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At least 523 records · Page 29

Evaluation of historical CMIP6 model simulations of extreme precipitation over contiguous US regions

Simulated historical precipitation is evaluated for Coupled Model Intercomparison Project Phase 6 (CMIP6) models using precipitation indices defined by the Expert Team on Climate Change Detection and Indices. The model indices are evaluated against corresponding indices from the CPC unified gauge-based analyses of precipitation over seven geographical regions across the contiguous US (CONUS). The regions assessed match those in recent US National Climate Assessment Reports. To estimate observational uncertainty, precipitation indices for three other observational datasets (HadEx2, Livneh and PRISM) are evaluated against the CPC analyses. Both the moderate and extreme mean precipitation intensities are overestimated over the western CONUS and underestimated in the areas of the Central Great Plains (CGP) in most CMIP6 models tested. Most CMIP6 models overestimate the mean and variability of wet spell durations and underestimate the mean and variability of dry spell durations across the CONUS. Biases in interannual variability of most of the indices have similar patterns to those in corresponding mean biases. The median and interquartile model spreads in CMIP6 model biases are clearly smaller than those in CMIP5 model biases for wet spell durations. Multimodel medians of CMIP6 (CMIP6-MMM) and CMIP5 (CMIP5-MMM) have similar biases in climatology and variability but biases tend to be smaller in CMIP6-MMM. Depending on the index, extreme precipitation is slightly better in parts of the eastern half of the CONUS in CMIP6-MMM, otherwise, the biases in climatology and variability are similar to CMIP5-MMM. CMIP6-MMM performs better than individual models and even observational datasets in some cases. Differences between observational datasets for most indices are comparable to the CMIP6 interquartile model spread. The better-performing observational and model datasets are different in different parts of the CONUS.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Contrasting Responses of Hailstorms to Anthropogenic Climate Change in Different Synoptic Weather Systems

Hailstones and extreme precipitation generate substantial economic losses across the United States (US) and the globe. Their strong association with short-lived, intense convective storms poses a great challenge in predicting their future changes. Here, we conducted model simulations at 1.2 km grid spacing for severe convective storms with large hail and heavy precipitation that occurred in two typical types of synoptic-scale environments in spring seasons over the central US under both current and future climate conditions. We find that the responses of large hail (diameters >2.5 cm) to anthropogenic climate change (ACC) are markedly different between the hailstorms developed in the two types of synoptic-scale environments, with over 110% increase in large hail occurrences for the frontal systems, whereas less than 30% increase for the Great Plains low-level jet (GPLLJ) systems. This is explained by the larger increase in convective intensity and updraft width and a smaller increase in warm cloud depth in the frontal storms compared with the GPLLJ storms. Interestingly, the occurrences and intensity of heavy precipitation (rain rate >20 mm hr-1) in both types of systems are similarly sensitive to ACC (e.g., 40% and 33% increases in the occurrences for the frontal and GPLLJ systems, respectively). These results advance our knowledge of hail projection and have important implications for managing risks for future hail.

54 ENVIRONMENTAL SCIENCES↗

Zn precipitation and Li depletion in Zn implanted ZnO

Ion implantation of Zn substituting elements in ZnO has been shown to result in a dramatic Li depletion of several microns in hydrothermally grown ZnO. This has been ascribed to a burst of mobile Zn interstials. In this study, we seek to understand the reason behind this interstitial mediated transient enhanced diffusion in Li-containing ZnO samples after Zn implantation. ZnO wafers were implanted with Zn to two doses, 5 × 10{sup 15} cm{sup −2} and 1 × 10{sup 17} cm{sup −2}. Secondary ion mass spectrometry was carried out to profile the Li depletion depth for different annealing temperatures between 600 and 800 °C. The 800 °C annealing had the most significant Li depletion of close to 60 μm. Transmission electron microscopy (TEM) was carried out in selected samples to identify the reason behind the Li depletion. In particular, TEM investigations of samples annealed at 750 °C show significant Zn precipitation just below the depth of the projected range of the implanted ions. We propose that the Zn precipitation is indicative of Zn supersaturation. Both the Li depletion and Zn precipitation are competing synchronous processes aimed at reducing the excess Zn interstitials.

36 MATERIALS SCIENCE↗

Li 2 S Film Formation on Lithium Anode Surface of Li–S batteries

The precipitation of lithium sulfide (Li 2 S) on the Li metal anode surface adversely impacts the performance of lithium–sulfur (Li–S) batteries. In this work, a first-principles approach including density functional theory (DFT) and ab initio molecular dynamics (AIMD) simulations is employed to theoretically elucidate the Li 2 S/Li metal surface interactions and the nucleation and growth of a Li 2 S film on the anode surface due to long-chain polysulfide decomposition during battery operation. DFT analyses of the energetic properties and electronic structures demonstrate that a single molecule adsorption on Li surface releases energy forming chemical bonds between the S atoms and Li atoms from the anode surface. Reaction pathways of the Li 2 S film formation on Li metal surfaces are investigated based on DFT calculations. It is found that a distorted Li 2 S (111) plane forms on a Li(110) surface and a perfect Li 2 S (111) plane forms on a Li(111) surface. The total energy of the system decreases along the reaction pathway; hence Li 2 S film formation on the Li anode surface is thermodynamically favorable. Finally, the calculated difference charge density of the Li 2 S film/Li surface suggests that the precipitated film would interact with the Li anode via strong chemical bonds. AIMD simulations reveal the role of the anode surface structure and the origin of the Li 2 S formation via decomposition of Li 2 S 8 polysulfide species formed at the cathode side and dissolved in the electrolyte medium in which they travel to the anode side during battery cycling.

25 ENERGY STORAGE↗

Transmission electron microscopy examinations of metal-oxide interface of zirconium-based alloys irradiated in Halden reactor-IFA-638 - 2016-0039

This paper provides the results of investigations by transmission electron microscopy (TEM) on the selected materials from in-reactor oxidation tests in the Halden test reactor (Reference No. IFA-638) from 1998 to 2006. The objective of the IFA-638 test was to study the corrosion behavior of modern zirconium-based claddings to high burnup in pressurized water reactor water chemistry and thermal hydraulic conditions. The aim of this paper is to report on the microstructure of selected materials (ZIRLO{sup R}, E635, and Alloy A) after the irradiation to different burnup levels to determine the modifications induced by irradiation and to correlate results to their oxidation behavior. The TEM examinations revealed the nature of secondary phase particles (SPPs) and their modification under irradiation. Four types of SPPs were observed, namely β-niobium precipitates, Zr{sub 0.5}Nb{sub 0.3}Fe{sub 0.2} (mainly in the ZIRLO alloy), Zr(Fe,Nb){sub 2} (in E635), and (Cr,Fe){sub 2}Zr,Nb with varying niobium content (present in Alloy A: Zr-0.58Sn-0.31Nb-0.36Fe-0.26Cr). TEM observations showed that all three materials contained still several precipitates after irradiation and in the case of the ZIRLO alloy even after high burnups. Furthermore, the analysis of the metal side of the interface and its comparison with the oxide side led to the conclusion that all types of precipitates dissolved to some extent under irradiation and that their alloying element content decreased. The dissolution was intensified in the oxide. However, a more detailed examination showed that the β-niobium precipitates dissolved at a slower rate, or knowing that their composition was much richer in niobium, the time needed for the precipitates to become fully depleted from niobium was longer. Regarding the amorphization under irradiation, the b-niobium- and chromium-containing precipitates did not amorphize in the metal part of the interface. This was not the case for the other types of precipitates. Furthermore, these two types of SPP both showed delayed oxidation and due to this behavior the typical crack above the SPP in the oxide was also observed. These results are discussed to gain an improved understanding of the oxidation behavior of materials studied as a function of irradiation and residence time. (authors)

36 MATERIALS SCIENCE↗

Laser weld-induced formation of amorphous Mn–Si precipitate in 304 stainless steel

In this paper, we report the formation of partially amorphous Mn-Si precipitates due to laser welding of face centered cubic (fcc) 304 stainless steel. Transmission electron microscopy and precession electron diffraction studies in the heat affected zone (HAZ) of the weldment indicate the formation of these precipitates in grain interiors. Precipitates have MnSi stoichiometry and the partially crystalline regions have a lattice constant of 0.45 nm. It is surmised that the rapid cooling rates during the laser weld melt pool solidification process may be sufficient to inhibit the complete crystallization of these precipitates.

304 stainless steel↗

A kriging and entropy-based approach to raingauge network design

Highlights: • A kriging and entropy theory-based approach is developed for gauge network design. • The method considers both minimum estimating error andoptimum rainfall information. • The best combination is verified to be effectiveto achieve final goals. Hydrological data, such as precipitation, is fundamental for planning, designing, developing, and managing water resource projects as well as for hydrologic research. An optimal raingauge network leads to more accurate estimates of mean or point precipitation at any site over the watershed. Some studies in the past have suggested increasing gauge network density for reducing the estimation error. However, more stations mean more cost of installation and monitoring. This study proposes an approach on the basis of kriging and entropy theory to determine an optimal network design in the city of Shanghai, China. Unlike the past studies using kriging interpolation and entropy theory for network design, the approach developed in the current study not only used the kriging method as an interpolator to determine rainfall data at ungauged locations but also incorporated the minimum kriging standard error (KSE) and maximum net information (NI) content. The approach would thus lead to an optimal network and would enable the reduction of kriging standard error of precipitation estimates throughout the watershed and achieve an optimum rainfall information. This study also proposed an NI-KSE-based criterion which is dependent on a single-objective optimization. To evaluate the final optimal gauge network, areal average rainfall was estimated and its accuracy was compared with that obtained with the existing rain gauge network.

54 ENVIRONMENTAL SCIENCES↗

Irradiation-assisted cracking of SA508-304L weldments with 308L groove filler and 309L butter in hot water immersion constant rate extension tests

Low alloy SA508 bainitic steel is often welded to 300 series austenitic stainless steel in nuclear power plants. These dissimilar metal weldments use 309L butter applied to the low alloy steel and 308L groove filler material to join the 309L to austenite. High alloy steels (such as the 308L and 309L material used here) have been identified as having greater susceptibility to irradiation-assisted stress corrosion cracking (IASCC). Evidence is presented here of cracking under tensile loads in 309L weldment butter in LWR hydrothermal conditions that correlates irradiation induced changes at δ ferrite–γ austenite phase boundaries and γ–γ grain boundaries; specifically intergranular Cr 23 C 6 precipitates. Cracking is not observed in irradiated 308L groove filler under the same conditions. Both the 309L butter and 308L filler material have a duplex or mixed δ–γ phase microstructure due to solidification during the welding procedure. We have performed constant extension rate autoclave immersion tests in BWR normal water chemistry hot water (288 °C, 10 MPa, 2000 wt. ppb dissolved oxygen, <100 nS/cm conductivity, neutral pH) of proton irradiated (2 MeV, approximately 3 displacements per atom at a depth of 10 μm) tensile specimens. Proton irradiation to the dpa levels used here induced Cr 23 C 6 carbide precipitation at γ–γ grain boundaries and δ–γ phase boundaries in the 309L butter but not the 308L filler. Cracking was observed in the proton-irradiated volume of 309L at these interfaces in the vicinity of the Cr 23 C 6 precipitates. We hypothesis the SA508 is the source of carbon in the 309L butter. Cr depletion at γ–γ grain boundaries was also observed and may also be a root cause of cracking. Furthermore, the 309L butter is under significant tensile residual stress in the weldment that adds to applied tensile loads and this too may be a contributing factor.

309L weld butter↗

Evolution of Precipitation Particle Size Distributions within MC3E Systems and its Impact on Aerosol-Cloud-Precipitation Interactions: Final Report

This is a multi-institutional, collaborative project using observations and modeling to study the evolution (e.g. formation and growth) of hydrometeors in continental convective clouds. Our contribution was in data analysis for the generation of high-value cloud and precipitation products and derive cloud statistics for model validation. There are two areas in data analysis that we contributed: i) the development of novel, state-of-the-art dual-wavelength radar algorithms for the retrieval of cloud microphysical properties and ii) the evaluation of large domain, high-resolution models using comprehensive multi-sensor observations. Our research group developed statistical summaries from numerous sensors and developed retrievals of vertical air motion in deep convection.

54 ENVIRONMENTAL SCIENCES↗

Effect of Groundwater Age and Recharge Source on Nitrate Concentrations in Domestic Wells in the San Joaquin Valley

Nitrate is one of the most abundant contaminants in groundwater globally, in the United States, and in California (CA). We studied well construction information, water chemistry, stable isotopes, and noble gases to understand how groundwater travel time and recharge source and mechanism control nitrate concentrations in domestic wells in the San Joaquin Valley (SJV), CA, a large semiarid, irrigated agricultural region. Using nonparametric statistics, we find a decreasing trend in nitrates with groundwater travel time and well depth. Samples collected from wells that are closer to rivers and that show indications of river water recharge, either low recharge temperature or low δ 18 O signature, have lower concentrations of nitrates than samples with isotopic signatures indicating mixed source or local precipitation recharge. The curbing effect of river water recharge on nitrate concentrations in domestic wells is similar for direct river recharge and water applied as irrigation. This suggests that irrigation with river water also has a diluting effect that reduces the concentration of nitrate found in groundwater. This conclusion supports the idea that flood-managed aquifer recharge may be considered for remediation of groundwater nitrate when designing replenishment of aquifers.

54 ENVIRONMENTAL SCIENCES↗

Impact of a 70 °C temperature on an ordinary Portland cement paste/claystone interface: An in situ experiment

Radioactive wastes in future underground disposal sites will induce a temperature increase at the interface between the cementitious materials and the host rock. To understand the evolution of Portland cement in this environment, an in situ specific device was developed in the Underground Research Laboratory in Tournemire (France). OPC cement paste was put into contact with clayey rock under water-saturated conditions at 70 °C. The initial temperature increase led to ettringite dissolution and siliceous katoite precipitation, without monosulfoaluminate formation. After 1 year of interaction, partial decalcification and diffuse carbonation (calcite precipitation) was observed over 800 μm in the cement paste. At the interface, a layer constituted of phillipsite (zeolite), tobermorite (well-crystallised C-S-H) and C-(A)-S-H had formed. Globally, porosity decreased at both sides of the interface. Geochemical modelling supports the experimental results, especially the coexistence of tobermorite and phillipsite at 70 °C, minerals never observed before in concrete/clay interface experiments.

36 MATERIALS SCIENCE↗

Notable impact of wildfires in the western United States on weather hazards in the central United States

Increased wildfire events constitute a significant threat to life and property in the United States. Wildfire impact on severe storms and weather hazards is another pathway that threatens society, and our understanding of which is very limited. Here, we use unique modeling developments to explore the effects of wildfires in the western US (mainly California and Oregon) on precipitation and hail in the central US. We find that the western US wildfires notably increase the occurrences of heavy precipitation rates by 38% and significant severe hail (≥2 in.) by 34% in the central United States. Both heat and aerosols from wildfires play an important role. By enhancing surface high pressure and increasing westerly and southwesterly winds, wildfires in the western United States produce ( 1 ) stronger moisture and aerosol transport to the central United States and ( 2 ) larger wind shear and storm-relative helicity in the central United States. Both the meteorological environment more conducive to severe convective storms and increased aerosols contribute to the enhancements of heavy precipitation rates and large hail. Moreover, the local wildfires in the central US also enhance the severity of storms, but their impact is notably smaller than the impact of remote wildfires in California and Oregon because of the lessened severity of the local wildfires. As wildfires are projected to be more frequent and severe in a warmer climate, the influence of wildfires on severe weather in downwind regions may become increasingly important.

54 ENVIRONMENTAL SCIENCES↗

Issues Regarding the Assimilation of Cloud and Precipitation Data

This is the authors' response to a set of criticisms regarding a previously published work. It briefly addresses the main criticisms. In particular, it explains why some papers identified as having some fundamental flaws were referenced in the original work without detailed exposition of those flaws. It also explains why parts of the conclusion criticized as being contradictory are, in fact, not. It further highlights the need for more publishing of scientific criticisms. In the December 2007, special issue of the Journal of Atmospheric Sciences devoted to the Workshop on Assimilation of Satellite Cloud and Precipitation Observations, the authors published an article summarizing the many critical issues that render observations of cloud and precipitation difficult to analyze. Essentially, these include the inaccuracies of both current instruments and the relationships between what is actually observed (infrared or microwave energy detected at the altitude of the satellite) to what is desired (e.g., estimates of cloud drop sizes or rain rates) and the chaotic nature of atmospheric behavior and the complex mathematics describing it. The paper also included recommendations for future research and brief descriptions of many previous works concerning the subject. One reader is now attempting to publish a criticism of that paper. Her three complaints are that there was insufficient explanation of the identification of some cited works as being fundamentally flawed, that as a review the paper should have referenced some works additional to those it did, and that two recommendations were contradictory. Each of these complaints is addressed briefly in this response. First we explain why a brief list of works cited in our paper were identified as "flawed" with only a brief explanation. The design and conduct of the experiments reported in those papers violate well-established fundamentals such that, once the errors are recognized, their interpretations are no longer supported. Unfortunately, over the years, no researchers have bothered to publish criticisms of those papers, such that there are now too many to address in any single paper not devoted to that purpose. Yet, those papers are so often cited that we could not simply ignore them. Furthermore, if we had cited them without warning our readers regarding their flaws, we would have perpetrated a great disservice. In our response, however, we do offer further explanation of why some details, neglected in these papers, are critical to proper scientific evaluation. Neither did we offer insufficient references. Although we intentionally did not claim to be a "review' paper, we did cite 100 papers. That number is approximately 5 times the usual amount cited in journal articles. Although we only referenced few papers published after 2005, that was because our manuscript was submitted in January 2006, with its final, editorially-reviewed form in June 2006. We therefore could not reference papers published after this date. The problem here is that our paper was "in press" for 18 months. Finally, we explain that a careful reading of our paper reveals that our recommendations are not contradictory. Essentially, although we recommend 2 very distinct research approaches, these are complimentary and either alone is insufficient to accelerate progress. In conclusion, we recommend that the scientific community expends greater effort in publishing careful scientific criticisms so that others do not face the same dilemma we did. Likely this requires some reward system for doing so.

Errico, Ronald M.↗

The plug-based nanovolume Microcapillary Protein Crystallization System (MPCS)

The Microcapillary Protein Crystallization System (MPCS) embodies a new semi-automated plug-based crystallization technology which enables nanolitre-volume screening of crystallization conditions in a plasticware format that allows crystals to be easily removed for traditional cryoprotection and X-ray diffraction data collection. Protein crystals grown in these plastic devices can be directly subjected to in situ X-ray diffraction studies. The MPCS integrates the formulation of crystallization cocktails with the preparation of the crystallization experiments. Within microfluidic Teflon tubing or the microfluidic circuitry of a plastic CrystalCard, {approx}10-20 nl volume droplets are generated, each representing a microbatch-style crystallization experiment with a different chemical composition. The entire protein sample is utilized in crystallization experiments. Sparse-matrix screening and chemical gradient screening can be combined in one comprehensive 'hybrid' crystallization trial. The technology lends itself well to optimization by high-granularity gradient screening using optimization reagents such as precipitation agents, ligands or cryoprotectants.

59 BASIC BIOLOGICAL SCIENCES↗

Characterization of Vertical Velocity and Drop Size Distribution Parameters in Widespread Precipitation at ARM Facilities

Extended, high-resolution measurements of vertical air motion and median volume drop diameter D0 in widespread precipitation from three diverse Atmospheric Radiation Measurement Program (ARM) locations [Lamont, Oklahoma, Southern Great Plains site (SGP); Niamey, Niger; and Black Forest, Germany] are presented. The analysis indicates a weak (0-10 cm{sup -1}) downward air motion beneath the melting layer for all three regions, a magnitude that is to within the typical uncertainty of the retrieval methods. On average, the hourly estimated standard deviation of the vertical air motion is 0.25 m s{sup -1} with no pronounced vertical structure. Profiles of D0 vary according to region and rainfall rate. The standard deviation of 1-min-averaged D0 profiles for isolated rainfall rate intervals is 0.3-0.4 mm. Additional insights into the form of the raindrop size distribution are provided using available dual-frequency Doppler velocity observations at SGP. The analysis suggests that gamma functions better explain paired velocity observations and radar retrievals for the Oklahoma dataset. This study will be useful in assessing uncertainties introduced in the measurement of precipitation parameters from ground-based and spaceborne remote sensors that are due to small-scale variability.

54 ENVIRONMENTAL SCIENCES↗

Framework for Processing Citizens Science Data for Applications to NASA Earth Science Missions

Citizen science (or crowdsourcing) has drawn much high-level recent and ongoing interest and support. It is poised to be applied, beyond the by-now fairly familiar use of, e.g., Twitter for natural hazards monitoring, to science research, such as augmenting the validation of NASA earth science mission data. This interest and support is seen in the 2014 National Plan for Civil Earth Observations, the 2015 White House forum on citizen science and crowdsourcing, the ongoing Senate Bill 2013 (Crowdsourcing and Citizen Science Act of 2015), the recent (August 2016) Open Geospatial Consortium (OGC) call for public participation in its newly-established Citizen Science Domain Working Group, and NASA's initiation of a new Citizen Science for Earth Systems Program (along with its first citizen science-focused solicitation for proposals). Over the past several years, we have been exploring the feasibility of extracting from the Twitter data stream useful information for application to NASA precipitation research, with both "passive" and "active" participation by the twitterers. The Twitter database, which recently passed its tenth anniversary, is potentially a rich source of real-time and historical global information for science applications. The time-varying set of "precipitation" tweets can be thought of as an organic network of rain gauges, potentially providing a widespread view of precipitation occurrence. The validation of satellite precipitation estimates is challenging, because many regions lack data or access to data, especially outside of the U.S. and in remote and developing areas. Mining the Twitter stream could augment these validation programs and, potentially, help tune existing algorithms. Our ongoing work, though exploratory, has resulted in key components for processing and managing tweets, including the capabilities to filter the Twitter stream in real time, to extract location information, to filter for exact phrases, and to plot tweet distributions. The key step is to process the "precipitation" tweets to be compatible with satellite-retrieved precipitation data. These key components for processing and managing "precipitation" tweets (and additional ones to be developed) are not limited to precipitation, nor are they limited to the Twitter social medium. Indeed, to maximize the value of our work for NASA earth science programs, these components should be generalized and be part of an overall framework for processing citizen science data for science research. In this paper, we outline such a framework.

earth science satellite data↗