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At least 523 records · Page 29

Angular motion of a PAH molecule in interstellar environment

Polycyclic aromatic hydrocarbon (PAH) molecules have recently been proposed as an important and hitherto undetected component of the Interstellar Medium (ISM). The theory was based on an explanation of the Unidentified IR Emission Bands by Leger et al. It has already led to a verified prediction on extended galactic and extragalactic emissions measured by IRAS, or by a recent balloon borne experiment. The physics that rules the motion of such molecules in the ISM was studied, taking into account their coupling with the ambient gas, the radiation field (absorption and emission) and the static magnetic field. This is important for many implications of the PAH theory such as the radio emission by these molecules or the expected polarization of their IR emission. A reflection nebulae is considered where the situation is rather well known. Every day life of a mean PAH molecule in such a region is as follows: every 3 hrs a UV photon is absorbed heating the molecule to a thousand degs; the temperature decay due to cooling by IR emission follows then within a few seconds. A collision with a molecule of gas occurs typically once a week, while an H atom is ejected or captured at the same rate. A typical cooling cycle after a heat impulse is given. The PAH molecules studied as representative of the family has typically 50 atoms, a radius of 4.5 A, is circular and has a molecular mass of M = 300; its permanent dipole moment is 3 Debye.

Rouan, D.↗

Chandra Observations of a Young Embedded Magnetic B Star in the p Ophiuchus Cloud

This paper reports the analysis of two Chandra X-ray observations of the young magnetic B star rho Ophiuchus S1. X-ray emission from the star was detected in both observations. The average flux is almost the same in both, but during each observation the flux shows significant time variations by a factor of two on timescales of 20-40 ksec. Each spectrum can be fit by either an absorbed power law model with a photon index of approx. -3 or a thin-thermal plasma model with a temperature of approx. 2 keV and an extremely low metal abundance (approx. less than 0.1 solar). The spectrum of the first observation has an apparent line feature at about 6.8 keV, which likely corresponds to highly ionized iron K alpha. In contrast, the spectrum of the second observation shows an anomalous edge absorption component at E approx. 1 keV. The continuum emission and log (L(sub X)/L(sub bol)) approx. -6 are similar to those of young intermediate-mass stars (Herbig Ae/Be stars) although the presence of the magnetic field inferred from the detection of non-thermal radio emission has drawn an analogy between rho Ophiuchus S1 and magnetic chemically peculiar (MCP) stars. If the X-ray emission is thermal, the highest plasma temperature observed is too high to be explained by the conventional theories of magnetic stars, and favors some kind of magnetic dynamo activity, while if the emission is nonthermal, it might be related to mass infall. The 6.8 keV line and 4 keV edge features are marginal but they give important information near the stellar body if they are real. Their physical interpretation is discussed.

Hamaguchi, Kenji↗

UV/Vis+ Photochemistry Database: Structure, Content and Applications

The “science-softCon UV/Vis+ Photochemistry Database” (www.photochemistry.org) is a large and comprehensive collection of EUV-VUV-UV–Vis-NIR spectral data and other photochemical information assembled from published peer-reviewed papers. The database contains photochemical data including absorption, fluorescence, photoelectron, and circular and linear dichroism spectra, as well as quantum yields and photolysis related data that are critically needed in many scientific disciplines. This manuscript gives an outline regarding the structure and content of the “science-softCon UV/Vis+ Photochemistry Database”. The accurate and reliable molecular level information provided in this database is fundamental in nature and helps in proceeding further to understand photon, electron and ion induced chemistry of molecules of interest not only in spectroscopy, astrochemistry, astrophysics, Earth and planetary sciences, environmental chemistry, plasma physics, combustion chemistry but also in applied fields such as medical diagnostics, pharmaceutical sciences, biochemistry, agriculture, and catalysis. In order to illustrate this, we illustrate the use of the UV/Vis+ Photochemistry Database in four different fields of scientific endeavor.

Photochemistry↗

Properties of the Upper Tropospheres of Uranus and Neptune Derived from Observations at Visible to Near-Infrared Wavelengths

Photons at wavelengths between 0.3 and 4.5 microns penetrate the atmospheres of Uranus and Neptune to pressures between about 0.01 bar and 10 bars. This pressure range brackets the radiative convective boundary in both atmospheres and is therefore designated upper troposphere. Physical processes which govern the transfer of radiation in Uranus's and Neptune's atmospheres at these wavelengths include Rayleigh/Raman scattering by hydrogen, scattering and broadband absorption by suspended aerosol particles and absorption in discrete bands and lines by methane and hydrogen. Consequently, tropospheric properties constrained by observations at these wavelengths include optical properties and distribution of aerosol particles, methane/hydrogen ratio, and ortho/para hydrogen ratio. Recent observations of Uranus and Neptune in this spectral range, are reviewed and compared with predictions based on models of the atmospheric structures. Significant results for Uranus include the presence of an opaque lower boundary to the visible atmosphere very near the level corresponding to 2 bars pressure, and consequently a methane/hydrogen ratio no less than 3 percent.

Bergstralh, J. T.↗

Photoionization of the diffuse interstellar medium and galactic halo by OB associtations

Assuming smoothly varying H I distributions in te Galactic disk, we have calculated the geometry of diffuse II regions due to OB associations in the Galactic plane. Near the solar circle, OB associations with a Lyman continuum (Lyc) photon luminosity Psi(sub Lyc) = 3.3 x 10(exp 7) cm(exp -2) s(exp -1), produce H II regions that are density bounded in the vertical direction (H II chimneys) allowing Lyc to escape the gaseous disk and penetrate into the Galactic halo. We provide analytic formulae for the Lyc escape fraction as functions of S(sub 0) O-star catalog of Garmany and a new Lyc stellar stellar Lyc stellar flux calibration, we find a production rate of Lyc photons by OB associations within 2.5 kpc of Psi(sub Lyc) = 3.3 x 10(exp 7) cm(exp -2) s(exp -1). Integrating the fraction of Lyc photons that escape the disk over our adopted luminosity function of OB associations, we estimate that approximately 7% of the ionizing photons, or Phi(sub Lyc) = 2.3 x 10(exp 6) cm(exp -2) s(exp -1), escape each side of the H I disk layer and penetrate the diffuse ionized medium ('Reynolds layer'). This flux is sufficient to explain the potoionization of this, although we have not constructed a model for the observed H-alpha emission and pulsar dispersion measures that is fully consistent with the absorption rate of Lyc in the H II layer. Since our quiescent model does not account for the effects of dynamic chimneys and superbubbles, which should enhance Lyc escape, we conclude the O stars are the probable source of ionizing radiation for the Reynolds layer. For a random distribution of OB associations throughout the disk, the Lyc flux is nearly uniform for heights Z is greater than approximately 0.8 kpc above the midplane.

Dove, James B.↗

Photon counting image sensor development for astronomical applications

Specially built intensified CCD (ICCD) detector tubes were purchased and the performance of the electron bombardment process was investigated. In addition to studying the signal characteristics of the photoevents, there was interest in demonstrating that back-illuminated chips were not susceptible to radiation damage to their clocking electrodes. How to perform a centroid analysis for a 2-dimensional Gaussian distribution of charge is described. Measurement of the projection (along columns or rows) of the average charge spread profile is discussed. The development and flight of the Interstellar Medium Absorption Profile Spectrograph (IMAPS) is discussed.

Jenkins, Edward B.↗

Quantitative absorption and fluorescence studies of NO between 1060 and 2000 A

Synchrotron radiation in the 1060 to 2000 A region was used to measure the average absorption and fluorescence cross sections of NO and to determine approximate photodissociation quantum yields. Several vibrational levels of the D(2) sigma(+), E(2) sigma(+), and B(2) delta states have high fluorescence quantum yields. The C(2) and B(2) states do not fluoresce when the excitation energies are above the first dissociation limit, in accord with previous experiments. In general, the fluorescence yields decrease with increasing photon energy. The quantitative measurements are compared with spectroscopic observations and are found to be reasonably consistent.

Guest, J. A.↗

Nuclear cascades in Saturn's rings - Cosmic ray albedo neutron decay and origins of trapped protons in the inner magnetosphere

The nearly equatorial trajectory of the Pioneer 11 spacecraft through Saturn's high energy proton radiation belts and under the main A-B-C rings provided a unique opportunity to study the radial dependence of the greater than 30 MeV proton intensities in the belts in terms of models for secondary nucleon production by cosmic ray interactions in the rings, in situ proton injection in the radiation belts by neutron beta decay, magnetospheric diffusion, and absorption by planetary rings and satellites. Maximum trapped proton intensities measured by Pioneer 11 in the radiation belts are compared with calculated intensities and found consistent with trapping times of roughly 40 years and a radial diffusion coefficient of about 10 to the -15th L to the 9th R sub s squared/s. Differential energy spectra proportional to E to the -2 estimated from integral measurements of trapped photons with E greater than 100 MeV are consistent with the beta decay model, but an inferred turndown of the spectra toward lower energies and reported integral proton anisotropies of a specified form both indicate the need for more realistic calculations of the neutron source from the rings and the radiation belt loss processes.

Cooper, J. F.↗

Comparative lifetesting results for microchannel plates in windowless EUV photon detectors

Microchannel plates (MCPs) from seven manufacturers were subjected to a series of tests to determine their suitability for the Extreme Ultraviolet Explorer satellite. Comparative data are presented for sixteen MCP tandem pairs with channel length to diameter ratios (l/d) ranging from 40:1 to 60:1 and for two saturable (curved channel) MCPs with l/d's of 80:1. Results for MCPs with funnelled channel throats are also discussed. Properties of the MCPs which were monitored include: background count rate, output charge pulse height distribution (PHD), modal gain, PHD full width half maximum (FWHM), and extreme ultraviolet (EUV) photon quantum efficiency. Five detectors were chosen for further lifetime testing consisting of a mild bake to 100 C, and charge extraction to 0.01 coulombs, repeated high voltage cycling and reexposure to one atmosphere conditions. The results of these tests and their implications for the flight detectors are discussed. Erratic events in the detector background were recorded, probably due to field emission from high voltage surfaces or the absorption of water vapor into the electrode following exposure to air. The steps taken to control the detector background are discussed.

Malina, R. F.↗

STXM-C-XANES, IR Microspectroscopy, and Raman Microspectroscopy Analysis of Organic Matter in the Chwichiya 002 C3.00-Ungrouped Chondrite

Chwichiya 002 is a C3.00-ungrouped carbonaceous chondrite discovered in Western Sahara in 2018. The presence of hydrated phases in Chwichiya 002 was not confirmed by XRD analysis, and only a faint water and Si-O band attributed to phyllosilicate were observed by infrared transmission spectroscopy, indicating a very low degree of aqueous alteration (Meteoritical Bulletin, 2020). The structural order of polycyclic aromatic hydrocarbons evaluated by Raman spectroscopy indicates that the effect of thermal metamorphism is less severe than in the Semarkona meteorite, an LL3.00 ordinary chondrite (Meteoritical Bulletin, 2020). Chiwichiya 002 is a very primitive carbonaceous chondrite and an important information source for the early stage of the evolution of organic matter in the solar system. In this study, we investigated the molecular structure and distribution of organic matter in Chiwichiya 002 by Carbon X-ray Absorption Near Edge Structure (C-XANES) analysis using a Scanning Transmission X-ray Microscope (STXM). The STXM-C-XANES analysis has a spatial resolution of 20~100 nm and can observe the spatial distribution of organic materials in microstructures. In addition, to investigate the degree of thermal metamorphism of the organic matter, micro-IR, and micro-Raman spectroscopic analyses were performed. In addition, the Murchison CM2 chondrite was also analyzed for comparison. To evaluate contamination during analytical procedures, antigorite, which was heated in air at 500°C for 5 hours to eliminate organic matter was also analyzed in the same manner. The samples were milled into 100 nm-thick, thin sections using a Focused Ion Beam (FIB), and C-XANES spectra were obtained using the STXM at the High Energy Accelerator Research Organization, Photon Factory (PF), BL-19B. The obtained C-XANES spectra were smoothed and then fitted with Gaussian functions using the method of Le Guillou et al. (2018). The C-XANES showed that the ratio of oxygenated functional group (ketone, phenolic) carbons in Chwichiya 002 was lower than in Murchison, whereas the ratio of aliphatic carbons was almost the same. This may reflect the low degree of aqueous alteration of Chwichiya 002. In addition, contamination peaks were detected at 287.3-287.7 eV and 288.3-288.7 eV in the C-XANES spectra of some of the antigorite samples. The source of these peaks is under investigation. Raman spectroscopic analysis showed that the intensity ratio of the D band to the G band of Chwichiya 002 was slightly higher than that of Murchison. IR absorption spectra showed aromatic absorption at 1630 cm -1 , but there was little absorption due to aliphatic C-H around 2900 cm -1 . These results suggest that the organic matter in Chwichiya 002 may be more heated than in Murchison.

Chwichiya 002↗

Photodissociation of CS2 in the vacuum ultraviolet - Determination of bond dissociation energy from the lowest vibrational level of the ground state CS2.

Photolysis in the vacuum ultraviolet results almost exclusively in the production of S(super-3)P atoms, which is in apparent violation of spin conservation. The threshold energy of incident photons required to produce fluorescence was used to calculate the bond dissociation energy (from the lowest vibrational level of the ground state), and the result agrees with the value previously derived from the photoionization of CS2. The fluorescence excitation spectrum shows peaks corresponding to Rydberg series I and II, indicating that the observed photodissociation of CS2 in the vacuum ultraviolet is mainly the result of predissociation from Rydberg states. The absorption coefficient of CS2 was measured in the region of 1200 to 1400 A.

Okabe, H.↗

A differential absorption technique to estimate atmospheric total water vapor amounts

Vertically integrated water-vapor amounts can be remotely determined by measuring the solar radiance reflected by the earth's surface with satellites or aircraft-based instruments. The technique is based on the method by Fowle (1912, 1913) and utilizes the 0.940-micron water-vapor band to retrieve total-water-vapor data that is independent of surface reflectance properties and other atmospheric constituents. A channel combination is proposed to provide more accurate results, the SE-590 spectrometer is used to verify the data, and the effects of atmospheric photon backscattering is examined. The spectrometer and radiosonde data confirm the accuracy of using a narrow and a wide channel centered on the same wavelength to determine water vapor amounts. The technique is suitable for cloudless conditions and can contribute to atmospheric corrections of land-surface parameters.

Frouin, Robert↗

Raman-Augmented Stratospheric-Ozone Lidar

Differential-absorption lidar (DIAL) system measures concentration of ozone in stratosphere augmented with subsystem measuring Raman scattering from nitrogen. One of number of DIAL systems used in long-term monitoring of stratospheric ozone. Raman scattering from nitrogen provides data to correct for effects of aerosols. Channels at wavelengths of 332 and 385 nm added to DIAL receiver to measure Raman backscattering from nitrogen molecules in stratosphere. Data-acquisition electronics sample photon counts at a rate of 250 MHz.

Mcdermid, I. Stuart↗

Optically thick X-ray transfer - The shell game

This paper investigates the radiative transfer of X-rays through a shell that is optically thick to Compton scattering, surrounding a point source of continuum X-rays. The emission and absorption of X-rays due to K-shell transitions of iron are included. The calculations are done in two entirely independent ways: by Monte Carlo simulation and by solving a Fokker-Planck diffusion equation. The emergent spectra agree very well for Thomson depths of at least about 2. The validity is confirmed of the modification to the Fokker-Planck equation of Kompaneets (1957) that is required when the photon energy is large compared with the average thermal energy of the electrons. A procedure is also developed for treating models of compact X-ray sources consisting of incomplete shells.

Langer, S. H.↗

Effects of high-energy neutrino production and interactions on stars in close X-ray binaries

Limits are discussed that may be placed on binary systems in which a compact partner is a strong source of high-energy particles that produce photons, neutrinos, and other secondary particles in the companion star. The highest energy neutrinos are absorbed deep in the companion and the associated energy deposition may be large enough to affect its structure or lead to its ultimate disruption. This neutrino heating is evaluated, starting with a detailed numerical calculation of the hadronic cascade induced in the atmosphere of the companion star. For some theoretical models, the resulting energy deposition from neutrino absorption may be so great as to disrupt the companion star over a time scale of 10,000-100,000 yr. Even if the energy deposition is smaller, it may still be high enough to alter the system substantially.

Gaisser, T. K.↗

Thin-film scintillators for extended ultraviolet /UV/ response silicon detectors

The preparation and radiometric properties of silicon detectors coated with fluorescent thin films are described. The films are deposited from solutions of clear plastics, such as acrylic resins, polyvinyl toluene or polystyrene, and of organic laser dyes in a common solvent. They are optically clear, mechanically and chemically stable, yet easily applied and removed. Multiple doped films of a few microns thickness exhibit broad-band absorption from less than 250 nm to about 450 nm and narrow band emissions with peaks ranging from 380 nm to 600 nm. Internal quantum efficiencies are close to 100 percent and fluorescence decay times are in the nanosecond range. When deposited on optically denser media, a large fraction of the fluorescent emission is trapped in the substrate. Silicon photodiodes coated with multiple doped films exhibit high external quantum efficiencies and virtually flat photon response in the near UV.

Viehmann, W.↗

KrF laser-induced OH fluorescence imaging in a supersonic combustion tunnel

Planar fluorescence images of OH in a continuous-flow, electrical-resistively heated, high enthalpy, hydrogen-air combustion tunnel, induced by a tunable KrF laser, were recorded. These images were compared to previously recorded fluorescence images induced by a doubled-dye laser under similar conditions. Images induced by the doubled-dye laser system demonstrated a severe distortion caused by absorption and fluorescence trapping. By contrast, images of the fluorescence induced by the tunable KrF laser retained the symmetry properties of the flow. Based on signal-to-noise ratio measurements the yield of the fluorescence induced by the doubled-dye laser is larger than the fluorescence yield induced by the KrF laser. The measurements in the present facility of OH fluorescence induced by the KrF laser were limited by the photon-statistical noise. Based 2 on this result, doubled-dye laser systems are recommended for OH imaging in small and OH lean (less than 10 exp 15/cu cm) facilities. KrF lasers should be selected otherwise.

Quagliaroli, T. M.↗

Gamma-ray emission and electron acceleration in solar flares

Recent observations have extended the spectra of the impulsive phase of flares to the GeV range. Such high-energy photons can be produced either by electron bremsstrahlung or by decay of pions produced by accelerated protons. In this paper we investigate the effects of processes which become important at high energies. We examine the effects of synchrotron losses during the transport of electrons as they travel from the acceleration region in the corona to the gamma-ray emission sites deep in the chromosphere and photosphere, and the effects of scattering and absorption of gamma rays on their way from the photosphere to space instruments. These results are compared with the spectra from so-called electron-dominated flares, observed by GRS on the Solar Maximum Mission, which show negligible or no detectable contribution from accelerated protons. The spectra of these flares show a distinct steepening at energies below 100 keV and a rapid falloff at energies above 50 MeV. Following our earlier results based on lower energy gamma-ray flare emission we have modeled these spectra. We show that neither the radiative transfer effects, which are expected to become important at higher energies, nor the transport effects (Coulomb collisions, synchrotron losses, or magnetic field convergence) can explain such sharp spectral deviations from a simple power law. These spectral deviations from a power law are therefore attributed to the acceleration process. In a stochastic acceleration model the low-energy steepening can be attributed to Coulomb collision and the rapid high-energy steepening can result from synchrotron losses during the acceleration process.

Petrosian, Vahe↗