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At least 523 records · Page 29

Evaluation by step response tests of prototype relief valves designed for YF-12 inlet stability bleed system

Two stability bleed system relief valves were tested in a special dynamic test facility. These poppet valves are prototypes for a stability bleed system designed for use in a YF-12 flight inlet. One valve is unshielded, while the other has a special shield to eliminate the flow effect pressures on the piston. The tests determined the size of a damping orifice to be used during wind tunnel tests of the bleed system and verified an analog simulation of the valves. The effects of initial pressure level, pressure step size, and spring rate were investigated.

Dustin, M. O.↗

Predicting Cycle-to-Cycle Variation With Concurrent Cycles in a Gasoline Direct Injected Engine With Large Eddy Simulations

High cycle-to-cycle variation (CCV) is detrimental to engine performance, as it leads to poor combustion and high noise and vibration. In this work, CCV in a gasoline engine is studied using large eddy simulation (LES). The engine chosen as the basis of this work is a single-cylinder gasoline direct injection (GDI) research engine. Two stoichiometric part-load engine operating points (6 BMEP, 2000 RPM) were evaluated: a non-dilute (0% EGR) case and a dilute (18% EGR) case. The experimental data for both operating conditions had 500 cycles. The measured CCV in IMEP was 1.40% for the non-dilute case and 7.78% for the dilute case. To estimate CCV from simulation, perturbed concurrent cycles of engine simulations were compared to consecutively obtained engine cycles. The motivation behind this is that running consecutive cycles to estimate CCV is quite time-consuming. For example, running 100 consecutive cycles requires 2–3 months (on a typical cluster), however, by running concurrently one can potentially run all 100 cycles at the same time and reduce the overall turnaround time for 100 cycles to the time taken for a single cycle (2 days). The goal of this paper is to statistically determine if concurrent cycles, with a perturbation applied to each individual cycle at the start, can be representative of consecutively obtained cycles and accurately estimate CCV. 100 cycles were run for each case to obtain statistically valid results. The concurrent cycles began at different timings before the combustion event, with the motivation to identify the closest time before spark to minimize the run time. Only a single combustion cycle was run for each concurrent case. The calculated standard deviation of peak pressure and coefficient of variance (COV) of indicated mean effective pressure (IMEP) were compared between the consecutive and concurrent methods to quantify CCV. It was found that the concurrent method could be used to predict CCV with either a velocity or numerical perturbation. Here, a large and small velocity perturbation were compared and both produced correct predictions, implying that the type of perturbation is not important to yield a valid realization. Starting the simulation too close to the combustion event, at intake valve close (IVC) or at spark timing, under-predicted the CCV. When concurrent simulations were initiated during or before the intake even, at start of injection (SOI) or earlier, distinct and valid realizations were obtained to accurately predict CCV for both operating points. By simulating CCV with concurrent cycles, the required wall clock time can be reduced from 2–3 months to 1–2 days. Additionally, the required core-hours can be reduced up to 41%, since only a portion of each cycle needs to be simulated.

42 ENGINEERING↗

Correlation and prediction of gaseous diffusion coefficients.

A new correlation method for binary gaseous diffusion coefficients from very low temperatures to 10,000 K is proposed based on an extended principle of corresponding states, and having greater range and accuracy than previous correlations. There are two correlation parameters that are related to other physical quantities and that are predictable in the absence of diffusion measurements. Quantum effects and composition dependence are included, but high-pressure effects are not. The results are directly applicable to multicomponent mixtures.

Marrero, T. R.↗

Effects of equilibrium pressure on plasma response to RMPs in a spherical tokamak

This study presents a comprehensive analysis of the equilibrium pressure on the plasma response to resonant magnetic perturbations (RMPs) in the spherical tokamak (ST) MAST-U, employing both single-fluid and MHD-kinetic hybrid models (implemented via the MARS-F/K codes). As a key finding, the study identifies two different pressure-driven eigenmodes, exhibiting Sturmian property, that affect the Troyon no-wall limits for the onset of the n = 1 and n = 2 ( n is the toroidal mode number) ideal external kink instabilities as well as the corresponding plasma response to the applied RMP. With increasing equilibrium pressure, the plasma response to RMPs is significantly enhanced in the ST plasma, particularly in the high-pressure regime where kinetic effects strongly stabilize the external kink instability. The Troyon no-wall limit divides the plasma response into two regions: well below the limit, the response amplitudes and trends (versus pressure) are similar between the fluid and kinetic models; as the equilibrium pressure approaches the Troyon limit, the kinetic model predicts significant amplification of the RMP field, up to 30 times for cases considered. A relatively weak dependence of the optimal coil phasing on the equilibrium pressure is computed in this ST plasma, similar to the trend obtained for the conventional aspect ratio devices. These findings underscore the importance of incorporating kinetic effects in accurate prediction of the plasma response to RMPs in high-pressure ST tokamak plasmas and provide a theoretical basis for optimizing RMP-based control of the edge-localized modes in future ST devices.

RMP↗

Thermal loading effects on chalk hydromechanical behavior for nuclear waste disposal

Safe disposal of heat-generating nuclear waste depends on host rock stability under thermal, hydrological, and mechanical stresses. This study investigates the effect of thermal loading on mechanical behavior of the shallowly buried Ghareb formation chalk through triaxial and hydrostatic constant strain rate and creep tests at temperatures up to 100 ˚C and effective pressures up to 20.7 MPa. Experimental results show that thermal loading reduces the elastic moduli of chalk by 50–75%, and a transition occurs above 60 ˚C where creep rates increase rapidly. Water saturation nearly doubles the thermally induced strain compared to dry conditions and strongly decreases material rigidity. Thermal loading also leads to significant pore pressure increases under undrained conditions and leads to reductions in the apparent permeability during drained conditions. Laboratory experimental data were used to parameterize and develop a preliminary constitutive model for predicting future deformation during repository operations in the Ghareb. The strongly coupled effects – mechanical weakening, fluid pressure fluctuations, and permeability modification – demonstrate that elevated repository temperatures will have a pronounced effect on the near field Ghareb behavior during waste disposal operations. The findings indicate that the coupled interactions must be considered in predictive models and repository design to ensure long-term nuclear waste isolation and safety.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Thermodynamic analysis of a two-stage binary-fluid ejector heat pump water heater

Ejector heat pump water heaters (EHPWHs) could significantly increase the thermal efficiency of domestic water heating and reduce greenhouse gas emissions. This study addresses two major technical barriers to using EHPWHs in domestic water heating—low heating cycle coefficient of performance (COP) and low condensation temperatures—using binary fluid pairs as a working fluid in a two-stage ejector system. A comprehensive, geometry-free model of binary-fluid ejectors was built and validated to predict the entrainment ratios of binary-fluid ejectors. A thermodynamic model of a two-stage binary-fluid ejector EHPWH was built to predict the heating cycle COP of EHPWHs. The performance of the EHPWH was theoretically evaluated using HFE7000 and Novec649 as primary fluids and R600 and R1234ze(Z) as secondary fluids. HFE7000/R600 gave the highest heating cycle COP (i.e., 1.356) in producing domestic hot water at 60.0 °C. An optimum evaporation temperature of the primary fluid was identified for the maximum effective entrainment ratio and effective pressure lift ratio of two-stage ejectors. Here, the effective entrainment ratio of the two-stage ejector dominated the heating cycle COP of the EHPWH. Primary fluids with lower latent heats of evaporation and/or secondary fluids with higher latent heats of evaporation yielded higher heating cycle COPs of EHPWHs.

42 ENGINEERING↗

Response of complex networks to compression: Ca, La, and Y aluminoborosilicate glasses formed from liquids at 1 to 3 GPa pressures

Aluminoborosilicate glasses containing relatively high field strength modifiers (Ca, La, and Y) have been compressed at pressures up to 3 GPa and near the glass transition temperature (T{sub g}) and quenched to room temperature at high pressure followed by decompression. Structural changes were quantified with high-resolution {sup 27}Al and {sup 11}B MAS nuclear magnetic resonance at 14.1–18.8 T. The changes with pressure in Al and B coordinations in the recovered samples are quite large with more than 50% decreases in tetrahedral aluminum ({sup IV}Al) and 200%-300% increases in tetrahedral boron ({sup IV}B). Glasses with higher field strength modifiers (La and Y) contain more high coordinated aluminum ({sup V,V} {sup I}Al) at all pressures studied. More high coordinated boron also correlates with higher field strength modifier if all three compositions are compared on an isothermal basis. Although lowering fictive temperature and increasing pressure both increase Al and B coordinations, our study shows that the actual mechanisms for structural changes are most probably different for temperature and pressure effects. Using a rough thermodynamic model to extrapolate to higher pressures, it appears that a simple non-bridging oxygen (NBO) consumption mechanism is not sufficient to convert all the aluminum to octahedral and boron to tetrahedral coordination, suggesting other mechanisms for structural changes could occur at high pressure as NBO becomes depleted.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High-temperature oxidation of transient-liquid phase bonded Ni-based alloys in 1 bar and 250 bar carbon dioxide

Compact microchannel heat exchanger designs for supercritical CO 2 power cycles are valued for equipment size reduction and increased heat transfer. They can be fabricated via transient-liquid phase (TLP) bonding, which utilizes a lower melting point interlayer for bonding facilitation of etched thin plates. Haynes 230 and 282 TLP bonded stacks were exposed to high-purity CO 2 at 1 bar/700 °C to 4000 h and 250 bar/720 °C (supercritical) to 1500 h. All samples obeyed parabolic kinetics after an oxide buildup stage of 500-1000 h. Mass gains were similar for the base and TLP bonded alloys, and oxide thicknesses and scales did not significantly differ around the TLP bond regions. Furthermore, there were some slight oxide compositional differences for the H282 TLP samples at 250 bar. There was a slight pressure effect on mass gain, as samples exposed at the higher pressure experienced higher initial mass gains, but then slower continued oxide growth.

36 MATERIALS SCIENCE↗

Radiation-driven rotational motion of nanoparticles

Focused synchrotron beams can influence a studied sample via heating, or radiation pressure effects due to intensity gradients. The high angular sensitivity of rotational X-ray tracking of crystalline particles via their Bragg reflections can detect extremely small forces such as those caused by field gradients. By tracking the rotational motion of single-crystal nanoparticles embedded in a viscous or viscoelastic medium, the effects of heating in a uniform gradient beam and radiation pressure in a Gaussian profile beam were observed. Changes in viscosity due to X-ray heating were measured for 42 µm crystals in glycerol, and angular velocities of 10 −6 rad s −1 due to torques of 10 −24 N m were measured for 340 nm crystals in a colloidal gel matrix. These results show the ability to quantify small forces using rotation motion of tracer particles.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Pressure dependence of the absolute rate constant for the reaction OH + C2H2 from 228 to 413 K

The pressure dependence of the absolute rate constant for the reaction of the hydroxyl radical with acetylene, important in both atmospheric and combustion chemistry, is determined for temperatures between 228 and 413 K. The flash photolysis-resonance fluorescence technique was employed at five temperatures over wide ranges of pressure and acetylene concentrations, with the OH produced by water photolysis and hydroxyl resonance fluorescent photons measured by multiscaling techniques. Results indicate that, except at the lowest temperature, the bimolecular rate constant for the reaction depends strongly on total pressure, with the pressure effect becoming more pronounced with increasing temperature. At limiting high pressures, the rate constant is found to be equal to 6.83 + or - 1.19 x 10 to the -12th exp (-646 + or - 47/T) cu cm/molecule per sec, where T is the temperature. Results thus demonstrate the importance of environmental conditions in theoretical studies of atmospheric and combustion product compositions

Michael, J. V.↗

The effect of oxygen pressure on volatility and morphology of LaB6 single crystal cathodes

The effect of oxygen pressure on the volatility and morphology of single crystal LaB6 cathodes, heated to different temperatures, was investigated. At a temperature of 1600 K, an increase of oxygen pressure from 1 x 10 to the -8th torr to 1 x 10 to the -6th torr has led to a 100-fold enhancement in cathode volatility. The enhancement effect of oxygen pressure diminished with increasing temperature: at a cathode operating temperature of 1900 K, the volatility enhancement due to the same oxygen pressure was negligible. It was shown that the faceting frequently observed during evaporation of conically shaped emitters is due to a crystallograpic anisotropy of the oxidation rate of LaB6. No facet formation occurs during evaporation at oxygen pressures below -110 to the -8th torr.

Davis, P. R.↗

Waste Control Specialists Technical Review Team Report

1. Modeling of Drum 68660 and the WCS Drums: A calibrated model of Los Alamos National Laboratory (LANL) Drum 68660 indicates that pressurization of the drum by restriction of drum venting could have led to the thermal runaway reaction at the Waste Isolation Pilot Plant (WIPP) in 2014, supporting the hypothesis that the contents of the drum were not fundamentally different from the overall remediated nitrate salt (RNS) waste stream. 2. Nitric Acid Reactions and Aging of the Waste: The stability of the WCS RNS waste with respect to autocatalytic thermal runaway due to nitric acid chemistry should increase over time as the nitric acid is depleted from chemical reactions in the drum. However, this cannot be confirmed because of the lack of long-term experimental data on the impact of aging on the reactivity of RNS waste. The calibrated model indicates that the waste drums retain most of their reactive components, metal nitrate salts and sWheat Scoop ® , even after eight years. 3. Pressure Effects and Runaway Reactions: The calibrated model indicates that if the drums and standard waste boxes (SWBs) are not allowed to pressurize during transport or storage and they are stored at historical WIPP repository temperatures, then an autocatalytic thermal runaway event is not expected to occur. Since the cause of Drum 68660 pressurization is not known, decision makers are not able to tailor mitigating strategies to the initiating event. Consequently, mitigating strategies must consider all feasible internal and external events that could lead to the pressurization of the drums. 4. Temperature Effects and Runaway Reactions: Temperature also has a strong influence on the stability of the waste. The calibrated model indicates that cooling the drums or SWBs can reduce the possibility of autocatalytic thermal runaway reactions. Simulations suggest that for a drum with a plugged vent, the probability of thermal runaway may be reduced or eliminated if wastes are maintained at or below 43 °F through active cooling measures from the initiation of transport until emplacement at WIPP.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Effect of high pressure homogenization on aqueous phase solvent extraction of lipids from Nannochloris Oculata microalgae

The ability to extract lipids from high-moisture Nannochloris Oculata algal biomass disrupted with high pressure homogenization was investigated. During the first phase, the effect of high pressure homogenization (system pressure and number of passes) on disrupting aqueous algae (of different concentrations and degree of stress) was investigated. Secondly, the effect of degree of cell wall disruption on the amount of lipids extracted with three solvents, namely: hexane, dichloromethane and chloroform, were compared. Studies reveled that high pressure homogenization is effective on cell disruption while the amount of system pressure being the most significant factor affecting the degree of cell breakage. Although the number of passes had some impact, the level of disruption seemed to level-off after a certain number of passes. The study revealed that slightly polar solvents (such as chloroform and dichloromethane) performed better in aqueous-phase lipid extractions as compared to hexane. Also, it was revealed that it was not necessary to disrupt the algal cells completely to achieve appreciable levels of lipid yields. In fact, conditions that exerted only 20% of the cells to completely disrupt, allowed sufficient damage to liberate most of the lipids contained in the remainder of the cells.

09 BIOMASS FUELS↗

Pressure induced Invar effect in Fe 55 ⁢Ni 45 : An experimental study with nuclear resonant scattering

Pressure-dependent synchrotron x-ray diffraction (XRD), nuclear resonant inelastic x-ray scattering (NRIXS), and nuclear forward scattering (NFS) measurements were made on 57 Fe 55 Ni 45 . XRD measurements were at 298 and 392 K at pressures up to 20 GPa, confirming a pressure-induced Invar effect between 7 and 13 GPa. A decrease of the 57 Fe magnetic moment was found in NFS measurements under pressure, showing an increase in magnetic entropy. The 57 Fe phonon density of states (DOS) was obtained from NRIXS measurements. The low thermal expansion in the high-pressure Invar region originates from a competition between the thermal expansion from spins and phonons as calculated from Maxwell relations. Finally, the longitudinal phonon modes changed their pressure dependence near the Curie transition, which is evidence for a spin-phonon interaction.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗