SEARCH · Engineering Papers
Results for “Solution structure”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Optimal local control of flexible structures
The steady state solution of the linear quadratic optimal control problem with the constraint that only partial state information is available for feedback is derived. This development results in a systematic and computationally efficient approach for reducing the complexity of the control law for high order systems. Numerical examples and performance evaluation of (1) a simple fourth order system, and (2) a free-free flexible beam, are included.
Analysis of lossy composite terminating structures
A finite element solution and computer code for the electromagnetic scattering of inhomogeneous penetrable bodies is presented. The application for the code is for the analysis and design of leading and trailing edge terminations when conducting and nonconducting materials are used. Examples of simple triangular shaped terminations are also presented.
Review of Current State of the Art and Key Design Issues With Potential Solutions for Liquid Hydrogen Cryogenic Storage Tank Structures for Aircraft Applications
Due to its high specific energy content, liquid hydrogen (LH2) is emerging as an alternative fuel for future aircraft. As a result, there is a need for hydrogen tank storage systems, for these aircraft applications, that are expected to provide sufficient capacity for flight durations ranging from a few minutes to several days. It is understood that the development of a large, lightweight, reusable cryogenic liquid storage tank is crucial to meet the goals of and supply power to hydrogen-fueled aircraft, especially for long flight durations. This report provides an annotated review (including the results of an extensive literature review) of the current state of the art of cryogenic tank materials, structural designs, and insulation systems along with the identification of key challenges with the intent of developing a lightweight and long-term storage system for LH2. The broad classes of insulation systems reviewed include foams (including advanced aerogels) and multilayer insulation (MLI) systems with vacuum. The MLI systems show promise for long-term applications. Structural configurations evaluated include single- and double-wall constructions, including sandwich construction. Potential wall material candidates are monolithic metals as well as polymer matrix composites and discontinuously reinforced metal matrix composites. For short-duration flight applications, simple tank designs may suffice. Alternatively, for longer duration flight applications, a double-wall construction with a vacuum-based insulation system appears to be the most optimum design. The current trends in liner material development are reviewed in the case that a liner is required to minimize or eliminate the loss of hydrogen fuel through permeation.
Atmospheric-pressure ionization and fragmentation of molecules for structural elucidation
A solution-cathode glow discharge (SCGD) spectrometry apparatus may comprise an SCGD source and a mass or ion mobility spectrometer. A method for ionizing a molecular analyte may comprise contacting the molecular analyte with a plasma discharge to form ions and separating the ions in a mass spectrometer or ion mobility spectrometer. The contacting step may occur under atmospheric pressure and/or ambient conditions. The molecular analyte may be fragmented by the plasma discharge.
Atmospheric-pressure ionization and fragmentation of molecules for structural elucidation
A solution-cathode glow discharge mass spectrometry (SCGD-MS) apparatus comprises a SCGD source and a mass spectrometer. The SCGD source may comprise conductive rods, a power source, and a capillary. A method for ionizing an analyte comprises flowing an electrically conductive liquid onto a conductive rod, applying an electric potential to a second conductive rod such that a plasma discharge forms between the first conductive rod and the electrically conductive liquid to produce ions, and separating the ions in a mass spectrometer. The analyte may be a polypeptide that may be contacted with trypsin. The analyte may be a solid, liquid, gas, chemical complex, or ion in solution. The method may comprise sequencing the polypeptide.
Decoding the 2D IR spectrum of the aqueous proton with high-level VSCF/VCI calculations
The aqueous proton is a common and long-studied species in chemistry, yet there is currently intense interest devoted to understanding its hydration structure and transport dynamics. Typically described in terms of two limiting structures observed in gas-phase clusters, the Zundel H 5 O 2 + and Eigen H 9 O 4 + ions, the aqueous structure is less clear due to the heterogeneity of hydrogen bonding environments and room-temperature structural fluctuations in water. The linear infrared (IR) spectrum, which reports on structural configurations, is challenging to interpret because it appears as a continuum of absorption, and the underlying vibrational modes are strongly anharmonically coupled to each other. Recent two-dimensional IR (2D IR) experiments presented strong evidence for asymmetric Zundel-like motifs in solution, but true structure–spectrum correlations are missing and complicated by the anharmonicity of the system. In this study, we employ high-level vibrational self-consistent field/virtual state configuration interaction calculations to demonstrate that the 2D IR spectrum reports on a broad distribution of geometric configurations of the aqueous proton. We find that the diagonal 2D IR spectrum around 1200 cm –1 is dominated by the proton stretch vibrations of Zundel-like and intermediate geometries, broadened by the heterogeneity of aqueous configurations. There is a wide distribution of multidimensional potential shapes for the proton stretching vibration with varying degrees of potential asymmetry and confinement. In conclusion, we find specific cross peak patterns due to aqueous Zundel-like species. These studies provide clarity on highly debated spectral assignments and stringent spectroscopic benchmarks for future simulations.
Free vibration and dynamic response analysis of spinning structures
The proposed effort involved development of numerical procedures for efficient solution of free vibration problems of spinning structures. An eigenproblem solution procedure, based on a Lanczos method employing complex arithmetic, was successfully developed. This task involved formulation of the numerical procedure, FORTRAN coding of the algorithm, checking and debugging of software, and implementation of the routine in the STARS program. A graphics package for the E/S PS 300 as well as for the Tektronix terminals was successfully generated and consists of the following special capabilities: (1) a dynamic response plot for the stresses and displacements as functions of time; and (2) a menu driven command module enabling input of data on an interactive basis. Finally, the STARS analysis capability was further improved by implementing the dynamic response analysis package that provides information on nodal deformations and element stresses as a function of time. A number of test cases were run utilizing the currently developed algorithm implemented in the STARS program and such results indicate that the newly generated solution technique is significantly more efficient than other existing similar procedures.
Effects of Intra- and Interchain Interactions on Exciton Dynamics of PTB7 Revealed by Model Oligomers
Recent studies have shown that molecular aggregation structures in precursor solutions of organic photovoltaic (OPV) polymers have substantial influence on polymer film morphology, exciton and charge carrier transport dynamics, and hence, the resultant device performance. To distinguish photophysical impacts due to increasing π-conjugation from chain lengthening and π–π stacking from single/multi chain aggregation in solution and film, we used oligomers of a well-studied charge transfer polymer PTB7 with different lengths as models to reveal intrinsic photophysical properties of a conjugated segment in the absence of inter-segment aggregation. In comparison with previously studied photophysical properties in polymeric PTB7, we found that oligomer dynamics are dominated by a process of planarization of the conjugated backbone into a quinoidal structure that resembles the self-folded polymer and that, when its emission is isolated, this quinoidal excited state resembling the planar polymer chain exhibits substantial charge transfer character via solvent-dependent emission shifts. Furthermore, the oligomers distinctly lack the long-lived charge separated species characteristic of PTB7, suggesting that the progression from charge transfer character in isolated chains to exciton splitting in neat polymer solution is modulated by the interchain interactions enabled by self-folding.
Periodic Trends within Actinyl(VI) Nitrates and Their Structures, Vibrational Spectra, and Electronic Properties
In this work, a series of actinyl(VI) nitrate salts of the form MAnO 2 (NO 3 ) 3 , where M = NH 4 + K + , Rb + , Cs + , and Me 4 N + and AnO 2 2+ = U, Np, Pu, and AnO 2 (NO 3 ) 2 (H 2 O) 2 ·H 2 O, and the uranyl tetranitrates M 2 UO 2 (NO 3 ) 4 have been synthesized from aqueous solution and their structures determined using single-crystal X-ray diffraction. Together, these complexes represent an isostructural series of actinide complexes among the salts crystallized with the same charge-compensating cation and have been studied using vibrational spectroscopy including Raman and Fourier-transform infrared. Periodic trends in both the structural properties of these complexes and their vibrational spectra are presented and discussed, in particular the invariant nature of the O≡An≡O asymmetric stretching frequencies observed across the actinyl series. Electronic structure calculations were performed at a variety of levels of theory to aid in the interpretation of the vibrational data and to correlate trends in the data with the underlying electronic properties of these molecules.
Performance Evaluation of Comparative Vacuum Monitoring and Piezoelectric Sensors for Structural Health Monitoring of Rotorcraft Components
The costs associated with the increasing maintenance and surveillance needs of aging structures are rising at an unexpected rate. Multi-site fatigue damage, hidden cracks in hard-to-reach locations, disbonded joints, erosion, impact, and corrosion are among the major flaws encountered in today’s extensive fleet of aging aircraft and space vehicles. Aircraft maintenance and repairs represent about a quarter of a commercial fleet’s operating costs. The application of Structural Health Monitoring (SHM) systems using distributed sensor networks can reduce these costs by facilitating rapid and global assessments of structural integrity. The use of in-situ sensors for real-time health monitoring can overcome inspection impediments stemming from accessibility limitations, complex geometries, and the location and depth of hidden damage. Reliable, structural health monitoring systems can automatically process data, assess structural condition, and signal the need for human intervention. The ease of monitoring an entire on-board network of distributed sensors means that structural health assessments can occur more often, allowing operators to be even more vigilant with respect to flaw onset. SHM systems also allow for condition-based maintenance practices to be substituted for the current time-based or cycle-based maintenance approach thus optimizing maintenance labor. The Federal Aviation Administration has conducted a series of SHM validation and certification programs intended to comprehensively support the evolution and adoption of SHM practices into routine aircraft maintenance practices. This report presents one of those programs involving a Sandia Labs-aviation industry effort to move SHM into routine use for aircraft maintenance. The Airworthiness Assurance NDI Validation Center (AANC) at Sandia Labs, in conjunction with Sikorsky, Structural Monitoring Systems Ltd., Anodyne Electronics Manufacturing Corp., Acellent Technologies Inc., and the Federal Aviation Administration (FAA) carried out a trial validation and certification program to evaluate Comparative Vacuum Monitoring (CVM) and Piezoelectric Transducers (PZT) as a structural health monitoring solution to specific rotorcraft applications. Validation tasks were designed to address the SHM equipment, the health monitoring task, the resolution required, the sensor interrogation procedures, the conditions under which the monitoring will occur, the potential inspector population, adoption of CVM and PZT systems into rotorcraft maintenance programs and the document revisions necessary to allow for their routine use as an alternate means of performing periodic structural inspections. This program addressed formal SHM technology validation and certification issues so that the full spectrum of concerns, including design, deployment, performance and certification were appropriately considered. Sandia Labs designed, implemented, and analyzed the results from a focused and statistically relevant experimental effort to quantify the reliability of a CVM system applied to Sikorsky S-92 fuselage frame application and a PZT system applied to an S-92 main gearbox mount beam application. The applications included both local and global damage detection assessments. All factors that affect SHM sensitivity were included in this program: flaw size, shape, orientation and location relative to the sensors, as well as operational and environmental variables. Statistical methods were applied to performance data to derive Probability of Detection (POD) values for SHM sensors in a manner that agrees with current nondestructive inspection (NDI) validation requirements and is acceptable to both the aviation industry and regulatory bodies. The validation work completed in this program demonstrated the ability of both CVM and PZT SHM systems to detect cracks in rotorcraft components. It proved the ability to use final system response parameters to provide a Green Light/Red Light (“GO” – “NO GO”) decision on the presence of damage. In additional to quantifying the performance of each SHM system for the trial applications on the S-92 platform, this study also identified specific methods that can be used to optimize damage detection, guidance on deployment scenarios that can affect performance and considerations that must be made to properly apply CVM and PZT sensors. These results support the main goal of safely integrating SHM sensors into rotorcraft maintenance programs. Additional benefits from deploying rotorcraft Health and Usage Monitoring Systems (HUMS) may be realized when structural assessment data, collected by an SHM system, is also used to detect structural damage to compliment the operational environment monitoring. The use of in-situ sensors for health monitoring of rotorcraft structures can be a viable option for both flaw detection and maintenance planning activities. This formal SHM validation will allow aircraft manufacturers and airlines to confidently make informed decisions about the proper utilization of CVM and PZT technology. It will also streamline future regulatory actions and formal certification measures needed to assure the safe application of SHM solutions.
Numerical Simulation of THM Growth of CdTe in Presence of Rotating Magnetic Fields
The influence of rotating magnetic fields (RMF) on the flow pattern and compositional uniformity in the solution zone of a traveling heater method (THM) system for growth of CdTe is numerically investigated. The analysis is conducted at the 10(exp -6) and 10(exp -1) g(sub 0) as representative of space and ground processing conditions. It is shown that under microgravity conditions, application of RMF can be used to overwhelm residual buoyancy-induced convection and to control the uniformity of solution-zone composition at the growth front without appreciable modification of the growth interface shape. At high gravity levels, RMF is found not to be able to completely dominate buoyancy-induced convection. In this regime, for the range of field strengths studied, RMF is found to result in a) complex flow structures in the solution zone, b) enhancement of compositional non-uniformities at the growth front, and c) increased convexity of the growth interface. A scaling analysis of convection in the solution zone is used to generate a non-dimensional map delineating the RMF- and gravity-dominated flow regimes.
Analysis of shell type structures subjected to time dependent mechanical and thermal loading
A general mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic or static thermomechanical loads is considered. Among the system responses, which are associated with these load conditions, are thermal buckling, creep buckling and ratchetting. Thus, geometric as well as material-type nonlinearities (of high order) can be anticipated and must be considered in the development of the mathematical model.
Effect of heat treatment on creep behavior of 316 L stainless steel manufactured by laser powder bed fusion
The objective of this study is to understand the thermal stability of microstructure and its effect on the creep behavior of additively-manufactured 316L stainless steel (AM 316L SS). Creep specimens were fabricated from rods printed by a laser powder bed fusion process. Six different heat treatments, namely 650 °C/1 h, 700 °C/1 h, 750 °C/1 h, 800 °C/1 h, 900 °C/1 h and 1050 °C/1 h were applied to the creep specimens. The heat-treated specimens were creep-tested under the same condition, 550 °C/275 MPa to evaluate the effect of post-build heat treatment on the creep behavior of AM 316L SS. In the temperature range of 650-750 °C, dislocation density within cells, and cell size and wall thickness were affected by the heat treatment, while elemental segregation at boundaries remained unchanged and Mn-enriched Si oxide particles remained stable. In the temperature range of 750-900 °C, concurrent changes were observed in dislocation cell structures, elemental segregation and oxide particles. The 1050 °C-heat treatment removed cell structures and boundary solute segregations, leading to formation of equiaxed grains; Mn-enriched Si oxide particles in the as-built specimen were replaced by more stable Mn-enriched Cr oxides. The creep life of AM 316L SS increased after the heat treatment at 650 °C and then decreased with increasing temperature up to 900 °C where cell/subgrain structures still existed. The creep rate and creep elongation followed an opposite trend. The creep rate can be correlated with the structural parameters of cell/subgrain size and cell wall/boundary thickness and can be rationalized by different strengthening mechanisms of dislocation cells and subgrains. The heat treatment affected strongly the primary and secondary creep but had a minimal effect on the tertiary creep of AM 316L SS.
Dirac oscillator: An alternative basis for nuclear structure calculations
The isotropic harmonic oscillator supplemented by a strong spin-orbit interaction has been the cornerstone of nuclear structure since its inception more than seven decades ago. In this paper we introduce—or rather re-introduce—the “Dirac oscillator,” a fully relativistic basis that has all the desired attributes of the ordinary harmonic oscillator while naturally incorporating a strong spin-orbit coupling. To assess the power and flexibility of the Dirac oscillator basis in the solution of nuclear structure problems within the framework of covariant density-functional theory. Here, self-consistent calculations of binding energies and ground-state densities for a selected set of doubly magic nuclei are performed using the Dirac oscillator basis and are then compared against results obtained with the often-used Runge-Kutta method. Results obtained using the Dirac oscillator basis reproduce with high accuracy those derived using the Runge-Kutta method and suggest a clear path for a generalization to systems with axial symmetry. Although the harmonic oscillator with spin-orbit corrections has been the staple of the nuclear shell model since the beginning, the Dirac oscillator is practically unknown among the nuclear physics community. In this paper we illustrate the power and flexibility of the Dirac oscillator and suggest extensions to the study of systems without spherical symmetry, as required in constrained calculations of nuclear excitations.
New class of Si-based superlattices - Alternating layers of crystalline Si and porous amorphous Si(1-x)Ge(x) alloys
Superlattices consisting of alternating layers of crystalline Si and porous amorphous Si(1-x)Ge(x) have been fabricated. This is accomplished by first growing a Si/Si(0.7)Ge(0.3) superlattice by molecular beam epitaxy, followed by Ar-ion milling to form mesa structures, and finally by immersion in HF:HNO3:H2O. This solution creates a porous structure similar to that created by anodic etching, and a high selectivity is observed for the conversion of the alloy layers relative to the Si layers. The degree of selectivity is found to depend on alloy-layer thickness and strain. Superlattices have been fabricated from 1-micron wide mesas with Si(0.7)Ge(0.3) layers fully converted to 5-nm thick porous amorphous material.
Free vibration analysis of spinning flexible space structures
Efficient computation of natural frequencies and associated free vibration modes of spinning flexible structures is required to accurately determine the nature of interaction between the flexible structure and the attitude control system, which is vital in relating control torques to attitude angles. While structural discretization is effected by the finite element method, the resulting eigenvalue problem is solved by a combined Sturm sequence and inverse iteration procedure that yields a few specified roots and associated vectors. An eigenvalue procedure, based on a simultaneous iteration technique, provides efficient computation of the first few roots and vectors; a modal synthesis procedure proves to be useful for eigenproblem solutions of unusual structures such as spacecraft.
Free vibration analysis of spinning flexible space structures
Efficient computation of natural frequencies and associated free vibration modes of spinning flexible structures is required to accurately determine the nature of interaction between the flexible structure and the attitude control system, which is vital in relating control torques to attitude angles. While structural discretization is effected by the finite element method, the resulting eigenvalue problem is solved by a combined Sturm sequence and inverse iteration procedure that yields a few specified roots and associated vectors. An eigenvalue procedure, based on a simultaneous iteration technique, provides efficient computation of the first few roots and vectors; a modal synthesis procedure proves to be useful for eigenproblem solutions of unusual structures such as spacecraft.