Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Solar to Hydrogen”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 523 records · Page 29

Alternate space station freedom configuration considerations to accommodate solar dynamic power

The results of a technical audit of the Space Station Freedom Program conducted by the Program Director was announced in early 1989 and included a proposal to use solar dynamic power generation systems to provide primary electrical energy for orbital flight operations rather than photovoltaic solar array systems. To generate the current program baseline power of 75 kW, two or more solar concentrators approximately 50 feet in diameter would be required to replace four pairs of solar arrays whose rectangular blanket size is approximately 200 feet by 30 feet. The photovoltaic power system concept uses solar arrays to generate electricity that is stored in nickel-hydrogen batteries. The proposed concept uses the solar concentrator dishes to reflect and focus the Sun's energy to heat helium-xenon gas to drive electricity generating turbines. The purpose here is to consider the station configuration issues for incorporation of solar dynamic power system components. Key flight dynamic configuration geometry issues are addressed and an assembly sequence scenario is developed.

Deryder, L. J.↗

Electrically enhanced thermochemical cycles for hydrogen generation

In two-step metal-oxide (MO) solar thermochemical cycles, high temperature solar thermal energy is first converted to chemical energy in the form of a reduced MO. The reduced MO is then reoxidized in a second step with steam (or carbon dioxide) to produce hydrogen (or carbon monoxide) at a lower temperature. Solar thermochemical cycles of this type circumvent heat-to-electrical conversion required for electrochemical water splitting and promise high efficiencies. However, significant challenges remain to implementation. Ultra-high temperatures and efficiency-sapping low per-cycle conversion stand out as particularly difficult hurdles. Hybrid approaches utilizing both thermal and electrical energy provide some of the advantages of each, and can facilitate lower temperature operation and offer better per-pass utilization than thermochemical alone. However, early concepts for implementing the thermo-electrochemical approach introduced substantial new challenges including difficult separations, corrosive environments, and energy losses from large temperature swings and phase changes. We are currently investigating two different options for implementation. In the first, a MO that reduces at lower temperature is selected. As the reduced MO lacks the full thermodynamic driving force to effectively split water, the reaction is driven forward by an electrically-assisted proton-conducting membrane that separates and recovers hydrogen as it is produced. This approach produces a pure hydrogen stream, is mechanically simple, and has unique thermodynamic advantages. The second option seeks to more directly couple the electrical boost to the solid MO to drive either the reduction or oxidation step, or both, through the utilization of layered MO materials and advanced reactors. This approach could be applied to both water and carbon dioxide splitting. The results of process modeling and optimization will be presented, and progress towards demonstrating the concepts at the laboratory scale will be discussed.

08 HYDROGEN↗

No cometesimals in the inner solar system

Ultraviolet measurements made by Voyager 2, apparently showing a rapid decrease in hydrogen Lyman-alpha emission with distance from the sun, were taken by Donahue et al. (1987) as evidence for a source of atomic hydrogen in the very local interstellar medium (VLISM). The suggested source of the hydrogen is a class of small comets at solar distances of about 1 AU. This claim has been adduced as evidence for a theory that the earth is subject to a large influx of cometary material significantly affecting atmospheric evolution. The Voyager 2 data have been reanalyzed, and it is shown that no source of hydrogen in the VLISM is required other than the inflow of neutral atoms.

Hall, D. T.↗

The Stability of the Low Degree 5 Minute Solar Oscillations

The decay rate for many of the low degree p modes observed as 5 minute oscillations of the Sun is discussed and decay rates for modes ranging from radial (l=0) to the nonradial ones with l=5 for overtones 10 through 28. Parameters needed for he solar model are given and the hydrogen mass fraction composition structure is shown as well as the structure given by Christensen-Dalsgaard (1982) for an evolved solar model. The special equation of state and opacity table with X=0.74 for the hydrogen mass fraction in the outer 0.40 of the mass needs slightly more hydrogen in the central regions than obtained by Christensen-Dalsgaard in order to give a complete and consistent model. The difference in helium production between these two models is about 10%, meaning that the total energy radiated by the Sun during its lifetime thus far agrees satisfactorily with accurately calculated evolution sequences.

Kidman, R. B.↗

Solar source regions of 3HE-rich particle events

Hydrogen alpha X-ray, and metric and kilometric radio data to examine the solar sources of energetic 3He-rich particle events observed near earth in association with impulsive 2 to 100 keV electron events were applied. Each 3He/electron event is associated with a kilometric type 3 burst belonging to a family of such bursts characterized by similar interplanetary propagation paths from the same solar active region. The 3He/electron events correlate very well with the interplanetary low frequency radio brightnesses of these events, but progressively worse with signatures from regions closer to the Sun. When H alpha brightnings can be associated with 3He/electron events, they have onsets coinciding to within 1 min of that of the associated metric type 3 burst but are often too small to be reported. The data are consistent with the earlier idea that many type 3 bursts, the 3He/electron events, are due to particle acceleration in the corona, well above the associated H alpha and X-ray flares.

Kahler, S. W.↗

Material Interactions with Solar Wind Ion Environments

Solar wind composition is dominated by hydrogen (approx.96%) and helium (approx.3 to 4%) with a minor fraction (less than or equal to 1%) of heavy ions. Hydrogen (helium) ions impact spacecraft surfaces with energies from 0.5 to 5 keV (1.8 to 21 keV) due to variations in solar wind velocity from 300 km/s to 1000 km/sec with extremes of a few 10 s keV during periods of extremely high solar wind velocity exceeding 1000 km/sec. Mean impact energies are typically on the order of approximately 1 keV and 4 keV for hydrogen ions and helium ions, respectively. These energies are typically of the peak of the energy dependent light ion sputter yields for hydrogen and helium on many metals. In addition, light ions with kilovolt energies have been shown to produce blister (or exfoliation) damage to metal surfaces due to formation of high pressure gas bubbles within the materials when exposed to ion fluences on the order of 10(exp 16 to (10(exp 17 ions/sq cm. A number of spacecraft designs for current and future missions include gossamer polymer structures with thin metallic reflection coatings to shield instruments from the Sun or solar sail propulsion systems for use in a variety of locations in the inner solar system from 0.5 to 1 AU. In addition, there is interest in designing spacecraft for solar physics missions requiring operations as close to the Sun as 0.16 to 0.2 AU. Integrity of the metallic coatings is critical in many of these applications since degradation will result in modification of material thermal properties or exposure of polymers to solar UV photons which can compromise mission requirements. This paper will evaluate the relative contributions of sputtering and blister formation to material degradation in solar wind environments over a range of radial distances from the Sun to demonstrate where solar wind environments become important for materials selection. We will first review the physics and results from laboratory measurements of light ion sputtering, blistering, and exfoliation of metallic surfaces to establish the order of magnitude ion fluence required for significant surface damage. Solar wind ion fluence environments will then be evaluated due to variations in solar wind conditions as a function of solar cycle for varying distances from the Sun using models for radial variations in solar wind ion number density, temperature, and velocity to determine where sputtering and blistering is most likely to be an issue. Finally, ion fluence statistics for varying radial distances from the Sun will be shown to establish the mission duration and radial distances from the Sun where missions will encounter sufficient ion fluence to exhibit damage to metallic surfaces.

Minow, Joseph I.↗

H2Integrate [SWR-23-31]

H2Integrate(H2I) is an open-source Python package for hybrid systems engineering design and technoeconomic analysis. It models and optimizes hybrid energy plants that produce electricity, hydrogen, ammonia, steel, and other products. H2Integrate is designed to be flexible and extensible, allowing users to create their own components and models for various energy systems. The tool currently includes distributed energy generation (wind, solar, wave, tidal), battery storage, hydrogen, ammonia, methanol, and steel technologies. Other elements such as desalination systems, pipelines, compressors, and storage systems can also be included as developed by users. Some modeling capabilities in H2Integrate are provided by integrating existing tools, such as HOPP, PySAM, ORBIT, and ProFAST. The H2Integrate tool is built on top of NASA's OpenMDAO framework, which provides a powerful and flexible environment for modeling and optimization.

King, Jennifer [National Renewable Energy Laborato↗

Solar Metal Sulfate-Ammonia Based Thermochemical Water Splitting Cycle for Hydrogen Production

Two classes of hybrid/thermochemical water splitting processes for the production of hydrogen and oxygen have been proposed based on (1) metal sulfate-ammonia cycles (2) metal pyrosulfate-ammonia cycles. Methods and systems for a metal sulfate MSO.sub.4--NH3 cycle for producing H2 and O2 from a closed system including feeding an aqueous (NH3)(4)SO3 solution into a photoctalytic reactor to oxidize the aqueous (NH3)(4)SO3 into aqueous (NH3)(2)SO4 and reduce water to hydrogen, mixing the resulting aqueous (NH3)(2)SO4 with metal oxide (e.g. ZnO) to form a slurry, heating the slurry of aqueous (NH4)(2)SO4 and ZnO(s) in the low temperature reactor to produce a gaseous mixture of NH3 and H2O and solid ZnSO4(s), heating solid ZnSO4 at a high temperature reactor to produce a gaseous mixture of SO2 and O2 and solid product ZnO, mixing the gaseous mixture of SO2 and O2 with an NH3 and H2O stream in an absorber to form aqueous (NH4)(2)SO3 solution and separate O2 for aqueous solution, recycling the resultant solution back to the photoreactor and sending ZnO to mix with aqueous (NH4)(2)SO4 solution to close the water splitting cycle wherein gaseous H2 and O2 are the only products output from the closed ZnSO4--NH3 cycle.

Huang, Cunping↗

Spatial structure of a two-phase solar flare observed in the EUV by OSO-7

Soft X-ray and hydrogen alpha observations on the structure of a solar flare show the typical flare behavior - a rapid rise to maximum and a gradual exponential decay, with good time correlation between the soft X-rays and H alpha. The emission is identified by Fe XI ion, and the emitting region is contoured on EUV maps.

Thomas, R. J.↗

CNO abundances and hydrodynamic models of the nova outburst. II - 1.00 solar mass models with enhanced carbon and oxygen

Results of a computation of a variety of evolutionary sequences involving thermonuclear runaways in the hydrogen-rich envelopes of 1.00-solar-mass carbon-oxygen white dwarfs. The evidence concerning the location of the outburst in the nova system is reexamined, and it is concluded that the white dwarf is the seat of the outburst. An order-of-magnitude argument is presented which indicates that for a 1.00-solar-mass white dwarf it is impossible to achieve mass ejection without an energy generation of approximately 10 to the 16th ergs/g/sec. A description is given of models with low nuclear enhancements that do not produce an outburst, although their evolution has certain implications for the cause of the dwarf-nova outburst. The results for models that produced a nova outburst are then presented, and on the basis of these results it is found possible to explain continuous ejection, Kukarkin and Parenago's (1934) relationship, and other gross features of the nova phenomena.

Starrfield, S.↗

Very low mass stars and white dwarfs in NGC 6397

Deep Wide Field/Planetary Camera 2 (WFPC2) images in wide bands centered at 606 and 802 nm were taken with the Hubble Space Telescope (HST) 4.6 min from the center of the galactic globular cluster NGC 6397. The images were used to accurately position approximately 2120 stars detected in the field on a color magnitude diagram down to a limiting magnitude m(sub 814) approximately = m(sub I) approximately = 26 determined reliably and solely by counting statistics. A white dwarf sequence and a rich, narrow cluster main sequence are detected for the first time, the latter stretching from m(sub 814) = 18.5 to m(sub 814) = 24.0 where it becomes indistinguishable from the field population. Two changes of slope of the main sequence at m(sub 814) approximately = 20 and m(sub 814) approximately = 22.5 are evident. The corresponding luminosity function increases slowly from M(sub 814) approximately = 6.5 to 8.5 are expected from ground-based observations but then drops sharply from there dwon to the measurement limit. The corresponding mass function obtained bu using the only presently available mass-luminosity function for the cluster's metallicity rises to a plateau between approximately 0.25 and approximately 0.15 solar mass, but drops toward the expected mass limit of the normal hydrogen burning main sequence at approximately 0.1 solar mass. This result is in clear contrast to that obtained from the ground and implies either a substantial modification of the cluster's initial mass function due to dynamical evolution in its lifetime, or that very low mass stars are not produced in any dynamically significant amount by clusters of this type. The white dwarf sequence is in reasonable agreement with a cooling sequence of models of mass 0.5 solar mass at the canonical distance of NGC 6397 with a scatter that is most likely due to photometric errors, but may also reflect real differences in mass or chemical composition. Contamination from unresolved galaxies, which cannot be reliably identified with our filters, makes it difficult to meaningfully compare the observed white dwarf luminosity function with its theoretical counterpart.

Paresce, Francesco↗

Spectroscopic observations of the planets

The first phase of a program to determine D/H in the atmospheres of all of the major planets and Titan was completed. D/H on Titan and Uranus is significantly higher than on Jupiter and Saturn. Titan has the highest value, consistent with the possibility for hydrogen escape. These measurements were all made in terms of CH3D/CH4. They suggest that at least two reservoirs for deuterium exist in the outer solar system - a large one in hydrogen and a much smaller one in hydrogen-containing compounds that have not isotopically equilibrated with the hydrogen. This result also demonstrates that a large fraction of the carbon in the outer solar nebula was in the form of methane and it supports the nucleation model for the formation of the outer planets. Other studies included an investigation of the phosphine abundance over the Great Red Spot (GRS) of Jupiter, pre-Voyager determination of the amount of acetylene on Uranus, and the carbon isotope ratio in Halley's Comet. UV spectra of the GRS obtained with the IUE show no evidence of the enhancement of phosphine that would be expected if the red color of this object is caused by P4.

Owen, T.↗

Hydrogen Passivation of Interstitial Zn Defects in Heteroepitaxial InP Cell Structures and Influence on Device Characteristics

Hydrogen passivation of heteroepitaxial InP solar cells is of recent interest for deactivation of dislocations and other defects caused by the cell/substrate lattice mismatch that currently limit the photovoltaic performance of these devices. In this paper we present strong evidence that, in addition to direct hydrogen-dislocation interactions, hydrogen forms complexes with the high concentration of interstitial Zn defects present within the p(+) Zn-doped emitter of MOCVD-grown heteroepitaxial InP devices, resulting in a dramatic increase of the forward bias turn-on voltage by as much as 280 mV, from ~680 mV to ~960 mV. This shift is reproducible and thermally reversible and no such effect is observed for either n(+)p structures or homoepitaxial p(+)n structures grown under identical conditions. A combination of photoluminescence (PL), electrochemical C-V dopant profiling, SIMS and I-V measurements were performed on a set of samples having undergone a matrix of hydrogenation and post-hydrogenation annealing conditions to investigate the source of this voltage enhancement and confirm the expected role of interstitial Zn and hydrogen. A precise correlation between all measurements is demonstrated which indicates that Zn interstitials within the p(+) emitter and their interaction with hydrogen are indeed responsible for this device behavior.

Ringel, S. A.↗

The solar ionisation rate deduced from Ulysses measurements and its implications to interplanetary Lyman alpha-intensity

We have developed a computer code which can be used to study 3-dimensional and time-dependent effects of the solar cycle on the interplanetary (IP) hydrogen distribution. The code is based on the inverted Monte Carlo simulation. In this work we have modelled the temporal behaviour of the solar ionisation rate. We have assumed that during the most of the time of the solar cycle there is an anisotopic latitudinal structure but right at the solar maximum the anisotropy disappears. The effects of this behaviour will be discussed both in regard to the IP hydrogen distribution and IP Lyman a a-intensity.

Summanen, T.↗

Global atomic hydrogen density derived from OGO-6 Lyman-alpha measurements

The paper analyzes a one-year set of Lyman-alpha airglow data measured in the local zenith at altitudes from 400 to 1100 km by a UV photometer aboard OGO-6. The zenith-intensity data are fitted to theoretical airglow calculations in four spherically symmetric models of the hydrogen geocorona to determine both the Ly-alpha solar flux at line center and the average atomic hydrogen column density. After correcting for a loss of instrument sensitivity, the Ly-alpha flux is found to be linearly correlated with daily Zurich sunspot number. It is also found that the hydrogen density is inversely correlated with Jacchia exospheric temperature, but the dependence is not that predicted by steady-state models with Jeans evaporative escape as the only loss mechanism. It is suggested that charge-exchange production of fast hydrogen atoms from 'hot' ionospheric protons might provide the additional loss this result requires.

Thomas, G. E.↗

Termination of the solar wind in the hot, partially ionized interstellar medium

Theoretical foundations for understanding the problem of the termination of the solar wind are reexamined in the light of most recent findings concerning the states of the solar wind and the local interstellar medium. The investigation suggests that a simple extention of Parker's (1961) analytical model provides a useful approximate description of the combined solar wind, interstellar wind plasma flowfield under conditions presently thought to occur. A linear perturbation solution exhibiting both the effects of photoionization and charge exchange is obtained for the supersonic solar wind. A numerical algorithm is described for computing moments of the non-equilibrium hydrogen distribution function and associated source terms for the MHD equations. Computed using the algorithm in conjunction with the extended Parker solution to approximate the plasma flowfield, profiles of hydrogen number density are given in the solar wind along the upstream and downstream axes of flow with respect to the direction of the interstellar wind. Predictions of solar Lyman-alpha backscatter intensities to be observed at 1 a.u. have been computed, in turn, from a set of such hydrogen number density profiles varied over assumed conditions of the interstellar wind.

Lombard, C. K.↗