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At least 523 records · Page 29

Enhanced Surface Properties and Microstructure Evolution of Cr12MoV Using Ultrasonic Surface Rolling Process Combined with Deep Cryogenic Treatment

In this study, the enhanced surface properties and microstructure evolution of quenched and tempered cold work die steel Cr12MoV, which were induced by ultrasonic surface rolling process combined with deep cryogenic treatment (UDCT), were systematically investigated. The results indicated that UDCT had an advantage over conventional ultrasonic surface rolling process (USRP) in improving surface mechanical properties, including smaller surface roughness and smoother machined surface with less cracks and defects; higher surface microindentation hardness with the value of ~ 890 HV (increased by ~ 6.2% compared with USRP); and lower friction coefficient. Such enhancements in surface properties are mainly attributed to the martensitic transformation of retained austenite, the dispersion strengthening of small secondary carbides and the homogenized carbides distribution during UDCT.

36 MATERIALS SCIENCE↗

Bulk texture evolution of nanolamellar Zr–Nb composites processed via accumulative roll bonding

We report that it was recently demonstrated that bulk two-phase 50/50 Zr–Nb nanolayered composites with 90 nm individual layers can be fabricated from an initial coarse-layered composite with 1 mm layers via the severe plastic deformation process of accumulative roll bonding. During the deformation, the Zr phase retained its hcp crystal structure and the Zr–Nb interface remained sharp. Here we use a combination of neutron diffraction and dislocation-based polycrystal plasticity constitutive modeling to assess the evolution of texture and deformation mechanisms over a four order-of-magnitude range in layer thickness. The phase textures in the nanocomposite strongly deviate from that of Zr or Nb rolled in monolithic form, becoming highly peaked and intense. The model suggests that texture development in the Nb phase is associated with multiple slip and contributions from both {1 1 2} <1 1 0> slip and {1 1 0} <1 1 0> slip. Lastly, in the Zr phase the model suggests that the texture develops due to a predominance of prismatic and basal slip.

36 MATERIALS SCIENCE↗

Rolling Optimization of Transmission Network Recovery and Load Restoration Considering Hybrid Wind-Storage System and Cold Load Pickup

A common solution to deal with the stochasticity introduced by fast-ramping wind power integration is to equip wind farms (WFs) with energy storage systems (ESSs) to formulate hybrid WF-ESSs. In addition to leveling off wind power fluctuations during normal operations, a hybrid WF-ESS can be a flexible power source to accumulate the power system restoration. In this paper, we propose a rolling optimization model for transmission network recovery and load restoration considering the contributions of WF-ESSs. The proposed model is formulated as a mixed integer linear programming problem that simultaneously optimizes the amount and location of restorable load blocks as well as the restoration lines. The cold load pickup features of interrupted loads considering the outage duration are modeled in detail. A chance-constrained method is employed to deal with the uncertainty of wind power, and a rolling horizon-based framework is adopted to reduce the influence of forecast error. Case studies are conducted on both New England 39-bus system and part of a provincial power system in China. The results show that the load restoration process can be significantly accelerated by employing the proposed method and contributions of hybrid WF-ESSs to power system restoration are validated.

chance-constrained optimization↗

High-resolution electron microscopy observation and dislocation reaction mechanism of fivefold twinning in a Cu-rich precipitate in a cold rolled ferritic steel containing copper

Ferritic steels containing copper have been studied as model systems for clusters/precipitate formation in reactor pressure vessel steels. The samples were aged at 400 °C for 4000 h and subsequently cold rolled to 30% reduction at room temperature. The microstructural characteristics of the samples were analyzed using high-resolution transmission electron microscopy. Direct evidence was found that the fivefold twinning occurs via simultaneous emission of two Shockley partial dislocations from two particular α-Fe/Cu interfaces, and then the pileup tips of the twofold twin. - Highlights: • Fivefold twin is observed in a Cu-rich precipitate in cold rolled ferritic steels. • A dislocation reaction mechanism for the fivefold twin formation is proposed. • Two particular mismatching α-Fe/Cu-rich precipitate interfaces play a critical role.

36 MATERIALS SCIENCE↗

Deformation textures of aluminum in a multilayered Ti/Al/Nb composite severely deformed by accumulative roll bonding

The accumulative roll bonding process was carried out to produce multilayered Ti/Al/Nb composites up to four cycles. Scanning electron microscopy, transmission electron microscopy electron backscattered diffraction and nanoindentation were employed to investigate the microstructural and texture evolution. A homogenous distribution of Ti/Nb necking layers in Al matrix was achieved after four ARB cycles. Grain refinement was observed to increase with increasing number of ARB cycles. The fraction of high-angle grain boundaries as also increased. Strong recrystallization texture appeared for high number of ARB cycles due to the adiabatic heat that occurs during ARB processing. The shear band at the Ti/Al interface reduced the intensity of the cold rolling fiber textures of Al. There was no evidence of shear component from the orientation distribution function results.

36 MATERIALS SCIENCE↗

Deformation induced dynamic recrystallization and precipitation strengthening in an Mg−Zn−Mn alloy processed by high strain rate rolling

The microstructure of a high strain-rate rolled Mg−Zn−Mn alloy was investigated by transmission electron microscopy to understand the relationship between the microstructure and mechanical properties. The results indicate that: (1) a bimodal microstructure consisting of the fine dynamic recrystallized grains and the largely deformed grains was formed; (2) a large number of dynamic precipitates including plate-like MgZn{sub 2} phase, spherical MgZn{sub 2} phase and spherical Mn particles distribute uniformly in the grains; (3) the major facets of many plate-like MgZn{sub 2} precipitates deviated several to tens of degrees (3°–30°) from the matrix basal plane. It has been shown that the high strength of the alloy is attributed to the formation of the bimodal microstructure, dynamic precipitation, and the interaction between the dislocations and the dynamic precipitates. - Highlights: •A bimodal microstructure was formed in a high strain-rate rolled Mg−Zn−Mn alloy. •Plate-like MgZn{sub 2}, spherical MgZn{sub 2} and spherical Mn phases were observed. •The major facet of the plate-like MgZn{sub 2} deviated from the matrix basal plane.

36 MATERIALS SCIENCE↗

Twinning behaviors of a rolled AZ31 magnesium alloy under multidirectional loading

The microstructure and texture evolution of an AZ31 magnesium rolled sheet during quasi-static compression at strain rates of 10{sup −3} s{sup −1} has been investigated by in situ electron backscattered diffraction. The influence of the initial and pre-deformed texture on the predominant deformation mechanisms during compression has been examined. It has been found that extensive grain reorientation due to (10 − 12) tensile twinning appeared when compressed along transverse direction. Tensile twin variants were observed under this loading condition, and different variants will cause an effect to the following deformation. Several twinning modes occurred with continuative loading along rolling direction. - Highlights: •Twinning behaviors were investigated through in situ multidirectional compressive tests. •Deformation behavior was affected by the twin variants. •Four types of twinning behaviors were observed during deformation process.

36 MATERIALS SCIENCE↗

A quasi-in-situ EBSD observation of the transformation from rolling texture to recrystallization texture in V-4Cr-4Ti alloy

Recrystallization texture evolution of rolled V-4Cr-4Ti alloy has been investigated by quasi-in-situ EBSD (electron back-scattering diffraction) method. Concurrently, the precipitates were characterized by SEM (Scanning Electron Microscopy). It was found that both the initial rolling textures and the distribution of the precipitates affected the formation of the recrystallization texture. It was revealed that the texture transformations of (558) 〈110〉 + (665) 〈110〉 to (334) 〈483〉 + (665) 〈1 1 2.4〉 were possibly attributed to the selective drag induced by the sparsely dispersed Ti-rich precipitates. While the densely distributed Ti-rich precipitates were responsible for the randomized recrystallization texture. Finally, when the precipitates were absent, the orientation changes from (112) 〈110〉 and (558) 〈110〉 to (111) 〈112〉 and (001) <110> to (001) <520> were observed. - Highlights: • Micro recrystallization texture evolution in V-4Cr-4Ti alloys is reported for the first time. • The volume fraction of Ti-rich precipitates has significant effect on the recrystallization texture evolution. • The dissolution of the Ti-rich precipitates above 1100 °C induces the strengthening of (111) <112> texture.

36 MATERIALS SCIENCE↗

Microstructure evolution and mechanical performance of copper processed by equal channel angular rolling

Highlights: • Copper was processed by equal channel angular rolling (ECAR) up to 33 passes. • A very fine grained microstructure with high dislocation density was developed. • A decrease of dislocation density was observed for high numbers of passes. • The proof stress saturated at a value of about 400 MPa. • ECAR is a possible way of commercialization of ultrafine-grained materials. - Abstract: Ultrafine-grained (UFG) oxygen free high conductivity (OFHC) Cu samples were processed by severe plastic deformation (SPD) using the method of equal channel angular rolling (ECAR) up to 33 passes at room temperature. It was found that the grain size gradually decreased from ~ 40 μm to ~ 250 nm with increasing the number of passes. A maximum dislocation density of ~ 21 × 10{sup 14} m{sup − 2} was achieved after 13 passes of ECAR. For large numbers of passes (between 23 and 33), the dislocation density decreased to ~ 14 × 10{sup 14} m{sup − 2}. The proof stress was saturated at the value of about 400 MPa. The stored energy was measured by calorimetry and compared with the values calculated from the parameters of the microstructure. The reduction of the released heat after 13 and 33 passes suggested structural relaxation of the UFG microstructure. For these numbers of passes, the reduction of area in tensile testing was improved without decreasing the proof stress. The correlation between the microstructure and the mechanical behavior was discussed in detail. It was found that ECAR is capable for the mass-production of UFG metallic materials with high strength, therefore this method is a possible way of commercialization of SPD-processed materials.

36 MATERIALS SCIENCE↗

Dynamic condensation model of rolling droplets for high-performance heat transfer

Condensation is a critical process during vapor-liquid phase change in relation to heat transfer. To achieve a high heat transfer coefficient, the classical model for dropwise condensation requires a low contact angle and low contact angle hysteresis, failing to align with experimental observations on a hydrophobic and slippery quasi-liquid surface (QLS). Here, we report a dynamic condensation model that incorporates high-frequency condensate removal by emphasizing the role of timescale during droplet growth and shedding. Our model agrees well with the experimental result that a surface with high contact angle and low contact angle hysteresis promotes condensation, particularly during rolling-propelled condensate removal. Particle image velocimetry reveals that rolling droplets on a hydrophobic QLS exhibit 4-fold higher shedding speeds than the sliding droplets on a hydrophilic QLS, leading to significant heat transfer enhancement. This work deepens our theoretical understanding of condensation heat transfer and provides advanced physics-informed design rationales for water and energy systems.

42 ENGINEERING↗

Two novel bipolar hosts based on 1,2,4-triazole derivatives for highly efficient red phosphorescent OLEDs showing a small efficiency roll-off

Achieving high efficiency and small efficiency roll-off simultaneously for red phosphorescent organic light-emitting diodes (PhOLEDs) is still a challenge, which is largely related to the host material used in device fabrication. In this wok, we designed and synthesized two novel bipolar host materials, termed 2Cz-TAZ-2Cz and 3Cz-TAZ-3Cz in which 1,2,4-triazole was introduced at the C-2 and C-3 positions of 9-phenylcarbazole, respectively. The materials' photophysical properties were studied in detail.. It was found that 2Cz-TAZ-2Cz and 3Cz-TAZ-3Cz possess excellent thermal stability with thermal decomposition temperature (Td) of 457 and 432 °C, respectively, and that 2Cz-TAZ-2Cz has a better bipolar carrier transport compared to the typical host 4, 4'-bis(9H-carbazole-9-yl)-biphenyl (CBP). Based on the excellent performance of these materials, red phosphorescent OLEDs with 2Cz-TAZ-2Cz and 3Cz-TAZ-3Cz as hosts and bis(1-phenylisoquinoline)(acetylacetonate)iridium (III) (Ir(piq) 2 acac) as emitter were fabricated. The optimized 2Cz-TAZ-2Cz -based device achieved a high maximum current efficiency and external quantum efficiency (EQE) of 12.4 cd/A and 16.60%, respectively. Moreover, this device also exhibits a small efficiency roll-off, i.e., the EQE is lowered by only 12.0% and 29.4% at a brightness of 1000 cd/m 2 and 10,000 cd/m 2 , respectively, which is superior to CBP-based device, indicating a potential far-reaching application.

42 ENGINEERING↗

Thermal Properties of Polymer Hole-Transport Layers Influence the Efficiency Roll-off and Stability of Perovskite Light-Emitting Diodes

While the performance of metal halide perovskite light-emitting diodes (PeLEDs) has rapidly improved in recent years, their stability remains a bottleneck to commercial realization. Here, we show that the thermal stability of polymer hole-transport layers (HTLs) used in PeLEDs represents an important factor influencing the external quantum efficiency (EQE) roll-off and device lifetime. We demonstrate a reduced EQE roll-off, a higher breakdown current density of approximately 6 A cm -2 , a maximum radiance of 760 W sr -1 m -2 , and a longer device lifetime for PeLEDs using polymer HTLs with high glass-transition temperatures. Furthermore, for devices driven by nanosecond electrical pulses, a record high radiance of 1.23 MW sr -1 m -2 and an EQE of approximately 1.92% at 14.6 kA cm -2 are achieved. Thermally stable polymer HTLs enable stable operation of PeLEDs that can sustain more than 11.7 million electrical pulses at 1 kA cm -2 before device failure.

14 SOLAR ENERGY↗

A simplified model for dynamics of cell rolling and cell-surface adhesion

We propose a three dimensional model for the adhesion and rolling of biological cells on surfaces. We study cells moving in shear flow above a wall to which they can adhere via specific receptor-ligand bonds based on receptors from selectin as well as integrin family. The computational fluid dynamics are governed by the lattice-Boltzmann method. The movement and the deformation of the cells is described by the immersed boundary method. Both methods are fully coupled by implementing a two-way fluid-structure interaction. The adhesion mechanism is modelled by adhesive bonds including stochastic rules for their creation and rupture. We explore a simplified model with dissociation rate independent of the length of the bonds. We demonstrate that this model is able to resemble the mesoscopic properties, such as velocity of rolling cells.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Deformation mechanism study of a hot rolled Zr-2.5Nb alloy by transmission electron microscopy. I. Dislocation microstructures in as-received state and at different plastic strains

Thin foil dog bone samples prepared from a hot rolled Zr-2.5Nb alloy have been deformed by tensile deformation to different plastic strains. The development of slip traces during loading was observed in situ through SEM, revealing that deformation starts preferentially in certain sets of grains during the elastic-plastic transition region. TEM characterization showed that sub-grain boundaries formed during hot rolling consisted of screw 〈a〉 dislocations or screw 〈c〉 and 〈a〉 dislocations. Prismatic 〈a〉 dislocations with large screw or edge components have been identified from the sample with 0.5% plastic strain. Basal 〈a〉 and pyramidal 〈c + a〉 dislocations were found in the sample that had been deformed with 1.5% plastic strain, implying that these dislocations require larger stresses to be activated.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Intermixing in Cu/Ni multilayers induced by cold rolling

Repeated cold rolling was performed on multilayers of Cu60/Ni40 and Cu40/Ni60 foil arrays to study the details of driven atomic scale interfacial mixing. With increasing deformation, there is a significant layer refinement down to the nm level that leads to the formation of a solid solution phase from the elemental end members. Intriguingly, the composition of the solid solution is revealed by an oscillation in the composition profile across the multilayers, which is different from the smoothly varying profile due to thermally activated diffusion. During the reaction, Cu mixed into Ni preferentially compared to Ni mixing into Cu, which is also in contrast to the thermal diffusion behavior. This is confirmed by observations from X-ray diffraction, electron energy loss spectrum and atom probe tomography. The diffusion coefficient induced by cold rolling is estimated as 1.7 × 10{sup −17} m{sup 2}/s, which cannot be attributed to any thermal effect. The effective temperature due to the deformation induced mixing is estimated as 1093 K and an intrinsic diffusivity d{sub b}, which quantifies the tendency towards equilibrium in the absence of thermal diffusion, is estimated as 6.38 × 10{sup −18} m{sup 2}/s. The fraction of the solid solution phase formed is illustrated by examining the layer thickness distribution and is described by using an error function representation. The evolution of mixing in the solid solution phase is described by a simplified sinusoid model, in which the amplitude decays with increased deformation level. The promoted diffusion coefficient could be related to the effective temperature concept, but the establishment of an oscillation in the composition profile is a characteristic behavior that develops due to deformation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Scale-dependent gravitational waves from a rolling axion

We consider a model in which a pseudo-scalar field σ rolls for some e-folds during inflation, sourcing one helicity of a gauge field. These fields are only gravitationally coupled to the inflaton, and therefore produce scalar and tensor primordial perturbations only through gravitational interactions. These sourced signals are localized on modes that exit the horizon while the roll of σ is significant. We focus our study on cases in which the model can simultaneously produce (i) a large gravitational wave signal, resulting in observable B-modes of the CMB polarizations, and (ii) sufficiently small scalar perturbations, so to be in agreement with the current limits from temperature anisotropies. Different choices of parameters can instead lead to a localized and visible departure from gaussianity in the scalar sector, either at CMB or LSS scales.

79 ASTRONOMY AND ASTROPHYSICS↗

Report on the Second ARM Mobile Facility (AMF2) Roll, Pitch, and Heave (RPH) Stabilization Platform: Design and Evaluation

One of the primary objectives of the U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) Climate Research Facility’s second Mobile Facility (AMF2) is to obtain reliable measurements of solar, surface, and atmospheric radiation, as well as cloud and atmospheric properties, from ocean-going vessels. To ensure that these climatic measurements are representative and accurate, many AMF2 instrument systems are designed to collect data in a zenith orientation. A pillar of the AMF2 strategy in this effort is the use of a stable platform. The purpose of the platform is to 1) mitigate vessel motion for instruments that require a truly vertical orientation and keep them pointed in the zenith direction, and 2) allow for accurate positioning for viewing or shading of the sensors from direct sunlight. Numerous ARM instruments fall into these categories, but perhaps the most important are the vertically pointing cloud radars, for which vertical motions are a critical parameter. During the design and construction phase of AMF2, an inexpensive stable platform was purchased to perform the stabilization tasks for some of these instruments. The first table compensated for roll, pitch, and yaw (RPY) and was reported upon in a previous technical report (Kafle and Coulter, 2012). Subsequently, a second table was purchased specifically for operation with the Marine W-band cloud radar (MWACR). Computer programs originally developed for RPY were modified to communicate with the new platform controller and with an inertial measurements platform that measures true ship motion components (roll, pitch, yaw, surge, sway, and heave). This platform could not be tested dynamically for RPY because of time constraints requiring its deployment aboard the container ship Horizon Spirit in September 2013. Hence the initial motion tests were conducted on the initial cruise. Subsequent cruises provided additional test results. The platform, as tested, meets all the design and performance criteria established for its use. This is a report of the results of those efforts and the critical points in moving forward

54 ENVIRONMENTAL SCIENCES↗

Phonon Spectrum Engineering in Rolled-up Micro- and Nano-Architectures

We report on a possibility of efficient engineering of the acoustic phonon energy spectrum in multishell tubular structures produced by a novel high-tech method of self-organization of micro- and nano-architectures. The strain-driven roll-up procedure paved the way for novel classes of metamaterials such as single semiconductor radial micro- and nano-crystals and multi-layer spiral micro- and nano-superlattices. The acoustic phonon dispersion is determined by solving the equations of elastodynamics for InAs and GaAs material systems. It is shown that the number of shells is an important control parameter of the phonon dispersion together with the structure dimensions and acoustic impedance mismatch between the superlattice layers. The obtained results suggest that rolled up nano-architectures are promising for thermoelectric applications owing to a possibility of significant reduction of the thermal conductivity without degradation of the electronic transport.

acoustic phonon energy spectrum↗