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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Introductory study of the chemical behavior of jet emissions in photochemical smog

Jet aircraft emissions data from the literature were used as initial conditions for a series of computer simulations of photochemical smog formation in static air. The chemical kinetics mechanism used in these simulations was an updated version which contains certain parameters designed to account for hydrocarbon reactivity. These parameters were varied to simulate the reaction rate constants and average carbon numbers associated with the jet emissions. The roles of surface effects, variable light sources, NO/NO2 ratio, continuous emissions, and untested mechanistic parameters were also assessed. The results of these calculations indicate that the present jet emissions are capable of producing oxidant by themselves. The hydrocarbon/nitrous oxides ratio of present jet aircraft emissions is much higher than that of automobiles. These two ratios appear to bracket the hydrocarbon/nitrous oxides ratio that maximizes ozone production. Hence an enhanced effect is seen in the simulation when jet exhaust emissions are mixed with automobile emissions.

Whitten, G. Z.↗
NASA NTRS1979

The probability distribution of the predicted CFM-induced ozone depletion

It is argued from the central limit theorem that the uncertainty in model predicted changes of the ozone column density is best represented by a normal probability density distribution. This conclusion is validated by comparison with a probability distribution generated by a Monte Carlo technique. In the case of the CFM-induced ozone depletion, and based on the estimated uncertainties in the reaction rate coefficients alone the relative mean standard deviation of this normal distribution is estimated to be 0.29.

Ehhalt, D. H.↗
NASA NTRS1979

The history of an atmosphere of impact origin

Most of the masses accreting onto the earth and terrestrial planets impacted at sufficiently high velocities to release their volatiles into the atmosphere by impact-heating. However, based on models of planetary growth by accumulation from solid bodies, the time-scale for accretion was sufficiently long that the average surface temperatures could not have risen above 320 K. Using measured reaction rates, the released volatiles should have been re-incorporated into the planet by hydrating the surface minerals and were subsequently buried during accretion. Rapid hydration of impact products precludes the formation of a thick atmosphere as the planet accreted. Thus, only the subsequent differentiation and evolution of the terrestrial planets determined the size and composition of each planet's atmosphere.

Jakosky, B. M.↗
NASA NTRS1980

Evaluation of a locally homogeneous flow model of spray combustion

A simplified model of spray combustion was evaluated. The model was compared with measurements in both a gaseous propane flame and an air atomized n-pentane spray flame (35 micron Sauter mean diameter). Profiles of mean velocity, temperature, and species concentrations, as well as velocity fluctuations and Reynolds stress, were measured. The predictions for the gas flame were in excellent agreement with measurements, except for product species concentrations where errors due to finite reaction rates were detected. Predictions within the spray were qualitatively correct, but the model overestimated the rate of development of the flow; e.g., predicted flame lengths were 30% shorter than measured. Calibrated drop-life-history calculations showed that finite interphase transport rates caused the discrepancy and that initial drop diameters less than 20 microns would be required for quantitative accuracy of the model.

Mao, C.-P.↗
NASA NTRS1980

A study of the cleft region using synoptic ionospheric plasma data obtained by the polar orbiting satellites Aeros-B and Isis-2

The concentrations of O(+) and NO(+) in the dayside high-latitude cleft region of the ionosphere are investigated based on synoptic particle and plasma measurements obtained by the polar orbiting Aeros-B and Isis-2 satellites. At a time when the orbital planes of the satellites are almost at right angles to each other, three maxima in ion temperature are observed, with two of them accompanied by an increased electron temperature and electron density irregularities, and the density of the molecular ions NO(+) and O2(+) is found to increase at the expense of O(+) density. Results are discussed in terms of a theory relating perpendicular electric fields to oxygen atom reaction rates. Systematic analysis of the Aeros data base reveals 14 additional instances of O(+) to NO(+) conversion, with a large variety of forms and structures reflecting the complex structure and dynamics of the high-latitude dayside ionosphere.

Kist, R.↗
NASA NTRS1980

Theory of bubble dynamics in condensed explosive during start-up transient

Test firings with experimental liquid propellant gun systems indicate that the main concern standing in the way of practical application of LPG's is the possibility of unexpected explosions during start up when pressure is rapidly applied to the liquid monopropellant in the chamber. The phenomenon of many collapse-rebound cycles of imploding bubbles is theorized as the probable cause of explosions in LP systems. It may be concluded that LPG safety would be enhanced by choosing an LP with low bulk modulus, as well as low decomposition reaction rate, and that a benign looking DTA trace is not a sufficient quarantee of insensitivity to a pressure induced explosion. It is also shown that pre-pressurizing an LP charge, thus pre-compressing the bubbles near-isothermally, makes the system relatively insensitive to such pressure induced explosions. The applicability of this analysis to the question of acceleration induced explosion of explosive filled warheads is indicated.

Benreuven, M.↗
NASA NTRS1980

Environmental effects of an aircraft at cruise: An update

The status of the calculations of ozone change due to high altitude aircraft is critically reviewed and important areas of uncertainty identified. Laboratory determinations of chemical reaction rates and modeling refinements show that the effect of cruise altitude emissions on stratospheric ozone has changed from one of ozone decrease to one of slight increase. It is concluded that the uncertainties in the present understanding of the effects of high altitude aircraft are such as to warrant continued studies.

Sundararaman, N.↗
NASA NTRS1981

Effect of water vapor on sound absorption in nitrogen at low frequency/pressure ratios

Sound absorption measurements were made in N2-H2O binary mixtures at 297 K over the frequency/pressure range f/P of 0.1-2500 Hz/atm to investigate the vibrational relaxation peak of N2 and its location on f/P axis as a function of humidity. At low humidities the best fit to a linear relationship between the f/P(max) and humidity yields an intercept of 0.013 Hz/atm and a slope of 20,000 Hz/atm-mole fraction. The reaction rate constants derived from this model are lower than those obtained from the extrapolation of previous high-temperature data.

Zuckerwar, A. J.↗
NASA NTRS1981

A kinetics study of the reaction of SO2 with CH3O2

The reaction of CH3O2 with SO2 has been studied using the flash photolysis/ultraviolet absorption technique. In contrast to previous measurements, no reaction could be detected over the temperature range 298-423 K. An upper limit of 5 x 10 to the -17th cu cm/molecule/sec has been determined for the reaction rate constant.

Sander, S. P.↗
NASA NTRS1981

Implications of smaller concentrations of stratospheric OH - A two-dimensional model study of ozone perturbations

There is growing observational evidence that stratospheric OH concentrations are smaller than models have been predicting. Using very recent HOx reaction rate coefficient measurements in a two-dimensional photochemical model, results which support these observations are obtained. As a consequence of smaller OH concentrations, we show that perturbations of stratospheric ozone by NOx (SST emissions and nitrogen fertilizers) may be larger than expected, while perturbations due to added water vapor and chlorine (SSTs and chlorofluoromethanes, respectively) may be smaller.

Whitten, R. C.↗
NASA NTRS1981

Metal-semiconductor interfacial reactions - Ni/Si system

X-ray photoelectron spectroscopy and channeling measurements with MeV He-4(+) ions have been used to probe the structure of the interface in the Ni/Si system. It is found that reactions occur where Ni is deposited on Si at 10 to the -10th torr: Si atoms are displaced from lattice sites, the Ni atoms are in an Si-rich environment, and the Ni/Si interface is graded in composition. Composition gradients are present at both interfaces in the Si/Ni2/Si/Ni system. For the Ni-Si system, cooling the substrate to 100 K slows down the reaction rate. The temperature dependence of the interfacial reactivity indicates the kinetic nature of metal-semiconductor interfaces.

Cheung, N. W.↗
NASA NTRS1981

Evolutionary variations of solar luminosity

Theoretical arguments for a 30% increase in the solar luminosity over the past 4.7 billion years are reviewed. A scaling argument shows that this increase can be predicted without detailed numerical calculations. The magnitude of the increase is independent of nuclear reaction rates, as long as conversion of hydrogen to helium provides the basic energy source of the Sun. The effect of the solar luminosity increase on the terrestrial climate is briefly considered. It appears unlikely that an enhanced greenhouse effect, due to reduced gases (NH3, CH4), can account for the long-term paleoclimatic trends.

Endal, A. S.↗
NASA NTRS1982

Evolutionary variations of solar luminosity

The Theoretical arguments for a 30% increase in the solar luminosity over the past 4.7 billion years are reviewed. A scaling argument shows that this increase can be predicted without detailed numerical calculations. The magnitude of the increase is independent of nuclear reaction rates, as long as conversion of hydrogen to helium provides the basic energy source of the Sun. The effect of the solar luminosity increase on the terrestrial climate is briefly considered. It appears unlikely that an enhanced greenhouse effect, due to reduced gases (NH3, CH4), can account for the long-term paleoclimatic trends.

Endal, A. S.↗
NASA NTRS1982

Pulsed radiolysis of model aromatic polymers and epoxy based matrix materials

Models of primary processes leading to deactivation of energy deposited by a pulse of high energy electrons were derived for epoxy matrix materials and polyl-vinyl naphthalene. The basic conclusion is that recombination of initially formed charged states is complete within 1 nanosecond, and subsequent degradation chemistry is controlled by the reactivity of these excited states. Excited states in both systems form complexes with ground state molecules. These excimers or exciplexes have their characteristics emissive and absorptive properties and may decay to form separated pairs of ground state molecules, cross over to the triplet manifold or emit fluorescence. ESR studies and chemical analyses subsequent to pulse radiolysis were performed in order to estimate bond cleavage probabilities and net reaction rates. The energy deactivation models which were proposed to interpret these data have led to the development of radiation stabilization criteria for these systems.

Gupta, A.↗
NASA NTRS1981

The dissociative recombination of O2/+/ in the ionosphere

Aeronomical determinations of the dissociative recombination reaction rate coefficient for O2(+) and alpha depend directly on a knowledge of the rate coefficient for the charge exchange of O(+) with O2 and k. The aeronomical determination of alpha is reevaluated using Atmosphere Explorer satellite data in light of a subsequent laboratory measurement of k (Chen et al., 1978). The results are found to be in good agreement with laboratory determinations of the coefficient for night-time conditions. For data obtained under sunlit conditions, however, the results differed significantly with those of the laboratory measurements. These results imply that the state of the O2(+) molecule major thermospheric processes needs to be examined in greater detail.

Torr, M. R.↗
NASA NTRS1982

Non-isothermal effects on SO2 absorption by water droplets. I - Model development. II - Results and discussion

An analytic model of SO2 absorption in a falling water droplet is developed and a simulation of SO2 washout is performed. Nonisothermic effects on drop growth, droplet physical parameters, reaction rates, and multicomponent diffusion are treated in the model. The gas-liquid interface is assumed to be at equilibrium, and interfacial resistance is negligible. Raindrops are simulated as falling from a 2 km height through an atmospheric region containing SO2. The droplets decrease in size from evaporation and cooling, and their slightly basic pH aids SO2 absorption. The simulation indicates higher SO2 absorption at higher altitudes, and desorption may occur at ground level. Isothermal effects are concluded to be significant, and quantification of effects will depend on further modelling.

Reda, M.↗
NASA NTRS1982

Nucleosynthesis in novae - A source of Ne-E and Al-26

It is shown upon computation of the nucleosynthesis products of explosive hydrogen burning, in the framework of recent nova models, that nova condensates will probably contain isotopic anomalies in Ne-22, from Na-22 decay, and Mg-26, from Al-26 decay. It is found, for all the models considered, that while too much Ne-20 and -21 is produced relative to Ne-22 to explain the presumably almost pure Ne-22 meteoritic Ne-E component, the Na-22 abundance is high enough to explain Ne-E as its decay product if nova condensates are preserved in Ne samples. It is also determined that while Al-26 is coproduced with Na-22, its total amount strongly depends on the uncertain, Si-27(p, gamma)P-28 reaction rate. The abundances of all nuclides, up to Ar, are computed and found to be clearly nonsolar in many cases.

Hillebrandt, W.↗
NASA NTRS1982

Theory and observation of a dynamically evolving negative ion plasma

The study described here examines the full range of negative-ion chemistry in the upper ionosphere by using current reaction rate data to investigate the many chemical paths SF6-type injections might take in an F region environment. Special attention is given to the conditions required to create heavy negative ions that persist long enough to affect the dynamical properties of the F region. The ambipolar diffusion characteristics of a three-component plasma are described, and estimates are given of the incoherent scatter spectra obtained from such a plasma. Model calculations using a first-order chemical code are defined and tested in order to investigate the actual types of negative-ion plasma capable of being created under nighttime conditions.

Mendillo, M.↗