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At least 523 records · Page 29

All sources NASA NTRS DOE OSTI

NASA NTRS2005

Development of an Optimal Water Allocation Decision Tool for the Major Crops During the Water Deficit Period in the Southeast U.S.

We developed a dynamic model to optimize irrigation application in three major crops (corn, cotton and peanuts) grown in the Southeast USA. Water supply amount is generated from an engineering model which is then combined with economic models to find the optimal amount of irrigation water to apply on each crop field during the six critical water deficit weeks in summer. Results indicate that water is applied on the crop with the highest marginal value product of irrigation. Decision making tool such as the one developed here would help farmers and policy makers to find the maximum profitable solution when water shortage is a serious concern.

Paudel, Krishna P.↗

NASA NTRS2022

Chesapeake Bay Water Resources: Characterization of Sediment Dynamics for Enhanced Water Quality Monitoring in the Chesapeake Bay

An increase in total suspended sediment (TSS) concentrations and turbidity have contributed to poor water quality in the Chesapeake Bay since the 1970s. Although turbidity and TSS have been moderately improving over the past few decades, poor water quality is detrimental to the Chesapeake Bay’s ecosystems and the surrounding watersheds. The Summer 2022 Chesapeake Bay Water Resources project observed sediment dynamics and turbidity in the York River watershed using remote sensing tools, models, and Earth observations including NASA and United States Geological Survey’s (USGS) Landsat satellite series, NASA DEVELOP’s Optical Reef Coastal Area Assessment Tool 2.0 (ORCAA), and Soil and Water Assessment Tool (SWAT). The collaborators on this project were the Chesapeake Bay National Estuarine Research Reserve (CBNERR), Group on Earth Observations (GEO) AquaWatch, the Committee on Earth Observation Satellites Coastal Observations, Applications, Services and Tools (CEOS COAST), and the Virginia Department of Environmental Quality (VA DEQ). The team concluded that the upstream sections of the York River watershed increased in TSS from 2009–2019. However, the seasonal TSS patterns often correlated with higher precipitation levels, although not necessarily major storm events. This may be due to factors like wind and waves contributing to the sedimentation trends observed. Although projects have been conducted to improve water quality, additional efforts like planting riparian buffers along areas with high TSS are needed to reduce the intensity of runoff. The team’s results will allow the end user, the VA DEQ, to inform their policymaking regarding future Bay conservation efforts.

Katherine Hahn↗

NASA NTRS2026

Hot Water, Cold Reality: Feasibility Assessment of Iodine Removal in Heated Spacecraft Potable Water Systems

The current eXploration Potable Water Dispenser (xPWD) design removes iodine upstream of the heated leg due to concerns with the Activated Carbon and Ion Exchange (ACTEX) functionality in hot water, leaving the downstream volume without residual biocide. The NESC determined that this non-iodinated volume is a concern for microbial growth during exploration missions and proposed 33 biocide architecture options for future missions that could address this concern. The top-ranked architecture out of the report was Option 1: moving the iodine removal media as close to the dispensing needle as possible to minimize the wetted components without biocide in the xPWD. Three main challenges were identified with this proposed configuration. First, the hot water at 175 ± 25 °F is a concern for the potential physical degradation of the ion exchange resin and lowered adsorption capacity in activated carbon. Second, moving the ACTEX or alternative sorption media closer to the dispense needle increases the unheated volume downstream of the heater, challenging the ability for dispensed water to meet temperature requirements. Finally, bubbles evolved from dissolved gas coming out of solution in the heater could clog or reduce the efficiency of the sorption media. To address the first challenge, more thermally robust ion exchange resins were identified and adsorption capacity tests were planned and will be discussed in a companion ICES paper (ICES-2026-5). To address the dispense temperature concerns, allowable bed size and architectural configuration changes are proposed. The value of adding phase separators to remove bubbles and potential implementation schemes are discussed. These findings support the development of potable water systems resilient to microbial risks during long-duration space missions.

Biocide↗

NASA NTRS2026

Hot Water, Cold Reality: Feasibility Assessment of Iodine Removal in Heated Spacecraft Potable Water Systems

PWD↗

DOE OSTI2024

Performance Evaluation of Drain Water Heat Recovery Exchangers for Heat Pump Water Heaters

Water heating constitutes approximately 18% of energy consumption and is the second largest energy expenses in United States homes. Heat pump water heaters (HPWHs) are energy efficient technologies with lower carbon footprints as compared to conventional water heating technologies, such as gas and electrical resistance heaters. The performance of water-source HPWHs can be improved by recovering heat from blackwater using drain heat recovery heat exchangers. Depending on water draw patterns of single family and multifamily residences, the operation and heat transfer performance of these heat exchangers are highly transient. This paper examines the thermo-hydraulic performance of a drain heat recovery heat exchanger during its transient and steady-state operations. The heat recovery performance of the exchanger was evaluated at different inlet temperatures and flow rates ranging from 9°C to 36°C and 0.03 kg/s to 0.28 kg/s, respectively. The obtained effectiveness varies from 45%–85% depending on the operating conditions. The test facility, steady-state and transient experimental procedures are reported in detail. Further, the effect of operating conditions on the effectiveness is discussed. The experimental approach and results of the study will provide insights into the transient operation of drain recovery heat exchangers as well as, guide sizing for various steady state conditions.

Krishnan, Easwaran↗

DOE OSTI2024

Numerical Analysis of Water Harvesting from Saturated Vapor with the Electrospray Water Droplet Injection in The Solar-Driven Desalination Applications

Solar-driven seawater desalination systems provide freshwater through environmentally friendly and carbon-neutral processes. Air humidification and dehumidification desalination (HDD) systems extract water directly from moist air. This paper focuses on a new solar-driven seawater desalination system that shares some common traits with HDD systems but in which the air is eliminated from the process. Seawater is vaporized by solar thermal radiation in high-performance solar panels. Water vapor flows to a new electro-condensation chamber and passes through a series of electrosprays, which inject small nuclei of freshwater droplets into the vapor clouds. Here, due to dielectrophoresis and electrohydrodynamic flows, the vapor molecules are captured by the charged droplets, and vapor is condensed at the droplet surface. The water vapor condensation was modeled by using the multiphase flow numerical model. The CFD model, which was also experimentally validated, used SprayFoam solver modules available in the Open FOAM® CFD open-source software. In preliminary results, 802 grams/(hr-m2) (grams per hour per unit area) of water was harvested directly from moist air at 24C and 90% relative humidity. The simulation results indicated that freshwater productivity could increase up to 4,000 grams/(hr-m2) for fully saturated air conditions. This represents about 5 times the water productivity rate of current conventional HDD systems today. In addition, energy consumption could be reduced by 80 percent compared to conventional HDD systems.

Electrospray, electro-condensation, solar, droplet↗

DOE OSTI2015

A review of the remote sensing of lower tropospheric thermodynamic profiles and its indispensable role for the understanding and the simulation of water and energy cycles: REMOTE SENSING OF THERMODYNAMIC PROFILES

A review of remote sensing technology for lower tropospheric thermodynamic (TD) profiling is presented with focus on high accuracy and high temporal-vertical resolution. The contributions of these instruments to the understanding of the Earth system are assessed with respect to radiative transfer, land surface-atmosphere feedback, convection initiation, and data assimilation. We demonstrate that for progress in weather and climate research, TD profilers are essential. These observational systems must resolve gradients of humidity and temperature in the stable or unstable atmospheric surface layer close to the ground, in the mixed layer, in the interfacial layer—usually characterized by an inversion—and the lower troposphere. A thorough analysis of the current observing systems is performed revealing significant gaps that must be addressed to fulfill existing needs. We analyze whether current and future passive and active remote sensing systems can close these gaps. A methodological analysis and demonstration of measurement capabilities with respect to bias and precision is executed both for passive and active remote sensing including passive infrared and microwave spectroscopy, the global navigation satellite system, as well as water vapor and temperature Raman lidar and water vapor differential absorption lidar. Whereas passive remote sensing systems are already mature with respect to operational applications, active remote sensing systems require further engineering to become operational in networks. However, active remote sensing systems provide a smaller bias as well as higher temporal and vertical resolutions. For a suitable mesoscale network design, TD profiler system developments should be intensified and dedicated observing system simulation experiments should be performed.

58 GEOSCIENCES↗

DOE OSTI2018

Role of water-rock interaction in the geochemical evolution of Marcellus Shale produced waters

Gaining knowledge of geochemical processes that occur during hydraulic fracturing of shale resources for natural gas recovery can provide insight into in situ mineral precipitation and dissolution reactions that affect shale pore and fracture networks, and ultimately the ability to recover natural gas. Measurement of dissolved chemical species in produced waters, which serve as indicators of water-rock reactions in the reservoir, is one approach for monitoring subsurface geochemistry. However, an ability to distinguish effects of water-rock reactions versus reservoir fluid mixing on chemical concentration and speciation in produced waters requires experimental investigation to better understand natural geochemical tracer behavior.

04 OIL SHALES AND TAR SANDS↗

DOE OSTI2024

Shifting groundwater fluxes in bedrock fractures: Evidence from stream water radon and water isotopes

Geologic features (e.g., fractures and alluvial fans) can play an important role in the locations and volumes of groundwater discharge and degree of groundwater-surface water (GW-SW) interactions. However, the role of these features in controlling GW-SW dynamics and streamflow generation processes are not well constrained. GW-SW interactions and streamflow generation processes are further complicated by variability in precipitation inputs from summer and fall monsoon rains, as well as declines in snowpack and changing melt dynamics driven by warming temperatures. Using high spatial and temporal resolution radon and water stable isotope sampling and a 1D groundwater flux model, we evaluated how groundwater contributions and GW-SW interactions varied along a stream reach impacted by fractures (fractured-zone) and below the fractured hillslope (non-fractured zone) in Coal Creek, a Colorado River headwater stream affected by summer monsoons. During early summer, groundwater contributions from the fractured zone dominated, but declined throughout the summer. Groundwater contributions from the non-fractured zone were constant throughout the summer and became proportionally more important later in the summer. We hypothesize that groundwater in the non-fractured zone is dominantly sourced from a high-storage alluvial fan at the base of a tributary that is connected to Coal Creek throughout the summer and provides consistent groundwater influx. Water isotope data revealed that Coal Creek responds quickly to incoming precipitation early in the summer, and summer precipitation becomes more important for streamflow generation later in the summer. We quantified the change in catchment dynamic storage and found it negatively related to stream water isotope values, and positively related to modeled groundwater discharge and the ratio of fractured zone to non-fractured zone groundwater. Importantly, we interpret these relationships as declining hydrologic connectivity throughout the summer leading to late summer streamflow supported predominantly by shallow flow paths, with variable response to drying from geologic features based on their storage. As groundwater becomes more important for sustaining summer flows, quantifying local geologic controls on groundwater inputs and their response to variable moisture conditions may become critical for accurate predictions of streamflow.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2019

Interfacial Water Features at Air-Water Interfaces as Influenced by Charged Surfactants

The features of interfacial water at air-water interfaces of anionic sodium dodecyl sulfate (SDS) and cationic dodecyl amine hydrochloride (DDA) solutions were examined by combining sum frequency generation (SFG) vibrational spectroscopy measurements and molecular dynamics simulations (MDS). The SFG spectra and MDS results revealed that interfacial water molecules for SDS solutions were highly-ordered compared with those for DDA solutions. Also, SFG results showed that interfacial water molecules at pH 9 in both SDS and DDA solutions were less-ordered than at pH 7. Experiments on foam stability and foam weight were conducted under the same conditions. Foams for SDS solutions were more stable at pH 7 than at pH 9. The opposite was observed for DDA solutions, in which case stability decreased when pH increased. Results were explained based on the extent of surfactant hydration at interfaces, which is thought to account for film rupture based on foam stability results. This research was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences.

molecular dynamics simulations (MDS), film stabili↗

DOE OSTI2016

Experimental investigation of defect-assisted and intrinsic water vapor permeation through ultrabarrier films

In the development of ultrabarrier films for packaging electronics, the effective water vapor transmission rate is a combination of permeation through pinhole defects and the intrinsic permeation through the actual barrier film. While it is possible to measure the effective permeation rate through barriers, it is important to develop a better understanding of the contribution from defects to the overall effective barrier performance. Here, we demonstrate a method to investigate independently defect-assisted permeation and intrinsic permeation rates by observing the degradation of a calcium layer encapsulated with a hybrid barrier film, that is, prepared using atomic layer deposition (ALD) and plasma enhanced deposition (PECVD). The results are rationalized using an analytical diffusion model to calculate the permeation rate as a function of spatial position within the barrier. It was observed that a barrier film consisting of a PECVD SiN{sub x} layer combined with an ALD Al{sub 2}O{sub 3}/HfO{sub x} nanolaminate resulted in a defect-assisted water vapor transmission rate (WVTR) of 4.84 × 10{sup −5} g/m{sup 2} day and intrinsic WVTR of 1.41 × 10{sup −4} g/m{sup 2} day at 50 °C/85% RH. Due to the low defect density of the tested barrier film, the defect-assisted WVTR was found to be three times lower than the intrinsic WVTR, and an effective (or total) WVTR value was 1.89 × 10{sup −4} g/m{sup 2} day. Thus, improvements of the barrier performance should focus on reducing the number of defects while also improving the intrinsic barrier performance of the hybrid layer.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2016

Titanium and/or Aluminum Rod-Replacement Experiments in Fully-Reflected Water-Moderated Square-Pitched U(6.90)O 2 Fuel Rod Lattices with 0.67 Fuel to Water Volume Ratio (0.800 CM Pitch)

The US Department of Energy (DOE) Nuclear Energy Research Initiative funded the design and construction of the Seven Percent Critical Experiment (7uPCX) at Sandia National Laboratories. The start-up of the experiment facility and the execution of the experiments described here were funded by the DOE Nuclear Criticality Safety Program. The 7uPCX is designed to investigate critical systems with fuel for light water reactors in the enrichment range above 5% 235 U. The 7uPCX assembly is a water-moderated and -reflected array of aluminum-clad square-pitched UO2 fuel rods. The uranium is enriched to 6.90% by mass. Sets of 36 titanium and aluminum experiment rods with the same nominal outside diameter as the fuel rods were fabricated and used as replacements for fuel rods in the array. The twenty-four 7uPCX critical experiments reported here compare the effects of the titanium and aluminum replacement rods on nearly critical fuel rod arrays. The fuel used in these experiments was fabricated using unirradiated UO 2 fuel pellets from fuel elements designed to be used in the internal nuclear superheater section of the Pathfinder boiling water reactor operated in South Dakota by the Northern States Power Company in the 1960s. The fuel elements were obtained from The Pennsylvania State University where they had been stored for many years. The fuel pellets in those fuel elements were removed from the original Incoloy cladding and reclad in 3003 aluminum tubes and end caps for use in the experiments reported here. The nominal outside diameter of the fuel pellets is 0.207 in (0.52578 cm). The nominal outside diameter of the fuel rod cladding is 0.250 in (0.635 cm). The distance between the fuel rods in the square-pitched array is 0.315 in (0.8001 cm). This geometry gives a fuel-to-water volume ratio of 0.67 in the array. The twenty-four critical experiments in this series were performed in 2015 and 2016 at the Sandia Critical Experiments Facility. The first of the experiments had no replacement rods in the array and was intended to provide a baseline against which the experiments containing replacement rods could be compared. Eight critical experiments had titanium replacement rods in various numbers and arrangements near the center of the fuel array. Eight critical experiments had aluminum replacement rods in the same numbers and arrangements as in the eight experiments containing titanium experiment rods. In the final four experiments, fuel rods were removed from a central region of the array so that the pitch of the fuel rods in this part of the array was effectively doubled. This softened the neutron spectrum in the central part of the fuel array. Thirty-six replacement rods in different combinations of titanium and/or aluminum were placed in the interstices created in the center of the array. All twenty-four critical experiments are judged to be acceptable as benchmark experiments.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2021

Surface Water Chemistry and Water and Nitrogen Isotopes, Teller Road Site, Seward Peninsula, Alaska, 2016 and 2017

Data include results from water chemistry and water isotope analyses for surface water samples collected at the NGEE Arctic Teller Road site at mile marker 27 (TL_MM27) on the Seward Peninsula, Alaska, July through September of 2016 and May through September of 2017. The samples were collected using automated samplers (ISCO Model 6712; Teledyne, USA), with regular collection (every 24 hrs in 2016 and every 48 hrs in 2017). Surface water samples were collected from three locations along the main drainage: ISCO 1 from the tributary (64.729060°, -165.946210°), ISCO 3 which was located upstream (64.733640°, -165.955410°) and ISCO 2 which was located downstream (64.726410°, -165.946820°). Dataset includes a *.pdf user guide and one *.csv data file.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2019

Evaluating Water Assets Using Water Efficiency Framework for Infrastructure Intensive Agency

Water infrastructure-intensive organizations should incorporate sustainability principles when making decisions on infrastructure investments to ensure the long-term resilience of mission-critical equipment and components. A water efficiency evaluation framework to inform infrastructure investments is discussed and applied to three federal campuses. The methodology considered emphasizes the iterative process between data analysis and decision-making; evaluates cost-sharing solution alternatives when making final recommendations; considers both internal and external stakeholder perceptions of project outcomes and future planning; and makes explicit government and community preferences when evaluating projects. Case study findings underscore condition evaluations for infrastructure that are critical to setting a baseline for system performance and determining desired potential upgrades and sustainment strategies. Such a holistic approach has demonstrated effectiveness for understanding, classifying, and recommending innovative water asset solutions that are necessary for the public sector to consider in today’s complex, modern planning environment.

Asset Management, Alternative Water, evaluation, P↗

DOE OSTI2018

Association of hydrophilic derivatives of chlorophyll a in ethanol–water and ethanol–water–solubilizer systems

Electronic absorption spectroscopy and fluorescence spectroscopy were used to study conditions for the formation of associates of amphiphilic phorbins and chlorins in an ethanol–water system. The conditions and degree of disaggregation in the presence of solubilizing additives of nonionic surfactants (Tween 80) and biocompatible polymers (polyethylene glycol and polyvinylpyrrolidone) were also investigated. The propensity of the macroheterocycles based on chlorophyll a to association in water-alcoholic solutions decreases on going from covalently bound dimeric structures to monomeric ones, on going from phorbins to chlorins and on accumulating hydrophilic glycol or positively charged alkylammonium fragments in the molecule. Among the considered solubilizers, the nonionic surfactant Tween 80 emerged as the most efficient means for destroying chlorin associates in water–alcohol solutions with a high content of water.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Hourly water-carbon interactions modulate decadal water-use efficiency trends inferred from ecosystem-scale measurements

Plant stomatal conductance regulates photosynthesis and transpiration. This physiological link affects ecosystem responses to microclimate and harmonizes carbon, energy, and water exchanges between the biosphere and atmosphere. The relationship between water losses via transpiration and carbon gains via photosynthesis can be quantified by plant water-use efficiency (WUE). While leaf- and ecosystem-scale observations both suggest rising WUE in recent decades, WUE trends inferred from the ecosystem scale are much larger than those inferred from the leaf scale or implied by theory. The unexpectedly large ecosystem-scale WUE trends complicate interpretation of ecophysiological responses to changing environmental conditions. Here, we analyze ecosystem-scale WUE inferred from 40 FLUXNET sites, each with at least 10 years of measurements. Furthermore, our results demonstrate that observed ecosystem-scale WUE trends are more sensitive to hourly weather conditions than longer-term changes in atmospheric carbon dioxide or vapor pressure deficit. Our analysis shows that Earth System Models participating in CMIP6 did not capture the observed WUE sensitivity to inter-site variability and microclimatic conditions. Collectively, our findings suggest that ecosystem-scale WUE trends reflect water-carbon interactions across multiple temporal scales, and disentangling factors contributing to emergent ecosystem responses is needed to infer ecophysiological relationships and model structures from observations.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2017

Clustering of water molecules in ultramicroporous carbon: In-situ small-angle neutron scattering

Not Available

Bahadur, J. (ORCID:0000000225472907)↗

DOE OSTI2018

The nexus between water, energy, and food in the context of the global risks: An analysis of the interactions between food, water, and energy security

The purpose of this article is to analyze the interactions between water, energy, and food security, referenced in this study as the nexus between water, energy, and food, and the impacts of global risks using the World Economic Forum's, 2017 Global Risks Report as a guideline. In this analysis, the authors reveal that water, energy, and food are interdependent and essential resources demanding sustainable, integrated and intelligent management. These vital resources are susceptible to many global risks which are maximized by extreme weather events, mass involuntary human migrations, and other hazards that predominantly endanger the vulnerable communities of less developed countries. In conclusion, policies carried out by the international community, decision-makers, civil society, and the private sector, must align to target and mitigate global risks, specifically, water, energy and food security.

54 ENVIRONMENTAL SCIENCES↗