elementUSM3Ddiscretization and defect-correction schemes have been made. A new methodology for nonlinear iterations, called the Hierarchical Adaptive Nonlinear Iteration Method, has been developed and implemented. The Hierarchical Adaptive Nonlinear Iteration Method provides two additional hierarchies around a simple and approximate preconditioner of USM3D. The hierarchies are a matrix-free linear solver for the exact linearization of Reynolds-averaged Navier-Stokes equations and a nonlinear control of the solution update. Two variants of the Hierarchical Adaptive Nonlinear Iteration Method are assessed on four benchmark cases, namely, a zero-pressure-gradient flat plate, a bump-in-channel configuration, the NACA 0012 airfoil, and a NASA Common Research Model configuration. The new methodology provides a convergence acceleration factor of 1.4 to 13 over the preconditioner-alone method representing the baseline solver technology.

Pandya, Mohagna J.↗

Improved Convergence and Robustness of USM3D Solutions on Mixed-Element Grids

Several improvements to the mixed-element USM3D discretization and defect-correction schemes have been made. A new methodology for nonlinear iterations, called the Hierarchical Adaptive Nonlinear Iteration Method, has been developed and implemented. The Hierarchical Adaptive Nonlinear Iteration Method provides two additional hierarchies around a simple and approximate preconditioner of USM3D. The hierarchies are a matrix-free linear solver for the exact linearization of Reynolds-averaged Navier-Stokes equations and a nonlinear control of the solution update. Two variants of the Hierarchical Adaptive Nonlinear Iteration Method are assessed on four benchmark cases, namely, a zero-pressure-gradient flat plate, a bump-in-channel configuration, the NACA 0012 airfoil, and a NASA Common Research Model configuration. The new methodology provides a convergence acceleration factor of 1.4 to 13 over the preconditioner-alone method representing the baseline solver technology.

Pandya, Mohagna J.↗

Competing conduction mechanisms in high performance carbon nanotube fibers

The performance of carbon nanotube (CNT) cables, a contender for copper-wire replacement, is tied to its metallic and semi-conducting-like conductivity responses with temperature; the origin of the semi-conducting-like response however is an underappreciated incongruity in literature. With controlled aspect-ratio and doping-degree, over 61 unique cryogenic experiments including anisotropy and Hall measurements, CNT cable performance is explored at extreme temperatures (65 mK) and magnetic-fields (60 T). A semi-conducting-like conductivity response with temperature becomes temperature-independent approaching absolute-zero, uniquely demonstrating for the first time the necessity of heterogeneous fluctuation induced tunneling; complete de-doping leads to localized hopping, contrasting graphite's pure metallic-like response. High-field magneto-resistance (including novel +22 % longitudinal magneto-resistance near room-temperature) is analyzed with hopping and classical two-band models, both yielding a similar parameter useful for conductor development. Varying field-orientation angle uncovers significant two- and four-fold symmetries that are shown to be from Aharonov-Bohm-like corrections to the curvature-induced bandgap, a first for macroscale CNT fibers. Tight-binding calculations using Green's Function formalism model the largest, coherent transport to-date in commensurate CNT bundles in magnetic-field, revealing non-uniform transmission across bundle cross-sections with doping restoring uniformity; independent of doping, transport in bundle-junction-bundle systems are predominantly from CNTs adjacent to the other bundle—demonstrating that smaller bundles are more efficient for electronic transport. The final impact is predicting the ultimate conductivity of heterogeneous CNT cables using temperature and field-dependent transport, surpassing conductivity of traditional metals.

36 MATERIALS SCIENCE↗

The variation in engine power with altitude determined from measurements in flight with a hub dynamometer

The rate of change in power of aircraft engines with altitude has been the subject of considerable discussion. Only a small amount of data from direct measurements of the power delivered by airplane engines during flight, however, has been published. This report presents the results of direct measurements of the power delivered by a Liberty 12 airplane engine taken with a hub dynamometer at standard altitudes from zero to 13,000 feet. Six flights were made with the engine installed in a modified DH-4 airplane. The experimental relation of brake horsepower to altitude is compared with two theoretical relations and with the experimental results, for a second Liberty 12 engine, given in NACA Technical Report no. 252. The rate of change in power with altitude of a third Liberty engine, measured with a calibrated propeller, is also given for comparison. The data presented substantiate the theoretical relation of brake horsepower to altitude based on the correction of ground level indicated horsepower for change in atmospheric temperature and pressure with the subsequent deduction of friction horsepower corrected for altitude. (author)

Gove, W D↗

Improving Photometric Calibration of Meteor Video Camera Systems

We present the results of new calibration tests performed by the NASA Meteoroid Environment Office (MEO) designed to help quantify and minimize systematic uncertainties in meteor photometry from video camera observations. These systematic uncertainties can be categorized by two main sources: an imperfect understanding of the linearity correction for the MEO's Watec 902H2 Ultimate video cameras and uncertainties in meteor magnitudes arising from transformations between the Watec camera's Sony EX-View HAD bandpass and the bandpasses used to determine reference star magnitudes. To address the first point, we have measured the linearity response of the MEO's standard meteor video cameras using two independent laboratory tests on eight cameras. Our empirically determined linearity correction is critical for performing accurate photometry at low camera intensity levels. With regards to the second point, we have calculated synthetic magnitudes in the EX bandpass for reference stars. These synthetic magnitudes enable direct calculations of the meteor's photometric flux within the camera bandpass without requiring any assumptions of its spectral energy distribution. Systematic uncertainties in the synthetic magnitudes of individual reference stars are estimated at approx. 0.20 mag, and are limited by the available spectral information in the reference catalogs. These two improvements allow for zero-points accurate to 0.05 - 0.10 mag in both filtered and unfiltered camera observations with no evidence for lingering systematics. These improvements are essential to accurately measuring photometric masses of individual meteors and source mass indexes.

Steven Ehlert↗

ZTF SN Ia DR2 follow-up: Exploring the origin of the Type Ia supernova host galaxy step through Si II velocities

The relation between Type Ia supernovae (SNe Ia) and the stellar masses of their host galaxy is well documented. In particular, Hubble residuals display a distinct luminosity shift based on host mass. This is known as the mass step. This effect is widely used as an additional correction factor in the standardisation of SN Ia luminosities. We investigate the Hubble residuals and the mass step of normal SNe Ia in the context of Si IIλ6355 velocities based on 277 normal SNe Ia that are near their peak in the second data release (DR2) of the Zwicky Transient Facility (ZTF). We divided the sample into high-velocity (HV) and normal-velocity (NV) SNe Ia, separated at 12,000 km s −1 . This produced a sample of 70 HV and 207 NV objects. We then explored potential environment- and/or progenitor-related effects by investigating the Si IIλ6355 velocities with parameters such as the light-curve stretch x 1 , the colour c, and the host galaxy properties. Although we only find a marginal difference between the Hubble residuals of HV and NV SNe Ia, the NV mass step is 0.149 ± 0.024 mag (6.3σ). The HV mass step is smaller, 0.046 ± 0.041 mag (1.1σ), and is consistent with zero. The difference between the NV and HV mass steps is modest, at ∼2.2σ. Moreover, the clearest subtype difference appears for SNe in central regions (d DLR < 1), where NV SNe Ia show a large mass step, whereas HV SNe Ia are consistent with no step, yielding a difference of 3.1–3.6σ between NV and HV SNe Ia. We observe a host-colour step for both subtypes. NV SNe Ia show a step of 0.142 ± 0.024 mag (5.9σ), while HV SNe Ia show a step of 0.158 ± 0.042 mag (3.8σ), where the HV SNe Ia step appears to be larger, but the significance is lower because the sample size is smaller. Overall, the NV and HV colour steps are statistically consistent. HV SNe Ia also show modest (∼2.5–3σ) steps in certain subsets, such as those in outer regions (d DLR > 1), whereas NV SNe display stronger environmental trends. Our results indicate that NV SNe Ia appear to be more environmentally sensitive, particularly in central likely metal-rich and older regions, while HV SNe Ia show weaker and subset-dependent trends. This suggests that applying a universal mass-step correction might introduce biases, and that incorporating refined classifications and/or environment-dependent factors, such as the location within the host, might improve future cosmological analyses beyond the standard x 1 and c cuts.

supernovae: general↗

Noisy quantum trees: infinite protection without correction

We study quantum networks with tree structures, in which information propagates from a root to leaves. At each node in the network, the received qubit unitarily interacts with fresh ancilla qubits, after which each qubit is sent through a noisy channel to a different node in the next level. Therefore, as the tree depth grows, there is a competition between the irreversible effect of noise and the protection against such noise achieved by the delocalization of information. In the classical setting, where each node simply copies the input bit into multiple output bits, this model has been studied as the broadcasting or reconstruction problem on trees, which has broad applications. In this work, we study the quantum version of this problem. We consider a Clifford encoder at each node that encodes the input qubit in a stabilizer code, along with a single qubit Pauli noise channel at each edge. Such noisy quantum trees describe a scenario in which one has access to a stream of fresh (low-entropy) ancilla qubits, but cannot perform error correction. Therefore, they provide a different perspective on quantum fault tolerance. Furthermore, they provide a useful model for describing the effect of noise within the encoders of concatenated codes. We prove that above certain noise thresholds, which depend on the properties of the code such as its distance, as well as the properties of the encoder, information decays exponentially with the depth of the tree. On the other hand, by studying certain efficient decoders, we prove that for codes with distance d ≥ 2 and for sufficiently small (but non-zero) noise, classical information and entanglement propagate over a noisy tree with infinite depth. Indeed, we find that this remains true even for binary trees with certain 2-qubit encoders at each node, which encodes the received qubit in the binary repetition code with distance d = 1.

Quantum information↗